With the further implementation of the knowledge innovation program (KIP), piloted by the Chinese Academy of Sciences (CAS), encouraging progress has been made in contributing to the development of the country's h...With the further implementation of the knowledge innovation program (KIP), piloted by the Chinese Academy of Sciences (CAS), encouraging progress has been made in contributing to the development of the country's high-tech industry, and forging S&T cooperation with local governments and industrial sectors. This was revealed at the Second CAS Conference on High-tech Industrialization April 25 - 29 in Shenzhen, Guangdong Province.展开更多
A fundamental step in the production of an industrial catalyst is its crushing strength assessment. Limited literature exists in which the strength reliability of supported catalysts is investigated from production to...A fundamental step in the production of an industrial catalyst is its crushing strength assessment. Limited literature exists in which the strength reliability of supported catalysts is investigated from production to their application in a reactor. In this work, cylindrical supports were prepared by pelletizing high poros- ity γ-alumina powder, and Cu-Znf/γ-Al2O3 catalysts were prepared by impregnation of the pelletized γ-alumina supports with an aqueous solution of copper and zinc nitrates. The support-forming variables, such as binder concentration, compaction pressure, calcination temperature, and drying procedure were investigated. The Weibull method was used to analyze the crushing strength data of the supports, and the fresh and used catalysts before and after the low-temperature water gas shift reaction. Support formation at a 50 wt% binder concentration, 1148 MPa compaction pressure, 500 ℃ calcination temperature, and rapid drying （100 ℃, 8 h） led to the maximum support mechanical reliability. The most reliable catalyst with respect to simultaneous appropriate catalytic performance and mechanical strength was prepared from a support with the lowest mean crushing strength （26.25 MPa）. This work illustrates the impor- tance of the Weibull modulus as a useful mechanical reliability index in manufacturing a supported solid catalyst.展开更多
文摘With the further implementation of the knowledge innovation program (KIP), piloted by the Chinese Academy of Sciences (CAS), encouraging progress has been made in contributing to the development of the country's high-tech industry, and forging S&T cooperation with local governments and industrial sectors. This was revealed at the Second CAS Conference on High-tech Industrialization April 25 - 29 in Shenzhen, Guangdong Province.
文摘A fundamental step in the production of an industrial catalyst is its crushing strength assessment. Limited literature exists in which the strength reliability of supported catalysts is investigated from production to their application in a reactor. In this work, cylindrical supports were prepared by pelletizing high poros- ity γ-alumina powder, and Cu-Znf/γ-Al2O3 catalysts were prepared by impregnation of the pelletized γ-alumina supports with an aqueous solution of copper and zinc nitrates. The support-forming variables, such as binder concentration, compaction pressure, calcination temperature, and drying procedure were investigated. The Weibull method was used to analyze the crushing strength data of the supports, and the fresh and used catalysts before and after the low-temperature water gas shift reaction. Support formation at a 50 wt% binder concentration, 1148 MPa compaction pressure, 500 ℃ calcination temperature, and rapid drying （100 ℃, 8 h） led to the maximum support mechanical reliability. The most reliable catalyst with respect to simultaneous appropriate catalytic performance and mechanical strength was prepared from a support with the lowest mean crushing strength （26.25 MPa）. This work illustrates the impor- tance of the Weibull modulus as a useful mechanical reliability index in manufacturing a supported solid catalyst.
