The rate of hydrothermal reaction of SiO_2 and/or A1_2O_3 in the system of CaO-Al_2O_3-SiO_2-H_2O at 200℃ and the factors which influence the reactions are investigated by determining the reaction ratio.The rate of r...The rate of hydrothermal reaction of SiO_2 and/or A1_2O_3 in the system of CaO-Al_2O_3-SiO_2-H_2O at 200℃ and the factors which influence the reactions are investigated by determining the reaction ratio.The rate of reactions depends on the reactive activities of raw materials, initial composition of mixture and relative activity of SiO_2 and A12O3. The hydrothermal reaction can be accelerated by sodium hydroxide,in the case of silica,which has low activity, this is quite obvious.展开更多
In order to study the mechanism of water inrush from a concealed, confined karst cave, we established a fluid–solid coupling model of water inrush from a concealed karst cave ahead of a roadway and a strength reducti...In order to study the mechanism of water inrush from a concealed, confined karst cave, we established a fluid–solid coupling model of water inrush from a concealed karst cave ahead of a roadway and a strength reduction method in a rock pillar for preventing water inrush based on catastrophic theory. Fluid–solid coupling effects and safety margins in a rock pillar were studied. Analysis shows that rock pillar instability, exerted by disturbance stress and seepage stress, is the process of rock pillar catastrophic destabilization induced by nonlinear extension of plastic zones in the rock pillar. Seepage flow emerges in the rock pillar for preventing water inrush, accompanied by mechanical instability of the rock pillar. Taking the accident of a confined karst cave water-inrush of Qiyi Mine as an example, by studying the safety factor of the rock pillar and the relationship between karst cave water pressure and thickness of the rock pillar,it is proposed that rock pillar thickness with a safety factor equal to 1.5 is regarded as the calculated safety thickness of the rock pillar, which should be equal to the sum of the blasthole depth, blasting disturbance depth and the calculated safety thickness of the rock pillar. The cause of the karst water inrush at Qiyi Mine is that the rock pillar was so small that it did not possess a safety margin. Combining fluid–solid coupling theory, catastrophic theory and strength reduction method to study the nonlinear mechanical response of complicated rock engineering, new avenues for quantitative analysis of rock engineering stability evaluation should be forthcoming.展开更多
The unsteady condition of rolling Mill vibration that was caused by flexural vibration of strip was investigated. The parametric flexural vibration equation of rolled strip was established. The parametric flexural vib...The unsteady condition of rolling Mill vibration that was caused by flexural vibration of strip was investigated. The parametric flexural vibration equation of rolled strip was established. The parametric flexural vibration stability of rolled strip was studied and region of stability and unstability was determined based on Floquet theory and perturbation method. The flexural-vibration of strip was unstable if the frequency of variable tension was twice as the natural frequency of flexural-vibration strip. The characteristics of electric current in a temp driving motor’s main loop was studied and tested, and approved that there were 6 humorous current ponderance and 12 humorous current ponderance in main circuit of driving motor. Vertical vibration of working roller was tested, the test approved that there were running unsteady caused by parametric vibration. It attached importance to the parametric vibration of rolling mill.展开更多
The theoretical research of cable-driven mechanisms is developed with its broad applications. The first prototype of cable-driven mechanisms is RoboCrane, which was developed by the National Institute of Standards and...The theoretical research of cable-driven mechanisms is developed with its broad applications. The first prototype of cable-driven mechanisms is RoboCrane, which was developed by the National Institute of Standards and Technology (NIST). Then many excellent properties were developed and they have a variety of applications such as aerospace, aircraft and automobile industries [1]. Example application for RoboCrane in the field of aircraft mainte- nance is equipped with a quick-change mechanism to remove the robot arm remotely.展开更多
The article discusses the early abandonment of mechanical theories about eye enlargement in degenerative myopia at the turn of the 20th century.At that time,the number of theories about myopia grew unrestricted,but wi...The article discusses the early abandonment of mechanical theories about eye enlargement in degenerative myopia at the turn of the 20th century.At that time,the number of theories about myopia grew unrestricted,but with scant support from the experimental field.The mechanical theories vanished as a new wave of metabolism-based theories appeared,propelled by the huge advances in molecular biology.Modern techniques allow reconsidering those theories and to put them to test with higher confidence.展开更多
In this paper we consider that the momentum of a free particle motion withhigh-level speed presenting nonlinear effects may be expanded by using Laurent seriesand then obtain the complete expression of nonlinear and u...In this paper we consider that the momentum of a free particle motion withhigh-level speed presenting nonlinear effects may be expanded by using Laurent seriesand then obtain the complete expression of nonlinear and unsteady momentum. These nonlinear and unsieady phenoniena of high-level speed may further expand to the theory of kinematics and it may be determined by Fredholm's integral equation of the first kind. In addition, according to the nonlinear and unsteady momentum obtained the relations of the nonlinear mechanics equations .work and energy, mass and energymay be derived.Finaly .this paper also calculates those experimental results which done in particle physics for mu-mesons u±and fast neutrons n, these results are in agreement with data perfectly.展开更多
As is Wellknown in both elastic mechanics andfluid mechanics, the plane problems are more convenient than space problems. One of the causes is that there has been a complete theory about the complex Junction and the a...As is Wellknown in both elastic mechanics andfluid mechanics, the plane problems are more convenient than space problems. One of the causes is that there has been a complete theory about the complex Junction and the analytic junction, hut in space problems, the case is quite different.We have no effective method to deal with these problems. In this paper, we first introduces general theories of Clifford algebra. Then we emphatically explain Clifford algebra in three dimensions and establish theories of regular Junction in three dimensions analogically to analytic function in plane. Thus we extend some results of plane problem-la three dimensions or high dimensions. Obviously, it is very important for elastic and fluid mechanics. But because Clifford algebra is not a commutative algebra, we can't simply extend the results of two dimensions to high dimensions. The left problems are yet to be found out.展开更多
This research aims to integrate Bekenstein’s bound and Landauer’s principle, providing a unified framework to understand the limits of information and energy in physical systems. By combining these principles, we ex...This research aims to integrate Bekenstein’s bound and Landauer’s principle, providing a unified framework to understand the limits of information and energy in physical systems. By combining these principles, we explore the implications for black hole thermodynamics, astrophysics, astronomy, information theory, and the search for new laws of nature. The result includes an estimation of the number of bits stored in a black hole (less than 1.4 × 10<sup>30</sup> bits/m<sup>3</sup>), enhancing our understanding of information storage in extreme gravitational environments. This integration offers valuable insights into the fundamental nature of information and energy, impacting scientific advancements in multiple disciplines.展开更多
As an important component of nanodevices and nanomachine constructions, the mechanical performance of nanowires (NWs) has been a subject of intense research efforts due to gaining relevance in controlling functional...As an important component of nanodevices and nanomachine constructions, the mechanical performance of nanowires (NWs) has been a subject of intense research efforts due to gaining relevance in controlling functionality of nanoelectromechanical systems (NEMS); meanwhile, one of the characteristics of the NEMS is the dependence of the functionality of the systems upon the applied electric field. The study of the electric effects on the Young's modulus of nanostructures is of certain usefulness in the design of NEMS and the precise measurement of mechanical properties of one-dimensional nanostructures. This paper reviews the origin of the size-dependence of the elastic property of NWs and the factors influencing the discrepancies and inconsistencies in the measured values of the Young's modulus for the NW, besides the surface effects, nonlinear effects, the electromechanical coupling effects as a possible effect responsible for the differences in quantitative and qualitative performance of the measured Young's modulus for the NWs versus the diameter are clarified.展开更多
Conventional overconstrained parallel manipulators have been widely studied both in industry and academia,however the structural synthesis of hybrid mechanisms with additional constraints is seldom studied,especially ...Conventional overconstrained parallel manipulators have been widely studied both in industry and academia,however the structural synthesis of hybrid mechanisms with additional constraints is seldom studied,especially for the four degrees of freedom(DOF) hybrid mechanisms.In order to develop a manipulator with additional constraints,a class of important spatial mechanisms with coupling chains(CCs) whose motion type is two rotations and two translations(2R2T) is presented.Based on screw theory,the combination of different types of limbs which are used to construct parallel mechanisms and coupling chains is proposed.The basic types of the general parallel mechanisms and geometric conditions of the kinematic chains are given using constraint synthesis method.Moreover,the 2R2T motion pattern hybrid mechanisms which are derived by adding coupling chains between different serial kinematic chains(SKCs) of the corresponding parallel mechanisms are presented.According to the constraint analysis of the mechanisms,the movement relationship of the moving platform and the kinematic chains is derived by disassembling the coupling chains.At last,fourteen novel hybrid mechanisms with two or three serial kinematic chains are presented.The proposed novel hybrid mechanisms and construction method enrich the family of the spatial mechanisms and provide an instruction to design more complex hybrid mechanisms.展开更多
Fast pyrolysis of biomass will produce various furan derivatives, among which 5-hydroxymethyl furfural(5-HMF) and furfural(FF) are usually the two most important compounds derived from holocellulose. In this study...Fast pyrolysis of biomass will produce various furan derivatives, among which 5-hydroxymethyl furfural(5-HMF) and furfural(FF) are usually the two most important compounds derived from holocellulose. In this study, density functional theory(DFT) calculations are utilized to reveal the formation mechanisms and pathways of 5-HMF and FF from two hexose units of holocellulose, i.e., glucose and mannose. In addition, fast pyrolysis experiments of glucose and mannose are conducted to substantiate the computational results, and the orientation of 5-HMF and FF is determined by 13C-labeled glucoses. Experimental results indicate that C1 provides the aldehyde group in both 5-HMF and FF, and FF is mainly derived from C1 to C5 segment. According to the computational results, glucose and mannose have similar reaction pathways to form 5-HMF and FF with d-fructose(DF) and 3-deoxy-glucosone(3-DG) as the key intermediates. 5-HMF and FF are formed via competing pathways. The formation of 5-HMF is more competitive than that of FF, leading to higher yield of 5-HMF than FF from both hexoses. In addition, compared with glucose,mannose can form 5-HMF and FF via extra pathways because of the epimerization at C2 position. Therefore, mannose pyrolysis results in higher yields of 5-HMF and FF than glucose pyrolysis.展开更多
The nonthermal components in hard X-rays have been detected in two young supernova remnants (SNRs): SN 1006 and Kepler's SNR. Various theoretical models showed that the amplification of the magnetic field was cruc...The nonthermal components in hard X-rays have been detected in two young supernova remnants (SNRs): SN 1006 and Kepler's SNR. Various theoretical models showed that the amplification of the magnetic field was crucial to explain their multiband emission properties. We investigate the evolution of the magnetic field and model the multiband emissions from these two young SNRs with a time-dependent injection model. The results indicate that (1) the radio and X-ray emissions are re- produced by synchrotron radiation of the injected electrons, while the y-rays can be explained as inverse Compton scattering of the relativistic electrons and proton-proton interaction of the high-energy protons; and (2) the amplification of the magnetic field spontaneously happens with reasonable parameters.展开更多
Based on the principal-agent theory, this paper analyzes the current situation and the developing trends of Chinese private enterprises. It points out the obstacles confronted by Chinese private enterprise in setting ...Based on the principal-agent theory, this paper analyzes the current situation and the developing trends of Chinese private enterprises. It points out the obstacles confronted by Chinese private enterprise in setting up the principal-agent mechanism and proposes the corresponding solutions to these problems.展开更多
Using density functional theory,noncovalent interactions and four mechanisms of covalent functionalization of capecitabine anticancer drug onto γ-Fe2O3 nanoparticles have been investigated.Quantum molecular descripto...Using density functional theory,noncovalent interactions and four mechanisms of covalent functionalization of capecitabine anticancer drug onto γ-Fe2O3 nanoparticles have been investigated.Quantum molecular descriptors of noncovalent configurations were studied.It was specified that binding of capecitabine onto γ-Fe2O3 nanoparticles is thermodynamically suitable.Hardness and the gap of energy between LUMO and HOMO of capecitabine are higher than the noncovalent configurations,showing the reactivity of capecitabine increases in the presence of γ-Fe2O3 nanoparticles.Capecitabine can bond to γ-Fe2O3 nanoparticles through OH(k1 mechanism),NH(k2 mechanism),CO(k3 mechanism) and F(k4 mechanism) groups.The activation energies,activation enthalpies and activation Gibbs free energies of these reactions were calculated.It was specified that the k1 and k2 mechanisms are under thermodynamic control and k3 and k4 under kinetic control.These results could be generalized to other similar drugs.展开更多
We present a new solution for the elastic displacement and strain fields on or near Earth’s surface due to rectangular faults in an anisotropic half-space,expressed as a summation of(A)the solution in an infinite spa...We present a new solution for the elastic displacement and strain fields on or near Earth’s surface due to rectangular faults in an anisotropic half-space,expressed as a summation of(A)the solution in an infinite space which is singular,and(B)the complementary part which is regular and well-behaved.These two solutions are expressed in terms of the mathematically elegant and computationally powerful Stroh formalism and can be applied to the generally anisotropic rock half-space or a transversely isotropic rock mass with any oriented plane of isotropy.For any flat fault of polygonal shape,one needs only to carry out a simple line integral from 0 to 7 r in order to express the fault-induced response.Numerical examples are presented to demonstrate the significant effect of the rock anisotropy and layer orientation on the fault-induced displacement and strain fields in anisotropic rocks.Potential applications are wide ranging,from faults in sedimentary strata to strongly deformed metamorphic rocks with steeply dipping foliation.展开更多
Appearing in the composite spectral data of BATSE, EGRET and COMPTEL for GRB 910503, there is a bump at around 1600keV. We perform a statistical analysis on the spectral data, trying to find out if the bump could be a...Appearing in the composite spectral data of BATSE, EGRET and COMPTEL for GRB 910503, there is a bump at around 1600keV. We perform a statistical analysis on the spectral data, trying to find out if the bump could be accounted for by a blue-shifted and significantly broadened rest frame line due to the Doppler effect of an expanding fireball surface. We made an F-test and adopted previously proposed criteria. The study reveals that the criteria are well satisfied and the feature can be interpreted as the blue shifted 6.4 keV line. From the fit with this line taken into account, we find the Lorentz factor of this source to be F = 116-9^+9 (at the 68% confident level, △X^2 = 1) and the rest frame spectral peak energy to be E0,p=2.96-0.18^+0.24 ke V.Although the existence of the emission line feature requires other independent tests to confirm, the analysis suggests that it is feasible to detect emission line features in the high energy range of GRB spectra when taking into account the Doppler effect of fireball expansion.展开更多
The Konigl inhomogeneous jet model can successfully reproduce most observational features of jets in active galactic nuclei (AGN), when suitable physical parameters are adopted. We improve Konigl's calculations on ...The Konigl inhomogeneous jet model can successfully reproduce most observational features of jets in active galactic nuclei (AGN), when suitable physical parameters are adopted. We improve Konigl's calculations on the core emission from the jet with a small viewing angle θ0 - φ (φ is half opening angle of the conical jet). The proper motion of the jet component provides a constraint on the jet kinematics. Based on the inhomogeneous jet model, we use the proper motion data of the jet component to calculate the minimal kinetic luminosity of the jet required to reproduce the core emission measured by the very-long- baseline interferometry (VLBI) for a sample of BL Lac objects. Our results show that the minimal kinetic luminosity is slightly higher than the bolometric luminosity for most sources in the sample, which implies that radiatively inefficient accretion flows (RIAFs) may be in those BL Lac objects, or/and the properties of their broad-line regions (BLRs) are significantly different from flat-spectrum radio-loud quasars.展开更多
The cosmological constant A is the simplest model for explaining the dark energy which supposedly drives the observed accelerated expansion rate of the Universe. Together with the concept of cold dark matter, it satis...The cosmological constant A is the simplest model for explaining the dark energy which supposedly drives the observed accelerated expansion rate of the Universe. Together with the concept of cold dark matter, it satisfactorily accommo- dates a wealth of observations related to cosmology. Due to its assumed constancy throughout the Universe, A might also affect the dynamics of the planets in the so- lar system, although with extremely small effects. However, modern high-precision ephemerides provide a promising tool for constraining it. Using the supplementary advances in the perihelia provided by current INPOP10a and EPM2011 ephemerides, we obtain a new upper limit on A in the solar system when the Lense-Thirring ef- fect due to the Sun's angular momentum and the uncertainty of the Sun's quadrupole moment are properly taken into account. These two factors were mostly absent in pre- vious works dealing with A. We find that INPOP10a yields an upper limit of A = (0.26±1.45) × 10^-43 m^-2 and EPM2011 gives A = (-0.44 4±8.93) × 10^-43 m^-2. Such bounds are about 10 times less than previously estimated results.展开更多
Given the booming of internet usage in its domain, Chinese on-line shopping business is not growing proportionately. The absence of a market mechanism based on trust among suppliers and customers is to blame, although...Given the booming of internet usage in its domain, Chinese on-line shopping business is not growing proportionately. The absence of a market mechanism based on trust among suppliers and customers is to blame, although other factors as well holding the responsibility. Beginning with an introduction to the theory of "lemons", this paper reviews the status quo of trust in the Chinese cyber market, from the perspective of legislation, regulation and institution. It also prescribes several possible micro-solutions.展开更多
基金National H-Tech Program under contract 863-7152101
文摘The rate of hydrothermal reaction of SiO_2 and/or A1_2O_3 in the system of CaO-Al_2O_3-SiO_2-H_2O at 200℃ and the factors which influence the reactions are investigated by determining the reaction ratio.The rate of reactions depends on the reactive activities of raw materials, initial composition of mixture and relative activity of SiO_2 and A12O3. The hydrothermal reaction can be accelerated by sodium hydroxide,in the case of silica,which has low activity, this is quite obvious.
基金Financial supports for this work, provided by the National Natural Science Foundation of China (No. 51274097)the Scientific Research Fund of Hunan Provincial Education Department of China (No. 13A020)the Open Projects of State Key Laboratory of Coal Resources and Safe Mining, CUMT (No. 13KF03)
文摘In order to study the mechanism of water inrush from a concealed, confined karst cave, we established a fluid–solid coupling model of water inrush from a concealed karst cave ahead of a roadway and a strength reduction method in a rock pillar for preventing water inrush based on catastrophic theory. Fluid–solid coupling effects and safety margins in a rock pillar were studied. Analysis shows that rock pillar instability, exerted by disturbance stress and seepage stress, is the process of rock pillar catastrophic destabilization induced by nonlinear extension of plastic zones in the rock pillar. Seepage flow emerges in the rock pillar for preventing water inrush, accompanied by mechanical instability of the rock pillar. Taking the accident of a confined karst cave water-inrush of Qiyi Mine as an example, by studying the safety factor of the rock pillar and the relationship between karst cave water pressure and thickness of the rock pillar,it is proposed that rock pillar thickness with a safety factor equal to 1.5 is regarded as the calculated safety thickness of the rock pillar, which should be equal to the sum of the blasthole depth, blasting disturbance depth and the calculated safety thickness of the rock pillar. The cause of the karst water inrush at Qiyi Mine is that the rock pillar was so small that it did not possess a safety margin. Combining fluid–solid coupling theory, catastrophic theory and strength reduction method to study the nonlinear mechanical response of complicated rock engineering, new avenues for quantitative analysis of rock engineering stability evaluation should be forthcoming.
文摘The unsteady condition of rolling Mill vibration that was caused by flexural vibration of strip was investigated. The parametric flexural vibration equation of rolled strip was established. The parametric flexural vibration stability of rolled strip was studied and region of stability and unstability was determined based on Floquet theory and perturbation method. The flexural-vibration of strip was unstable if the frequency of variable tension was twice as the natural frequency of flexural-vibration strip. The characteristics of electric current in a temp driving motor’s main loop was studied and tested, and approved that there were 6 humorous current ponderance and 12 humorous current ponderance in main circuit of driving motor. Vertical vibration of working roller was tested, the test approved that there were running unsteady caused by parametric vibration. It attached importance to the parametric vibration of rolling mill.
基金Supported by National Natural Science Foundation of China(Grant No.51575150)
文摘The theoretical research of cable-driven mechanisms is developed with its broad applications. The first prototype of cable-driven mechanisms is RoboCrane, which was developed by the National Institute of Standards and Technology (NIST). Then many excellent properties were developed and they have a variety of applications such as aerospace, aircraft and automobile industries [1]. Example application for RoboCrane in the field of aircraft mainte- nance is equipped with a quick-change mechanism to remove the robot arm remotely.
文摘The article discusses the early abandonment of mechanical theories about eye enlargement in degenerative myopia at the turn of the 20th century.At that time,the number of theories about myopia grew unrestricted,but with scant support from the experimental field.The mechanical theories vanished as a new wave of metabolism-based theories appeared,propelled by the huge advances in molecular biology.Modern techniques allow reconsidering those theories and to put them to test with higher confidence.
文摘In this paper we consider that the momentum of a free particle motion withhigh-level speed presenting nonlinear effects may be expanded by using Laurent seriesand then obtain the complete expression of nonlinear and unsteady momentum. These nonlinear and unsieady phenoniena of high-level speed may further expand to the theory of kinematics and it may be determined by Fredholm's integral equation of the first kind. In addition, according to the nonlinear and unsteady momentum obtained the relations of the nonlinear mechanics equations .work and energy, mass and energymay be derived.Finaly .this paper also calculates those experimental results which done in particle physics for mu-mesons u±and fast neutrons n, these results are in agreement with data perfectly.
基金This is a comprehensive report at the Second National Symposium on Modern Mathematics and MechanicsProject Supported by the Science Foundation of the Chinese Academy of Sciences
文摘As is Wellknown in both elastic mechanics andfluid mechanics, the plane problems are more convenient than space problems. One of the causes is that there has been a complete theory about the complex Junction and the analytic junction, hut in space problems, the case is quite different.We have no effective method to deal with these problems. In this paper, we first introduces general theories of Clifford algebra. Then we emphatically explain Clifford algebra in three dimensions and establish theories of regular Junction in three dimensions analogically to analytic function in plane. Thus we extend some results of plane problem-la three dimensions or high dimensions. Obviously, it is very important for elastic and fluid mechanics. But because Clifford algebra is not a commutative algebra, we can't simply extend the results of two dimensions to high dimensions. The left problems are yet to be found out.
文摘This research aims to integrate Bekenstein’s bound and Landauer’s principle, providing a unified framework to understand the limits of information and energy in physical systems. By combining these principles, we explore the implications for black hole thermodynamics, astrophysics, astronomy, information theory, and the search for new laws of nature. The result includes an estimation of the number of bits stored in a black hole (less than 1.4 × 10<sup>30</sup> bits/m<sup>3</sup>), enhancing our understanding of information storage in extreme gravitational environments. This integration offers valuable insights into the fundamental nature of information and energy, impacting scientific advancements in multiple disciplines.
基金supported by the National Basic Research Program of China (No2007CB607506)the NSFC's program(No90405005)+1 种基金the PhD Fund (No20050730016)the Fund of the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing(Wuhan University of Technology)(NoWUT2005Z04)
文摘As an important component of nanodevices and nanomachine constructions, the mechanical performance of nanowires (NWs) has been a subject of intense research efforts due to gaining relevance in controlling functionality of nanoelectromechanical systems (NEMS); meanwhile, one of the characteristics of the NEMS is the dependence of the functionality of the systems upon the applied electric field. The study of the electric effects on the Young's modulus of nanostructures is of certain usefulness in the design of NEMS and the precise measurement of mechanical properties of one-dimensional nanostructures. This paper reviews the origin of the size-dependence of the elastic property of NWs and the factors influencing the discrepancies and inconsistencies in the measured values of the Young's modulus for the NW, besides the surface effects, nonlinear effects, the electromechanical coupling effects as a possible effect responsible for the differences in quantitative and qualitative performance of the measured Young's modulus for the NWs versus the diameter are clarified.
基金Supported by National Natural Science Foundation of China(Grant Nos.51175029,51475035)
文摘Conventional overconstrained parallel manipulators have been widely studied both in industry and academia,however the structural synthesis of hybrid mechanisms with additional constraints is seldom studied,especially for the four degrees of freedom(DOF) hybrid mechanisms.In order to develop a manipulator with additional constraints,a class of important spatial mechanisms with coupling chains(CCs) whose motion type is two rotations and two translations(2R2T) is presented.Based on screw theory,the combination of different types of limbs which are used to construct parallel mechanisms and coupling chains is proposed.The basic types of the general parallel mechanisms and geometric conditions of the kinematic chains are given using constraint synthesis method.Moreover,the 2R2T motion pattern hybrid mechanisms which are derived by adding coupling chains between different serial kinematic chains(SKCs) of the corresponding parallel mechanisms are presented.According to the constraint analysis of the mechanisms,the movement relationship of the moving platform and the kinematic chains is derived by disassembling the coupling chains.At last,fourteen novel hybrid mechanisms with two or three serial kinematic chains are presented.The proposed novel hybrid mechanisms and construction method enrich the family of the spatial mechanisms and provide an instruction to design more complex hybrid mechanisms.
基金financial support from the National Natural Science Foundation of China (51576064, 51676193)Beijing Nova Program (Z171100001117064)+2 种基金Beijing Natural Science Foundation (3172030)the Foundation of Stake Key Laboratory of Coal Combustion (FSKLCCA1706)the Fundamental Research Funds for the Central Universities (2017MS071, 2016YQ05)
文摘Fast pyrolysis of biomass will produce various furan derivatives, among which 5-hydroxymethyl furfural(5-HMF) and furfural(FF) are usually the two most important compounds derived from holocellulose. In this study, density functional theory(DFT) calculations are utilized to reveal the formation mechanisms and pathways of 5-HMF and FF from two hexose units of holocellulose, i.e., glucose and mannose. In addition, fast pyrolysis experiments of glucose and mannose are conducted to substantiate the computational results, and the orientation of 5-HMF and FF is determined by 13C-labeled glucoses. Experimental results indicate that C1 provides the aldehyde group in both 5-HMF and FF, and FF is mainly derived from C1 to C5 segment. According to the computational results, glucose and mannose have similar reaction pathways to form 5-HMF and FF with d-fructose(DF) and 3-deoxy-glucosone(3-DG) as the key intermediates. 5-HMF and FF are formed via competing pathways. The formation of 5-HMF is more competitive than that of FF, leading to higher yield of 5-HMF than FF from both hexoses. In addition, compared with glucose,mannose can form 5-HMF and FF via extra pathways because of the epimerization at C2 position. Therefore, mannose pyrolysis results in higher yields of 5-HMF and FF than glucose pyrolysis.
基金supported by the National Natural Science Foundation of China(Grant No.11173020)the National Basic Research Program of China(973Program,2009CB824800)
文摘The nonthermal components in hard X-rays have been detected in two young supernova remnants (SNRs): SN 1006 and Kepler's SNR. Various theoretical models showed that the amplification of the magnetic field was crucial to explain their multiband emission properties. We investigate the evolution of the magnetic field and model the multiband emissions from these two young SNRs with a time-dependent injection model. The results indicate that (1) the radio and X-ray emissions are re- produced by synchrotron radiation of the injected electrons, while the y-rays can be explained as inverse Compton scattering of the relativistic electrons and proton-proton interaction of the high-energy protons; and (2) the amplification of the magnetic field spontaneously happens with reasonable parameters.
文摘Based on the principal-agent theory, this paper analyzes the current situation and the developing trends of Chinese private enterprises. It points out the obstacles confronted by Chinese private enterprise in setting up the principal-agent mechanism and proposes the corresponding solutions to these problems.
文摘Using density functional theory,noncovalent interactions and four mechanisms of covalent functionalization of capecitabine anticancer drug onto γ-Fe2O3 nanoparticles have been investigated.Quantum molecular descriptors of noncovalent configurations were studied.It was specified that binding of capecitabine onto γ-Fe2O3 nanoparticles is thermodynamically suitable.Hardness and the gap of energy between LUMO and HOMO of capecitabine are higher than the noncovalent configurations,showing the reactivity of capecitabine increases in the presence of γ-Fe2O3 nanoparticles.Capecitabine can bond to γ-Fe2O3 nanoparticles through OH(k1 mechanism),NH(k2 mechanism),CO(k3 mechanism) and F(k4 mechanism) groups.The activation energies,activation enthalpies and activation Gibbs free energies of these reactions were calculated.It was specified that the k1 and k2 mechanisms are under thermodynamic control and k3 and k4 under kinetic control.These results could be generalized to other similar drugs.
基金the China Scholarship Council(CSC) for supporting her visit at the University of Akron
文摘We present a new solution for the elastic displacement and strain fields on or near Earth’s surface due to rectangular faults in an anisotropic half-space,expressed as a summation of(A)the solution in an infinite space which is singular,and(B)the complementary part which is regular and well-behaved.These two solutions are expressed in terms of the mathematically elegant and computationally powerful Stroh formalism and can be applied to the generally anisotropic rock half-space or a transversely isotropic rock mass with any oriented plane of isotropy.For any flat fault of polygonal shape,one needs only to carry out a simple line integral from 0 to 7 r in order to express the fault-induced response.Numerical examples are presented to demonstrate the significant effect of the rock anisotropy and layer orientation on the fault-induced displacement and strain fields in anisotropic rocks.Potential applications are wide ranging,from faults in sedimentary strata to strongly deformed metamorphic rocks with steeply dipping foliation.
基金Supported by the National Natural Science Foundation of China.
文摘Appearing in the composite spectral data of BATSE, EGRET and COMPTEL for GRB 910503, there is a bump at around 1600keV. We perform a statistical analysis on the spectral data, trying to find out if the bump could be accounted for by a blue-shifted and significantly broadened rest frame line due to the Doppler effect of an expanding fireball surface. We made an F-test and adopted previously proposed criteria. The study reveals that the criteria are well satisfied and the feature can be interpreted as the blue shifted 6.4 keV line. From the fit with this line taken into account, we find the Lorentz factor of this source to be F = 116-9^+9 (at the 68% confident level, △X^2 = 1) and the rest frame spectral peak energy to be E0,p=2.96-0.18^+0.24 ke V.Although the existence of the emission line feature requires other independent tests to confirm, the analysis suggests that it is feasible to detect emission line features in the high energy range of GRB spectra when taking into account the Doppler effect of fireball expansion.
基金Supported by the National Natural Science Foundation of China.
文摘The Konigl inhomogeneous jet model can successfully reproduce most observational features of jets in active galactic nuclei (AGN), when suitable physical parameters are adopted. We improve Konigl's calculations on the core emission from the jet with a small viewing angle θ0 - φ (φ is half opening angle of the conical jet). The proper motion of the jet component provides a constraint on the jet kinematics. Based on the inhomogeneous jet model, we use the proper motion data of the jet component to calculate the minimal kinetic luminosity of the jet required to reproduce the core emission measured by the very-long- baseline interferometry (VLBI) for a sample of BL Lac objects. Our results show that the minimal kinetic luminosity is slightly higher than the bolometric luminosity for most sources in the sample, which implies that radiatively inefficient accretion flows (RIAFs) may be in those BL Lac objects, or/and the properties of their broad-line regions (BLRs) are significantly different from flat-spectrum radio-loud quasars.
基金Supported by the National Natural Science Foundation of China
文摘The cosmological constant A is the simplest model for explaining the dark energy which supposedly drives the observed accelerated expansion rate of the Universe. Together with the concept of cold dark matter, it satisfactorily accommo- dates a wealth of observations related to cosmology. Due to its assumed constancy throughout the Universe, A might also affect the dynamics of the planets in the so- lar system, although with extremely small effects. However, modern high-precision ephemerides provide a promising tool for constraining it. Using the supplementary advances in the perihelia provided by current INPOP10a and EPM2011 ephemerides, we obtain a new upper limit on A in the solar system when the Lense-Thirring ef- fect due to the Sun's angular momentum and the uncertainty of the Sun's quadrupole moment are properly taken into account. These two factors were mostly absent in pre- vious works dealing with A. We find that INPOP10a yields an upper limit of A = (0.26±1.45) × 10^-43 m^-2 and EPM2011 gives A = (-0.44 4±8.93) × 10^-43 m^-2. Such bounds are about 10 times less than previously estimated results.
文摘Given the booming of internet usage in its domain, Chinese on-line shopping business is not growing proportionately. The absence of a market mechanism based on trust among suppliers and customers is to blame, although other factors as well holding the responsibility. Beginning with an introduction to the theory of "lemons", this paper reviews the status quo of trust in the Chinese cyber market, from the perspective of legislation, regulation and institution. It also prescribes several possible micro-solutions.