Underplating of Mesozoic Mantle-derived Magmas in Tongling, Anhui Province: Evidence from Megacrysts and Xenoliths

Lithological observations and mineralogical analyses on pyroxene and hornblende megacrysts and pyroxene and hornblende cumulates in xenoliths in the Mesozoic plutons of the Tongling region, Anhui Province, provide evidence for the magmatic underplating of mantle-derived alkali-olivine basalt at circa 140 Ma. The pyroxene and hornblende megacrysts and cumulates were formed through the AFC process at depths ranging from 27 to 35 km.

GEOCHRONOLOGY AND STRONTIUM,NEODYMIUM ISOTOPE OF MANTLE-DERIVED MAGMATITES FROM THEBU′S GOLD DEPOSIT, NORTHERN XINJIANG,CHINA

Bu’s gold deposit is geographically situated in the northern side of Sawuer Mt., Western Jungar. Magmatites in Bu’s deposit including extrusive and intrusive rocks are widespread and have genetic relationship with the deposit. One volcanic suite and two intrusives are studied here. Extrusive products were formed in the Early Carboniferous with a whole-rock Rb-Sr isochron age of 347 Ma and fossil ages, while intrusions have Rb-Sr isochron ages from 310 to 329 Ma and are intrusive into the Lower Carboniferous and Upper Devonian.The isotope parameters I ranges from 0. 7037 to 0. 7046, from -5. 65^+6.67 and more,goes from +5. 65~ +7. 96, displaying that they have similar material sources and are derived from mantle magmas or their derivatives. The continental crust of Zhaisang diwa region may be initially formed in the Late-Proterozoic or even more earlier and grew probably in terms of non-proportionated model like S. China, N. American and other parts in the world.

Mantle-derived magmas:intraplate,hot-spots and mid-ocean ridges

Primary or parental magmas act as probes to infer eruption and source temperatures for both mid-ocean ridge （MOR） and‘hot-spot＇ magmas （tholeiitic picrites）. The experimental petrogenetic constraints （＇inverse＇ experiments） argue for no significant temperature differences between them. However, there are differences in major, minor and trace elements which characterise geochemical, not thermal, anomalies beneath ‘hot-spots＇. We suggest that diapiric upwelling from interfaces （redox contrasts） between old subducted slab and normal MOR basalt source mantle is the major reason for the observed characteristics of island chain or ‘hot-spot＇ volcanism. Intraplate basalts also include widely distributed volcanic centres containing lherzolite xenoliths, i.e. mantle-derived magmas. Inverse experiments on olivine basalt, alkali oli- vine basalt, olivine basanite, olivine nephelinite, olivine melilitite and olivine leucitite （lamproite） determined liquidus phases as a function of pressure, initially under anhydrous and CO2-absent conditions. Under C- and H-absent conditions, only tholeiites to alkali olivine basalts had O1 ＋ Opx 4-Cpx as high-pressure liquidus phases. Addition of H20 accessed olivine basanites at 2.5-3 GPa, ,- 1,200 ℃, but both CO2 and H20 were necessary to obtain saturation with O1, Opx, Cpx and Ga at 2.5-3.5 GPa for olivine nephelinite and olivine melilitite. The forward and inverse experimental studies are combined to formulate a petrogenetic grid for intraplate, ‘hot-spot＇ and MOR magmatism within the plate tectonics paradigm. The asthenosphere is geochemically zoned by slow upward migration of incipient melt. The solidus and phasestabilities of lherzolite with very small water contents （〈3,000 ppm） determine the thin plate behaviour of the oceanic lithosphere and thus the Earth＇s convection in the form of plate tectonics. There is no evidence from the parental magmas of MOR and ‘hot-spots＇ to support the ＇deep mantle thermal plume＇ hypothesis. The preferred alternative is the presence of old subducted slabs, relatively buoyant and oxidised with respect to MORB source mantle and suspended or upwelling in or below the lower asthenosphere （and thus detached from overlying plate movement）.

Mantle-derived magmatic gas releasing features at the Rehai area, Tengchong county, Yunnan Province, China

This paper deals with the chemical and isotopic compositions of escaped gases from the Rehai geothermal area in Tengchong county of Yunnan Province. Results indicate that there is the mantle-derived magmatic intrusion in shallow crust at this area. Modern mantle-derived mag-matic volatiles are being released currently in a steady stream by way of active faults. The escaped gases are mostly composed of CO2, together with subordinate amounts of H2S, N2, H2, CH4, SO2, CO and He. At the studied area, the north-south directed fault is the deepest, and it may be interlinked with the deep-seated thermal reservoir that would be directly recharged by the mantle-derived magmatic volatile. The He, C isotopic evidence reveals that the modern active magma beneath Rehai area may originate from the historical mantle-derived magma which caused the latest eruptive activity of volcanoes in that region.

Mixing events between the crust- and mantle-derived magmas in Eastern Kunlun: Evidence from zircon SHRIMP Ⅱ chronology

Various shaped mafic microgranular enclaves (MMEs) together with several mafic massifs are developed within the Yuegelu granitoid pluton in the eastern part of the Eastern Kunlun. On the basis of detailed field geological surveying and of the results of the petrological and geo-chemical studies it is suggested that there must be some ge-netic relationship among the granodiorite host, the MMEs and the hornblende (Hb)-gabbro massifs. Magmatic zircon grains are extracted from samples of granodiorite host rock, Hb-gabbro and the MMEs for U-Pb dating. The U-Pb ages are determined by using SHRIMP Ⅱ technique, which yields the ages of 242±6 Ma, 239±6 Ma and 241±5 Ma, respectively. The overall correspondence in the U-Pb dating results of them excludes the possibility that the MMEs in the granitoids are solid refractory relics from the source region or that they are xenoliths from the wall rocks. It can also rule out the possibility of a later emplacement of basic magma after the solidification of the granitoids. This dating result indicates that they are the products of magma mixing in early-mid Triassic epoch. Among them the granitoid host is chemically akin to the acidic end member during the magma mixing process, the Hb-gabbro is akin to the basic ones while the MMEs are the incompletely mixed basic magma clots trapped in the acidic magma. Combined with the results from other researches on this pluton it is reasonable to con-sider that in the mid-Triassic the Eastern Kunlun granitoid belt had undergone a process of magma mixing between the mantle-derived basic magma and the crustal acidic magma which indicates that the injection of mantle materials and energy into the crust and the reactions between them played an important role in the formation of the granitoid rocks.

Magma Mixing Genesis of the Mafic Enclaves and Related Granitoids in the Kan Granite-Gneiss Complex of Central Côte d’Ivoire: Evidence from Geology, Petrology and Geochemistry

The mafic enclaves from Paleoproterozoic domain are considered to be the results of large-scale crust-mantle interaction and magma mixing. In this paper, petrography, mineralogy and geochemistry were jointly used to determine the origin of the mafic enclaves and their relationship with the host granitoids of the Kan granite-gneiss complex. This study also provides new information on crust-mantle interactions. The mafic enclaves of the Kan vary in shape and size and have intermediate chemical compositions. The diagrams used show a number of similarities in the major elements (and often in the trace elements) between the mafic enclaves and the host granitoids. Geochemical show that the Kan rock are metaluminous, enriched in silica, medium to high-K calc-alkaline I-type granite. The similarities reflect a mixing of basic and acid magma. Mafic enclaves have a typical magmatic structure, which is characterized by magma mixing. The genesis of these rocks is associated with the context of subduction. They result from the mixing of a mafic magma originating from the mantle and linked to subduction, and a granitic magma (type I granite) that arises from the partial melting of the crust.

Mineral Chemistry,Trace Elements,Isotopic Analysis and Zircon U-Pb Dating in the Hesar Pluton,Northern UDMA,Iran:Implications for Pre-Collisional Magma Mixing

The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested that the rocks are metaluminous(A/CNK=1.32-1.45),subduction-related I-type calc-alkaline gabbro to diorite with similar mineral assemblages and geochemical signatures.The host rocks yielded an U-Pb crystallization age of 37.3±0.4 Ma for gabbro-diorite.MMEs have relatively low SiO_(2) contents(52.9-56.6 wt%)and high Mg^(#)(49.8-58.7),probably reflecting a mantle-derived origin.Chondrite-and mantle-normalized trace element patterns are characterized by LREE and LILE enrichment,HREE and HFSE depletion with slight negative Eu anomalies(Eu/Eu^(*)=0.86-1.03).The host rocks yield(^(87)Sr/^(86)Sr)_(i) ratios of 0.70492-0.70510,positive ε_(Nd)(t)values of+1.55-+2.06 and T_(DM2)of 707-736 Ma,which is consistent with the associated mafic microgranular enclaves((^(87)Sr/^(86)Sr)_(i)=0.705014,ε_(Nd)(t)=+1.75,T_(DM2)=729 Ma).All data suggest magma-mixing for enclave and host rock formation,showing a complete equilibration between mixed-mafic and felsic magmas,followed by rapid diffusion.The T_(DM1)(Nd)and T_(DM2)(Nd)model ages and U-Pb dating indicate that the host pluton was produced by partial melting of the lower continental crust and subsequent mixing with injected lithospheric mantlederived magmas in a pre-collisional setting of Arabian-Eurasian plates.Clinopyroxene composition indicates a crystallization temperature of~1000℃ and a depth of~9 km.

Petrology,geochemistry,and crystal size distribution of the basaltic andesite-dacite association at Mt.Sumbing,Central Java,Indonesia:Insights to magma reservoir dynamics and petrogenesis

Ten rock samples consisting of one pyroclastic density current(PDC1)deposit,seven lava flows(LF1–7),and two summit lava domes(LD1,2)were studied to understand the petrogenesis and magma dynamics at Mt.Sumbing.The stratigraphy is arranged as LF1,PDC1,LF2,LF3,LF4,LF5,LF6,LF7,LD1,and LD2;furthermore,these rocks were divided into two types.TypeⅠ,observed in the oldest(LF1)sample,has poor MgO and high Ba/Nb,Th/Yb and Sr.The remaining samples(PDC1–LD2)represent typeⅡ,characterized by high MgO and low Ba/Nb,Th/Yb and Sr values.We suggest that type I is derived from AOC(altered oceanic crust)-rich melts that underwent significant crustal assimilation,while typeⅡoriginates from mantle-rich melts with less significant crustal assimilation.The early stage of typeⅡmagma(PDC1–LF3)was considered a closed system,evolving basaltic andesite into andesite(55.0–60.2 wt%SiO_(2))with a progressively increasing phenocryst(0.30–0.48φ_(PC))and decreasing crystal size distribution(CSD)slope(from-3.9 to-2.9).The evidence of fluctuating silica and phenocryst contents(between 55.9–59.7 wt%and 0.25–0.41φ_(PC),respectively),coupled with the kinked and steep(from-5.0 to-3.3)CSD curves imply the interchanging condition between open(i.e.,magma mixing)and closed magmatic systems during the middle stage(LF4–LF6).Finally,it underwent to closed system again during the final stage(LF7–LD2)because the magma reached dacitic composition(at most 68.9 wt%SiO_(2))with abundant phenocryst(0.38–0.45φ_(PC))and gentle CSD slope(from-4.1 to-1.2).

The Applicability and Productiveness of a Systematic Literature Review Methodology in Volcanology Research: Case of the Magma Pathway at the Mount Cameroon Volcano

The presented research illustrates the applicability and productiveness of the systematic literature review methodology, a non-empirical methodology in the geological sciences, particularly volcanology. The systematic literature review methodology is a replicable, rigorous, and transparent methodology for synthesizing existing literature to answer questions on a specific topic. The synthesis allows for knowledge consolidation, such as identifying knowledge gaps. In our illustration of this methodology, we focused on the expanding knowledge about the magma pathway at Mount Cameroon, one of Africa’s active volcanoes. Our synthesis of the relevant international geoscience research literature is based on the framework of knowledge about the magma pathway beneath a typical basaltic volcano. The framework has three primary components: magma supply, storage, and transport to erupting vents. Across these components is a total of twelve secondary components. The result is a previously non-existent and fragmented overall understanding of the magma pathway at Mount Cameroon. The gaps in the understanding (such as in the magma supply rates, timescales of chamber processes, and magma ascent rates) may be addressed in future research. Another key implication of the presented research lies in the proof of concept of the systematic literature review methodology as an applicable qualitative research methodology in the study of volcanoes.

Source Enrichment Control on the Scale of Magmatic-Hydrothermal W-Sn Mineralization:Insights from Triassic and Jurassic Magma Reservoirs in the Continental Crust,Xitian,South China

There are two factors,source composition and magmatic differentiation,potentially controlling W-Sn mineralization.Which one is more important is widely debated and may need to be determined for each individual deposit.The Xitian granite batholith located in South China is a natural laboratory for investigating the above problem.It consists essentially of two separate components,formed in the Triassic at ca.226 Ma and Jurassic at ca.152 Ma,respectively.The Triassic and Jurassic rocks are both composed of porphyritic and fine-grained phases.The latter resulted from highlydifferentiated porphyritic ones but they have similar textural characteristics and mineral assemblages,indicating that they reached a similar degree of crystal fractionation.Although both fine-grained phases are highly differentiated with elevated rare metal contents,economic W–Sn mineralization is rare in the Triassic granitoids and this can be attributed to less fertile source materials than their Jurassic counterparts,with a slightly more enriched isotopic signature and whole-rockεNd(226 Ma)of−10.4 to−9.2(2σ=0.2)compared withεNd(152 Ma)of−9.2 to−8.2(2σ=0.2)for the Jurassic rocks.The initial W-Sn enrichment was derived from the metasedimentary rocks and strongly enhanced by reworking of the continental crust,culminating in the Jurassic.

Mantle-derived CO_(2) in Hot Springs of the Rehai Geothermal Field,Tengchong,China

Gas concentrations and isotopic compositions of He and CO2 were determined on free gas samples from ten hot springs of the Rehai geothermal field, Tengchong, China. The results showed that hot-spring CO2 gas, together with He, was derived mainly from the mantle, indicating the accumulation of mantle-derived volatiles beneath the survey area. The δ 13C values of CO2, higher than those of the typical mantle-derived carbon and the isotopic composition of hot-spring-free CO2 in unequilibrium with dissolved CO2, are recognized only in the Rehai geothermal field, suggesting that there seems to be a still-degassing magmatic intrusion at depths, which provides mantle-derived volatiles to the hydrothermal system above. The accumulation of those volatiles has probably played an important role in triggering earthquakes in this region. In addition, the isotopic characteristics of He and C also indicate that the magmatic intrusion seems to have been derived from the MORB source, and could be contaminated by crustal materials during its upwelling through the continental crust.

Enrichment of Mantle-derived Fluids in the Formation Process of Granitoids: Evidence from the Himalayan Granitoids around Kunjirap in the Western Qinghai-Tibet Plateau

Taking the Himalayan granitoids around Kunjirap in the western Qinghai-Tibetplateau as an example, the authors present in this paper the characteristics of the granitoids richin mantle-derived fluid components and discuss their rock-forming mechanism. The research resultsindicate that the rock assemblage of the studied granitoids involves diopside syenite-diopsidegranite-biotite (monzonitic) granite, consisting mainly of K-feldspar, oligoclase, quartz,iron-phlogolite, diopside and edenite. The rocks are rich in mantle-derived fluid components ofvolatiles including F, alkali metal elements such as K, Na, Rb, Sr and Ha, and radiogenicheat-producing elements such as U and Th. They were generated by the influx of mantle-derived fluidsinto the lower crest to give rise to partial melting during the lithosphere thinning in theQinghai-Tibet plateau.

Gold Content of Mantle-Derived Rocks from Eastern China and Its Implications

We have analyzed the gold content of 65 samples of mantle-derived xenoliths and their host rocks from eastern China, which is found to be inhomogeneous, falling in the ranges of 1.0×109-8.2×109 (averaging 3.8 ×10-9) and 0.2×10-9-5.3×10-9 (averaging 2.7×10-9) in the mantle-derived xenoliths and the host basalts respectively. Except the samples from Wanquan County of Hebei Province and Anding County of Hainan Province, the gold content is the highest on the margins of the North China platform and decreases spatially towards the north and south, and temporally the samples of the Tertiary have a higher gold content than those of the Quaternary. The gold content of the mantle-derived xenoliths and the host Paleozoic kimberlites is 3.8×10-9-180×109and 0.1×10-9-38.0×10-9 respectively, which are higher than that in the mantle-derived xenoliths in basalt and the host Cenozoic basalts. The mantle-derived xenoliths have a higher gold content than the host rocks, but their relativity is not very clear, suggesting that the genetic relationship between them is complex. Our data indicate that the average gold content of the lithospheric mantle in eastern China is approximately equal to or approaching 3.8×10-9, which is lower than the average abundance of the upper mantle (5.0×10-9), higher than the average abundance of the continental crust (3.0×10-9) and only slightly higher than the average abundance of the lower continental crust (3.4×10-9). Except the samples from Hainan Province, the mantle-derived xenoliths in basalts with a high gold content are distributed on the two margins of the North China platform, corresponding to the gold deposits-concentrated districts in northwest Hebei Province and Shandong Province, showing the control by the old continental lithospheric mantle and the lower continental crust on the margins of the North China platform. The gold content of the mantle-derived xenoliths from Hainan Province ranges from 7.1×10-9 to 15×10-9, suggesting that some blocks of the lithospheric mantle in Hainan Province may be derived from the ancient gold-rich lithospheric mantle of western Australia and that Hainan Province may possibly be an important gold deposits-concentrated district. Some mantle-derived xenoliths in kimberlite of Shandong Province have an excessively high gold content amounting to 180×10-9, which provides new evidence for the possibility of 'finding gold deposits near kimberlite pipes or alkali-basalt volcanic vents'. Thererfore, the gold content of the mantle-derived xenoliths may be an indicator to the distribution of gold deposits-concentrated districts.

A Study on the Ore-forming Effect of Mantle-derived Fluid

Based on summarizing of the effect of mantle-derived fluid on the formation of ores, especially on gold ore, and with the latest investigations, such as the formation of ore from the action of shallow-deep fluid, the transportation effect of the thermal energy by mantle-derived fluid, this paper mainly aims at the effect of mantle-derived fluid on the generation of hydrocarbons. With the proof from geochemistry and fluid inclusion, it was suggested that the mantle-derived fluid not only supplied source materials for hydrocarbons, but also supplied essential energy and matter necessary for the generation of hydrocarbons. The mantle-derived fluid had a good effect, but at the same time it had an adverse effect under specific conditions, on the formation of reservoirs. This paper also discusses the future direction and significance of studying mantle-derived fluid.

The Principles for Discrimination of the Source Composition of Mantle-Derived Igneous Rocks and the Nature of the Mantle Source Region of the Emeishan Basalts

This paper discusses the discrimination principles. deduction and methods for probing into the source composition of mantle-derived magma. The magmatophile (incompatible) source elements are not all optimal tracers for mantle source composition. The ratios of two strong magmatophile elements (D<1) or the ratios of two trace elements with the same D value are not controlled by the formation mode and evolution degree of a magma, but maintain the characteristics of their composition in mantle source region prior to the magma formation. The ratios are related to different mantle-crust structures and dynamics. The mantle source composition of the Emeishan Basalt series is similar to that of the South Atlantic Rio Grande Rise-Walvis Ridge Basalts and Brazil continental-margin basalts. This may indicate that these basalt series might have similar source regions and tectonic environments.

The Discovery and Study of Mantle-Derived Dunite Inclusions in Hornblende-Diorite in the Handan-Xingtai Area,Hebei

Phlogopiie-and diopside-bearing dunite occurs as rounded inclusions in hornblende-diorite. Thepetrofabrics, mineral composition and abundances of the trace elements in the dunite indicate that the inclu-sions were derived from the upper mantle and are the residues of high-degree partial melting of mantlepeirdotite. The study of trace elements in the inclusions and their host rocks shows that the magma was origi-nated from the mantle which was enriched in incompatible elements by mantle metasomatism prior to the par-tial melting.

GEOCHEMISTRY AND TECTONIC ENVIRONMENT AND RESERVOIR FORMATION OF MANTLE-DERIVED NATURAL GAS IN THE SONGLIAO BASIN, NORTHEASTERN CHINA

During several decades of exploration, a number of mantle-derived natural gas pools have been discovered in the vicinities of deep faults in the Songliao Basin, northeastern China. The natural gas in these pools has a δ13C1 value of ?16.50/00 to ?24.20/00, a reversed arrangement in the amount of carbon isotopes in methane and its endogamous products (namely, δ13C1 >δ13C2 >δ13C3 >δ13C4), a 3He/4He value of 1.97 to 2.34×10-6,and an Ar/36Ar value of 1063 to 1949. This indicates a mantle 40 source for the natural gas. The trace elements Cd, In, Te and Re, never found in organic-sourced hydrocarbons, are highly enriched in certain crude oils from the Basin; respectively, concentrations of these elements were found to be 751, 28, 16 and 323 times the average crustal values in China, and this also supports a mantle-derived natural gas origin. The characteristics of mantled-derived magmatic rocks, hydrothermal fluids and gaseous fractions distributed in and near the deep Songliao Basin faults indicate that rifting tectonics is providing the mechanisms for this outgassing of the mantle. Deep extensional (normal) faults provide pathways for upward movement of these materials, and in the Songliao Basin, these deep rift fault zones are associated with reservoir occurrence and cap rock seals, forming good sites for accumulation of mantle-derived natural gas. Furthermore, a layer of low velocity, low density and high conductivity in the deep crust has been identified as a potential reservoir for mantle-derived natural gas.

The Characteristics of Spinels in Mantle-derivedXenoliths in Cenozoic Basalts from Eastern Chinaand Their Thermal States

: The colours and chemical composition variations of 160 spinels in peridotite and pyroxenite xenoliths from Cenozoic basalts in eastern China and their petrogeneses have been studied in detail. The relationships between major elements of spinels are discussed. The equilibrium temperatures, pressures and oxygen fugacities of spinels and their coexisting olivines, orthopyroxenes and clinopyroxenes have been determined using the Brey—kohler's T—P calculation methods (1990) and Ballhaus' fo2 calculation method (1991). The relationships between the composition and the equilibrium temperatures, pressures or oxygen fugacities of spinels in peridotite xenoliths from the basalts and the stable field of the spinels in the upper mantle have been shown.

基于MAGMA的铝合金发动机缸体低压铸造工艺优化

以铝合金发动机缸体的低压铸造过程为研究对象,应用MAGMA铸造模拟软件对充型及凝固过程进行模拟,将固相分数、充型温度、虚拟实验设计以及非热平衡状态的模拟结果和实际生产情况相结合,制定工艺参数,预测缺陷产生的位置,确定最佳工艺参数组合,优化生产工艺,保证质量稳定。

Magmatic Evolution of the Western Branch of the East African Rift System Melts: Evidence by Silicate Melt Inclusions, Rock Petrography and Geochemistry of the Nyiragongo 1977 and 2002 Lavas in DRC

Nyiragongo volcanic eruptions of 1977 and 2002 emitted silica-undersaturated lavas named melilite-nephelinites with microlithic to sub-porphyritic textures, and consisted of olivine, clinopyroxene (augite), phlogopite, melilite, magnetite, and rare plagioclases. This melilite-nephelinite as an evolved rock, shows low SiO2 (38.40 - 39.52 wt%) and MgO (3.10 - 4.01 wt%), and relatively high FeOt (13.76 - 14.10 wt%), Al2O3 (15.01 - 16.48 wt%), CaO (11.00 - 12.29 wt%) and Na2O + K2O (10.34 - 11.85 wt%). Unlike LA-ICP-MS on silicate melt inclusions (SMIs) hosted in augite show a pristine melt of picrobasaltic (low Ti-picrite) rock poor in SiO2 (31.14 - 32.26 wt%), FeOt (2.19 - 2.79 wt%), Al2O3 (8.01 - 9.57 wt%), and Na2O + K2O (2.34 - 3.05 wt%), while enriched in MgO (20.27 - 28.63 wt%), and CaO (24.95 - 33.17 wt%). The sums (∑REEs) for lavas and SMIs are ranging 712 - 799 and 43 - 119 ppm respectively. REE contracted multi-element patterns showed a W-feature for most lavas except for SMIs. High Rb/Sr, and low Ba/Rb, Zr/Nb, and Sm/Hf ratios of lavas suggest a phlogopite-rich source of materials. .