Basalt is a major component of the earth and moon crust.Mineral composition and temperature influence frictional instability and thus the potential for seismicity on basaltic faults.We performed velocitystepping shear...Basalt is a major component of the earth and moon crust.Mineral composition and temperature influence frictional instability and thus the potential for seismicity on basaltic faults.We performed velocitystepping shear experiments on basalt gouges at a confining pressure of 100 MPa,temperatures in the range of 100-400℃ and with varied obsidian mass fractions of 0-100%under wet/dry conditions to investigate the frictional strength and stability of basaltic faults.We observe a transition from velocity-neutral to velocity-weakening behaviors with increasing obsidian content.The frictional stability response of the mixed obsidian/basalt gouges is characterized by a transition from velocitystrengthening to velocity-weakening at 200℃ and another transition to velocity-strengthening at temperatures>300℃.Conversely,frictional strengths of the obsidian-bearing gouges are insensitive to temperature and wet/dry conditions.These results suggest that obsidian content dominates the potential seismic response of basaltic faults with the effect of temperature controlling the range of seismogenic depths.Thus,shallow moonquakes tend to occur in the lower lunar crust due to the corresponding anticipated higher glass content and a projected temperature range conducive to velocity-weakening behavior.These observations contribute to a better understanding of the nucleation mechanism of shallow seismicity in basaltic faults.展开更多
Global warming has greatly threatened the human living environment and carbon capture and storage(CCS)technology is recognized as a promising way to reduce carbon emissions.Mineral storage is considered a reliable opt...Global warming has greatly threatened the human living environment and carbon capture and storage(CCS)technology is recognized as a promising way to reduce carbon emissions.Mineral storage is considered a reliable option for long-term carbon storage.Basalt rich in alkaline earth elements facilitates rapid and permanent CO_(2) fixation as carbonates.However,the complex CO_(2)-fluid-basalt interaction poses challenges for assessing carbon storage potential.Under different reaction conditions,the carbonation products and carbonation rates vary.Carbon mineralization reactions also induce petrophysical and mechanical responses,which have potential risks for the long-term injectivity and the carbon storage safety in basalt reservoirs.In this paper,recent advances in carbon mineralization storage in basalt based on laboratory research are comprehensively reviewed.The assessment methods for carbon storage potential are introduced and the carbon trapping mechanisms are investigated with the identification of the controlling factors.Changes in pore structure,permeability and mechanical properties in both static reactions and reactive percolation experiments are also discussed.This study could provide insight into challenges as well as perspectives for future research.展开更多
To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs)...To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs) formed by basalt saw mud under autoclave curing in ordinary structural concrete.In our work,two types of prewetted functional aggregates were taken as replacements for natural aggregates with different volume substitution rates(0%,5%,10%,15%,20%,25%,and 30%) in the preparation of ordinary structural concrete with water-to-binder ratios(W/B) of 0.48 and 0.33.The effects of the functional aggregate properties and content,W/B,and curing age on the fluidity,density,mechanical properties and autogenous shrinkage of ordinary concrete were analyzed.The experimental results showed that the density of concrete declined at a rate of not more than 5%,and the 28 d compressive strength could reach 31.0-68.2 MPa.Low W/B,long curing age and high-quality functional aggregates were conducive to enhancing the mechanical properties of SPFAs concrete.Through the rolling effects,SPFAs can optimize the particle gradation of aggregate systems and improve the fluidity of concrete,and the water stored inside SPFAs provides an internal curing effect,which prolongs the cement hydration process and considerably reduces the autogenous shrinkage of concrete.SPFAs exhibits high strength and high density,as well as being more cost-effective and ecological,and is expected to be widely employed in ordinary structural concrete.展开更多
With the development of the hyperspectral remote sensing technique,extensive chemical weathering profiles have been identified on Mars.These weathering sequences,formed through precipitation-driven leaching processes,...With the development of the hyperspectral remote sensing technique,extensive chemical weathering profiles have been identified on Mars.These weathering sequences,formed through precipitation-driven leaching processes,can reflect the paleoenvironments and paleoclimates during pedogenic processes.The specific composition and stratigraphic profiles mirror the mineralogical and chemical trends observed in weathered basalts on Hainan Island in south China.In this study,we investigated the laboratory reflectance spectra of a 53-m-long drilling core of a thick basaltic weathering profile collected from Hainan Island.We established a quantitative spectral model by combining the genetic algorithm and partial least squares regression(GA-PLSR)to predict the chemical properties(SiO2,Al2O3,Fe2O3)and index of laterization(IOL).The entire sample set was divided into a calibration set of 25 samples and a validation set of 12 samples.Specifically,the GA was used to select the spectral subsets for each composition,which were then input into the PLSR model to derive the chemical concentration.The coefficient of determination(R2)values on the validation set for SiO2,Al2O3,Fe2O3,and the IOL were greater than 0.9.In addition,the effects of various spectral preprocessing techniques on the model accuracy were evaluated.We found that the spectral derivative treatment boosted the prediction accuracy of the GA-PLSR model.The improvement achieved with the second derivative was more pronounced than when using the first derivative.The quantitative model developed in this work has the potential to estimate the contents of similar weathering basalt products,and thus infer the degree of alteration and provide insights into paleoclimatic conditions.Moreover,the informative bands selected by the GA can serve as a guideline for designing spectral channels for the next generation of spectrometers.展开更多
The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus ar...The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.展开更多
Fibre reinforced polymer composites have become a new generation of structural materials due to their unique advantages such as high specific strength,designability,good dimensional stability and ease of large-area mo...Fibre reinforced polymer composites have become a new generation of structural materials due to their unique advantages such as high specific strength,designability,good dimensional stability and ease of large-area monolithic forming.However,the problem of interfacial bonding between the resin matrix and the fibres limits the direct use of reinforcing fibres and has become a central difficulty in the development of basalt fibre-epoxy composites.This paper proposes a solution for enhancing the strength of the fibre-resin interface using maize starch nanocrystals,which are highly yield and eco-friendly.Firstly,in this paper,corn starch nanocrystals(SNC)were prepared by hydrolysis,and were deposited on the surface of basalt fibers by electrostatic adsorption.After that,in order to maximize the modification effect of nano-starch crystals on the interface,the basalt fiber-epoxy resin composite samples were prepared by mixing in a pressureless molding method.The test results shown that the addition of basalt fibers alone led to a reduction in the strength of the sample.Deposition of 0.1 wt%SNC on the surface of basalt fibers can make the strength consistent with pure epoxy resin.When the adsorption amount of SNC reached 0.5 wt%,the tensile strength of the samples was 23.7%higher than that of pure epoxy resin.This is due to the formation of ether bond homopolymers between the SNC at the fibre-epoxy interface and the epoxy resin,which distorts the originally smooth interface,leading to increased stress concentration and the development of cracks.This enhances the binding of basalt fibers.The conclusions of this paper can provide an effective,simple,low-cost and non-polluting method of interfacial enhancement modification.展开更多
The Jiadi and Damaidi gold deposits in southwest Guizhou Province are the largest basalt-hosted Carlintype gold deposits recently discovered in China.This study uses the Tescan Integrated Mineral Analyzer,supported by...The Jiadi and Damaidi gold deposits in southwest Guizhou Province are the largest basalt-hosted Carlintype gold deposits recently discovered in China.This study uses the Tescan Integrated Mineral Analyzer,supported by detailed field investigations,regional geological data,and extensive sample collections,including mineralized ore,altered wall rock,and unaltered basalt samples,for orebearing and geochemical analyses.Comparative analysis between altered and unaltered basalt samples revealed a mineral assemblage of sericite,quartz,and pyrite.This mineral composition forms through the hydrothermal alteration of unaltered basalt,originally containing feldspar,pyroxene,and ilmenite.The wall rock primarily features sericite,quartz,and hematite.During the alteration process,major,trace,and rare earth elements notably migrate.In the Jiadi deposit,K_(2)O,Rb,Au,and REE significantly increase,while Na_(2)O,CaO,MgO,and MnO decrease.SiO_(2),Al_(2)O_(3),and Fe_(2)O_(3)levels remain relatively stable.In the Damaidi deposit,K_(2)O,Rb,and Au enrich,contrasting with the depletion of Na_(2)O,CaO,MgO,and MnO,while SiO_(2),Fe_(2)O_(3),Al_(2)O_(3),TiO_(2),and REE show no significant changes.In the wall rock,TiO_(2),Al_(2)O_(3),K_(2)O,and REE increase,while Na_(2)O,CaO,MgO,and MnO decrease;SiO_(2)and Fe_(2)O_(3)content remains unchanged.The mineralization process likely originated from mid-to low-temperature,reductive magmatic hydrothermal fluids rich in CO_(2),CH_(4),N_(2),H^(+),S^(2-),HS^(-),H_(3)AsO_(3),and[Au(HS_(2)]^(-).These fluids migrated to tectonically weak zones in the Lianhuashan area,where Emeishan basalts are present.They reacted with Fe-bearing minerals in the basalt,such as ferro-hornblende and ilmenite,forming pyrite,arsenic-bearing pyrite,and arsenopyrite,thus enriching Au in these minerals.Additionally,K^(+)and H^(+)in the fluid reacted with plagioclase in the basalt,forming sericite and quartz.As the fluid entered the wall rock from structural weak zones,its oxidation increased,leading to the complete or partial reaction of Fe-bearing minerals in the wall rock,resulting in the formation of hematite or magnetite.This mineralization process is similar to that observed in carbonate-hosted Carlin-type gold deposits in southwest Guizhou,with the primary distinction being the iron source.In carbonate deposits,iron originates from ferridolomite within the wall rock,while in basalt-hosted deposits,it derives from ferripyroxene and ilmenite.展开更多
As one of the micro-blocks dispersed in the South China Sea(SCS), the basement of the Xisha Islands has rarely been drilled because of the thick overlying Cenozoic sediments, which has led to a confused understanding ...As one of the micro-blocks dispersed in the South China Sea(SCS), the basement of the Xisha Islands has rarely been drilled because of the thick overlying Cenozoic sediments, which has led to a confused understanding of the pre-Cenozoic basement of the Xisha Islands. Well CK-1, a kilometer-scale major scientific drill in the Xisha Islands in the northwestern SCS, penetrated thick reefal limestone(0–888.4 m) and the underlying basement rocks(888.4–901.4 m). In this study, we present the zircon U-Pb ages of basement basaltic pyroclastic rocks from Well CK-1 in the Xisha Islands of the northwestern SCS to investigate the basement nature of the Xisha microblock. The basement of Well CK-1 consists of basaltic pyroclastic rocks on the seamount. The zircon grains yielded apparent ages ranging from ca. 2 138.9 Ma to ca. 36 Ma. The old group of zircon grains from Well CK-1 was considered to be inherited zircons. Two Cenozoic zircons gave a weighted mean 206Pb/238U age of(36.3 ± 1.1) Ma,Mean Squared Weighted Deviations(MSWD) = 1.2, which may represent the maximum age of the volcano eruption. The Yanshanian inherited zircons(116.9–105.7 Ma and 146.1–130.2 Ma) from Well CK-1 are consistent with the zircons from Well XK-1, indicating that the basement of Chenhang Island may be similar to that of Well XK-1. We propose that the Xisha micro-block may have developed on a uniform Late Jurassic metamorphic crystalline basement, intruded by Cretaceous granitic magma.展开更多
Glued timber structure is one of the main forms of modern wood architecture,which has gradually developed towards mid-and high-rise buildings.Glue-laminated timber(GLT)is comprised of several laminates of parallel-to-...Glued timber structure is one of the main forms of modern wood architecture,which has gradually developed towards mid-and high-rise buildings.Glue-laminated timber(GLT)is comprised of several laminates of parallel-to-grain dimension lumber that are bonded together with durable,moisture resistant structural adhesives.GLT can be used in horizontal applications as a beam and in vertical applications as a post.So,its compressive performance has a significant impact on structural safety.Fiber reinforced polymers(FRPs)were commonly used to improve the bearing capacity of GLT components,and the structural and process parameters largely determined the reinforcement effect.This study was aimed at investigating the influence of structural and process parameters on the axial compression performance of GLT components.Three wrapping methods(middle-part,end-part and full wrapping)and three lengths(0.6,0.8,and 1.0 m)of wood post specimens were designed in this work and the axial compression performance and ductility of GLT post specimens modified by basalt fiber reinforced polymer(BFRP)were studied.The results showed that the effect of different BFRP wrapping methods on the compressive strength and elastic modulus of laminated wood was not statistically significant(P>0.05).The compressive bearing capacity of unreinforced GLT posts decreased with the increase of aspect ratio.The GLT posts with middle-part and end-part wrapping still followed this pattern,while the compressive bearing capacity of GLT posts with full wrapping showed a pattern of first decreasing and then increasing.For GLT with low aspect ratios(4.0 or 5.3),there was no correlation between the wrapping method and the compressive bearing capacity,while the compressive bearing capacity of GLT with a high aspect ratio(6.7)for middle-part,end-part and full wrapping increased by 3.5%,7.5%and 9.7%,respectively.Compared to the unreinforced group,the ultimate axial compressive strength and modulus of elasticity(MOE)of the 6-E series specimens reinforced at both ends decreased by 2.58%and 6.70%,respectively.The ultimate axial compressive strength of the 8-E specimens reinforced at both ends increased by 8.62%and the MOE decreased by 1.91%.The compressive strength of the 10-E specimens reinforced at both ends increased by 7.51%and the MOE increased by 8.14%.The failure modes of GLT with different aspects were consistent under the same BFRP wrapping,while the failure modes of GLT with the same aspect ratio were different for different BFRP wrapping methods.The ductility performance of GLT with different aspects ratio was improved by the BFRP wrapping.展开更多
Mineral carbonation, which precipitates dissolved carbon dioxide(CO_(2)) as carbonate minerals in basaltic groundwater environments, is a potential technique for negative emissions. The Leizhou Peninsula in southwest ...Mineral carbonation, which precipitates dissolved carbon dioxide(CO_(2)) as carbonate minerals in basaltic groundwater environments, is a potential technique for negative emissions. The Leizhou Peninsula in southwest Guangdong province has extensive basalt, indicating a promising potential for CO_(2) storage through rapid mineralization. However, understanding of the basic geological setting, potential, and mechanisms of CO_(2) mineralization in the basalts of the Leizhou Peninsula is still limited. The mineralization processes associated with CO_(2)storage at two candidate sites in the area are investigated in this paper: Yongshi Farm and Tianyang Basin(of the dried maar lake). Petrography,rock geochemistry, basalt petrophysical properties, and groundwater hydrochemistry analyses are included in the study. Numerical simulation is used to examine the reaction process and its effects. The results show that basalts in the study areas mainly comprise plagioclase, pyroxene, and Fe–Ti oxides, revealing a total volume fraction exceeding 85%. Additionally, small amounts of quartz and fayalite are available, with volume fractions of 5.1% and 1.0%, respectively. The basalts are rich in divalent metal cations, which can form carbonate minerals, with an average of approximately 6.2 moles of metal cations per 1 kg of rock. The groundwater samples have a pH of 7.5–8.2 and are dominated by the Mg–Ca–HCO3 type. The basalts demonstrate a porosity range of 10.9% to 28.8%, with over 70% of interconnected pores. A 20-year geochemical simulation revealed that CO_(2) injection dissolves primary minerals, including anorthite, albite, and diopside, while CO_(2)mineralization dissolves precipitation secondary minerals, such as calcite, siderite, and dolomite. Furthermore, a substantial rise in pH from 7.6to 10.6 is observed in the vicinity of the injected well, accompanied by a slight reduction in porosity from 20% to 19.8%. Additionally, 36.8% of the injected CO_(2) underwent complete mineralization within five years, revealing an increasing percentage of 66.1% if the experimental period is extended to 20 years. The presence of abundant divalent metal cations in basalts and water-bearing permeable rocks in the Leizhou Peninsula supports the potential for mineral carbonation in basalts, as indicated by the geochemical simulation results. Additional research is necessary to identify the factors that influence the CO_(2) mineralization, storage, and sensitivity analysis of basalt in the Leizhou Peninsula.展开更多
The molybdenum(Mo)isotope system is pivotal in reconstructing marine redox changes throughout Earth’s history and has emerged as a promising tracer for igneous and metamorphic processes.Understanding its composition ...The molybdenum(Mo)isotope system is pivotal in reconstructing marine redox changes throughout Earth’s history and has emerged as a promising tracer for igneous and metamorphic processes.Understanding its composition and variation across major geochemical reservoirs is essential for its application in investigating high-temperature processes.However,there is debate regarding theδ^(98/95)Mo value of the Earth’s mantle,with estimates ranging from sub-chondritic to super-chondritic values.Recent analyses of global mid-ocean ridge basalt(MORB)glasses revealed significantδ^(98/95)Mo variations attributed to mantle heterogeneity,proposing a two-component mixing model to explain the observed variation.Complementary studies confirmed the sub-chondriticδ^(98/95)Mo of the depleted upper mantle,suggesting remixing of subduction-modified oceanic crust as a plausible mechanism.These findings underscore the role of Mo isotopes as effective tracers for understanding dynamic processes associated with mantle-crustal recycling.展开更多
Recent seismic evidence shows that basalt accumulation is widespread in the mantle transition zone(MTZ),yet its ubiquity or sporadic nature remains uncertain.To investigate this phenomenon further,we characterized the...Recent seismic evidence shows that basalt accumulation is widespread in the mantle transition zone(MTZ),yet its ubiquity or sporadic nature remains uncertain.To investigate this phenomenon further,we characterized the velocity structure across the 660-km discontinuity that separates the upper mantle from the lower mantle beneath the Sea of Okhotsk by modeling the waveform of the S660P phase,a downgoing S wave converting into a P wave at the 660-km interface.These waves were excited by two regional>410-km-deep events and were recorded by stations in central Asia.Our findings showed no need to introduce velocity anomalies at the base of the MTZ to explain the S660P waveforms because the IASP91 model adequately reproduced the waveforms.This finding indicates that the basalt accumulation has not affected the bottom of the MTZ in the study area.Instead,this discontinuity is primarily controlled by temperature or water content variations,or both.Thus,we argue that the basalt accumulation at the base of the MTZ is sporadic,not ubiquitous,reflecting its heterogeneous distribution.展开更多
The importance of this study is to identify the newly reordered and recognized basaltic intrusion for the first time in Maasser El Chouf in Lebanon. The recorded basaltic intrusion cut the Jurassic-Lower Cretaceous ro...The importance of this study is to identify the newly reordered and recognized basaltic intrusion for the first time in Maasser El Chouf in Lebanon. The recorded basaltic intrusion cut the Jurassic-Lower Cretaceous rock in this area. Necessary field inspection, geology, mineralogy and chemical tests were carried out on 8 basalt samples to determine their mineralogy, petrography and chemical composition. Representative samples have been tested with polarizing microscope, X-ray diffraction (XRD) and X-ray fluorescence (XRF). Petrographic and mineralogical studies show that the basalt is characterized by presence mainly of calcic-plagioclase feldspar, pyroxene-augite and olivine minerals. Secondary minerals of iron oxides also present (ilmenite and magnetite). The most appeared property is the alteration of olivine mineral to iddingsite that indicated highly weathered process. The composition of the basaltic samples reflects ultrabasic-basic type (Basanite-Tholeiitic basalt). The existence of volcanic activity occurred mostly with Pliocene age (< 2 Ma) as indicated by previous studies for similar basalt in Lebanon. Possibly, these boulders have been carried up from some deeper intrusive magmatic body under very active tension zones. Volcanism of Lebanon basalts belong to the alkaline olivine basalt, suite generally associated with tension, rifting and block faulting movements of the continental crust. Most of the volcanisms in Lebanon and in Harrat Ash Shaam Basalt from Syria and Palestine through Jordan to Saudi Arabia are related and connected to the opening of the Red Sea Rift System, making the area with tremendous volcanic tectonic activities.展开更多
The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the...The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the type of melts and temperature have been studied.The mechanisms of refractory corrosion by the used melts and the factors contributing to the inhibition of corrosion development have been investigated by the method of petrographic analysis.On the basis of obtained results,the use of high-alumina,chromic oxide,and AZS/Cr refractories in the sections of glass furnace linings,experiencing the intensive impact of aluminaboronsilicate glasses and basalt melts,has been confirmed and scientifically substantiated.展开更多
The composition of mantle-derived basalts reflects the nature of their mantle source regions,which constrain magma generation and composition.Here we present a new whole rock major and trace elements and phenocryst co...The composition of mantle-derived basalts reflects the nature of their mantle source regions,which constrain magma generation and composition.Here we present a new whole rock major and trace elements and phenocryst composition of the basaltic lava in the central Mariana Trough.These data provide insights into the mantle source characteristics affected by subduction components.The rocks range from basalts to basaltic andesites,which have high subduction-mobile element contents(e.g.,K,U,Th,LREE)related to N-MORB.The calculated temperature and depth of magma generation are about 1300℃and 30 km,respectively.Although the results above suggest that the addition of hydrous fluid and/or a melt derived from a slab decreases the temperature of mantle partial melting and mildly modifies the composition of a mantle source,the mantle source lithology from which primary magma is generated remains to be peridotite.展开更多
Continuous basalt fiber(CBF)is an outstanding inorganic fiber produced from nature,which has a wide range of applications in the field of armor protection of national defense military.However,the mechanical response a...Continuous basalt fiber(CBF)is an outstanding inorganic fiber produced from nature,which has a wide range of applications in the field of armor protection of national defense military.However,the mechanical response and failure mechanism of 3D printed CBF reinforced components are still not well understood.Here,the 3D printing thermoplastic composites with high volume fraction CBF have been successfully prepared by fused deposition modelling(FDM)method.The effects of fiber printing direction and polymer matrix type on the tensile and flexural properties of the 3D printed composites have been explored,and the detailed failure morphology has been characterized using scanning electron microscopy and optical microscopy.It was found that under high fiber volume fraction,3D printed CBF reinforced polyamides(PA)composites have the best ability to maintain material integrity of the composites,followed by acrylonitrile butadiene styrene(ABS)and high impact polystyrene(HIPS).Besides,the results from rule of mixtures can accurately predict the longitudinal Young’s modulus of the 3D printed specimens,but there exists a large discrepancy for the prediction of the tensile strength.The microstructure analysis shows that the failure modes of 3D printed composites mainly include fiber debonding,fiber pull-out,stress whitening and matrix cracking.展开更多
Based on five types of conventional logging curves including GR,RLLD,CNL,DEN and AC,and 39 core samples from 30 representative boreholes,the logging characteristics and lithofacies and sub-facies of the basaltic rocks...Based on five types of conventional logging curves including GR,RLLD,CNL,DEN and AC,and 39 core samples from 30 representative boreholes,the logging characteristics and lithofacies and sub-facies of the basaltic rocks were studied.Three basaltic facies and four sub-facies are recognized from the well logs,includ-ing volcanic conduit facies(post intrusive sub-facies),explosive facies,and effusive lava flow facies(tabular flow,compound flow and hyaloclastite sub-facies).The post intrusive,tabular flow and compound flow sub-facies logging curves are mainly controlled by the distribution of vesiculate zones and vesiculate content,which are characterized by four curves with good correlation.Post intrusive sub-facies are characterized by high RLLD,high DEN,with a micro-dentate logging curve pattern,abrupt contact relationships at the top and base.Tabular flow sub-facies are characterized by high RLLD,high DEN,with a bell-shaped log curve pattern,abrupt contact at the base and gradational contact at the top.Compound flow sub-facies are characterized by medium-low RLLD,with a micro-dentate or finger-like logging curve pattern,abrupt contact at the base and gradational contact at the top.Explosive facies and hyaloclastite sub-facies logging curves are mainly controlled by the distribution of the size and sorting of rock particles,which can be recognized by four kinds of logging curves with poor cor-relation.Explosive facies are characterized by low RLLD,medium-low CNL and low DEN,with a micro-dentate logging curve pattern.Hyaloclastite sub-facies are characterized by low RLLD,high CNL,low DEN and high AC,with a micro-dentate logging curve pattern.The present research is beneficial for the prediction of basaltic reser-voirs not only in the Liaohe depression but also in the other volcanic-sedimentary basins.展开更多
The development of recycled aggregate concrete(RAC)provides a new approach to limiting the waste of natural resources.In the present study,the mechanical properties and deformability of RACs were improved by adding ba...The development of recycled aggregate concrete(RAC)provides a new approach to limiting the waste of natural resources.In the present study,the mechanical properties and deformability of RACs were improved by adding basalt fibers(BFs)and using external restraints,such as a fiber-reinforced polymer(FRP)jacket or a PVC pipe.Samples were tested under axial compression.The results showed that RAC(50%replacement of aggregate)containing 0.2%BFs had the best mechanical properties.Using either BFs or PVC reinforcement had a slight effect on the loadbearing capacity and mode of failure.With different levels of BFs,the compressive strengths of the specimens reinforced with 1-layer and 3-layer basalt fiber reinforced polymer(BFRP)increased by 6.7%–10.5%and 16.5%–23.7%,respectively,and the ultimate strains increased by 48.5%–80.7%and 97.1%–141.1%,respectively.The peak stress of the 3-layer BFRP-PVC increased by 42.2%,and the ultimate strain improved by 131.3%,relative to the control.This reinforcement combined the high tensile strength of BFRP,which improved the post-peak behavior,and PVC,which enhanced the structural durability.In addition,to investigate the influence of the various constraints on compressive behavior,the stress-strain response was analyzed.Based on the analysis of experimental results,a peak stress-strain model and an amended ultimate stress-strain model were proposed.The models were verified as well;the result showed that the predictions from calculations are generally consistent with the experimental data(error within 10%).The results of this study provide a theoretical basis and reference for future applications of fiber-reinforced recycled concrete.展开更多
The frictional strength and sliding stability of faults are crucial in interpreting earthquake mechanisms and cycles.Herein,we report friction experiments on basalt fractures,using a self-designed triaxial apparatus t...The frictional strength and sliding stability of faults are crucial in interpreting earthquake mechanisms and cycles.Herein,we report friction experiments on basalt fractures,using a self-designed triaxial apparatus that allows direct shear of samples under coupled hydro-mechanical conditions.Velocitystepping(VS)and slide-hold-slide(SHS)experiments are performed on both bare and gouge-bearing surfaces of Xiashan basalt subjected to cyclic shear velocities at 1e30 mm/s,effective normal stresses of 1e5 MPa,and pore pressures of 70e300 kPa.The measured basalt friction coefficients are in the range of 0.67e0.74,which is sensitive to gouge thickness,normal stress,and water.Specifically,a reduction in friction coefficient is observed with an increment in gouge thickness,normal stress,and pore pressure.Based on the microscopic observation of the pre-and post-shearing sliding surfaces,this weakening effect in friction coefficient can be attributed to powder lubrication.Furthermore,the VS test results reveal predominantly velocity-strengthening behavior at investigated slip velocities,and this velocity strengthening behavior does not appear to be influenced by variations in normal stress,gouge thickness,and water.However,changes in sliding velocity and normal stress can lead to a shift between stable and unstable sliding.Specifically,stable sliding is favored by high sliding velocities and low normal stress applied in this study.Finally,we analyze the experimental data by calculating the rate-and-state parameters using the rate-and state-dependent friction(RSF)theory.Importantly,the calculated friction rate parameter(a-b)supports the velocity-strengthening behavior.Both frictional relaxation(Dmc)during hold periods and frictional healing(Dm)upon re-shearing are linearly proportional to the logarithmic hold time,which may be attributed to the growth in true contact area with hold time.This study sheds light on the roles of sliding velocity,and gouge thickness in controlling frictional strength and stability of basalt fractures.展开更多
To enhance the sulfate attack resistance performance of concrete,Sulfate erosion test was carried out on basalt fiber concrete with different contents,selecting a concentration of 5%sulfate solution and using a dry−we...To enhance the sulfate attack resistance performance of concrete,Sulfate erosion test was carried out on basalt fiber concrete with different contents,selecting a concentration of 5%sulfate solution and using a dry−wet cycle mechanism attack of basalt fiber-reinforced concrete(BFRC).Every 15 dry−wet cycles,the mass,compressive strength,splitting tensile strength,and relative dynamic elastic modulus of BFRC were tested,and the SO_(4)^(2−)con-centration was measured.This work demonstrates that the mass,relative dynamic elastic modulus,compressive and splitting tensile strength of BFRC reveal a trend of climb up and then decline with the process of the dry−wet cycle.Basalt fiber can enhance the sulfate corrosion resistance of concrete by delaying the erosion of concrete induced by SO_(4)^(2−)and increasing the bearing and anti-deformation capacities of concrete by improving its inter-nal structure.Additionally,when mixing 0.2%basalt fiber into concrete,the strength deterioration rate will be reduced when the peak values of splitting tensile and compressive strength appear at 60 and 75 times the alter-nating dry−wet cycles,respectively.Adverse effects will occur when the fiber volume fraction exceeds 0.2%.The research in this paper can provide a foundation for the engineering applications of basalt fiber concrete.展开更多
基金funded by the National Natural Science Foundation of China(Nos.42320104003 and 42107163)the Funda mental Research Funds for the Central Universities.Derek Elsworth acknowledges support from the G.Albert Shoemaker endowment.
文摘Basalt is a major component of the earth and moon crust.Mineral composition and temperature influence frictional instability and thus the potential for seismicity on basaltic faults.We performed velocitystepping shear experiments on basalt gouges at a confining pressure of 100 MPa,temperatures in the range of 100-400℃ and with varied obsidian mass fractions of 0-100%under wet/dry conditions to investigate the frictional strength and stability of basaltic faults.We observe a transition from velocity-neutral to velocity-weakening behaviors with increasing obsidian content.The frictional stability response of the mixed obsidian/basalt gouges is characterized by a transition from velocitystrengthening to velocity-weakening at 200℃ and another transition to velocity-strengthening at temperatures>300℃.Conversely,frictional strengths of the obsidian-bearing gouges are insensitive to temperature and wet/dry conditions.These results suggest that obsidian content dominates the potential seismic response of basaltic faults with the effect of temperature controlling the range of seismogenic depths.Thus,shallow moonquakes tend to occur in the lower lunar crust due to the corresponding anticipated higher glass content and a projected temperature range conducive to velocity-weakening behavior.These observations contribute to a better understanding of the nucleation mechanism of shallow seismicity in basaltic faults.
基金funding support from the National Key R&D Program of China(Grant No.2022YFE0115800)the Creative Groups of Natural Science Foundation of Hubei Province(Grant No.2021CFA030)Shanxi Provincial Key Research and Development Project(Grant No.202102090301009).
文摘Global warming has greatly threatened the human living environment and carbon capture and storage(CCS)technology is recognized as a promising way to reduce carbon emissions.Mineral storage is considered a reliable option for long-term carbon storage.Basalt rich in alkaline earth elements facilitates rapid and permanent CO_(2) fixation as carbonates.However,the complex CO_(2)-fluid-basalt interaction poses challenges for assessing carbon storage potential.Under different reaction conditions,the carbonation products and carbonation rates vary.Carbon mineralization reactions also induce petrophysical and mechanical responses,which have potential risks for the long-term injectivity and the carbon storage safety in basalt reservoirs.In this paper,recent advances in carbon mineralization storage in basalt based on laboratory research are comprehensively reviewed.The assessment methods for carbon storage potential are introduced and the carbon trapping mechanisms are investigated with the identification of the controlling factors.Changes in pore structure,permeability and mechanical properties in both static reactions and reactive percolation experiments are also discussed.This study could provide insight into challenges as well as perspectives for future research.
基金Funded by the National Natural Science Foundation of China(No.52378213)the Technology Development Project(No.20201902977180010) of CABR Technology Co.,Ltd。
文摘To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs) formed by basalt saw mud under autoclave curing in ordinary structural concrete.In our work,two types of prewetted functional aggregates were taken as replacements for natural aggregates with different volume substitution rates(0%,5%,10%,15%,20%,25%,and 30%) in the preparation of ordinary structural concrete with water-to-binder ratios(W/B) of 0.48 and 0.33.The effects of the functional aggregate properties and content,W/B,and curing age on the fluidity,density,mechanical properties and autogenous shrinkage of ordinary concrete were analyzed.The experimental results showed that the density of concrete declined at a rate of not more than 5%,and the 28 d compressive strength could reach 31.0-68.2 MPa.Low W/B,long curing age and high-quality functional aggregates were conducive to enhancing the mechanical properties of SPFAs concrete.Through the rolling effects,SPFAs can optimize the particle gradation of aggregate systems and improve the fluidity of concrete,and the water stored inside SPFAs provides an internal curing effect,which prolongs the cement hydration process and considerably reduces the autogenous shrinkage of concrete.SPFAs exhibits high strength and high density,as well as being more cost-effective and ecological,and is expected to be widely employed in ordinary structural concrete.
基金National Key Research and Development Project(Grant No.2019YFE0123300)National Natural Science Foundation of China(Grant Nos.42072337,42241111,and 42241129)+1 种基金Pandeng Program of National Space Science Center,Chinese Academy of Sciences.Xing Wu also acknowledges support from the Young Elite Scientists Sponsorship Program by the China Association for Science and Technology(Grant No.2022QNRC001)China Postdoctoral Science Foundation(Grant No.2021M700149).
文摘With the development of the hyperspectral remote sensing technique,extensive chemical weathering profiles have been identified on Mars.These weathering sequences,formed through precipitation-driven leaching processes,can reflect the paleoenvironments and paleoclimates during pedogenic processes.The specific composition and stratigraphic profiles mirror the mineralogical and chemical trends observed in weathered basalts on Hainan Island in south China.In this study,we investigated the laboratory reflectance spectra of a 53-m-long drilling core of a thick basaltic weathering profile collected from Hainan Island.We established a quantitative spectral model by combining the genetic algorithm and partial least squares regression(GA-PLSR)to predict the chemical properties(SiO2,Al2O3,Fe2O3)and index of laterization(IOL).The entire sample set was divided into a calibration set of 25 samples and a validation set of 12 samples.Specifically,the GA was used to select the spectral subsets for each composition,which were then input into the PLSR model to derive the chemical concentration.The coefficient of determination(R2)values on the validation set for SiO2,Al2O3,Fe2O3,and the IOL were greater than 0.9.In addition,the effects of various spectral preprocessing techniques on the model accuracy were evaluated.We found that the spectral derivative treatment boosted the prediction accuracy of the GA-PLSR model.The improvement achieved with the second derivative was more pronounced than when using the first derivative.The quantitative model developed in this work has the potential to estimate the contents of similar weathering basalt products,and thus infer the degree of alteration and provide insights into paleoclimatic conditions.Moreover,the informative bands selected by the GA can serve as a guideline for designing spectral channels for the next generation of spectrometers.
基金supported by the National Natural Science Foundation of China(Nos.41472065 and 42073059).
文摘The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.
基金Supported by National Key Research and Development Project of China (Grant Nos.2018YFA0703300,52105300)National Natural Science Foundation of China (Grant No.52075215)+2 种基金Science and Technology Development Plan Project of Jilin Province of China (Grant No.20200201061JC)Science and Technology Research Project of Jilin Provincial Education Department of China (Grant No.JJKH20221021KJ)Changchun Municipal Key Research and Development Program of China (Grant No.21ZGN22)。
文摘Fibre reinforced polymer composites have become a new generation of structural materials due to their unique advantages such as high specific strength,designability,good dimensional stability and ease of large-area monolithic forming.However,the problem of interfacial bonding between the resin matrix and the fibres limits the direct use of reinforcing fibres and has become a central difficulty in the development of basalt fibre-epoxy composites.This paper proposes a solution for enhancing the strength of the fibre-resin interface using maize starch nanocrystals,which are highly yield and eco-friendly.Firstly,in this paper,corn starch nanocrystals(SNC)were prepared by hydrolysis,and were deposited on the surface of basalt fibers by electrostatic adsorption.After that,in order to maximize the modification effect of nano-starch crystals on the interface,the basalt fiber-epoxy resin composite samples were prepared by mixing in a pressureless molding method.The test results shown that the addition of basalt fibers alone led to a reduction in the strength of the sample.Deposition of 0.1 wt%SNC on the surface of basalt fibers can make the strength consistent with pure epoxy resin.When the adsorption amount of SNC reached 0.5 wt%,the tensile strength of the samples was 23.7%higher than that of pure epoxy resin.This is due to the formation of ether bond homopolymers between the SNC at the fibre-epoxy interface and the epoxy resin,which distorts the originally smooth interface,leading to increased stress concentration and the development of cracks.This enhances the binding of basalt fibers.The conclusions of this paper can provide an effective,simple,low-cost and non-polluting method of interfacial enhancement modification.
基金funded by the Talent Team Program of Science and Technology Foundation of Guizhou Province(CXTD[2021]007)the Key Project of Natural Science Basic Research Program of Shannxi Province(2023-JC-ZD-16)+4 种基金the National Natural Science Fund of China(U1812402)the National Natural Science Fund of China(41962008)the National Key Research and Development Program of China“Exploration and Exploitation of Deep Earth Resources”(2017YFC0601500)the Guizhou Province Graduate Research Fund(YJSCXJH[2020]095)the public welfare and fundamental project Fund of Guizhou Province(520000214 TLCOG7DGTNRG)。
文摘The Jiadi and Damaidi gold deposits in southwest Guizhou Province are the largest basalt-hosted Carlintype gold deposits recently discovered in China.This study uses the Tescan Integrated Mineral Analyzer,supported by detailed field investigations,regional geological data,and extensive sample collections,including mineralized ore,altered wall rock,and unaltered basalt samples,for orebearing and geochemical analyses.Comparative analysis between altered and unaltered basalt samples revealed a mineral assemblage of sericite,quartz,and pyrite.This mineral composition forms through the hydrothermal alteration of unaltered basalt,originally containing feldspar,pyroxene,and ilmenite.The wall rock primarily features sericite,quartz,and hematite.During the alteration process,major,trace,and rare earth elements notably migrate.In the Jiadi deposit,K_(2)O,Rb,Au,and REE significantly increase,while Na_(2)O,CaO,MgO,and MnO decrease.SiO_(2),Al_(2)O_(3),and Fe_(2)O_(3)levels remain relatively stable.In the Damaidi deposit,K_(2)O,Rb,and Au enrich,contrasting with the depletion of Na_(2)O,CaO,MgO,and MnO,while SiO_(2),Fe_(2)O_(3),Al_(2)O_(3),TiO_(2),and REE show no significant changes.In the wall rock,TiO_(2),Al_(2)O_(3),K_(2)O,and REE increase,while Na_(2)O,CaO,MgO,and MnO decrease;SiO_(2)and Fe_(2)O_(3)content remains unchanged.The mineralization process likely originated from mid-to low-temperature,reductive magmatic hydrothermal fluids rich in CO_(2),CH_(4),N_(2),H^(+),S^(2-),HS^(-),H_(3)AsO_(3),and[Au(HS_(2)]^(-).These fluids migrated to tectonically weak zones in the Lianhuashan area,where Emeishan basalts are present.They reacted with Fe-bearing minerals in the basalt,such as ferro-hornblende and ilmenite,forming pyrite,arsenic-bearing pyrite,and arsenopyrite,thus enriching Au in these minerals.Additionally,K^(+)and H^(+)in the fluid reacted with plagioclase in the basalt,forming sericite and quartz.As the fluid entered the wall rock from structural weak zones,its oxidation increased,leading to the complete or partial reaction of Fe-bearing minerals in the wall rock,resulting in the formation of hematite or magnetite.This mineralization process is similar to that observed in carbonate-hosted Carlin-type gold deposits in southwest Guizhou,with the primary distinction being the iron source.In carbonate deposits,iron originates from ferridolomite within the wall rock,while in basalt-hosted deposits,it derives from ferripyroxene and ilmenite.
基金The National Natural Science Foundation of China under contract Nos 42030502, 42090041 and 42166003the Guangxi Scientific Projects under contract Nos AD17129063 and AA17204074+1 种基金the Guangxi Youth Science Fund Project under contract 2019GXNSFBA185016the Ph.D. Research Start-up Foundation of Guangxi University under contract No. XBZ170339。
文摘As one of the micro-blocks dispersed in the South China Sea(SCS), the basement of the Xisha Islands has rarely been drilled because of the thick overlying Cenozoic sediments, which has led to a confused understanding of the pre-Cenozoic basement of the Xisha Islands. Well CK-1, a kilometer-scale major scientific drill in the Xisha Islands in the northwestern SCS, penetrated thick reefal limestone(0–888.4 m) and the underlying basement rocks(888.4–901.4 m). In this study, we present the zircon U-Pb ages of basement basaltic pyroclastic rocks from Well CK-1 in the Xisha Islands of the northwestern SCS to investigate the basement nature of the Xisha microblock. The basement of Well CK-1 consists of basaltic pyroclastic rocks on the seamount. The zircon grains yielded apparent ages ranging from ca. 2 138.9 Ma to ca. 36 Ma. The old group of zircon grains from Well CK-1 was considered to be inherited zircons. Two Cenozoic zircons gave a weighted mean 206Pb/238U age of(36.3 ± 1.1) Ma,Mean Squared Weighted Deviations(MSWD) = 1.2, which may represent the maximum age of the volcano eruption. The Yanshanian inherited zircons(116.9–105.7 Ma and 146.1–130.2 Ma) from Well CK-1 are consistent with the zircons from Well XK-1, indicating that the basement of Chenhang Island may be similar to that of Well XK-1. We propose that the Xisha micro-block may have developed on a uniform Late Jurassic metamorphic crystalline basement, intruded by Cretaceous granitic magma.
文摘Glued timber structure is one of the main forms of modern wood architecture,which has gradually developed towards mid-and high-rise buildings.Glue-laminated timber(GLT)is comprised of several laminates of parallel-to-grain dimension lumber that are bonded together with durable,moisture resistant structural adhesives.GLT can be used in horizontal applications as a beam and in vertical applications as a post.So,its compressive performance has a significant impact on structural safety.Fiber reinforced polymers(FRPs)were commonly used to improve the bearing capacity of GLT components,and the structural and process parameters largely determined the reinforcement effect.This study was aimed at investigating the influence of structural and process parameters on the axial compression performance of GLT components.Three wrapping methods(middle-part,end-part and full wrapping)and three lengths(0.6,0.8,and 1.0 m)of wood post specimens were designed in this work and the axial compression performance and ductility of GLT post specimens modified by basalt fiber reinforced polymer(BFRP)were studied.The results showed that the effect of different BFRP wrapping methods on the compressive strength and elastic modulus of laminated wood was not statistically significant(P>0.05).The compressive bearing capacity of unreinforced GLT posts decreased with the increase of aspect ratio.The GLT posts with middle-part and end-part wrapping still followed this pattern,while the compressive bearing capacity of GLT posts with full wrapping showed a pattern of first decreasing and then increasing.For GLT with low aspect ratios(4.0 or 5.3),there was no correlation between the wrapping method and the compressive bearing capacity,while the compressive bearing capacity of GLT with a high aspect ratio(6.7)for middle-part,end-part and full wrapping increased by 3.5%,7.5%and 9.7%,respectively.Compared to the unreinforced group,the ultimate axial compressive strength and modulus of elasticity(MOE)of the 6-E series specimens reinforced at both ends decreased by 2.58%and 6.70%,respectively.The ultimate axial compressive strength of the 8-E specimens reinforced at both ends increased by 8.62%and the MOE decreased by 1.91%.The compressive strength of the 10-E specimens reinforced at both ends increased by 7.51%and the MOE increased by 8.14%.The failure modes of GLT with different aspects were consistent under the same BFRP wrapping,while the failure modes of GLT with the same aspect ratio were different for different BFRP wrapping methods.The ductility performance of GLT with different aspects ratio was improved by the BFRP wrapping.
基金funded by the National Natural Science Foundation of China (U1901217)Guangdong Basic and Applied Basic Research Foundation (2021A1515011298)+1 种基金the National Key R&D Program of China (2021YFF0501202)Special Fund of South China Sea Institute of Oceanology of the Chinese Academy of Sciences (SCSIO2023QY06)。
文摘Mineral carbonation, which precipitates dissolved carbon dioxide(CO_(2)) as carbonate minerals in basaltic groundwater environments, is a potential technique for negative emissions. The Leizhou Peninsula in southwest Guangdong province has extensive basalt, indicating a promising potential for CO_(2) storage through rapid mineralization. However, understanding of the basic geological setting, potential, and mechanisms of CO_(2) mineralization in the basalts of the Leizhou Peninsula is still limited. The mineralization processes associated with CO_(2)storage at two candidate sites in the area are investigated in this paper: Yongshi Farm and Tianyang Basin(of the dried maar lake). Petrography,rock geochemistry, basalt petrophysical properties, and groundwater hydrochemistry analyses are included in the study. Numerical simulation is used to examine the reaction process and its effects. The results show that basalts in the study areas mainly comprise plagioclase, pyroxene, and Fe–Ti oxides, revealing a total volume fraction exceeding 85%. Additionally, small amounts of quartz and fayalite are available, with volume fractions of 5.1% and 1.0%, respectively. The basalts are rich in divalent metal cations, which can form carbonate minerals, with an average of approximately 6.2 moles of metal cations per 1 kg of rock. The groundwater samples have a pH of 7.5–8.2 and are dominated by the Mg–Ca–HCO3 type. The basalts demonstrate a porosity range of 10.9% to 28.8%, with over 70% of interconnected pores. A 20-year geochemical simulation revealed that CO_(2) injection dissolves primary minerals, including anorthite, albite, and diopside, while CO_(2)mineralization dissolves precipitation secondary minerals, such as calcite, siderite, and dolomite. Furthermore, a substantial rise in pH from 7.6to 10.6 is observed in the vicinity of the injected well, accompanied by a slight reduction in porosity from 20% to 19.8%. Additionally, 36.8% of the injected CO_(2) underwent complete mineralization within five years, revealing an increasing percentage of 66.1% if the experimental period is extended to 20 years. The presence of abundant divalent metal cations in basalts and water-bearing permeable rocks in the Leizhou Peninsula supports the potential for mineral carbonation in basalts, as indicated by the geochemical simulation results. Additional research is necessary to identify the factors that influence the CO_(2) mineralization, storage, and sensitivity analysis of basalt in the Leizhou Peninsula.
基金the National Natural Science Foundation of China(Nos.42176087,42322605)the Laoshan Laboratory(No.LSKJ202204100)the Youth Innovation Promotion Association,Chinese Academy of Sciences(No.2021206)。
文摘The molybdenum(Mo)isotope system is pivotal in reconstructing marine redox changes throughout Earth’s history and has emerged as a promising tracer for igneous and metamorphic processes.Understanding its composition and variation across major geochemical reservoirs is essential for its application in investigating high-temperature processes.However,there is debate regarding theδ^(98/95)Mo value of the Earth’s mantle,with estimates ranging from sub-chondritic to super-chondritic values.Recent analyses of global mid-ocean ridge basalt(MORB)glasses revealed significantδ^(98/95)Mo variations attributed to mantle heterogeneity,proposing a two-component mixing model to explain the observed variation.Complementary studies confirmed the sub-chondriticδ^(98/95)Mo of the depleted upper mantle,suggesting remixing of subduction-modified oceanic crust as a plausible mechanism.These findings underscore the role of Mo isotopes as effective tracers for understanding dynamic processes associated with mantle-crustal recycling.
基金support from the National Natural Science Foundation of China(Grant No.42276049)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB42020103).
文摘Recent seismic evidence shows that basalt accumulation is widespread in the mantle transition zone(MTZ),yet its ubiquity or sporadic nature remains uncertain.To investigate this phenomenon further,we characterized the velocity structure across the 660-km discontinuity that separates the upper mantle from the lower mantle beneath the Sea of Okhotsk by modeling the waveform of the S660P phase,a downgoing S wave converting into a P wave at the 660-km interface.These waves were excited by two regional>410-km-deep events and were recorded by stations in central Asia.Our findings showed no need to introduce velocity anomalies at the base of the MTZ to explain the S660P waveforms because the IASP91 model adequately reproduced the waveforms.This finding indicates that the basalt accumulation has not affected the bottom of the MTZ in the study area.Instead,this discontinuity is primarily controlled by temperature or water content variations,or both.Thus,we argue that the basalt accumulation at the base of the MTZ is sporadic,not ubiquitous,reflecting its heterogeneous distribution.
文摘The importance of this study is to identify the newly reordered and recognized basaltic intrusion for the first time in Maasser El Chouf in Lebanon. The recorded basaltic intrusion cut the Jurassic-Lower Cretaceous rock in this area. Necessary field inspection, geology, mineralogy and chemical tests were carried out on 8 basalt samples to determine their mineralogy, petrography and chemical composition. Representative samples have been tested with polarizing microscope, X-ray diffraction (XRD) and X-ray fluorescence (XRF). Petrographic and mineralogical studies show that the basalt is characterized by presence mainly of calcic-plagioclase feldspar, pyroxene-augite and olivine minerals. Secondary minerals of iron oxides also present (ilmenite and magnetite). The most appeared property is the alteration of olivine mineral to iddingsite that indicated highly weathered process. The composition of the basaltic samples reflects ultrabasic-basic type (Basanite-Tholeiitic basalt). The existence of volcanic activity occurred mostly with Pliocene age (< 2 Ma) as indicated by previous studies for similar basalt in Lebanon. Possibly, these boulders have been carried up from some deeper intrusive magmatic body under very active tension zones. Volcanism of Lebanon basalts belong to the alkaline olivine basalt, suite generally associated with tension, rifting and block faulting movements of the continental crust. Most of the volcanisms in Lebanon and in Harrat Ash Shaam Basalt from Syria and Palestine through Jordan to Saudi Arabia are related and connected to the opening of the Red Sea Rift System, making the area with tremendous volcanic tectonic activities.
文摘The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the type of melts and temperature have been studied.The mechanisms of refractory corrosion by the used melts and the factors contributing to the inhibition of corrosion development have been investigated by the method of petrographic analysis.On the basis of obtained results,the use of high-alumina,chromic oxide,and AZS/Cr refractories in the sections of glass furnace linings,experiencing the intensive impact of aluminaboronsilicate glasses and basalt melts,has been confirmed and scientifically substantiated.
基金the Shandong Provincial Natural Science Foundation,China(Nos.ZR2017PD002 and ZR2019BD010)the Open Fund of the Key Laboratory of Marine Geology and Environment,Chinese Academy of Sciences(Nos.MGE2019KG05 and MG E2021KG01)the Fundamental Research Funds for the Central Universities(No.202051009)。
文摘The composition of mantle-derived basalts reflects the nature of their mantle source regions,which constrain magma generation and composition.Here we present a new whole rock major and trace elements and phenocryst composition of the basaltic lava in the central Mariana Trough.These data provide insights into the mantle source characteristics affected by subduction components.The rocks range from basalts to basaltic andesites,which have high subduction-mobile element contents(e.g.,K,U,Th,LREE)related to N-MORB.The calculated temperature and depth of magma generation are about 1300℃and 30 km,respectively.Although the results above suggest that the addition of hydrous fluid and/or a melt derived from a slab decreases the temperature of mantle partial melting and mildly modifies the composition of a mantle source,the mantle source lithology from which primary magma is generated remains to be peridotite.
基金the financial support from the National Key Research and Development Program of China(grant no.2020YFA0711800)National Natural Science Foundation of China(grant no.11802027)+2 种基金State Key Laboratory of Explosion Science and Technology(grant no.YPJH20-6,QNKT20-01,JCRC18-01)BITBRFFR Joint Research Program(BITBLR2020018)Beijing Institute of Technology Research Fund。
文摘Continuous basalt fiber(CBF)is an outstanding inorganic fiber produced from nature,which has a wide range of applications in the field of armor protection of national defense military.However,the mechanical response and failure mechanism of 3D printed CBF reinforced components are still not well understood.Here,the 3D printing thermoplastic composites with high volume fraction CBF have been successfully prepared by fused deposition modelling(FDM)method.The effects of fiber printing direction and polymer matrix type on the tensile and flexural properties of the 3D printed composites have been explored,and the detailed failure morphology has been characterized using scanning electron microscopy and optical microscopy.It was found that under high fiber volume fraction,3D printed CBF reinforced polyamides(PA)composites have the best ability to maintain material integrity of the composites,followed by acrylonitrile butadiene styrene(ABS)and high impact polystyrene(HIPS).Besides,the results from rule of mixtures can accurately predict the longitudinal Young’s modulus of the 3D printed specimens,but there exists a large discrepancy for the prediction of the tensile strength.The microstructure analysis shows that the failure modes of 3D printed composites mainly include fiber debonding,fiber pull-out,stress whitening and matrix cracking.
文摘Based on five types of conventional logging curves including GR,RLLD,CNL,DEN and AC,and 39 core samples from 30 representative boreholes,the logging characteristics and lithofacies and sub-facies of the basaltic rocks were studied.Three basaltic facies and four sub-facies are recognized from the well logs,includ-ing volcanic conduit facies(post intrusive sub-facies),explosive facies,and effusive lava flow facies(tabular flow,compound flow and hyaloclastite sub-facies).The post intrusive,tabular flow and compound flow sub-facies logging curves are mainly controlled by the distribution of vesiculate zones and vesiculate content,which are characterized by four curves with good correlation.Post intrusive sub-facies are characterized by high RLLD,high DEN,with a micro-dentate logging curve pattern,abrupt contact relationships at the top and base.Tabular flow sub-facies are characterized by high RLLD,high DEN,with a bell-shaped log curve pattern,abrupt contact at the base and gradational contact at the top.Compound flow sub-facies are characterized by medium-low RLLD,with a micro-dentate or finger-like logging curve pattern,abrupt contact at the base and gradational contact at the top.Explosive facies and hyaloclastite sub-facies logging curves are mainly controlled by the distribution of the size and sorting of rock particles,which can be recognized by four kinds of logging curves with poor cor-relation.Explosive facies are characterized by low RLLD,medium-low CNL and low DEN,with a micro-dentate logging curve pattern.Hyaloclastite sub-facies are characterized by low RLLD,high CNL,low DEN and high AC,with a micro-dentate logging curve pattern.The present research is beneficial for the prediction of basaltic reser-voirs not only in the Liaohe depression but also in the other volcanic-sedimentary basins.
基金supported by the Natural Science Foundation Project of Liaoning Provincial Department of Education of China under Grant No.JJL201915404,Zhejiang Provincial Natural Science Foundation of China under Grant No.LQ22E080024 and Zhejiang Province Department of Education Fund of China under Grant No.Y202146776.
文摘The development of recycled aggregate concrete(RAC)provides a new approach to limiting the waste of natural resources.In the present study,the mechanical properties and deformability of RACs were improved by adding basalt fibers(BFs)and using external restraints,such as a fiber-reinforced polymer(FRP)jacket or a PVC pipe.Samples were tested under axial compression.The results showed that RAC(50%replacement of aggregate)containing 0.2%BFs had the best mechanical properties.Using either BFs or PVC reinforcement had a slight effect on the loadbearing capacity and mode of failure.With different levels of BFs,the compressive strengths of the specimens reinforced with 1-layer and 3-layer basalt fiber reinforced polymer(BFRP)increased by 6.7%–10.5%and 16.5%–23.7%,respectively,and the ultimate strains increased by 48.5%–80.7%and 97.1%–141.1%,respectively.The peak stress of the 3-layer BFRP-PVC increased by 42.2%,and the ultimate strain improved by 131.3%,relative to the control.This reinforcement combined the high tensile strength of BFRP,which improved the post-peak behavior,and PVC,which enhanced the structural durability.In addition,to investigate the influence of the various constraints on compressive behavior,the stress-strain response was analyzed.Based on the analysis of experimental results,a peak stress-strain model and an amended ultimate stress-strain model were proposed.The models were verified as well;the result showed that the predictions from calculations are generally consistent with the experimental data(error within 10%).The results of this study provide a theoretical basis and reference for future applications of fiber-reinforced recycled concrete.
基金funded by National Natural Science Foundation of China(Grant Nos.51509154 and 42077247)Natural Science Foundation of Zhejiang Province(Grant No.LGJ20E090001).
文摘The frictional strength and sliding stability of faults are crucial in interpreting earthquake mechanisms and cycles.Herein,we report friction experiments on basalt fractures,using a self-designed triaxial apparatus that allows direct shear of samples under coupled hydro-mechanical conditions.Velocitystepping(VS)and slide-hold-slide(SHS)experiments are performed on both bare and gouge-bearing surfaces of Xiashan basalt subjected to cyclic shear velocities at 1e30 mm/s,effective normal stresses of 1e5 MPa,and pore pressures of 70e300 kPa.The measured basalt friction coefficients are in the range of 0.67e0.74,which is sensitive to gouge thickness,normal stress,and water.Specifically,a reduction in friction coefficient is observed with an increment in gouge thickness,normal stress,and pore pressure.Based on the microscopic observation of the pre-and post-shearing sliding surfaces,this weakening effect in friction coefficient can be attributed to powder lubrication.Furthermore,the VS test results reveal predominantly velocity-strengthening behavior at investigated slip velocities,and this velocity strengthening behavior does not appear to be influenced by variations in normal stress,gouge thickness,and water.However,changes in sliding velocity and normal stress can lead to a shift between stable and unstable sliding.Specifically,stable sliding is favored by high sliding velocities and low normal stress applied in this study.Finally,we analyze the experimental data by calculating the rate-and-state parameters using the rate-and state-dependent friction(RSF)theory.Importantly,the calculated friction rate parameter(a-b)supports the velocity-strengthening behavior.Both frictional relaxation(Dmc)during hold periods and frictional healing(Dm)upon re-shearing are linearly proportional to the logarithmic hold time,which may be attributed to the growth in true contact area with hold time.This study sheds light on the roles of sliding velocity,and gouge thickness in controlling frictional strength and stability of basalt fractures.
基金supports for the study were provided by the Natural Sciences Foundation Committee of China(Grant No.41472254,Jinming Xu,http://www.nsfc.gov.cn)。
文摘To enhance the sulfate attack resistance performance of concrete,Sulfate erosion test was carried out on basalt fiber concrete with different contents,selecting a concentration of 5%sulfate solution and using a dry−wet cycle mechanism attack of basalt fiber-reinforced concrete(BFRC).Every 15 dry−wet cycles,the mass,compressive strength,splitting tensile strength,and relative dynamic elastic modulus of BFRC were tested,and the SO_(4)^(2−)con-centration was measured.This work demonstrates that the mass,relative dynamic elastic modulus,compressive and splitting tensile strength of BFRC reveal a trend of climb up and then decline with the process of the dry−wet cycle.Basalt fiber can enhance the sulfate corrosion resistance of concrete by delaying the erosion of concrete induced by SO_(4)^(2−)and increasing the bearing and anti-deformation capacities of concrete by improving its inter-nal structure.Additionally,when mixing 0.2%basalt fiber into concrete,the strength deterioration rate will be reduced when the peak values of splitting tensile and compressive strength appear at 60 and 75 times the alter-nating dry−wet cycles,respectively.Adverse effects will occur when the fiber volume fraction exceeds 0.2%.The research in this paper can provide a foundation for the engineering applications of basalt fiber concrete.