Accelerated Sequential Deposition Reaction via Crystal Orientation Engineering for Low-Temperature,High-Efficiency Carbon-Electrode CsPbBr_(3) Solar Cells

Low-temperature,ambient processing of high-quality CsPbBr_(3)films is demanded for scalable production of efficient,low-cost carbon-electrode perovskite solar cells(PSCs).Herein,we demonstrate a crystal orientation engineering strategy of PbBr_(2)precursor film to accelerate its reaction with CsBr precursor during two-step sequential deposition of CsPbBr_(3)films.Such a novel strategy is proceeded by adding CsBr species into PbBr_(2)precursor,which can tailor the preferred crystal orientation of PbBr_(2)film from[020]into[031],with CsBr additive staying in the film as CsPb_(2)Br_(5)phase.Theoretical calculations show that the reaction energy barrier of(031)planes of PbBr_(2)with CsBr is lower about 2.28 eV than that of(O2O)planes.Therefore,CsPbBr_(3)films with full coverage,high purity,high crystallinity,micro-sized grains can be obtained at a low temperature of 150℃.Carbon-electrode PSCs with these desired CsPbBr_(3)films yield the record-high efficiency of 10.27%coupled with excellent operation stability.Meanwhile,the 1 cm^(2)area one with the superior efficiency of 8.00%as well as the flexible one with the champion efficiency of 8.27%and excellent mechanical bending characteristics are also achieved.

Effects of orientation on the fatigue crack growth behaviors of the ZK60 magnesium alloy in air and PBS

Strong anisotropic corrosion and mechanical properties caused by specimen orientations greatly limit the applications of wrought magnesium alloys.To investigate the influences of specimen orientation,the corrosion tests and(corrosion)fatigue crack growth tests were conducted.The rolled and transverse surfaces of the materials show distinct corrosion rate differences in the stable corrosion stage,but the truth is the opposite for the initial stage of corrosion.In air,specimen orientations have a significant influence on the plastic deformation mechanisms near the crack tip,which results in different fatigue fracture surfaces and cracking paths.Compared with R-T specimens,N-T specimens show a slower fatigue crack growth(FCG)rate in air,which can be attributed to crack closure effects and deformation twinning near the crack tip.The corrosion environment will not significantly change the main plastic deformation mechanisms for the same type of specimen.However,the FCG rate in phosphate buffer saline(PBS)is one order of magnitude higher than that in air,which is caused by the combined effects of hydrogen-induced cracking and anodic dissolution.Owing to the similar corrosion rates at crack tips,the specimens with different orientations display close FCG rates in PBS.

Evaluation of New Graduate Nursing Orientation Program

The study site is a holistic patient-centered organization that has developed a 16-week long orientation program for new graduate nurses entering the hospital setting. The purpose of the program is for new graduate nurses to gain the confidence, competence, and critical thinking skills for providing safe patient care. The issue occurring within the organization is that there is an increasing rise in the number of turnover rates of new graduates leaving the hospital, thus making evaluating the program a necessity to problem-solving. There has been no evaluation of the program in the past five years to reveal why the increase in the recent turnover rates. The data collected during the interview process was coded and categorized into three main sections: organizational, substantive, and theoretical. The evaluator used an organizational category to investigate for board areas or issues within the problem attempting to be solved. The evaluator concluded from the results and findings that the issue, a poor preceptor-preceptee relationship was seen by all stakeholders involved. The literature presented concludes that continuous evaluation of orientation programs is crucial for the professional and personal growth of new graduate nurses in the hospital.

Effects of mesoclimate and microclimate variations mediated by high altitude and row orientation on sucrose metabolism and anthocyanin synthesis in grape berries

Climate change and extreme weather pose significant challenges to the traditional viticulture regions.Emerging high-altitude grape-producing regions with diverse orientations have shown great potential in coping with this challenge.Stable,high-quality wine grape production may be achieved by synchronizing the meso-and microclimate.To clarify the role of high altitude and row orientation in meso-and microclimate and the response of berries to it,we evaluated seven years(2012-2018)of climate data,two years of basic grape(Cabernet Sauvignon,Vitis vinifera L.)quality,and one-year microclimate from veraison to harvest.By comparing two locations(Sidon 2047 m,Sinon 2208 m)in Yunnan Province,China,we found that the average temperature has been stable at approximately 15℃ for seven years,with no extreme weather or,noticeable global warming.The light intensity(LI)in the north-south(NS)was more balanced than the east-west(EW)direction,and the east-west to the south(EW-S)canopy side was almost higher than the other sides.High LI was associated with high photosynthetically active radiation(PAR),ultraviolet(UV),and infrared(IR)light and vice versa.The north-south to the east(NS-E)and east-west to the north(EWN)sides were characterized by lower LI and higher UV and IR light,and higher total anthocyanin content.Most anthocyanin synthesis-related genes,for example,VvF3'H and VvF3'5'H,were highly expressed in NS-E from veraison to maturity.Perhaps UV and IR light induced their expression.This study provides new insights on the role of differently orientated rows in controlling grape quality due to varied light quality.The findings are globally significant,particularly in the context of climate change,and offer fresh insights into berry physiological responses and decision-making for the management of existing vineyards.

Alleviating the anisotropic microstructural change and boosting the lithium ions diffusion by grain orientation regulation for Ni-rich cathode materials

Generally,layered Ni-rich cathode materials exhibit the morphology of polycrystalline secondary sphere composed of numerous primary particles.While the arrangement of primary particles plays a very important role in the properties of Ni-rich cathodes.The disordered particle arrangement is harmful to the cyclic performance and structural stability,yet the fundamental understanding of disordered structure on the structural degradation behavior is unclarified.Herein,we have designed three kinds of LiNi_(0.83)Co_(0.06)Mn_(0.11)O_(2) cathode materials with different primary particle orientations by regulating the precursor coprecipitation process.Combining finite element simulation and in-situ characterization,the Li^(+)transport and structure evolution behaviors of different materials are unraveled.Specifically,the smooth Li^(+)diffusion minimizes the reaction heterogeneity,homogenizes the phase transition within grains,and mitigates the anisotropic microstructural change,thereby modulating the crack evolution behavior.Meanwhile,the optimized structure evolution ensures radial tight junctions of the primary particles,enabling enhanced Li^(+)diffusion during dynamic processes.Closed-loop bidirectional enhancement mechanism becomes critical for grain orientation regulation to stabilize the cyclic performance.This precursor engineering with particle orientation regulation provides the useful guidance for the structural design and feature enhancement of Ni-rich layered cathodes.

A Cognitive Psychological Study on the Acquisition of Chinese Word’s Coloring Meaning--Chinese as a Second Language

Lexical meaning mainly includes rational meaning,grammatical meaning,and coloring meaning.Mastering the coloring meaning of vocabulary is of great significance for foreign students to use Chinese vocabulary correctly.This study mainly examines the psychological mechanism of Chinese second language learners mastering the coloring meaning of words,examines the psychological characteristics of students mastering the color meaning of words from the perspectives of second language learning theory and cognitive theory,establishes a cognitive schema for coloring meaning learning,and proposes corresponding learning models and teaching strategies.

Nonlinear Time History Analysis for the Different Column Orientations under Seismic Wave Synthetic Approach

The significant impact of earthquakes on human lives and the built environment underscores the extensive human and economic losses caused by structural collapses. Over the years, researchers have focused on improving seismic design to mitigate earthquake-induced damages and enhance structural performance. In this study, a specific reinforced concrete (RC) frame structure at Kyungpook National University, designed for educational purposes, is analyzed as a representative case. Utilizing SAP 2000, the research conducts a nonlinear time history analysis to assess the structural performance under seismic conditions. The primary objective is to evaluate the influence of different column section designs, while maintaining identical column section areas, on structural behavior. The study employs two distinct seismic waves from Abeno (ABN) and Takatori (TKT) for the analysis, comparing the structural performance under varying seismic conditions. Key aspects examined include displacement, base shear force, base moment, joint radians, and layer displacement angle. This research is anticipated to serve as a valuable reference for seismic restraint reinforcement work on RC buildings, enriching the methods used for evaluating structures through nonlinear time history analysis based on the synthetic seismic wave approach.

Integrating Virtual Reality and Energy Analysis with BIM to Optimize Window-to-Wall Ratio and Building’s Orientation for Age-in-Place Design at the Conceptual Stage

This study unfolds an innovative approach aiming to address the critical role of building design in global energy consumption, focusing on optimizing the Window-to-Wall Ratio (WWR), since buildings account for approximately 30% of total energy consumed worldwide. The greatest contributors to energy expenditure in buildings are internal artificial lighting and heating and cooling systems. The WWR, determined by the proportion of the building’s glazed area to its wall area, is a significant factor influencing energy efficiency and minimizing energy load. This study introduces the development of a semi-automated computer model designed to offer a real-time, interactive simulation environment, fostering improving communication and engagement between designers and owners. The said model serves to optimize both the WWR and building orientation to align with occupants’ needs and expectations, subsequently reducing annual energy consumption and enhancing the overall building energy performance. The integrated model incorporates Building Information Modeling (BIM), Virtual Reality (VR), and Energy Analysis tools deployed at the conceptual design stage, allowing for the amalgamation of owners’ inputs in the design process and facilitating the creation of more realistic and effective design strategies.

Exploring the meaning of care among lived experiences of patients with blindness:an interpretive phenomenological study

Objective:To explore the meaning of care experienced by people with blindness in hospitals.Methods:Interpretive phenomenology along with the 6-step method of van Manen was used to conduct the study.Using purposeful sampling,15 people with legal blindness were interviewed.Thematic analysis was used to isolate the meaning of care.Results:Five themes emerged:(a)nurses in the eyes of patients with blindness;(b)negligence in the caring moments;(c)being cared for in ambiguity;(d)Uncoordinated care;and(e)Psychological discomfor t.These sub-themes were condensed into an overarching theme titled as“marginalized patients inside the stereotypical healthcare system.”Conclusions:Lived experiences of patients with blindness revealed that hospitals provide stereotypic or inappropriate care for this minority group in society.Health professionals par ticularly nurses should be skilled to provide person-centered and coordinated care for patients with blindness.

Mean Shift跟踪算法创新实验项目设计

视频跟踪算法是计算机视觉实践课程中比较受关注的实验项目。针对突变情况下传统Mean Shift跟踪算法无法实时准确跟踪的问题,设计了基于模板更新和线性预估的Mean Shift跟踪算法创新实验项目。在模板更新策略下,引入背景模板,通过将原目标模板和背景模板与设定的阈值进行比较来对干扰因素进行判定,当干扰因素判定目标受到遮挡时,引入线性预估方程进行目标位置预测,有效解决目标在遮挡情况下跟踪丢失的问题。通过对测试视频的跟踪效果和性能进行对比分析,验证了算法在突变情况下相较于传统算法具有更好的抗干扰能力。以算法创新设计为核心,通过开放性创新实验项目的选题、设计、答辩、反馈的闭环实验过程,有效提高了学生算法创新设计能力。

加入跳跃连接的深度嵌入K-means聚类

现有的深度聚类算法大多采用对称的自编码器来提取高维数据的低维特征,但随着自编码器训练次数的不断增加,数据的低维特征空间在一定程度上发生了扭曲,这样得到的数据低维特征空间无法反映原始数据空间中潜在的聚类结构信息.为了解决上述问题,本文提出了一种新的深度嵌入K-means算法(SDEKC).首先,在低维特征提取阶段,在对称的卷积自编码器中相对应的编码器与解码器之间以一定的权重加入两个跳跃连接,以减弱解码器对编码器的编码要求同时突出卷积自编码器的编码能力,这样可以更好地保留原始数据空间中蕴含的聚类结构信息;其次,在聚类阶段,通过一个标准正交变换矩阵将低维数据空间转换为一个新的揭示聚类结构信息的空间;最后,本文以端到端的方式采用贪婪算法迭代优化数据的低维表示及其聚类,在6个真实数据集上验证了本文提出新算法的有效性.

基于蚁群算法的三支k-means聚类算法

在聚类分析中,三支k-means聚类算法较具有较强的处理边界不确定数据的能力,但仍然存在对初始聚类中心敏感的问题.通过将蚁群算法和三支k-means聚类算法相结合,给出了一种基于蚁群算法的三支k-means聚类算法来解决这一问题.利用蚁群算法中随机概率选择策略和信息素的正负反馈机制,动态调整权重的方法,对三支k-means聚类算法进行优化.在UCI数据集上实验证明,该方法对聚类结果的性能指标有所提高.

基于K-Means聚类与熵权TOPSIS法的岩石可爆性评价研究

露天矿山的爆破块度分布,直接影响到后续的采装、运输和破碎工作。为了控制石墨矿山不同区域爆破块度分布,基于K-means无监督聚类学习法与熵权TOPSIS评价法建立了一种新的岩石可爆性评价模型,选取岩石密度、动力能量耗散率、动态抗压强度、平均应变率、脆性指数作为评价指标,通过熵权计算,发现岩石破碎程度受脆性指数影响最大,受平均应变率影响最小。将此模型应用于实际石墨矿山,可爆性分为10个等级,统计不同分级下的岩石平均破碎粒径,发现可爆性分级等级越高平均粒径越大,有明显的分级特征,验证了模型的有效性。从爆破石墨矿石岩体类型看,岩石可爆性从易到难排序为:片岩、片麻岩、变粒岩、混合岩。结合石墨矿石微观观测结果分析可知:岩性从片岩向混合岩转变,岩石内部石墨晶质呈下降趋势,石墨矿石可爆性等级也随之越来越高。岩石密度、能量耗散率、动态抗压强度之间呈线性正相关,岩石可爆性与平均应变率、脆性指数存在负相关性。研究成果为矿山矿岩可爆性评价提供了一条新思路,对露天矿山爆破块度优化具有一定的理论和实践指导意义。

Crystallization and Orientation Modulation Enable Highly Efficient Doctor-Bladed Perovskite Solar Cells

With the rapid rise in perovskite solar cells(PSCs)performance,it is imperative to develop scalable fabrication techniques to accelerate potential commercialization.However,the power conversion efficiencies(PCEs)of PSCs fabricated via scalable two-step sequential deposition lag far behind the state-of-the-art spin-coated ones.Herein,the additive methylammonium chloride(MACl)is introduced to modulate the crystallization and orientation of a two-step sequential doctorbladed perovskite film in ambient conditions.MACl can significantly improve perovskite film quality and increase grain size and crystallinity,thus decreasing trap density and suppressing nonradiative recombination.Meanwhile,MACl also promotes the preferred face-up orientation of the(100)plane of perovskite film,which is more conducive to the transport and collection of carriers,thereby significantly improving the fill factor.As a result,a champion PCE of 23.14%and excellent longterm stability are achieved for PSCs based on the structure of ITO/SnO_(2)/FA_(1-x)MA_xPb(I_(1-y)Br_y)_3/Spiro-OMeTAD/Ag.The superior PCEs of 21.20%and 17.54%are achieved for 1.03 cm~2 PSC and 10.93 cm~2 mini-module,respectively.These results represent substantial progress in large-scale two-step sequential deposition of high-performance PSCs for practical applications.

光伏波动平抑下改进K-means的电池储能动态分组控制策略

针对电池储能系统(battery energy storage system,BESS)进行光伏波动平抑时寿命损耗高及荷电状态(state of charge,SOC)一致性差的问题,提出了光伏波动平抑下改进K-means的BESS动态分组控制策略。首先,采用最小最大调度方法获取光伏并网指令。其次,设计了改进侏儒猫鼬优化算法(improved dwarf mongoose optimizer,IDMO),并利用它对传统K-means聚类算法进行改进,加快了聚类速度。接着,制定了电池单元动态分组原则,并根据电池单元SOC利用改进K-means将其分为3个电池组。然后,设计了基于充放电函数的电池单元SOC一致性功率分配方法,并据此提出BESS双层功率分配策略,上层确定电池组充放电顺序及指令,下层计算电池单元充放电指令。对所提策略进行仿真验证,结果表明,所设计的IDMO具有更高的寻优精度及更快的寻优速度。所提BESS平抑光伏波动策略在有效平抑波动的同时,降低了BESS运行寿命损耗并提高了电池单元SOC的均衡性。

基于特征分箱和K-Means算法的用户行为分析方法

针对网购用户所产生的购物行为进行分析,首先通过数据处理构建客户关系管理模型(RFM模型),在此模型的基础上采用特征分箱法和K-Means聚类两种方法对用户进行细分,并对2种模型结果进行比较分析,讨论二者的差异性和具体的应用范围和意义.其中,基于特征分箱法的RFM模型将变量转化到相似的尺度上并将变量离散化,使得用户分类标签更加清晰,也可依据各类标签分类出不同类型的用户.K-Means算法通过轮廓系数评估聚类算法质量以至于选取最优K值.本文实验分析结果可为运营商提供更加可靠直观的数据,使得运营商可以根据不同用户的不同行为进行市场细分,进而进行精准营销和服务设置.

基于k-means聚类算法的兴义维蚋幼虫龄数的估算

目的探讨基于k-means聚类算法估算兴义维蚋幼虫的龄数,以明确虫龄与日龄及鳃斑发育阶段的关系。方法采集贵州青岩河流中兴义维蚋虫卵,于实验室的蚋类饲养系统中培育至幼虫,每日收集幼虫至大量化蛹,持续20 d;收集到幼虫1112头,于体视显微镜下测量头壳长(HCW)、后颊长(PGL)、上颚基横骨长(MPL)及体长(BL),观察不同虫龄幼虫的破卵器、鳃斑及性腺的形态学特征,并判断其龄期、分析虫龄与日龄和鳃斑发育关系;选取具有明显腮斑发育的兴义维蚋幼虫10头、制作石蜡切片,采用HE染色鉴定精巢和卵巢、辅助确认性别鉴定结果;采用k-means聚类方法划分形态计量学数据、利用Brooks-Dyar定律检测k-means聚类结果,R语言下行聚类与Brooks-Dyar定律检验、t检验等,根据拟合度分析判断兴义维蚋幼虫龄数。结果1112头兴义维蚋幼虫中有破卵器89头,出现鳃斑发育334头,6~7龄幼虫320头,有预蛹特征34头;Brooks-Dyar定律与破卵器、鳃斑形态特征显示7龄幼虫假设符合昆虫幼虫生长规律;组织学观察见幼虫精巢为椭圆形、体积大、外有几丁质层包裹,卵巢为长条形、体积小、后端有色素细胞包裹;鉴定6、7龄幼虫性别结果,仅7龄幼虫雌雄性PGL有差异(P<0.05);幼虫虫龄与日龄、鳃斑发育关系结果显示,约2~3 d对应1个幼虫生长龄期,第17天首见幼虫蛹化,6龄幼虫出现明显的鳃斑。结论兴义维蚋幼虫具7龄,实验室下幼虫发育约需3周,最短17 d;腮斑发育起始于6龄,7龄出现明显形态学特征。

管制扇区运行稳度K-means聚类与分析

为更好地分析管制扇区运行存在的稳定亚安全状态和不稳定亚安全状态,使用K-means算法划分超容比(ECR)、滞留度和飞行姿态混合比3个管制扇区运行稳度评价指标聚类,确定管制扇区运行稳度最佳等级划分;聚类分析单一指标,获得各等级对应的指标阈值,结合熵权法计算的指标权重,遵循隶属度最大原则,获取各时间段的管制扇区运行稳度等级,构建管制扇区运行稳度综合评价模型;选取厦门01号扇区的实际飞行数据,从稳度和趋度2个角度更加全面地分析管制扇区运行态势。结果表明:管制扇区运行稳度等级划分为3类时效果最好;稳度受空中交通流和管制状况的影响会随时间而变化,尤其7:30—9:15和20:00—21:00这2个时间段管制扇区运行稳度的变化最为明显,需引起管制员高度重视,提高空域运行安全。

基于改进K-means与机器视觉的档案数据分析技术

为了提升医疗信息系统对健康档案数据的分析效率,文中采用图像采集、降噪、配准与差分等技术提取医疗图像信息,进而有效提升信息系统的数据采集效率。同时还对传统的K-means算法加以改进,并提出了一种基于类间、类内距离的聚类初始化评价指标体系(BWP),将其应用于采集到的档案数据中,以实现快速的聚类分析。将所提算法在CUDA计算平台上进行了实现,测试结果表明,该方法的聚类精度和运行效率较现有算法均有显著提升。此外,改进后K-means算法的正确聚类样本数量占比提升了4.88%,高于现有的主流指标体系,且当聚类数k的取值为16或32时,运行时间大幅降低。

厄瓜多尔Oriente盆地白垩系Napo组LU亚段沉积模式

厄瓜多尔Oriente盆地北部白垩系Napo组LU亚段地层油气资源极其丰富,具有较大的油气勘探潜力,由于目前对LU亚段地层沉积模式认识不清晰,极大程度上限制了研究区进一步勘探开发。依据LU亚段岩芯观察、测井、成熟度分析以及镜下薄片等资料,通过岩芯岩性、结构等岩石学特征,沉积构造、生物遗迹化石、沉积韵律等沉积学特征,以及测井相标志认为,研究区LU亚段地层发育于潮汐作用为主的海陆过渡环境,并在前人研究基础上提出潮控河口湾与陆棚之间存在过渡带沉积,形成了潮控河口湾-过渡带-陆棚沉积体系,识别出潮汐水道、潮汐砂坝、砂坪、海绿石砂席、混合坪、陆棚泥和灰质滩共7种沉积微相,其中,优势储层相带为潮汐水道和潮汐砂坝,砂坪次之。建立研究区潮控河口湾-过渡带-陆棚沉积模式,以期对Oriente盆地白垩系Napo组油气勘探提供有利的科学依据。