Considering the economic and environmental benefits associated with the recycling of polyester(PET)fibres,it is vital to study the application of fibre-reinforced cement composites.According to the characteristics of ...Considering the economic and environmental benefits associated with the recycling of polyester(PET)fibres,it is vital to study the application of fibre-reinforced cement composites.According to the characteristics of the wind-blown sand environment in Inner Mongolia,the erosion resistance of the polyester fibre-reinforced cement composites(PETFRCC)with different PET fibre contents to various erosion angles,velocities and sand particle flows was investigated by the gas-blast method.Based on the actual conditions of sandstorms in Inner Mongolia,the sand erosion parameters required for testing were calculated by the similarity theory.The elastic-plastic model and rigid plastic model of PETFRCC and cement mortar were established,and the energy consumption mechanism of the model under particle impact was analyzed.The experimental results indicate that the microstructure of PETFRCC rafter hydration causes a spring-like buffering effect,and the deformation of PETFRCC under the same impact load is slightly smaller than that of cement mortar,and the damage mechanism of PETFRCC is mainly characterized by fiber deformation and slight brittle spalling of matrix.And under the most unfavorable conditions of the erosion,the erosion rate of 0.5PETFRCC is about 57.69%lower than that of cement mortar,showing better erosion resistance.展开更多
Self-assembly has been extensively studied in chemistry,physics,biology,and materials engineering and has become an important“bottom-up”approach in creating intriguing structures for different applications.Using dis...Self-assembly has been extensively studied in chemistry,physics,biology,and materials engineering and has become an important“bottom-up”approach in creating intriguing structures for different applications.Using dissipative self-assembly to construct fuel-dependent,energy-consuming,and dynamic nonequilibrium systems is important for developing intelligent life-like materials.Furthermore,dissipative self-assembly has become a research hotspot in materials chemistry,biomedical science,environmental chemistry,and physical chemistry.An in-depth understanding of the process and mechanism provides useful insights to the researchers for devel-oping materials using dissipative self-assembly and also helps guide future innovation in material fabrication.This critical review comprehensively analyzes various chemical fuel input and energy consumption mechanisms,supported by numerous illustrative examples.Versatile transient assemblies,including gels,vesicles,micelles,and nanoparticle aggregates,have been systematically studied in our and other laboratories.The relationship between the molecular structure of precursors and temporal assemblies in dissipative self-assemblies is discussed from the perspective of physical chemistry.Using dissipative self-assembly methods to construct functional assemblies provides important implications for constructing high-energy,nonequilibrium,and intelligent functional materials.展开更多
基金Funded by the National Natural Science Foundation of China(Nos.11162011,51468049 and 11862022)the Open Project Program of Fujian Key Laboratory of Novel Functional Textile Fibers and Materials+1 种基金Minjiang University(China)(No.FKLT FM1907)the Inner Mongolia Colleges and Universities Youth Science and Technology Talents Support Program(No.NJYT-17-A09)。
文摘Considering the economic and environmental benefits associated with the recycling of polyester(PET)fibres,it is vital to study the application of fibre-reinforced cement composites.According to the characteristics of the wind-blown sand environment in Inner Mongolia,the erosion resistance of the polyester fibre-reinforced cement composites(PETFRCC)with different PET fibre contents to various erosion angles,velocities and sand particle flows was investigated by the gas-blast method.Based on the actual conditions of sandstorms in Inner Mongolia,the sand erosion parameters required for testing were calculated by the similarity theory.The elastic-plastic model and rigid plastic model of PETFRCC and cement mortar were established,and the energy consumption mechanism of the model under particle impact was analyzed.The experimental results indicate that the microstructure of PETFRCC rafter hydration causes a spring-like buffering effect,and the deformation of PETFRCC under the same impact load is slightly smaller than that of cement mortar,and the damage mechanism of PETFRCC is mainly characterized by fiber deformation and slight brittle spalling of matrix.And under the most unfavorable conditions of the erosion,the erosion rate of 0.5PETFRCC is about 57.69%lower than that of cement mortar,showing better erosion resistance.
基金the National Natural Science Foundation of China(Grant Nos.22032003 and 22072073).
文摘Self-assembly has been extensively studied in chemistry,physics,biology,and materials engineering and has become an important“bottom-up”approach in creating intriguing structures for different applications.Using dissipative self-assembly to construct fuel-dependent,energy-consuming,and dynamic nonequilibrium systems is important for developing intelligent life-like materials.Furthermore,dissipative self-assembly has become a research hotspot in materials chemistry,biomedical science,environmental chemistry,and physical chemistry.An in-depth understanding of the process and mechanism provides useful insights to the researchers for devel-oping materials using dissipative self-assembly and also helps guide future innovation in material fabrication.This critical review comprehensively analyzes various chemical fuel input and energy consumption mechanisms,supported by numerous illustrative examples.Versatile transient assemblies,including gels,vesicles,micelles,and nanoparticle aggregates,have been systematically studied in our and other laboratories.The relationship between the molecular structure of precursors and temporal assemblies in dissipative self-assemblies is discussed from the perspective of physical chemistry.Using dissipative self-assembly methods to construct functional assemblies provides important implications for constructing high-energy,nonequilibrium,and intelligent functional materials.