Glasses based on ZnO-Bi_2O_3-B_2O_3 system are expected to be a new kind of sealing glasses because of their low melting temperature and other properties.In order to reveal the effect of B_2O_3 on the rheological beha...Glasses based on ZnO-Bi_2O_3-B_2O_3 system are expected to be a new kind of sealing glasses because of their low melting temperature and other properties.In order to reveal the effect of B_2O_3 on the rheological behavior of ZnO-Bi_2O_3-B_2O_3 system glass melt,the properties of viscosity,thermal expansion,fluxion property and wetting process between cylinder samples and stainless steel were investigated with the rotating crucible viscometer,dilato meter and high-temperature microscope.The structure of sintered glass samples was investigated with scanning electron microscope.The results show that the B_2O_3 content increasing in B_1-B_3 at the given temperature between 400 ℃ and 500 ℃ leads to the increasing of the sample viscosity.When the amount of B_2O_3 increases from 5.24%to 9.24%(mass fraction),the coefficients of thermal expansion of glass samples decrease smoothly from 10.94×10^(-6) to10.71×10^(-6) and 10.38×10^(-6) ℃^(-1) respectively.In the case of sealing temperature,its value increases from 453 ℃ to 494 ℃.ZnO-Bi_2O_3-B_2O_3 system low-melting glass powder sintering was with viscous liquid to participate,which could make the densification of glass sample more effective and more efficient.With the content of B_2O_3 increasing,the wetting angle between the glasses samples and stainless steel could also increase,and the resulting appropriate sealing temperature range is 460-490 ℃.展开更多
The Bi_2(Sr,Ca)_3Cu_2O_x system superconductor was prepared by different melting procedures and after treatment.The effects of cooling rate,annealing temperature and time,as well as melting procedures on phase transfo...The Bi_2(Sr,Ca)_3Cu_2O_x system superconductor was prepared by different melting procedures and after treatment.The effects of cooling rate,annealing temperature and time,as well as melting procedures on phase transformation were investigated.The structure and properties were examined by X-ray diffraction,optical microscopy,EPMA,DTA,TGA and measurements of electric and magnetic properties.When the melt of nominal composition Bi_2(Sr,Ca)_3Cu_2O_x solidified in air,the Bi_2(Sr,Ca)_3Cu_2O_(8+δ)(2212)superconducting phase is stable,the easily solidified product including Bi_2(Sr,Ca)_2CuO_(6+δ)(2201)phase is metastable, and another may be amorphous if rapidly quenched.The last two may transform into 2212 phase by after treatment at an optimal annealing temperature ranging 780—870℃.While 2201 phase,prepared by the laser floating zone melting method,may easily transform into 2212 phase at layer or filament in shape which is favourable to improve the links among superconducting grains and critical current density.展开更多
基金Project(2012BAA08B04)supported by the National“Twelfth Five-Year”Plan for Science&Technology Support of China
文摘Glasses based on ZnO-Bi_2O_3-B_2O_3 system are expected to be a new kind of sealing glasses because of their low melting temperature and other properties.In order to reveal the effect of B_2O_3 on the rheological behavior of ZnO-Bi_2O_3-B_2O_3 system glass melt,the properties of viscosity,thermal expansion,fluxion property and wetting process between cylinder samples and stainless steel were investigated with the rotating crucible viscometer,dilato meter and high-temperature microscope.The structure of sintered glass samples was investigated with scanning electron microscope.The results show that the B_2O_3 content increasing in B_1-B_3 at the given temperature between 400 ℃ and 500 ℃ leads to the increasing of the sample viscosity.When the amount of B_2O_3 increases from 5.24%to 9.24%(mass fraction),the coefficients of thermal expansion of glass samples decrease smoothly from 10.94×10^(-6) to10.71×10^(-6) and 10.38×10^(-6) ℃^(-1) respectively.In the case of sealing temperature,its value increases from 453 ℃ to 494 ℃.ZnO-Bi_2O_3-B_2O_3 system low-melting glass powder sintering was with viscous liquid to participate,which could make the densification of glass sample more effective and more efficient.With the content of B_2O_3 increasing,the wetting angle between the glasses samples and stainless steel could also increase,and the resulting appropriate sealing temperature range is 460-490 ℃.
文摘The Bi_2(Sr,Ca)_3Cu_2O_x system superconductor was prepared by different melting procedures and after treatment.The effects of cooling rate,annealing temperature and time,as well as melting procedures on phase transformation were investigated.The structure and properties were examined by X-ray diffraction,optical microscopy,EPMA,DTA,TGA and measurements of electric and magnetic properties.When the melt of nominal composition Bi_2(Sr,Ca)_3Cu_2O_x solidified in air,the Bi_2(Sr,Ca)_3Cu_2O_(8+δ)(2212)superconducting phase is stable,the easily solidified product including Bi_2(Sr,Ca)_2CuO_(6+δ)(2201)phase is metastable, and another may be amorphous if rapidly quenched.The last two may transform into 2212 phase by after treatment at an optimal annealing temperature ranging 780—870℃.While 2201 phase,prepared by the laser floating zone melting method,may easily transform into 2212 phase at layer or filament in shape which is favourable to improve the links among superconducting grains and critical current density.
