Addition of myrcene and 3-methyl-3-penten-2-one followed by cyclization afforded perfume 'Iso-E-Super' with 2(?)-acetyl-2β,3β,8,8-tetramethyl-1,2,3,4,5,6,7,8-octalin as main component on the basis of its spe...Addition of myrcene and 3-methyl-3-penten-2-one followed by cyclization afforded perfume 'Iso-E-Super' with 2(?)-acetyl-2β,3β,8,8-tetramethyl-1,2,3,4,5,6,7,8-octalin as main component on the basis of its spectroscopic data.展开更多
Three 1:1 adducts have been obtained by heating benzaldoxime dehydrodimer with styrene. The main product possesses the structure of bis-nitrone type. A radical addition mechanism is pro- posed.
文摘Addition of myrcene and 3-methyl-3-penten-2-one followed by cyclization afforded perfume 'Iso-E-Super' with 2(?)-acetyl-2β,3β,8,8-tetramethyl-1,2,3,4,5,6,7,8-octalin as main component on the basis of its spectroscopic data.
文摘Three 1:1 adducts have been obtained by heating benzaldoxime dehydrodimer with styrene. The main product possesses the structure of bis-nitrone type. A radical addition mechanism is pro- posed.
