The separation of aromatic/aliphatic hydrocarbon mixtures is a significant process in chemical industry, but challenged in some cases. Compared with conventional separation technologies, pervaporation is quite promisi...The separation of aromatic/aliphatic hydrocarbon mixtures is a significant process in chemical industry, but challenged in some cases. Compared with conventional separation technologies, pervaporation is quite promising in terms of its economical, energy-saving, and eco-friendly advantages. However, this technique has not been used in industry for separating aromatic/aliphatic mixtures yet. One of the main reasons is that the separation performance of existed pervaporation membranes is unsatisfactory. Membrane material is an important factor that affects the separation performance. This review provides an overview on the advances in studying membrane materials for the pervaporation separation of aromatic/aliphatic mixtures over the past decade. Explored pristine polymers and their hybrid materials(as hybrid membranes) are summarized to highlight their nature and separation performance. We anticipate that this review could provide some guidance in the development of new materials for the aromatic/aliphatic pervaporation separation.展开更多
By making the use of the processes which includes separating trash and solid materials from the wastewater-ammonia stripping tower-UASB-biological oxidation pond, we have treated the wastewater which comes from the sw...By making the use of the processes which includes separating trash and solid materials from the wastewater-ammonia stripping tower-UASB-biological oxidation pond, we have treated the wastewater which comes from the swine factory. The treated wastewater can meet the primary standard of The People's Republic of China based on sewage discharge standards and the wastewater treatment project design contract (GBl8596-2001), and the effluent will be used as irrigation-water. We introduce this project including the quality of influent and effluent and the flow scheme, the statement of every part, the investment and the effect, etc. The operation indicated that this process has many merits such as the stability in operation-effect and the convenience in management. So it will provide some help for the similar wastewater treatment.展开更多
A simple method for the magnetic modification of various types of powdered agglomerate forming dia- magnetic materials was developed. Magnetic iron oxide particles were prepared from ferrous sulfate by microwave assis...A simple method for the magnetic modification of various types of powdered agglomerate forming dia- magnetic materials was developed. Magnetic iron oxide particles were prepared from ferrous sulfate by microwave assisted synthesis. A suspension of the magnetic particles in water soluble organic solvent (methanol, ethanol, propanol, isopropyl alcohol, or acetone) was mixed with the material to be modified and then completely dried at elevated temperature. The magnetically modified materials were found to be stable in water suspension at least for 2 months.展开更多
Herein, a facile strategy for the synthesis of sandwich pyrolyzed bacterial cellulose(PBC)/graphene oxide(GO) composite was reported simply by utilizing the large-scale regenerated biomass bacterial cellulose as p...Herein, a facile strategy for the synthesis of sandwich pyrolyzed bacterial cellulose(PBC)/graphene oxide(GO) composite was reported simply by utilizing the large-scale regenerated biomass bacterial cellulose as precursor. The unique and delicate structure where three-dimensional interconnected bacterial cellulose(BC) network embedded in two-dimensional GO skeleton could not only work as an effective barrier to retard polysulfide diffusion during the charge/discharge process to enhance the cyclic stability of the Li–S battery, but also offer a continuous electron transport pathway for the improved rate capability.As a result, by utilizing pure sulfur as cathodes, the Li–S batteries assembled with PBC/GO interlayer can still exhibit a capacity of nearly 600 mAh·g^-1 at 3C and only 0.055% capacity decay per cycle can be observed over 200 cycles. Additionally, the cost-efficient and environmentfriendly raw materials may enable the PBC/GO sandwich interlayer to be an advanced configuration for Li–S batteries.展开更多
Separator between anode and cathode is an essential part of the microbial fuel cell (MFC) and its property could significantly influence the system perfor- mance. In this study we used polyvinyl alcohol (PVA) poly...Separator between anode and cathode is an essential part of the microbial fuel cell (MFC) and its property could significantly influence the system perfor- mance. In this study we used polyvinyl alcohol (PVA) polymer membrane crosslinked with sulfosuccinic acid (SSA) as a new separator for the MFC. The highest power density of 7594-4 mW-m-2 was obtained when MFC using the PVA membrane crosslinked with 15% of SSA due to its desirable proton conductivity (5.16 x 10-2 S.cml). The power density significantly increased to 11064- 30 mW.m-2 with a separator-electrode-assembly config- uration, which was comparable with glass fiber (11704- 46 mW.m-2). The coulombic efficiencies of the MFCs with crosslinked PVA membranes ranged from 36.3% to 45.7% at a fix external resistance of lO00f2. The crosslinked PVA membrane could be a promising alter- native to separator materials for constructing practical MFC system.展开更多
基金Supported by the National Natural Science Foundation of China(21406006,21576003)the Science and Technology Program of Beijing Municipal Education Commission(KM201510005010)+1 种基金the Importation and Development of High-Caliber Talents Project of Beijing Municipal Institutions(CIT&TCD20150309)the China Postdoctoral Science Foundation funded project(2015M580954)
文摘The separation of aromatic/aliphatic hydrocarbon mixtures is a significant process in chemical industry, but challenged in some cases. Compared with conventional separation technologies, pervaporation is quite promising in terms of its economical, energy-saving, and eco-friendly advantages. However, this technique has not been used in industry for separating aromatic/aliphatic mixtures yet. One of the main reasons is that the separation performance of existed pervaporation membranes is unsatisfactory. Membrane material is an important factor that affects the separation performance. This review provides an overview on the advances in studying membrane materials for the pervaporation separation of aromatic/aliphatic mixtures over the past decade. Explored pristine polymers and their hybrid materials(as hybrid membranes) are summarized to highlight their nature and separation performance. We anticipate that this review could provide some guidance in the development of new materials for the aromatic/aliphatic pervaporation separation.
文摘By making the use of the processes which includes separating trash and solid materials from the wastewater-ammonia stripping tower-UASB-biological oxidation pond, we have treated the wastewater which comes from the swine factory. The treated wastewater can meet the primary standard of The People's Republic of China based on sewage discharge standards and the wastewater treatment project design contract (GBl8596-2001), and the effluent will be used as irrigation-water. We introduce this project including the quality of influent and effluent and the flow scheme, the statement of every part, the investment and the effect, etc. The operation indicated that this process has many merits such as the stability in operation-effect and the convenience in management. So it will provide some help for the similar wastewater treatment.
文摘A simple method for the magnetic modification of various types of powdered agglomerate forming dia- magnetic materials was developed. Magnetic iron oxide particles were prepared from ferrous sulfate by microwave assisted synthesis. A suspension of the magnetic particles in water soluble organic solvent (methanol, ethanol, propanol, isopropyl alcohol, or acetone) was mixed with the material to be modified and then completely dried at elevated temperature. The magnetically modified materials were found to be stable in water suspension at least for 2 months.
基金financially supported by the Ministry of Science and Technology of China(No.2012CB933403)the National Natural Science Foundation of China(Nos.51425302 and 51302045)the Beijing Municipal Science and Technology Commission(No.Z121100006812003)
文摘Herein, a facile strategy for the synthesis of sandwich pyrolyzed bacterial cellulose(PBC)/graphene oxide(GO) composite was reported simply by utilizing the large-scale regenerated biomass bacterial cellulose as precursor. The unique and delicate structure where three-dimensional interconnected bacterial cellulose(BC) network embedded in two-dimensional GO skeleton could not only work as an effective barrier to retard polysulfide diffusion during the charge/discharge process to enhance the cyclic stability of the Li–S battery, but also offer a continuous electron transport pathway for the improved rate capability.As a result, by utilizing pure sulfur as cathodes, the Li–S batteries assembled with PBC/GO interlayer can still exhibit a capacity of nearly 600 mAh·g^-1 at 3C and only 0.055% capacity decay per cycle can be observed over 200 cycles. Additionally, the cost-efficient and environmentfriendly raw materials may enable the PBC/GO sandwich interlayer to be an advanced configuration for Li–S batteries.
文摘Separator between anode and cathode is an essential part of the microbial fuel cell (MFC) and its property could significantly influence the system perfor- mance. In this study we used polyvinyl alcohol (PVA) polymer membrane crosslinked with sulfosuccinic acid (SSA) as a new separator for the MFC. The highest power density of 7594-4 mW-m-2 was obtained when MFC using the PVA membrane crosslinked with 15% of SSA due to its desirable proton conductivity (5.16 x 10-2 S.cml). The power density significantly increased to 11064- 30 mW.m-2 with a separator-electrode-assembly config- uration, which was comparable with glass fiber (11704- 46 mW.m-2). The coulombic efficiencies of the MFCs with crosslinked PVA membranes ranged from 36.3% to 45.7% at a fix external resistance of lO00f2. The crosslinked PVA membrane could be a promising alter- native to separator materials for constructing practical MFC system.