Losses of the alloying elements during vacuum induction melting of the binary NiTi alloys were evaluated by visual observation and chemical analysis of the NiTi melted specimens and the scalp formed on the internal su...Losses of the alloying elements during vacuum induction melting of the binary NiTi alloys were evaluated by visual observation and chemical analysis of the NiTi melted specimens and the scalp formed on the internal surface of the crucible. The results indicated that the major sources of the losses were （a） evaporation of the metals, （b） formation of the NiTi scalp and （c） the sprinkling drops splashed out of the melt due to the exothermic reactions occurring between Ni and Ti to form the NiTi parent phase. Quantitative evaluations were made for the metallic losses by holding the molten alloy for 0.5, 3, 5, 10 and 15 min at around 100℃ above the melting point inside the crucible.Chemical analysis showed that there existed an optimum holding time of 3 min during which the alloying elements were only dropped to a predictable limit. Microstructure, chemical composition, shape memory and mechanical properties of the cast metal ingots were determined to indicate the appropriate achievements with the specified 3 min optimum holding time.展开更多
在连铸流程生产Incoloy825耐蚀合金时,AOD精炼过程中精炼渣易与合金中Al、Ti元素发生反应造成氧化损失。因此,本研究在1 kg MoSi2电阻炉中通过渣-金平衡试验考察了(CaO-SiO_(2)-Al_(2)O_(3)-MgO-CaF_(2)-TiO_(2))精炼渣系不同成分设计对...在连铸流程生产Incoloy825耐蚀合金时,AOD精炼过程中精炼渣易与合金中Al、Ti元素发生反应造成氧化损失。因此,本研究在1 kg MoSi2电阻炉中通过渣-金平衡试验考察了(CaO-SiO_(2)-Al_(2)O_(3)-MgO-CaF_(2)-TiO_(2))精炼渣系不同成分设计对Incoloy825合金Al、Ti氧化烧损的影响,并对渣系的熔点、黏度以及物相性质进行了分析。结果表明:增加SiO_(2)的含量能降低平衡时合金中Al、Ti的含量,Al_(2)O_(3)组元会造成烧钛增铝的现象,适量TiO_(2)可以降低Ti元素的氧化烧损。提高渣系中CaO、TiO_(2)含量能提高精炼渣熔点,渣中SiO_(2)、Al_(2)O_(3)及CaF_(2)的含量增加会导致熔点下降;高温下精炼渣的黏度变化小且有明显的温度转折点,属于短渣类型,转折温度与熔点的规律一致;精炼渣配比为49.87%CaO-2.13%SiO_(2)-24.79%Al_(2)O_(3)-7.40%MgO-4.79%CaF_(2)-9.87%TiO_(2)时,Al、Ti烧损小且熔点和黏度均满足精炼要求。展开更多
文摘Losses of the alloying elements during vacuum induction melting of the binary NiTi alloys were evaluated by visual observation and chemical analysis of the NiTi melted specimens and the scalp formed on the internal surface of the crucible. The results indicated that the major sources of the losses were （a） evaporation of the metals, （b） formation of the NiTi scalp and （c） the sprinkling drops splashed out of the melt due to the exothermic reactions occurring between Ni and Ti to form the NiTi parent phase. Quantitative evaluations were made for the metallic losses by holding the molten alloy for 0.5, 3, 5, 10 and 15 min at around 100℃ above the melting point inside the crucible.Chemical analysis showed that there existed an optimum holding time of 3 min during which the alloying elements were only dropped to a predictable limit. Microstructure, chemical composition, shape memory and mechanical properties of the cast metal ingots were determined to indicate the appropriate achievements with the specified 3 min optimum holding time.
文摘在连铸流程生产Incoloy825耐蚀合金时,AOD精炼过程中精炼渣易与合金中Al、Ti元素发生反应造成氧化损失。因此,本研究在1 kg MoSi2电阻炉中通过渣-金平衡试验考察了(CaO-SiO_(2)-Al_(2)O_(3)-MgO-CaF_(2)-TiO_(2))精炼渣系不同成分设计对Incoloy825合金Al、Ti氧化烧损的影响,并对渣系的熔点、黏度以及物相性质进行了分析。结果表明:增加SiO_(2)的含量能降低平衡时合金中Al、Ti的含量,Al_(2)O_(3)组元会造成烧钛增铝的现象,适量TiO_(2)可以降低Ti元素的氧化烧损。提高渣系中CaO、TiO_(2)含量能提高精炼渣熔点,渣中SiO_(2)、Al_(2)O_(3)及CaF_(2)的含量增加会导致熔点下降;高温下精炼渣的黏度变化小且有明显的温度转折点,属于短渣类型,转折温度与熔点的规律一致;精炼渣配比为49.87%CaO-2.13%SiO_(2)-24.79%Al_(2)O_(3)-7.40%MgO-4.79%CaF_(2)-9.87%TiO_(2)时,Al、Ti烧损小且熔点和黏度均满足精炼要求。
