Offshore carbon dioxide(CO_(2)) storage is an effective method for reducing greenhouse gas emissions. However, when using traditional seismic wave methods to monitor the migration of sequestration CO_(2) plumes, the c...Offshore carbon dioxide(CO_(2)) storage is an effective method for reducing greenhouse gas emissions. However, when using traditional seismic wave methods to monitor the migration of sequestration CO_(2) plumes, the characteristics of wave velocity changes tend to become insignificant beyond a certain limit. In contrast, the controllable source electromagnetic method(CSEM) remains highly sensitive to resistivity changes. By simulating different CO_(2) plume migration conditions, we established the relevant models and calculated the corresponding electric field response characteristic curves, allowing us to analyze the CSEM's ability to monitor CO_(2) plumes. We considered potential scenarios for the migration and diffusion of offshore CO_(2) storage, including various burial depths, vertical extension diffusion, lateral extension diffusion,multiple combinations of lateral intervals, and electric field components. We also obtained differences in resistivity inversion imaging obtained by CSEM to evaluate its feasibility in monitoring and to analyze all the electric field(Ex, Ey, and Ez) response characteristics. CSEM has great potential in monitoring CO_(2) plume migration in offshore saltwater reservoirs due to its high sensitivity and accuracy. Furthermore, changes in electromagnetic field response reflect the transport status of CO_(2) plumes, providing an important basis for monitoring and evaluating CO_(2)transport behavior during storage processes.展开更多
Since the ocean bottom is a sedimentary environment wherein stratification is well developed, the use of an anisotropic model is best for studying its geology. Beginning with Maxwell's equations for an anisotropic mo...Since the ocean bottom is a sedimentary environment wherein stratification is well developed, the use of an anisotropic model is best for studying its geology. Beginning with Maxwell's equations for an anisotropic model, we introduce scalar potentials based on the divergence-free characteristic of the electric and magnetic (EM) fields. We then continue the EM fields down into the deep earth and upward into the seawater and couple them at the ocean bottom to the transmitting source. By studying both the DC apparent resistivity curves and their polar plots, we can resolve the anisotropy of the ocean bottom. Forward modeling of a high-resistivity thin layer in an anisotropic half-space demonstrates that the marine DC resistivity method in shallow water is very sensitive to the resistive reservoir but is not influenced by airwaves. As such, it is very suitable for oil and gas exploration in shallowwater areas but, to date, most modeling algorithms for studying marine DC resistivity are based on isotropic models. In this paper, we investigate one-dimensional anisotropic forward modeling for marine DC resistivity method, prove the algorithm to have high accuracy, and thus provide a theoretical basis for 2D and 3D forward modeling.展开更多
An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is stud...An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.展开更多
Marine controlled source electromagnetic signal could be used in mineral resource exploration,reservoir appraisal and communicative technique in ocean. It's necessary to study the electromagnetic generated by MCSE...Marine controlled source electromagnetic signal could be used in mineral resource exploration,reservoir appraisal and communicative technique in ocean. It's necessary to study the electromagnetic generated by MCSEM. The propagation of the electromagnetic fields from a controlled source in the marine environment was studied with virtual interface method combined with discrete complex image method. Transmitter of finite length current source is approximated by dipole (HED) . A three-layered model is accepted,with sea water as intermediate conductive layer under air and a relatively high resistive seabed as basement,possibly containing a hydrogen layer of higher resistivity. The electromagnetic fields in whole space thus computed show that: (1) the spatial distribution of field component depends on its type; (2) inline Ex component is more sensitive to reservoir layer than that in broadside; (3) The airwave affects marine electromagnetic (MEM) exploration when sea water is relatively shallow; in the case of deep water MEM exploration,the airwave influence could be neglected; and (4) an appropriate frequency should be selected in order to balance the signal strength and electromagnetic induction effect.展开更多
The transient electromagnetic(TEM)method becomes more urgent than ever for marine ex-ploration due to abundant resource reserves and the increasing undersea engineering construction activities,especially in the offsho...The transient electromagnetic(TEM)method becomes more urgent than ever for marine ex-ploration due to abundant resource reserves and the increasing undersea engineering construction activities,especially in the offshore exploration of mineral deposits such as Sanshandao gold mine.However,the re-search and application of TEM method in marine environment are still challenged by many problems.Such contradiction motivates our study on the coincident-loop TEM in seafloor exploration.The TEM response of coincident loops is firstly derived in the integral form,based on the potential functions in Helmholtz equ-ations for a magnetic source locating in the whole-space layered model.The frequency-domain vertical magnetic field is described as the Hankel integral with double first-order Bessel functions of first kind.Se-condly,the time-domain induced voltage is obtained by transforming the frequency-domain response through the cosine transform and then taking the derivative of time.To simultaneously solve the Hankel transform and the cosine transform,a novel algorithm is introduced by adapting the fixed-point quadra-ture and extrapolation via the Shanks transformation.Finally,a typical conductivity model for marine po-lymetallic deposit is designed to investigate the characteristic of TEM response under various conditions.Numerical results demonstrate that existence of conductive seawater causes the TEM response to increase significantly and decay slower.The air-sea reflected electromagnetic waves lead to a significantly large fake negative response(NR)in shallower seawater with depth less than 300 m.Increase in the height of loops will weaken and delay the anomaly response and shorten the observation time-window.The height of configu-ration should be no more than 100 m for shallower targets and 50 m for deeper targets,respectively.The observation time-window should cover 10-1000 ms.Increase in the radius of loops only enhances the TEM response proportionally but hardly improves the relative anomaly.The vertical resolution on the low-resistivity target approximates 20 m for the configuration considered in the study.Decreases in D.C.resistivity and chargeability cause the positive response(PR)to increase significantly and decay more ra-pidly.Meanwhile,the NR is advanced and enlarged significantly and decays slower compared with the PR.The influence of time constant is not monotony and there exists an optimal value for producing the maxi-mum NR.As the frequency parameter increases,the PR is caused to decay more rapidly without magni-tude change and the NR is advanced and decays more rapidly with significant increase in magnitude.The influence of frequency parameter is more pronounced than that of time constant.展开更多
The wave-induced seepage force is investigated on marine structures resting on or buried in the seabed.The bed is modelled as a poroelastic medium containing a nearly saturated water.The governing equations are solved...The wave-induced seepage force is investigated on marine structures resting on or buried in the seabed.The bed is modelled as a poroelastic medium containing a nearly saturated water.The governing equations are solved with Finite Element Method.For a pipeline buried in the seabed,agreement between the present numerical results and that of Cheng H.D.(1986)is quite satisfactory.展开更多
基金Supported by Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (2019BT02H594)Sanya Technology Innovation Special Project (2022KJCX08)。
文摘Offshore carbon dioxide(CO_(2)) storage is an effective method for reducing greenhouse gas emissions. However, when using traditional seismic wave methods to monitor the migration of sequestration CO_(2) plumes, the characteristics of wave velocity changes tend to become insignificant beyond a certain limit. In contrast, the controllable source electromagnetic method(CSEM) remains highly sensitive to resistivity changes. By simulating different CO_(2) plume migration conditions, we established the relevant models and calculated the corresponding electric field response characteristic curves, allowing us to analyze the CSEM's ability to monitor CO_(2) plumes. We considered potential scenarios for the migration and diffusion of offshore CO_(2) storage, including various burial depths, vertical extension diffusion, lateral extension diffusion,multiple combinations of lateral intervals, and electric field components. We also obtained differences in resistivity inversion imaging obtained by CSEM to evaluate its feasibility in monitoring and to analyze all the electric field(Ex, Ey, and Ez) response characteristics. CSEM has great potential in monitoring CO_(2) plume migration in offshore saltwater reservoirs due to its high sensitivity and accuracy. Furthermore, changes in electromagnetic field response reflect the transport status of CO_(2) plumes, providing an important basis for monitoring and evaluating CO_(2)transport behavior during storage processes.
基金financially supported by the National Hi-tech Research and Development Program of China(863 Program)(No.2012AA09A20103)
文摘Since the ocean bottom is a sedimentary environment wherein stratification is well developed, the use of an anisotropic model is best for studying its geology. Beginning with Maxwell's equations for an anisotropic model, we introduce scalar potentials based on the divergence-free characteristic of the electric and magnetic (EM) fields. We then continue the EM fields down into the deep earth and upward into the seawater and couple them at the ocean bottom to the transmitting source. By studying both the DC apparent resistivity curves and their polar plots, we can resolve the anisotropy of the ocean bottom. Forward modeling of a high-resistivity thin layer in an anisotropic half-space demonstrates that the marine DC resistivity method in shallow water is very sensitive to the resistive reservoir but is not influenced by airwaves. As such, it is very suitable for oil and gas exploration in shallowwater areas but, to date, most modeling algorithms for studying marine DC resistivity are based on isotropic models. In this paper, we investigate one-dimensional anisotropic forward modeling for marine DC resistivity method, prove the algorithm to have high accuracy, and thus provide a theoretical basis for 2D and 3D forward modeling.
基金The China Ocean Mineral Resources Research and Development Association Research Program of the State Oceanic Administration of China under contract No.DY125-13-R-07the National Natural Science Foundation of China under contract Nos 41322036 and 41230960+1 种基金the Shandong Provincial Natural Science Foundation of China under contract No.ZR2014DP009the Special Basic Research Funds for Central Public Research Institutes for The First Institute of Oceanography,State Oceanic Administration of China under contract Nos GY0213G06 and GY02-2012G35
文摘An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.
基金Supperted by project of the National Science Foundation of China(No.40874050)
文摘Marine controlled source electromagnetic signal could be used in mineral resource exploration,reservoir appraisal and communicative technique in ocean. It's necessary to study the electromagnetic generated by MCSEM. The propagation of the electromagnetic fields from a controlled source in the marine environment was studied with virtual interface method combined with discrete complex image method. Transmitter of finite length current source is approximated by dipole (HED) . A three-layered model is accepted,with sea water as intermediate conductive layer under air and a relatively high resistive seabed as basement,possibly containing a hydrogen layer of higher resistivity. The electromagnetic fields in whole space thus computed show that: (1) the spatial distribution of field component depends on its type; (2) inline Ex component is more sensitive to reservoir layer than that in broadside; (3) The airwave affects marine electromagnetic (MEM) exploration when sea water is relatively shallow; in the case of deep water MEM exploration,the airwave influence could be neglected; and (4) an appropriate frequency should be selected in order to balance the signal strength and electromagnetic induction effect.
基金This research was supported by the National Key R&D Program of China(No.2018YFC0603806).
文摘The transient electromagnetic(TEM)method becomes more urgent than ever for marine ex-ploration due to abundant resource reserves and the increasing undersea engineering construction activities,especially in the offshore exploration of mineral deposits such as Sanshandao gold mine.However,the re-search and application of TEM method in marine environment are still challenged by many problems.Such contradiction motivates our study on the coincident-loop TEM in seafloor exploration.The TEM response of coincident loops is firstly derived in the integral form,based on the potential functions in Helmholtz equ-ations for a magnetic source locating in the whole-space layered model.The frequency-domain vertical magnetic field is described as the Hankel integral with double first-order Bessel functions of first kind.Se-condly,the time-domain induced voltage is obtained by transforming the frequency-domain response through the cosine transform and then taking the derivative of time.To simultaneously solve the Hankel transform and the cosine transform,a novel algorithm is introduced by adapting the fixed-point quadra-ture and extrapolation via the Shanks transformation.Finally,a typical conductivity model for marine po-lymetallic deposit is designed to investigate the characteristic of TEM response under various conditions.Numerical results demonstrate that existence of conductive seawater causes the TEM response to increase significantly and decay slower.The air-sea reflected electromagnetic waves lead to a significantly large fake negative response(NR)in shallower seawater with depth less than 300 m.Increase in the height of loops will weaken and delay the anomaly response and shorten the observation time-window.The height of configu-ration should be no more than 100 m for shallower targets and 50 m for deeper targets,respectively.The observation time-window should cover 10-1000 ms.Increase in the radius of loops only enhances the TEM response proportionally but hardly improves the relative anomaly.The vertical resolution on the low-resistivity target approximates 20 m for the configuration considered in the study.Decreases in D.C.resistivity and chargeability cause the positive response(PR)to increase significantly and decay more ra-pidly.Meanwhile,the NR is advanced and enlarged significantly and decays slower compared with the PR.The influence of time constant is not monotony and there exists an optimal value for producing the maxi-mum NR.As the frequency parameter increases,the PR is caused to decay more rapidly without magni-tude change and the NR is advanced and decays more rapidly with significant increase in magnitude.The influence of frequency parameter is more pronounced than that of time constant.
文摘The wave-induced seepage force is investigated on marine structures resting on or buried in the seabed.The bed is modelled as a poroelastic medium containing a nearly saturated water.The governing equations are solved with Finite Element Method.For a pipeline buried in the seabed,agreement between the present numerical results and that of Cheng H.D.(1986)is quite satisfactory.