A new fully automatic ^40Ar/^39Ar laboratory with a Thermo Scientific ARGUS VI mass spectrometer has been established in China University of Geosciences （Wuhan）. We designed and developed a mini efficient preparatio...A new fully automatic ^40Ar/^39Ar laboratory with a Thermo Scientific ARGUS VI mass spectrometer has been established in China University of Geosciences （Wuhan）. We designed and developed a mini efficient preparation system （80 mL）, a CO2 laser for heating samples, a crusher for extracting fluid inclusions within K-poor minerals and an air reservoir （31 L） and pipette （0.1 mL） system. The ARGUS VI mass spectrometer is operated by the Qtegra Noble Gas software, which can control the peripheral accessories, such as pneumatic valves, CO2 laser and crusher through a PeriCon （peripheral controller）. The experimental procedures of atmospheric argon ana- lyses, ^40Ar/^39Ar dating by laser stepwise heating and by progressive crushing in vacuo, can be fully automatically performed. The weighted mean of atmospheric ^40Ar/^36Ar ratios is 302.22＋0.03 （1σ, MSWD=0.74, n=200）, indicating that air reservoir and pipette system and the whole instrument sys- tem are very stable. This laboratory is a successful pioneer example in China to establish a new no- ble gas laboratory with self-made peripheral accessories expect for the mass spectrometer.展开更多
A single and dual parameter data acquisition, ion beam measurements and control system for accelerator mass spectrometry is described. The system hardware has been constructed with the advantage of the lower cost and ...A single and dual parameter data acquisition, ion beam measurements and control system for accelerator mass spectrometry is described. The system hardware has been constructed with the advantage of the lower cost and higher reliability. It is provided with varieties of functions such as selecting acquisition mode carrying out the multiple display, analyzing data and especially viewing isometric spectrum at different directions. It can also be used for ordinary nuclear spectrum system.展开更多
Nitrogen-15 isotope-modified compounds are widely used in medicine, pharmacology, agriculture and various fields of science and their nomenclature is gradually increasing. Their widespread use depends on the availabil...Nitrogen-15 isotope-modified compounds are widely used in medicine, pharmacology, agriculture and various fields of science and their nomenclature is gradually increasing. Their widespread use depends on the availability of inexpensive and simple isotope analysis methods. The present article is an attempt to determine the nitrogen-15 isotope content directly in organic compounds without their conversion. The general principle of possibility of determination of the isotopes of nitrogen directly in organic compounds is proposed. Based on the study of mass-spectra of Carbamide Carbonyldiamide, isocyanic acid and nitrobenzene the mass peaks are selected, by which it is possible to determine the atomic fraction of the isotopes of nitrogen. The respective formulas are proposed.展开更多
飞行时间质谱仪(ti me-of-flight mass spectrometer,TOF-MS)在分子团簇的激光电离/解离动力学研究中广泛使用。文章报道了在用脉冲355nm的YAG激光进行水/甲醇二元团簇的多光子电离研究中,发现在电离激光相对于脉冲分子束的不同延时下,...飞行时间质谱仪(ti me-of-flight mass spectrometer,TOF-MS)在分子团簇的激光电离/解离动力学研究中广泛使用。文章报道了在用脉冲355nm的YAG激光进行水/甲醇二元团簇的多光子电离研究中,发现在电离激光相对于脉冲分子束的不同延时下,即激光作用于脉冲束的不同位置,飞行时间质谱仪测得的离子的质谱峰值发生漂移。在激光作用于脉冲束的中段时,离子的信号最强,同时离子的峰值漂移达到最大。分析认为:这种峰值漂移不是因为新质量数谱峰的出现,而是离子在穿越质谱仪的离子引出区和加速区极板时发生部分离子吸附,引起极板间电压的起伏造成的。离子在电场起伏下的数值模拟与实验中观测到的离子峰值漂移规律一致。展开更多
fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7...fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7.75-22.00 eV. The threshold of ion-pair dissociation CFCl3-CFC12＋＋Cl- is experimentally determined to be 7.944-0.04 eV. With the references of the high-resolution photoabsorption spectra reported in the literatures, we make tentative assignments of the electron valence-to-Rydberg transitions. Furthermore, the multibody ion-pair fragmentation processes to Cl- are discussed by comparison between the calculated thermochemical thresholds and the experimental efficiency spectrum.展开更多
在小型磁偏转质谱计的调试过程中,需要由质谱计上位机软件向下位机发送间接指令并实现扫描控制和对离子流的采集、处理、存储和分析。基于此,本文采用面向对象的程序设计方法,在VC++6.0环境下对质谱计的上机位机软件进行设计与实现。质...在小型磁偏转质谱计的调试过程中,需要由质谱计上位机软件向下位机发送间接指令并实现扫描控制和对离子流的采集、处理、存储和分析。基于此,本文采用面向对象的程序设计方法,在VC++6.0环境下对质谱计的上机位机软件进行设计与实现。质谱计上位机软件通过CAN(Controller Area Network)总线与质谱计下位机进行通信,实现对下位机的控制和数据处理。利用质谱计上位机软件可以替代大量冗杂的人工处理数据的工作,而且可以数据实时采集存储,可以进行随时再现、分析、从中获得有用的数据,避免数据的丢失。调试结果表明,质谱计上位机软件设计正确,具有很强的工程实用性。展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 41503053, 41630315, 41688103, and 91128203)
文摘A new fully automatic ^40Ar/^39Ar laboratory with a Thermo Scientific ARGUS VI mass spectrometer has been established in China University of Geosciences （Wuhan）. We designed and developed a mini efficient preparation system （80 mL）, a CO2 laser for heating samples, a crusher for extracting fluid inclusions within K-poor minerals and an air reservoir （31 L） and pipette （0.1 mL） system. The ARGUS VI mass spectrometer is operated by the Qtegra Noble Gas software, which can control the peripheral accessories, such as pneumatic valves, CO2 laser and crusher through a PeriCon （peripheral controller）. The experimental procedures of atmospheric argon ana- lyses, ^40Ar/^39Ar dating by laser stepwise heating and by progressive crushing in vacuo, can be fully automatically performed. The weighted mean of atmospheric ^40Ar/^36Ar ratios is 302.22＋0.03 （1σ, MSWD=0.74, n=200）, indicating that air reservoir and pipette system and the whole instrument sys- tem are very stable. This laboratory is a successful pioneer example in China to establish a new no- ble gas laboratory with self-made peripheral accessories expect for the mass spectrometer.
文摘A single and dual parameter data acquisition, ion beam measurements and control system for accelerator mass spectrometry is described. The system hardware has been constructed with the advantage of the lower cost and higher reliability. It is provided with varieties of functions such as selecting acquisition mode carrying out the multiple display, analyzing data and especially viewing isometric spectrum at different directions. It can also be used for ordinary nuclear spectrum system.
文摘Nitrogen-15 isotope-modified compounds are widely used in medicine, pharmacology, agriculture and various fields of science and their nomenclature is gradually increasing. Their widespread use depends on the availability of inexpensive and simple isotope analysis methods. The present article is an attempt to determine the nitrogen-15 isotope content directly in organic compounds without their conversion. The general principle of possibility of determination of the isotopes of nitrogen directly in organic compounds is proposed. Based on the study of mass-spectra of Carbamide Carbonyldiamide, isocyanic acid and nitrobenzene the mass peaks are selected, by which it is possible to determine the atomic fraction of the isotopes of nitrogen. The respective formulas are proposed.
文摘飞行时间质谱仪(ti me-of-flight mass spectrometer,TOF-MS)在分子团簇的激光电离/解离动力学研究中广泛使用。文章报道了在用脉冲355nm的YAG激光进行水/甲醇二元团簇的多光子电离研究中,发现在电离激光相对于脉冲分子束的不同延时下,即激光作用于脉冲束的不同位置,飞行时间质谱仪测得的离子的质谱峰值发生漂移。在激光作用于脉冲束的中段时,离子的信号最强,同时离子的峰值漂移达到最大。分析认为:这种峰值漂移不是因为新质量数谱峰的出现,而是离子在穿越质谱仪的离子引出区和加速区极板时发生部分离子吸附,引起极板间电压的起伏造成的。离子在电场起伏下的数值模拟与实验中观测到的离子峰值漂移规律一致。
文摘fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7.75-22.00 eV. The threshold of ion-pair dissociation CFCl3-CFC12＋＋Cl- is experimentally determined to be 7.944-0.04 eV. With the references of the high-resolution photoabsorption spectra reported in the literatures, we make tentative assignments of the electron valence-to-Rydberg transitions. Furthermore, the multibody ion-pair fragmentation processes to Cl- are discussed by comparison between the calculated thermochemical thresholds and the experimental efficiency spectrum.
文摘在小型磁偏转质谱计的调试过程中,需要由质谱计上位机软件向下位机发送间接指令并实现扫描控制和对离子流的采集、处理、存储和分析。基于此,本文采用面向对象的程序设计方法,在VC++6.0环境下对质谱计的上机位机软件进行设计与实现。质谱计上位机软件通过CAN(Controller Area Network)总线与质谱计下位机进行通信,实现对下位机的控制和数据处理。利用质谱计上位机软件可以替代大量冗杂的人工处理数据的工作,而且可以数据实时采集存储,可以进行随时再现、分析、从中获得有用的数据,避免数据的丢失。调试结果表明,质谱计上位机软件设计正确,具有很强的工程实用性。
