The corrosion characteristic and mechanism of Mg-5Y-1.5Nd-xZn-0.5Zr(x=0,2,4,6 wt.%)alloys in marine atmospheric environment

The microstructure and precipitated phases of as-cast Mg-5Y-1.5Nd-x Zn-0.5Zr(x=0,2,4,6 wt.%)alloys were investigated by optical microscopy,scanning electron microscopy,energy-dispersive spectrometry and X-ray Diffraction.The exposure corrosion experiment of these magnesium alloys was tested in South China Sea and KEXUE vessel atmospheric environment.The corrosion characteristic and mechanism of magnesium alloys of Mg-5Y-1.5Nd-x Zn-0.5Zr(x=0,2,4,6 wt.%)alloys were analyzed by weight loss rate,corrosion depth,corrosion products and corrosion morphologies.The electrochemical corrosion tests were also measured in the natural seawater.The comprehensive results showed that Mg-5Y-1.5Nd-4Zn-0.5Zr magnesium alloy existed the best corrosion resistance whether in the marine atmospheric environment and natural seawater environment.That depended on the microstructure,type and distribution of precipitated phases in Mg-5Y-1.5Nd-4Zn-0.5Zr magnesium alloy.Sufficient quantity anodic precipitated phases in the microstructure of Mg-5Y-1.5Nd-4Zn-0.5Zr alloy played the key role in the corrosion resistance.

Marine Atmospheric Boundary Layers Associated with Summer Monsoon Onset over the South China Sea in 1998

The variations of the marine atmospheric boundary layer (MABL) associated with the South China Sea Summer Monsoon were examined using the Global Positioning System (GPS) sounding datasets obtained four times daily during May-June 1998 on board Research Vessels Kexue 1 and Shiyan 3. The MABL height is defined as the height at the lowest level where virtual potential temperature increases by 1 K from the surface. The results indicate that the MABL height decreased over the northern South China Sea (SCS) and remained the same over the southern SCS, as sea surface temperature (SST) fell for the northern and rose for the southern SCS after the monsoon onset. Over the northern SCS, a decrease in both the SST and the surface latent-heat flux after the onset resulted in a reduction of the MABL height as well as a decoupling of MABL from clouds. It was found that MABL height reduction corresponded to rainfall occurrence. Over the southern SCS, a probable reason for the constant increase of SST and surface heat flux was the rainfall and internal atmospheric dynamics.

The Effect of the East China Sea Kuroshio Front on the Marine Atmospheric Boundary Layer

Various satellite data,JRA-25(Japan reanalysis of 25 years) reanalyzed data and WRF(Weather Research Forecast) model are used to investigate the in situ effect of the ESKF(East China Sea Kuroshio Front) on the MABL(marine atmospheric boundary layer).The intensity of the ESKF is most robust from January to April in its annual cycle.The local strong surface northerly/northeasterly winds are observed right over the ESKF in January and in April and the wind speeds decrease upward in the MABL.The thermal wind effect that is derived from the baroclinic MABL forced by the strong SST gradient contributes to the strong surface winds to a large degree.The convergence zone existing along the warm flank of the ESKF is stronger in April than in January corresponding to the steeper SST(sea surface temperature) gradient.The collocations of the cloud cover maximum and precipitation maximum are basically consistent with the convergence zone of the wind field.The clouds develop higher(lower) in the warm(cold) flank of the ESKF due to the less(more) stable stratification in the MABL.The lowest clouds are observed in April on the cold flank of the ESKF and over the Yellow Sea due to the existence of the pronounced temperature inversion.The numerical experiments with smoothed SST are consistent with the results from the ovservations.

Study on Clouds and Marine Atmospheric Boundary Layer

A set of remote sensing instruments of Peking University, which includes mainly a dual-channel(22.235GHz and 35.5GHz) microwave radiometer, a 8mm microwave and a 5mm microwave radiometer, has been developed for the Western North-Pacific Cloud-Radiation Experiment (WENPEX). The instruments were used to observe the cloud and marine atmospheric boundary-layer in the southwest sea area of Japan in winter time from 1989 to 1991.In the weather change process, the characteristics of the marine atmospheric boundary-layer and liquid water content in cloud of this area in winter time are studied from observation data. A one-dimensional mixed layer model is presented for the growth and evolution of a cloud-topped marine boundary-layer. The model is used to study in the WENPEX. The simulation results are in agreement with observation data, especially the integral water in cloud.

Expired drugs as vapor-phase corrosion inhibitors of copper in simulated marine atmospheric environment

Urea,paracetamol and glutamine(based on the expired drugs)were selected as vapor-phase corrosion inhibitors(VCIs)to study their corrosion protection effect on red copper in simulated marine atmospheric environment by using weight loss,electrochemical measurement techniques(specially designed electrochemical testing device for simulating marine atmospheric environments)and surface morphology characterization analysis(SEM/EDS,XRD,RAMAN,XPS).Weight loss results show that the three corrosion inhibitors have good corrosion inhibition effect on red copper,and the corrosion inhibition efficiency in the order of glutamine(83.62%)>urea(68.46%)>paracetamol(61.47%).Surface morphology characterization analysis provides evidence of adsorption of corrosion inhibitors molecules on the red copper surface,thus forming a protective film that blocked the red copper surface from the aggressive chloride ion attack.

The concentration and distribution of dimethyl sulfide in the marine atmospheric boundary layer near the equator

A one-dimensional photochemical model with parameterized vertical eddy diffusion is used to simulate the dimethyl sulfide (DMS) in the marine atmospheric boundary layer near the equator. The boundary condition of theDMS flux over sea surface is assigned from gas exchange models that deped on sea surface wind speed and DMS concentration in surface water. Photolysis rates at various altitudes are calculated as a function of Solar zenith angle, andthe radiation calculation includes ozone absorption,surface reflection and molecular scattering.The simulated results of the DMS diurnal cycle are in good agreement with the observations. Sensitivity tests ofthe model indicate that the concentration of the DMS in the marine surface layer appears to be affected by a combination of chemical processes and meteorological conditions. In addition, photochemical processes are rather important.The reaction of the DMS with OH radical, the heterogeneous conversion of SO2 and the deposition of NSS-SO andthe methanesulfonic acid (MSA) are critical factors of controlling the DMS, SO2, NSS-SO and the MSA concentrations and distributions in the atmosphere.The DMS concentration in air is directly proportional to surface windspeed, but it is inversely proportional to boundary layer height in the convective boundary layer. The distributions ofthe DMS concentrations in air are strongly influenced by atmospheric stratification in stable conditions.

Structures and Characteristics of the Windy Atmospheric Boundary Layer in the South China Sea Region during Cold Surges

An observational analysis of the structures and characteristics of a windy atmospheric boundary layer during a cold air outbreak in the South China Sea region is reported in this paper. It is found that the main structures and characteristics are the same as during strong wind episodes with cold air outbreaks on land. The high frequency turbulent fluctuations （period 〈 1 min） are nearly random and isotropic with weak coherency, but the gusty wind disturbances （1 rain〈period 〈 10 min） are anisotropic with rather strong coherency. However, in the windy atmospheric boundary layer at sea, compared with that over land, there are some pronounced differences： （1） the average horizontal speed is almost independent of height, and the vertical velocity is positive in the lower marine atmospheric boundary layer; （2） the vertical flux of horizontal momentum is nearly independent of height in the low layer indicating the existence of a constant flux layer, unlike during strong wind over the land surface; （3） the kinetic energy and friction velocity of turbulent fluctuations are larger than those of gusty disturbances; （4） due to the independence of horizontal speed to height, the horizontal speed itself （not its vertical gradient used over the land surface） can be used as the key parameter to parameterize the turbulent and gusty characteristics with high accuracy.

Galvanic Corrosion Behaviour of Aluminium 3004 and Copper in Tropical Marine Atmosphere

The galvanic corrosion behaviour of aluminium 3004 and copper with different area ratios were studied in the tropical marine atmosphere at Tuticorin harbour over a period of 426 days. The area ratios OfAAI： Acu, studied were l：l, 1：2, l：4, 1：8, 2：1, 4：1 ＆ 8：1. The galvanic corrosion behaviour of metals was studied in terms of relative increase in the corrosion rate of aluminium due to galvanic coupling with copper, relative decrease in the corrosion rate of copper due to galvanic coupling with aluminium, and the susceptibility of aluminium to pitting owing to galvanic coupling with copper, The galvanic potential and galvanic current of the system were monitored. Pits of different dimensions ranging from mild etchings to perforations were experienced on the borders and the surfaces of the interface of aluminium in contact with copper. The weathering parameters and the environmental pollutants which have a major role in influencing the galvanic corrosion of metals were also monitored. The corrosion products resulting from galvanic corrosion were analysed using XRD and the pitting on aluminium resulting from galvanic corrosion has been highlighted in terms of pit depth, size and density of pit, using a high resolution microscope.

Characterization of Rust Layer Formed on Low Alloy Steel Exposed in Marine Atmosphere

The iron rust phases formed on low alloy steels containing different quantities of Cr element have been characterized using EPMA, Raman spectroscopy, TEM, optical microscopy etc. The ion selective properties of synthesized rust films with the same phase constituent as the atmospheric corrosion products were investigated using self-made apparatus. The results showed that corrosion loss of steels exposed in marine atmosphere decreased rapidly as the Cr content of the steel was increased. Cr-containing steels were covered by a uniform compacted rust layer composed of fine particles with an average diameter of several nanometers. Inner rust layer of Cr-containing steel (2 mass fraction) was composed of a-CrxFe1-xOOH, with Cr content of about 5 mass fraction. Such rust layer showed cation selective property, and could depress the penetration of Cl- to contact substrate steel directly.

Galvanic Interactions of Aluminium 3004 and ∝ Brass in Tropical Marine Atmosphere

The galvanic corrosion behaviour of alumiuium 3004 - ∝ brass with different area ratios was studied in the tropical marine atmosphere at Tuticorin harbour over a period of 426 days. The area ratios, viz. AAluminiurn：A∝ brass, studied were 0.125, 0.25, 0.5, 1, 2, 4 and 8. The galvanic corrosion behaviour of the metals was studied in terms of the relative increase in the corrosion rate of aluminium due to galvanic coupling with oc brass, the relative decrease in the corrosion rate of ∝ brass due to galvanic coupling with aluminium, and the susceptibility of aluminium to pitting owing to galvanic coupling with ∝ brass. The galvanic potential and galvanic current of the system were monitored. Pits of different dimensions ranging from mild etchings to perforations were experienced on the borders arid the surfaces of the interface of aluminium in contact with ∝ brass. The corrosion products resulting from galvanic corrosion were analysed using XRD and the pitting on aluminium as a result of galvanic corrosion was highlighted in terms of pit depth, size and density of pit, using a high resolution microscope. The most favourable area ratio of aluminium - ∝ brass in marine atmosphere in terms of gravimetric corrosion rate is 8：1 and the most unfavourable area ratio of aluminium - ∝ brass is 1：4.

Root cause of corrosion failure of tin coating on wire clamp in marine atmosphere

The failure cause of a tinned copper wire clamp in marine atmosphere was studied systematically by X-ray photoelectron spectroscopy,scanning electron microscopy with energy dispersive spectroscopy and electrochemical measurements.The main components of the green rust on the surface of the damaged wire clamp are SnO_(2),CuO,Cu_(2)Cl(OH)_(3) and CuCO(OH)_(2).Much of green rust distributes at the platform edge along the axial direction on the crimp connection,and severe corrosion and corrosion pits occur at the platform edge zone along the axial direction.The enriching Cl-at the marine atmosphere and the existing O_(2) in air collectively enhance the corrosion process of the tin coating and the copper matrix.Finite element model results show that the residual stress and strain of the tin coating are the largest at the platform edge along the axial direction on the crimp connection,and the corresponding electrode potential of the tin coating at this zone drops significantly.The above results indicate that the residual strain increases the driving force of the corrosion electrochemical reactions and accelerates the corrosion rate and the pit corrosion of the tin coating at this zone.

Corrosion mechanism of Zn-Al-Mg-coated steel in simulated polluted marine atmosphere

The corrosion behaviour of zinc–aluminium–magnesium-coated steel in a simulated polluted marine atmospheric environment was investigated.Therefore,an indoor ageing acceleration test was carefully designed by simulating a polluted marine environment.The objective was to in-depth investigate the corrosion mechanism of Zn–Al–Mg-coated steel exposed to a simulated polluted marine environment.The experiments were carried out by scanning electron microscopy for micro-morphological characterization,X-ray diffraction,electrochemical impedance spectroscopy and electrodynamic polarization curves for the aged samples.The analysis of the results obtained after an indoor accelerated ageing test shows that Zn–Al–Mg coatings generate insoluble Zn_(5)Cl_(2)(OH)_(8)·H_(2)O and Zn_(4)SO_(4)(OH)_(6)during the corrosion process,which hinders the diffusion of corrosive substances into the substrate,and the insoluble substances are structurally dense and thus inhibit further corrosion.Therefore,this effectively inhibits the occurrence of further corrosion,and thus,Zn–Al–Mg coating can significantly extend the service life of Zn–Al–Mg-coated steel.

Effects of Sea-Surface Waves and Ocean Spray on Air-Sea Momentum Fluxes

The effects of sea-surface waves and ocean spray on the marine atmospheric boundary layer （MABL） at different wind speeds and wave ages were investigated. An MABL model was developed that introduces a wave-induced component and spray force to the total surface stress. The theoretical model solution was determined assuming the eddy viscosity coefficient varied linearly with height above the sea surface. The wave-induced component was evaluated using a directional wave spectrum and growth rate. Spray force was described using interactions between ocean-spray droplets and wind-velocity shear. Wind profiles and sea-surface drag coefficients were calculated for low to high wind speeds for wind-generated sea at different wave ages to examine surface-wave and ocean-spray effects on MABL momentum distribution. The theoretical solutions were compared with model solutions neglecting wave-induced stress and/or spray stress. Surface waves strongly affected near-surface wind profiles and sea-surface drag coefficients at low to moderate wind speeds. Drag coefficients and near-surface wind speeds were lower for young than for old waves. At high wind speeds, ocean-spray droplets produced by wind-tearing breaking-wave crests affected the MABL strongly in comparison with surface waves, implying that wave age affects the MABL only negligibly. Low drag coefficients at high wind caused by ocean-spray production increased turbulent stress in the sea-spray generation layer, accelerating near-sea-surface wind. Comparing the analytical drag coefficient values with laboratory measurements and field observations indicated that surface waves and ocean spray significantly affect the MABL at different wind speeds and wave ages.

Tower-based observation of air-sea momentum flux:comparisons between onshore and offshore winds

We investigate the air-sea momentum flux in the marine atmospheric boundary layer using a tower-based direct measurement method.First,we compare the collected data with previous observations,and the results are roughly consistent.Next,in the low-to-moderate winds,the exchange coefficients(or drag coefficients)deviate between onshore and offshore winds,which exhibits the influence of surface wave on the momentum flux.Furthermore,we use a surface-wave-involved parameterization scheme to explain the dependence of momentum flux on surface wave.The results consolidate the influence of surface wave on momentum flux on the one hand,and validate the surface-wave-involved parameterization scheme on the other hand.

The effects of wind-driven waves and ocean spray on the drag coefficient and near-surface wind profiles over the ocean

By introducing a wave-induced component and a spray-induced component to the total stress, a mathematical model based on the Ekman theory is proposed to detail the influence of wind-driven waves and ocean spray on the momentum transport in a marine atmosphere boundary layer（MABL）. An analytic solution of the modified Ekman model can be obtained. The effect of the wave-induced stress is evaluated by a wind wave spectrum and a wave growth rate. It is found that the wave-induced stress and spray stress have a small impact compared with the turbulent stress on the drag coefficient and the wind profiles for low-to-medium wind speed. The spray contribution to the surface stress should be much more taken into account than the winddriven waves when the wind speed reaches above 25 m/s through the action of a ＂spray stress＂. As a result, the drag coefficient starts to decrease with increasing wind speed for high wind speed. The effects of the winddriven waves and spray droplets on the near-surface wind profiles are illustrated for different wave ages, which indicates that the production of the spray droplets leads the wind velocity to increase in the MABL. The solutions are also compared with the existed field observational data. Illustrative examples and the comparisons between field observations and the theoretical solutions demonstrate that the spray stress has more significant effect on the marine atmosphere boundary layer in the condition of the high wind speed compared with wave-induced stress.

Stress corrosion cracking behavior of high-strength mooring-chain steel in the SO_(2)-polluted coastal atmosphere

21Cr2NiMo steel is widely used to stabilize offshore oil platforms;however,it suffers from stress-corrosion cracking(SCC).Herein,we studied the SCC behavior of 21Cr2NiMo steel in SO_(2)-polluted coastal atmospheres.Electrochemical tests revealed that the addition of SO_(2) increased the corrosion current.Rust characterization showed that SO_(2) addition densified the corrosion products and promoted pitting.Furthermore,slow strain rate tests demonstrated a high susceptibility to SCC in high SO_(2) contents.Fracture morphologies revealed that the stress-corrosion cracks initiated at corrosion pits and the crack propagation showed transgranular and intergranular cracking modes.In conclusion,SCC is mix-controlled by anodic dissolution and hydrogen embrittlement mechanisms.

Maintenance and Sudden Change of a Strong Elevated Ducting Event Associated with High Pressure and Marine Low-Level Jet

Capture of a strong elevated ducting event,especially its maintenance and sudden change,is of great value to airborne radar to achieve its beyond-the-line-of-sight detection.However,the knowledge is not easily accessible over the open ocean and hence very rare.During the Air–Sea Interaction Survey(ASIS)over the western North Pacific(WNP)in May 2016,a strong elevated ducting event with a long-life period and sudden change in its evolution was observed.Measurements from the ASIS,images from the Himawari-8 satellite,reanalysis data from the ECMWF,and Weather Research and Forecasting(WRF)model,were used to analyze the maintenance and sudden change of this strong ducting event,together with the model performance on simulating it.The results showed that the maintenance of strong elevated ducts,with their tops ranging from 750 to 1050 m and average strength of approximately 38 M units,was caused by a strong dry air mass capping over the wet marine atmospheric boundary layer(MABL),together with the subsidence inversion associated with high pressure.The WRF model performs well in simulating them.However,a sudden increase in duct height with a slight decrease of strength was recorded by the subsequent GPS radiosonde,which was finally contributed to the mechanical turbulent inversion and hydrolapse associated with the marine low-level jet(MLLJ).The height of the maximum horizontal wind speed(Umh)of the MLLJ corresponds well with the bottom of the trapping layer.However,these jet-relevant ducts are generally weak and it is difficult to accurately simulate them by using the mesoscale numerical model,since the wind-shear produced eddies are too small to be properly parameterized.

Microstructure induced galvanic corrosion evolution of SAC305 solder alloys in simulated marine atmosphere

Motivated by the increasing use of Sn-3.0 Ag-0.5 Cu(SAC305)solder in electronics worked in marine atmospheric environment and the uneven distribution of Ag3Sn and Cu6Sn5 intermetallic compounds(IMCs)inβ-Sn matrix,comb-like electrodes have been designed for in-situ EIS measurements to study the microstructure induced galvanic corrosion evolution of SAC305 solder in simulated marine atmosphere with high-temperature and high-humidity.Results indicate that in-situ EIS measurement by comb-like electrodes is an effective method for corrosion evolution behavior study of SAC305 solder.Besides,the galvanic effect between Ag3Sn IMCs andβ-Sn matrix can aggravate the corrosion of both as-received and furnace-cooled SAC305 solder as the exposure time proceeds in spite of the presence of corrosion product layer.Pitting corrosion can be preferentially found on furnace-cooled SAC305 with larger Ag3Sn grain size.Moreover,the generated inner stress during phases transformation process with Sn3O(OH)2Cl2 as an intermediate and the possible hydrogen evolution at local acidified sites are supposed to be responsible for the loose,porous,cracked,and non-adherent corrosion product layer.These findings clearly demonstrate the corrosion acceleration behavior and mechanism of SAC305 solder,and provide potential guidelines on maintenance of microelectronic devices for safe operation and longer in-service duration.

Temperature and NaCl deposition dependent corrosion of SAC305 solder alloy in simulated marine atmosphere

The stable operation of electronic devices in marine atmospheric environment is affected by the corrosion deterioration of solder joints,and the effects by atmosphere temperature and chloride deposition are critical.In this work,NaCl deposition and temperature dependent corrosion of Pb-free SAC305 solder in simulated marine atmosphere has been investigated.The results indicate that higher NaCl deposition prolongs the surface wetting time and leads to the final thicker saturated electrolyte film for further corrosion.Higher temperature accelerates the evaporation and contributes to the final thinner saturated NaCl electrolyte film.Besides,the corrosion control process varies under the initially covered thicker NaCl electrolyte layer and under the final saturated much thinner NaCl electrolyte film as the evaporation proceeds.Moreover,the ready oxygen availability through the final thinner saturated NaCl electrolyte film facilitates the formation of corrosion product layer mainly of electrochemically stable SnO2,but higher temperature leads to the final corrosion product layer with smaller crystal size and large cracks.The findings clearly demonstrate the effects of NaCl deposition and temperature on corrosion evolution of SAC305 solder joints and are critical to the daily maintenance of electronic devices for longer service life in marine atmosphere.

A New Observation Operator for the Assimilation of Satellite-Derived Relative Humidity:Methodology and Experiments with Three Sea Fog Cases over the Yellow Sea

Assimilation of satellite-derived relative humidity(Satellite-RH)is capable of improving sea fog forecasts by saturating the background in the observed foggy areas.Previous studies have achieved saturation by increasing the moisture only(Method-q).However,this method can lead to large wetting and warming biases within the marine atmospheric boundary layer(MABL).A new method using an RH observation operator(Method-RH)is designed to alleviate these biases by simultaneously adjusting the moisture and the temperature.For comparison,saturation is also achieved by decreasing the temperature only(Method-t).The three Satellite-RH assimilation methods are implemented within the Gridpoint Statistical Interpolation-based three-dimensional variational system and examined for three sea fog cases over the Yellow Sea.The three cases on 28 April 2007,9 April 2009,and 29 March 2015 fail to be predicted without the Satellite-RH assimilation as their MABLs have both warming and drying,drying,and warming biases,respectively.Intercomparisons and evaluations show that Method-RH has the best overall performance of the three methods in terms of the forecast of sea fog and MABL structures as only Method-RH can fully or partially address all the bias scenarios in forecasting sea fog.Compared with Method-q,Method-RH produces more well-defined sea fog areas by adding a smaller amount of moisture as well as decreasing the temperature.Compared with Methodt,Method-RH enlarges the sea fog areas by increasing the amount of moisture in addition to the cooling.