Cryogenic treatment was used to improve the tribological properties of Ti6Al4V artificial hip joint implants.Cryogenic treatment at-196℃with different holding time were carried out on Ti6Al4V specimens fabricated usi...Cryogenic treatment was used to improve the tribological properties of Ti6Al4V artificial hip joint implants.Cryogenic treatment at-196℃with different holding time were carried out on Ti6Al4V specimens fabricated using electron beam melting(EBM),and their microstructure and tribological properties evolution were systematically analyzed by scanning electron microscopy(SEM),vickers hardness,and wear tests.The experimental results show that the as-fabricated specimen consists of lamellarαphase andβcolumnar crystal.While,the thickness of lamellarαphase decreased after cryogenic treatment.In addition,it can be found that the fineαphase was precipitated and dispersed between the lamellarαphase with the holding time increase.Vickers hardness shows a trend of first increasing and then decreasing.The wear rate of the specimen cryogenic treated for 24 h is the minimum and the average friction coefficient is 0.50,which is reduced by 14.61%compared with the as-fabricated.The wear mechanism of the as-fabricated specimen is severe exfoliation,adhesive,abrasive,and slight fatigue wear.However,the specimen cryogenic treated for 24 h shows slight adhesive and abrasive wear.It can be concluded that it is feasibility of utilizing cryogenic treatment to reduce the wear of EBMed Ti6Al4V.展开更多
In the context of global carbon neutrality, the application of lightweight magnesium alloys is becoming increasingly attractive. In this study, selective laser melting(SLM) was employed to achieve nearly full dense an...In the context of global carbon neutrality, the application of lightweight magnesium alloys is becoming increasingly attractive. In this study, selective laser melting(SLM) was employed to achieve nearly full dense and crack-free AZ91D components with fine equiaxed grain structure. The formation mechanism of typical pore defects(gas pore, lack-of-fusion pore and keyhole pore) and melting modes(keyhole mode and conduction mode) were systematically studied by varying the laser power and scanning speed. The morphology and volume fraction of the pores under different processing conditions were characterized. A criterion based on the depth-to-width ratio of the melt pool was established to identify different melting modes. The strength and ductility(tensile strength up to 340 MPa and uniform elongation of 8.9%)of the as deposited AZ91D are far superior to those of the casting components and are comparable to those of its wrought counterparts.The superior balance of strength and ductility of SLMed AZ91D, as well as the negligible anisotropic properties are mainly ascribed to the extremely fine equiaxed grain structure(with average grain size of ~1.2 μm), as well as the discontinuous distribution of β-Al_(12)Mg_(17) phases. It thus provides an alternative way to fabricate high-strength magnesium alloys with complex geometry.展开更多
To develop large-scale RP systems used to producing functional parts and large-sized models has become an urgentcall now. In this paper, a large-scale RP system, MEM600-l, based on the melted extrusion manufacturing (...To develop large-scale RP systems used to producing functional parts and large-sized models has become an urgentcall now. In this paper, a large-scale RP system, MEM600-l, based on the melted extrusion manufacturing (MEM)process has been developed successfully. And the key issues to develop such a system are discussed. Based on theactual forming experiment, it is concluded that the MEM600-l works reliably and the forming efficiency is muchhigher than its parallel equipments.展开更多
The characteristics of some elements in inoculant were analyzed.The effect of the morphology of instantaneous inoculant on its melting velocity was studied.When the inoculants pass through the same sieve number,the vo...The characteristics of some elements in inoculant were analyzed.The effect of the morphology of instantaneous inoculant on its melting velocity was studied.When the inoculants pass through the same sieve number,the volume and the ratio of surface area to volume are different.It is evident from the theoretical analysis and experiment under some conditions that the melting velocity of inoculant depends on the morphology of inoculant.The morphology of inoculant during production should be controlled carefully.展开更多
Selective laser melting(SLM)is an emerging additive manufacturing technology for fabricating aluminum alloys and aluminum matrix composites.Nevertheless,it remains unclear how to improve the properties of laser manufa...Selective laser melting(SLM)is an emerging additive manufacturing technology for fabricating aluminum alloys and aluminum matrix composites.Nevertheless,it remains unclear how to improve the properties of laser manufactured aluminum alloy by adding ceramic reinforcing particles.Here the effect of trace addition of TiB2 ceramic(1%weight fraction)on microstructural and mechanical properties of SLM-produced AlSi10Mg composite parts was investigated.The densification level increased with increasing laser power and decreasing scan speed.A near fully dense composite part(99.37%)with smooth surface morphology and elevated inter-layer bonding was successfully obtained.A decrease of lattice plane distance was identified by X-ray diffraction with the laser scan speed decreased,which implied that the crystal lattices were distorted due to the dissolution of Si and TiB2 particles.A homogeneous composite microstructure with the distribution of surface-smoothened TiB2 particles was present,and a small amount of Si particles precipitated at the interface between reinforcing particles and matrix.In contrast to the AlSi10Mg alloy,the composites showed a stabilized microhardness distribution.A higher ultimate tensile strength of 380.0 MPa,yield strength of 250.4 MPa and elongation of 3.43%were obtained even with a trace amount of ceramic addition.The improvement of tensile properties can be attributed to multiple mechanisms including solid solution strengthening,load-bearing strengthening and dispersion strengthening.This research provides a theoretical basis for ceramic reinforced aluminum matrix composites by additive manufacturing.展开更多
New materials and manufacturing technologies require applicable non-destructive techniques for quality assurance so as to achieve better performance.This study comprehensively investigated the effect of influencing fa...New materials and manufacturing technologies require applicable non-destructive techniques for quality assurance so as to achieve better performance.This study comprehensively investigated the effect of influencing factors includ-ing excitation frequency,lift-off distance,defect depth and size,residual heat,and surface roughness on the defect EC signals of an Inconel 738LC alloy produced by selective laser melting(SLM).The experimental investigations recorded the impedance amplitude and phase angle of EC signals for each defect to explore the feasibility of detecting sub-surface defects by merely analyzing these two key indicators.Overall,this study revealed preliminary qualitative and roughly quantitative relationships between influencing factors and corresponding EC signals,which provided a prac-tical reference on how to quantitively inspect subsurface defects using eddy current testing(ECT)on SLMed parts,and also made solid progress toward on-line ECT in additive/subtractive hybrid manufacturing(ASHM)for fabricating SLMed parts with enhanced quality and better performance.展开更多
Sequential melting theory is applied to reteal that fluctuation of chemical composition ofmelted iron in cupola is caused by the process of sequential melting. Fluctuation is incvitable andcyclc. Usting microcornputer...Sequential melting theory is applied to reteal that fluctuation of chemical composition ofmelted iron in cupola is caused by the process of sequential melting. Fluctuation is incvitable andcyclc. Usting microcornputer dynamic simulation has confirmed that the fluctuation situation ofchemical composition cf melted iron is contistent with actuaa production on the whole.展开更多
An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction ...An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction (XRD) was used to identify the phases. Microstructure and properties of laser melted layer of AZ31B magnesium alloy were observed or tested by means of optical microscope (OM), scanning electron microscope (SEM), micro-hardness equipment and electrochemical corrosion equipment etc. The results show that the microstructure of laser melted layer becomes finer significantly and uniform. Compared with the substrate, the content of β-Mg17 Al12 phase of melted layer decreases comparatively. Microhardness of the laser melted layer is improved to 50 -95 HV0. 05 as compared to 40 -45 HV0.05 of the AZ31B Mg alloy substrate. The results of electrochemical corrosion show that the corrosion resistance of laser surface melted layer has been improved.展开更多
Selective laser melted AlSi10Mg alloys with eutectic network structures were successfully joined by friction stir welding.Sound butt-lap joints have been achieved.A novel enlarged pin was designed to overcome kissing ...Selective laser melted AlSi10Mg alloys with eutectic network structures were successfully joined by friction stir welding.Sound butt-lap joints have been achieved.A novel enlarged pin was designed to overcome kissing bonding defects and increase interfacial bonding area.The hook defect in a conventional butt-lap joint was avoided due to the limitation of the upward flow of interfacial materials,and the interfacial joining width was 2.5 times of the plate thickness.The eutectic Si network structure was broken into the re-dispersed rich-Si phases,improving joint performance.The ultimate tensile strength reached 83.1%of the matrix,higher than those of conventional melting techniques.展开更多
The effects of vacuum induction melting(VIM) and vacuum arc remelting(VAR) processes on the microstructure and stress rupture properties of Ni-based GTD-111 superalloy were investigated. Samples of GTD-111 master allo...The effects of vacuum induction melting(VIM) and vacuum arc remelting(VAR) processes on the microstructure and stress rupture properties of Ni-based GTD-111 superalloy were investigated. Samples of GTD-111 master alloy were melted in VIM and VAR furnaces and then poured into a preheated ceramic mold for VIM melt or into a water-cooled copper mold for VAR melt. The as-cast samples were examined radiographically to ensure that no casting defects were present in the final castings; the samples were then heat-treated using a standard heat-treatment cycle. The microstructure of the samples was investigated using optical microscopy and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy for microanalysis. On the basis of standard ASTM-E139, stress rupture tests were carried out at 1000°C under a stress of 300 MPa. The results showed that a γ matrix, fine γ′ precipitates, a γ–γ′ eutectic structure, carbide particles, and some harmful phases such as σ and η phases were present in the as-cast samples. The γ′ precipitates with cubic morphology appeared in the matrix after the standard heat-treatment process. The extent of segregation and the amount of γ–γ′ eutectic structure formed in the VAR-prepared sample were less than in the VIM-prepared sample. The results of stress rupture tests showed that the rupture time for the VAR sample was 43% longer than that for the VIM sample.展开更多
Oxygen is crucial in influencing the microstructure evolution of selective laser melted(SLMed)Ti–6Al–4V,significantly impacting its applicability in various sectors.Therefore,this study investigates the influnce of ...Oxygen is crucial in influencing the microstructure evolution of selective laser melted(SLMed)Ti–6Al–4V,significantly impacting its applicability in various sectors.Therefore,this study investigates the influnce of oxygen on microstructure evolution,particularlyα′martensite transformation and refinement mechanisms.Four alloys,Ti–6Al–4V–xO(x=0.11,0.16,0.21,and 0.25 wt%),were fabricated by the SLM process.The martensite start temperature(M_(s))of Ti–6Al–4V,as evaluated by computation,is 656.8°C,and oxygen was found to increase the M_(s) by about 10°C per 0.1 wt%.The SLMed alloy samples exhibit[001]_(β)growth texture along the build direction.Crystallographic analysis of martensite morphology suggests internal twinning on{1011}planes as the lattice invariant strain,which becomes more predominant with increasing oxygen content.Refinement of α′martensite plates by oxygen is due to increased lattice distortion,reduced prior β grain size,and oxygen segregation toβgrain boundaries.Our findings contribute to improving the understanding of the effect of oxygen on the transformation mechanism ofα′martensite during SLM of Ti–6Al–4V.展开更多
Serrated chips,consisting of extremely uneven plastic deformation,are a prominent feature of high-speed machining of difficultto-machine materials.This paper focuses on the evolution of chip form,chip morphology featu...Serrated chips,consisting of extremely uneven plastic deformation,are a prominent feature of high-speed machining of difficultto-machine materials.This paper focuses on the evolution of chip form,chip morphology features(chip free surface,tool-chip contact surface,and chip edge),and chip segment parameters in subsequent high-speed(vc=50 and 150 m min-1)machining of selective laser melted(SLMed)Ti6Al4V alloys,which are significantly different from conventional Ti6Al4V alloy in microstructure,mechanical properties and machinability.The effect of laser beam scanning schemes(0°,67.5°,and 90°),machined surfaces(top and front),and cutting speeds on serrated chip characteristics of SLMed Ti6Al4Valloys was investigated.Based on the Johnson-Cook constitutive model of SLMed Ti6Al4Valloys,an orthogonal cutting model was developed to better understand the effect of physical-mechanical properties on the shear localization,which dominates the formation mechanism of serrated chips in post-machining of SLMed Ti6Al4V alloy.The results showed that the critical cutting speed(CCS)for chip serration of SLMed Ti6Al4V alloy is lower than that for serrated chips of conventional Ti6Al4V alloy,and the serrated profile of SLMed Ti6Al4V chips was more regular and pronounced.Besides,due to anisotropic microstructure and mechanical properties of SLMed Ti6Al4Valloys,the serration degree of chips produced on the top surfaces of SLMed Ti6Al4Valloys is more prominent than that of chips generated on the front surfaces.In addition,because of the poor deformation coordination and high plastic flow stresses of needle-like martensiteα′,the plastic flow and grain distortion in the adiabatic shear band(ASB)of SLMed Ti6Al4V chips are significantly smaller than those in the ASB of conventional Ti6Al4V with equiaxed grains.展开更多
Direct aging treatment is an important post-processing procedure,yet little research has been done on how it balances the mechanical properties and the stress removal for selective laser melted(SLMed)AlSi10Mg alloys.H...Direct aging treatment is an important post-processing procedure,yet little research has been done on how it balances the mechanical properties and the stress removal for selective laser melted(SLMed)AlSi10Mg alloys.Here,we proposed a typical direct aging treatment on SLMed AlSi10Mg alloys,and studied the effects on their microstructure,properties and residual stress evolution.The results indi-cate that the as-built microstructure is mainly composed of fine cellularα-Al and reticulated Si phases,and some pre-existing precipitates and dislocations are found in these cells.The direct aging treatment promotes the precipitation of nano-scaled Si phases and preserves a network-like Si structure.Therefore,the strength of the peak-aged alloy increases while the ductility decreases.As the aging temperature in-creases from 160 to 200℃,aging hardening behavior was accelerated significantly.Aging at 160℃ for 4-9 h removes 32.0%-43.0%of the residual stress,which is attributed to the decomposition of the su-persaturatedα-Al matrix,the precipitation of the nano-Si phase and the exposure of low-angle grain boundaries(LAGBs).Considering the overal alloy performance obtained,over-aging at 160℃ for 4 h is the optimized heat treatment regime.Under this condition,the yield strength(YS),ultimate tensile strength(UTS)and elongation(EL)of the alloy in the transverse and longitudinal direction are 309.5 MPa,464.4 MPa and 8.3%and 286.4 MPa,464.9 MPa and 5.1%,respectively.展开更多
In this study,a reduced-order crystal plasticity finite element(CPFE)model was developed to study the effects of the microstructural morphology and crystallographic texture on the mechanical anisotropy of selective la...In this study,a reduced-order crystal plasticity finite element(CPFE)model was developed to study the effects of the microstructural morphology and crystallographic texture on the mechanical anisotropy of selective laser melted(SLMed)Ti-6Al-4V.First,both hierarchical and equiaxed microstructures in columnar prior grains were modeled to examine the influence of the microstructural morphology on mechanical anisotropy.Second,the effects of crystallographic anisotropy and textural variability on mechanical anisotropy were investigated at the granular and representative volume element(RVE)scales,respectively.The results show that hierarchical and equiaxed CPFE models with the same crystallographic texture exhibit the same mechanical anisotropy.At the granular scale,the significance of crystallographic anisotropy varies with different crystal orientations.This indicates that the present SLMed Ti-6Al-4V sample with weak mechanical anisotropy resulted from the synthetic effect of crystallographic anisotropies at the granular scale.Therefore,combinations of various crystallographic textures were applied to the reduced-order CPFE model to design SLMed Ti-6Al-4V with different mechanical anisotropies.Thus,the crystallographic texture is considered the main controlling variable for the mechanical anisotropy of SLMed Ti-6Al-4V in this study.展开更多
Additive manufacturing is believed to open up a new era in precise microfabrication,and the dynamic microstructure evolution during the process as well as the experiment-simulation correlated study is conducted on a p...Additive manufacturing is believed to open up a new era in precise microfabrication,and the dynamic microstructure evolution during the process as well as the experiment-simulation correlated study is conducted on a prototype multi-principal-element alloys FeCrNi fabricated using selective laser melting(SLM).Experimental results reveal that columnar crystals grow across the cladding layers and the dense cellular structures develop in the filled crystal.At the micron scale,all constituent elements are evenly distributed,while at the near-atomic scale,Cr element is obviously segregated.Simulation results at the atomic scale illustrate that i)the solid-liquid interface during the grain growth changes from horizontal to arc due to the radial temperature gradient;ii)the precipitates,microscale voids,and stacking faults also form dynamically as a result of the thermal gradient,leading to the residual stress in the SLMed structure.In addition,we established a microstructure-based physical model based on atomic simulation,which indicates that strong interface strengthening exists in the tensile deformation.The present work provides an atomic-scale understanding of the microstructural evolution in the SLM process through the combination of experiment and simulation.展开更多
17-4 precipitation-hardened(PH)stainless steel(SS)exhibits high strength and good corrosion resistance via Cu-precipitation hardening.Unlike conventional wrought 17-4PH SS,Cu segregation andε-Cu pre-cipitates are obs...17-4 precipitation-hardened(PH)stainless steel(SS)exhibits high strength and good corrosion resistance via Cu-precipitation hardening.Unlike conventional wrought 17-4PH SS,Cu segregation andε-Cu pre-cipitates are observed in additively manufactured(AM)17-4PH SS owing to the repeated rapid cooling after heating,which characterizes the AM process.In this study,solution treatment was conducted under various temperatures(1,000,1,050,1,100,and 1,200℃)and durations(1,2,4,and 8 h)to minimize the negative effects of Cu segregation andε-Cu precipitates on precipitation hardening.The mechanical prop-erties and microstructures of each condition for the Cu precipitation behavior were examined.Although theε-Cu precipitates did not disappear after solution treatment,the average diameter of theε-Cu precipi-tates tended to decrease with increasing solution treatment temperature and duration.Therefore,solution treatment at a temperature of 1,200℃ for 8 h was the best,resulting in improved strength compared to the conventional solution treatment at 1,050℃.Solution treatment on at least 1,100℃ is effective in AM.展开更多
The porous metallic biomaterials have attracted significant attention for implants because their lower young's modulus matches the human bones, which can eliminate the stress shielding effect and facilitate the gr...The porous metallic biomaterials have attracted significant attention for implants because their lower young's modulus matches the human bones, which can eliminate the stress shielding effect and facilitate the growth of bone tissue cells. The porous metallic biomaterials fabricated by selective laser melting (SLM) have broad prospects, but the surface of the SLM-built porous structure has been severely adhered with unmelted powders, which affects the forming accuracy and surface quality. The porous metallic biomaterials face the corrosion problem of complex body fluid environments during service, so their corrosion resistance in the human body is extremely important. The surface quality will affect the corrosion resistance of the porous metallic biomaterials. Therefore, it is necessary to study the effect of post-treatment on the corrosion resistance of SLMed samples. In this work, the mechanical response and the electrochemical corrosion behavior in simulated body fluid of diamond and pentamode metamaterials Ti-6Al-4V alloy fabricated by SLM before and after sandblasting were studied. After sandblasting, the mechanical properties of the two porous metallic biomaterials were slightly improved, and the self-corrosion potential and pitting potential were more negative;meanwhile, the self-corrosion current density and passive current density increased, indicating that its corrosion performance decreased, and the passive film stability of sandblasted samples got worse.展开更多
Mercury(Hg) in the Arctic is a significant concern due to its bioaccumulative and neurotoxic properties, and the sensitivity of Arctic environments. Previous research has found high levels of Hg in snowpacks with hi...Mercury(Hg) in the Arctic is a significant concern due to its bioaccumulative and neurotoxic properties, and the sensitivity of Arctic environments. Previous research has found high levels of Hg in snowpacks with high chloride(Cl-) concentrations. We hypothesised that Cl- would increase Hg retention by decreasing Hg photoreduction to Hg(0) in melted Arctic snow. To test this, changes in Hg photoreduction kinetics in melted Alert, NU snow were quantified with changing Cl- concentration and UV intensity. Snow was collected and melted in Teflon bottles in May 2014, spiked with 0–10 μg/g Cl-, and irradiated with 3.52–5.78 W·m-2 UV(280–400 nm)radiation in a Luz Chem photoreactor. Photoreduction rate constants(k)(0.14–0.59 hr-1) had positive linear relationships with [Cl-], while photoreduced Hg amounts(Hg(Ⅱ)red) had negative linear relationships with [Cl-](1287–64 pg in 200 g melted snow). Varying UV and[Cl-] both altered Hg(Ⅱ)red amounts, with more efficient Hg stabilisation by Cl- at higher UV intensity, while k can be predicted by Cl- concentration and/or UV intensity, depending on experimental parameters. Overall, with future projections for greater snowpack Cl- loading,our experimental results suggest that more Hg could be delivered to Arctic aquatic ecosystems by melted snow(smaller Hg(Ⅱ)red expected), but the Hg in the melted snow that is photoreduced may do so more quickly(larger k expected).展开更多
The twin-body plasma arc has the decoupling control ability of heat transfer and mass transfer,which is beneficial to shape and property control in wire arc additive manufacturing.In this paper,with the wire feeding s...The twin-body plasma arc has the decoupling control ability of heat transfer and mass transfer,which is beneficial to shape and property control in wire arc additive manufacturing.In this paper,with the wire feeding speed as a characteristic quantity,the wire melting control ability of twin-body plasma arc was studied by adjusting the current separation ratio(under the condition of a constant total current),the wire current/main current and the position of the wire in the arc axial direction.The results showed that under the premise that the total current remains unchanged(100 A),as the current separation ratio increased,the middle and minimum melting amounts increased approximately synchronously under the effect of anode effect power,the first melting mass range remained constant;the maximum melting amount increased twice as fast as the middle melting amount under the effect of the wire feeding speed,and the second melting mass range was expanded.When the wire current increased,the anode effect power and the plasma arc power were both factors causing the increase in the wire melting amount;however,when the main current increased,the plasma arc power was the only factor causing the increase in the wire melting amount.The average wire melting increment caused by the anode effect power was approximately 2.7 times that caused by the plasma arc power.The minimum melting amount was not affected by the wire-torch distance under any current separation ratio tested.When the current separation ratio increased and reached a threshold,the middle melting amount remained constant with increasing wire-torch distance.When the current separation ratio continued to increase and reached the next threshold,the maximum melting amount remained constant with the increasing wire-torch distance.The effect of the wire-torch distance on the wire melting amount reduced with the increase in the current separation ratio.Through this study,the decoupling mechanism and ability of this innovative arc heat source is more clearly.展开更多
The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus ar...The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.展开更多
基金Funded by the National Natural Science Foundation of China(No.42102345)the Fundamental Research Funds for the Central Universities(No.2023ZKPYJD03)。
文摘Cryogenic treatment was used to improve the tribological properties of Ti6Al4V artificial hip joint implants.Cryogenic treatment at-196℃with different holding time were carried out on Ti6Al4V specimens fabricated using electron beam melting(EBM),and their microstructure and tribological properties evolution were systematically analyzed by scanning electron microscopy(SEM),vickers hardness,and wear tests.The experimental results show that the as-fabricated specimen consists of lamellarαphase andβcolumnar crystal.While,the thickness of lamellarαphase decreased after cryogenic treatment.In addition,it can be found that the fineαphase was precipitated and dispersed between the lamellarαphase with the holding time increase.Vickers hardness shows a trend of first increasing and then decreasing.The wear rate of the specimen cryogenic treated for 24 h is the minimum and the average friction coefficient is 0.50,which is reduced by 14.61%compared with the as-fabricated.The wear mechanism of the as-fabricated specimen is severe exfoliation,adhesive,abrasive,and slight fatigue wear.However,the specimen cryogenic treated for 24 h shows slight adhesive and abrasive wear.It can be concluded that it is feasibility of utilizing cryogenic treatment to reduce the wear of EBMed Ti6Al4V.
基金the financial support from the National Natural Science Foundation of China [51805415,51922048]China Postdoctoral Science Foundation [2019M663682]+2 种基金China Postdoctoral Science Foundation [Grant number 2019M663682]Young Elite Scientists Sponsorship Program by CAST [Grant number 2021QNRC001]the fund of State Key Laboratory of Long-life High Temperature Materials (DECSKL202104)。
文摘In the context of global carbon neutrality, the application of lightweight magnesium alloys is becoming increasingly attractive. In this study, selective laser melting(SLM) was employed to achieve nearly full dense and crack-free AZ91D components with fine equiaxed grain structure. The formation mechanism of typical pore defects(gas pore, lack-of-fusion pore and keyhole pore) and melting modes(keyhole mode and conduction mode) were systematically studied by varying the laser power and scanning speed. The morphology and volume fraction of the pores under different processing conditions were characterized. A criterion based on the depth-to-width ratio of the melt pool was established to identify different melting modes. The strength and ductility(tensile strength up to 340 MPa and uniform elongation of 8.9%)of the as deposited AZ91D are far superior to those of the casting components and are comparable to those of its wrought counterparts.The superior balance of strength and ductility of SLMed AZ91D, as well as the negligible anisotropic properties are mainly ascribed to the extremely fine equiaxed grain structure(with average grain size of ~1.2 μm), as well as the discontinuous distribution of β-Al_(12)Mg_(17) phases. It thus provides an alternative way to fabricate high-strength magnesium alloys with complex geometry.
基金The author would like to acknowledge the support by the National Natural Science Foundation of China (Grant No. 50105006)and the support by the 985 Foundation of Tsinghua University,Beijing, China.
文摘To develop large-scale RP systems used to producing functional parts and large-sized models has become an urgentcall now. In this paper, a large-scale RP system, MEM600-l, based on the melted extrusion manufacturing (MEM)process has been developed successfully. And the key issues to develop such a system are discussed. Based on theactual forming experiment, it is concluded that the MEM600-l works reliably and the forming efficiency is muchhigher than its parallel equipments.
文摘The characteristics of some elements in inoculant were analyzed.The effect of the morphology of instantaneous inoculant on its melting velocity was studied.When the inoculants pass through the same sieve number,the volume and the ratio of surface area to volume are different.It is evident from the theoretical analysis and experiment under some conditions that the melting velocity of inoculant depends on the morphology of inoculant.The morphology of inoculant during production should be controlled carefully.
基金Supported by National Key Research and Development Program“Additive Manufacturing and Laser Manufacturing”of China(Grant Nos.2016YFB1100101,2018YFB1106302)National Natural Science Foundation of China(Grant No.51735005)+4 种基金Jiangsu Provincial Natural Science Foundation for Youth(Grant No.BK20180439)National Natural Science Foundation of China for Creative Research Groups(Grant No.51921003)The 15th Batch of“Six Talents Peaks”Innovative Talents Team Program(Grant No.TD-GDZB-001)2017 Excellent Scientific and Technological Innovation Teams of Universities in Jiangsu ProvinceNanjing University of Aeronautics and Astronautics Graduate Innovation Base(Laboratory)Open Fund Project(Grant No.kfjj20190606).
文摘Selective laser melting(SLM)is an emerging additive manufacturing technology for fabricating aluminum alloys and aluminum matrix composites.Nevertheless,it remains unclear how to improve the properties of laser manufactured aluminum alloy by adding ceramic reinforcing particles.Here the effect of trace addition of TiB2 ceramic(1%weight fraction)on microstructural and mechanical properties of SLM-produced AlSi10Mg composite parts was investigated.The densification level increased with increasing laser power and decreasing scan speed.A near fully dense composite part(99.37%)with smooth surface morphology and elevated inter-layer bonding was successfully obtained.A decrease of lattice plane distance was identified by X-ray diffraction with the laser scan speed decreased,which implied that the crystal lattices were distorted due to the dissolution of Si and TiB2 particles.A homogeneous composite microstructure with the distribution of surface-smoothened TiB2 particles was present,and a small amount of Si particles precipitated at the interface between reinforcing particles and matrix.In contrast to the AlSi10Mg alloy,the composites showed a stabilized microhardness distribution.A higher ultimate tensile strength of 380.0 MPa,yield strength of 250.4 MPa and elongation of 3.43%were obtained even with a trace amount of ceramic addition.The improvement of tensile properties can be attributed to multiple mechanisms including solid solution strengthening,load-bearing strengthening and dispersion strengthening.This research provides a theoretical basis for ceramic reinforced aluminum matrix composites by additive manufacturing.
基金Supported by Basic Research Project of Science and Technology Plan of Shenzhen(Grant No.JCYJ20170817111811303).
文摘New materials and manufacturing technologies require applicable non-destructive techniques for quality assurance so as to achieve better performance.This study comprehensively investigated the effect of influencing factors includ-ing excitation frequency,lift-off distance,defect depth and size,residual heat,and surface roughness on the defect EC signals of an Inconel 738LC alloy produced by selective laser melting(SLM).The experimental investigations recorded the impedance amplitude and phase angle of EC signals for each defect to explore the feasibility of detecting sub-surface defects by merely analyzing these two key indicators.Overall,this study revealed preliminary qualitative and roughly quantitative relationships between influencing factors and corresponding EC signals,which provided a prac-tical reference on how to quantitively inspect subsurface defects using eddy current testing(ECT)on SLMed parts,and also made solid progress toward on-line ECT in additive/subtractive hybrid manufacturing(ASHM)for fabricating SLMed parts with enhanced quality and better performance.
文摘Sequential melting theory is applied to reteal that fluctuation of chemical composition ofmelted iron in cupola is caused by the process of sequential melting. Fluctuation is incvitable andcyclc. Usting microcornputer dynamic simulation has confirmed that the fluctuation situation ofchemical composition cf melted iron is contistent with actuaa production on the whole.
基金The research is supported by the Shanxi Natural Science Foundation (No. 2008011044).
文摘An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction (XRD) was used to identify the phases. Microstructure and properties of laser melted layer of AZ31B magnesium alloy were observed or tested by means of optical microscope (OM), scanning electron microscope (SEM), micro-hardness equipment and electrochemical corrosion equipment etc. The results show that the microstructure of laser melted layer becomes finer significantly and uniform. Compared with the substrate, the content of β-Mg17 Al12 phase of melted layer decreases comparatively. Microhardness of the laser melted layer is improved to 50 -95 HV0. 05 as compared to 40 -45 HV0.05 of the AZ31B Mg alloy substrate. The results of electrochemical corrosion show that the corrosion resistance of laser surface melted layer has been improved.
基金financial support by the National Natural Science Foundation of China(No.52175301)the China National Postdoctoral Program for Innovative Talents(No.BX20220384)the Shanghai Aerospace Science and Technology Innovation Fund of China(No.SAST2020-108)。
文摘Selective laser melted AlSi10Mg alloys with eutectic network structures were successfully joined by friction stir welding.Sound butt-lap joints have been achieved.A novel enlarged pin was designed to overcome kissing bonding defects and increase interfacial bonding area.The hook defect in a conventional butt-lap joint was avoided due to the limitation of the upward flow of interfacial materials,and the interfacial joining width was 2.5 times of the plate thickness.The eutectic Si network structure was broken into the re-dispersed rich-Si phases,improving joint performance.The ultimate tensile strength reached 83.1%of the matrix,higher than those of conventional melting techniques.
文摘The effects of vacuum induction melting(VIM) and vacuum arc remelting(VAR) processes on the microstructure and stress rupture properties of Ni-based GTD-111 superalloy were investigated. Samples of GTD-111 master alloy were melted in VIM and VAR furnaces and then poured into a preheated ceramic mold for VIM melt or into a water-cooled copper mold for VAR melt. The as-cast samples were examined radiographically to ensure that no casting defects were present in the final castings; the samples were then heat-treated using a standard heat-treatment cycle. The microstructure of the samples was investigated using optical microscopy and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy for microanalysis. On the basis of standard ASTM-E139, stress rupture tests were carried out at 1000°C under a stress of 300 MPa. The results showed that a γ matrix, fine γ′ precipitates, a γ–γ′ eutectic structure, carbide particles, and some harmful phases such as σ and η phases were present in the as-cast samples. The γ′ precipitates with cubic morphology appeared in the matrix after the standard heat-treatment process. The extent of segregation and the amount of γ–γ′ eutectic structure formed in the VAR-prepared sample were less than in the VIM-prepared sample. The results of stress rupture tests showed that the rupture time for the VAR sample was 43% longer than that for the VIM sample.
基金financially supported by the National Natural Science Foundation of China(No.52205431)the CAS Interdisciplinary Innovation Team Project(No.JCTD-2020-10)。
文摘Oxygen is crucial in influencing the microstructure evolution of selective laser melted(SLMed)Ti–6Al–4V,significantly impacting its applicability in various sectors.Therefore,this study investigates the influnce of oxygen on microstructure evolution,particularlyα′martensite transformation and refinement mechanisms.Four alloys,Ti–6Al–4V–xO(x=0.11,0.16,0.21,and 0.25 wt%),were fabricated by the SLM process.The martensite start temperature(M_(s))of Ti–6Al–4V,as evaluated by computation,is 656.8°C,and oxygen was found to increase the M_(s) by about 10°C per 0.1 wt%.The SLMed alloy samples exhibit[001]_(β)growth texture along the build direction.Crystallographic analysis of martensite morphology suggests internal twinning on{1011}planes as the lattice invariant strain,which becomes more predominant with increasing oxygen content.Refinement of α′martensite plates by oxygen is due to increased lattice distortion,reduced prior β grain size,and oxygen segregation toβgrain boundaries.Our findings contribute to improving the understanding of the effect of oxygen on the transformation mechanism ofα′martensite during SLM of Ti–6Al–4V.
基金supported by the National Natural Science Foundation of China(Grant Nos.51975112 and 51575289)。
文摘Serrated chips,consisting of extremely uneven plastic deformation,are a prominent feature of high-speed machining of difficultto-machine materials.This paper focuses on the evolution of chip form,chip morphology features(chip free surface,tool-chip contact surface,and chip edge),and chip segment parameters in subsequent high-speed(vc=50 and 150 m min-1)machining of selective laser melted(SLMed)Ti6Al4V alloys,which are significantly different from conventional Ti6Al4V alloy in microstructure,mechanical properties and machinability.The effect of laser beam scanning schemes(0°,67.5°,and 90°),machined surfaces(top and front),and cutting speeds on serrated chip characteristics of SLMed Ti6Al4Valloys was investigated.Based on the Johnson-Cook constitutive model of SLMed Ti6Al4Valloys,an orthogonal cutting model was developed to better understand the effect of physical-mechanical properties on the shear localization,which dominates the formation mechanism of serrated chips in post-machining of SLMed Ti6Al4V alloy.The results showed that the critical cutting speed(CCS)for chip serration of SLMed Ti6Al4V alloy is lower than that for serrated chips of conventional Ti6Al4V alloy,and the serrated profile of SLMed Ti6Al4V chips was more regular and pronounced.Besides,due to anisotropic microstructure and mechanical properties of SLMed Ti6Al4Valloys,the serration degree of chips produced on the top surfaces of SLMed Ti6Al4Valloys is more prominent than that of chips generated on the front surfaces.In addition,because of the poor deformation coordination and high plastic flow stresses of needle-like martensiteα′,the plastic flow and grain distortion in the adiabatic shear band(ASB)of SLMed Ti6Al4V chips are significantly smaller than those in the ASB of conventional Ti6Al4V with equiaxed grains.
基金This work was financially supported by Ji Hua Laboratory“Development of additive manufactured core process and special equipment for key parts of aero-engines”(No.X190351TM190)the Basic and Applied Basic Research Foundation of Guangdong Province(No.2022A1515011597).
文摘Direct aging treatment is an important post-processing procedure,yet little research has been done on how it balances the mechanical properties and the stress removal for selective laser melted(SLMed)AlSi10Mg alloys.Here,we proposed a typical direct aging treatment on SLMed AlSi10Mg alloys,and studied the effects on their microstructure,properties and residual stress evolution.The results indi-cate that the as-built microstructure is mainly composed of fine cellularα-Al and reticulated Si phases,and some pre-existing precipitates and dislocations are found in these cells.The direct aging treatment promotes the precipitation of nano-scaled Si phases and preserves a network-like Si structure.Therefore,the strength of the peak-aged alloy increases while the ductility decreases.As the aging temperature in-creases from 160 to 200℃,aging hardening behavior was accelerated significantly.Aging at 160℃ for 4-9 h removes 32.0%-43.0%of the residual stress,which is attributed to the decomposition of the su-persaturatedα-Al matrix,the precipitation of the nano-Si phase and the exposure of low-angle grain boundaries(LAGBs).Considering the overal alloy performance obtained,over-aging at 160℃ for 4 h is the optimized heat treatment regime.Under this condition,the yield strength(YS),ultimate tensile strength(UTS)and elongation(EL)of the alloy in the transverse and longitudinal direction are 309.5 MPa,464.4 MPa and 8.3%and 286.4 MPa,464.9 MPa and 5.1%,respectively.
基金supported by National Natural Science Founda-tion of China(Grant Nos.51971113,51905279,11972202)Zhe-jiang Provincial Natural Science Foundation of China(Grant No.LY21A020002).
文摘In this study,a reduced-order crystal plasticity finite element(CPFE)model was developed to study the effects of the microstructural morphology and crystallographic texture on the mechanical anisotropy of selective laser melted(SLMed)Ti-6Al-4V.First,both hierarchical and equiaxed microstructures in columnar prior grains were modeled to examine the influence of the microstructural morphology on mechanical anisotropy.Second,the effects of crystallographic anisotropy and textural variability on mechanical anisotropy were investigated at the granular and representative volume element(RVE)scales,respectively.The results show that hierarchical and equiaxed CPFE models with the same crystallographic texture exhibit the same mechanical anisotropy.At the granular scale,the significance of crystallographic anisotropy varies with different crystal orientations.This indicates that the present SLMed Ti-6Al-4V sample with weak mechanical anisotropy resulted from the synthetic effect of crystallographic anisotropies at the granular scale.Therefore,combinations of various crystallographic textures were applied to the reduced-order CPFE model to design SLMed Ti-6Al-4V with different mechanical anisotropies.Thus,the crystallographic texture is considered the main controlling variable for the mechanical anisotropy of SLMed Ti-6Al-4V in this study.
基金supported by the National Natural Science Foundation of China(Nos.52020105013,51871092,and 11902113)the Natural Science Foundation of Hunan Province(Nos.2019JJ50068 and 2021JJ40032)+1 种基金the Changsha Municipal Natu-ral Science Foundation(No.kq2014126)support from the National Science Foundation(Nos.DMR-1611180 and 1809640).
文摘Additive manufacturing is believed to open up a new era in precise microfabrication,and the dynamic microstructure evolution during the process as well as the experiment-simulation correlated study is conducted on a prototype multi-principal-element alloys FeCrNi fabricated using selective laser melting(SLM).Experimental results reveal that columnar crystals grow across the cladding layers and the dense cellular structures develop in the filled crystal.At the micron scale,all constituent elements are evenly distributed,while at the near-atomic scale,Cr element is obviously segregated.Simulation results at the atomic scale illustrate that i)the solid-liquid interface during the grain growth changes from horizontal to arc due to the radial temperature gradient;ii)the precipitates,microscale voids,and stacking faults also form dynamically as a result of the thermal gradient,leading to the residual stress in the SLMed structure.In addition,we established a microstructure-based physical model based on atomic simulation,which indicates that strong interface strengthening exists in the tensile deformation.The present work provides an atomic-scale understanding of the microstructural evolution in the SLM process through the combination of experiment and simulation.
基金This work was funded by Yangyoung Foundation and supported by the Technology Innovation Program(grant No.20009815,Development of DfAM-based 3D printing technology for lightweight and integrated aerospace parts)funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea).
文摘17-4 precipitation-hardened(PH)stainless steel(SS)exhibits high strength and good corrosion resistance via Cu-precipitation hardening.Unlike conventional wrought 17-4PH SS,Cu segregation andε-Cu pre-cipitates are observed in additively manufactured(AM)17-4PH SS owing to the repeated rapid cooling after heating,which characterizes the AM process.In this study,solution treatment was conducted under various temperatures(1,000,1,050,1,100,and 1,200℃)and durations(1,2,4,and 8 h)to minimize the negative effects of Cu segregation andε-Cu precipitates on precipitation hardening.The mechanical prop-erties and microstructures of each condition for the Cu precipitation behavior were examined.Although theε-Cu precipitates did not disappear after solution treatment,the average diameter of theε-Cu precipi-tates tended to decrease with increasing solution treatment temperature and duration.Therefore,solution treatment at a temperature of 1,200℃ for 8 h was the best,resulting in improved strength compared to the conventional solution treatment at 1,050℃.Solution treatment on at least 1,100℃ is effective in AM.
基金supported by the Joint Program of the National Natural Science Foundation of China(U1808216)the National Natural Science Foundation of China(Grant No.52275331)+2 种基金the Key Research and Development Program of Hubei Province(No.2022BAA011)the Academic Frontier Youth Team(2018QYTD04)at Huazhong University of Science and Technology(HUST)the Laboratory Project of Science and Technology on Power Beam Processes Laboratory and the Hong Kong Scholars Program(No.XJ2022014).
文摘The porous metallic biomaterials have attracted significant attention for implants because their lower young's modulus matches the human bones, which can eliminate the stress shielding effect and facilitate the growth of bone tissue cells. The porous metallic biomaterials fabricated by selective laser melting (SLM) have broad prospects, but the surface of the SLM-built porous structure has been severely adhered with unmelted powders, which affects the forming accuracy and surface quality. The porous metallic biomaterials face the corrosion problem of complex body fluid environments during service, so their corrosion resistance in the human body is extremely important. The surface quality will affect the corrosion resistance of the porous metallic biomaterials. Therefore, it is necessary to study the effect of post-treatment on the corrosion resistance of SLMed samples. In this work, the mechanical response and the electrochemical corrosion behavior in simulated body fluid of diamond and pentamode metamaterials Ti-6Al-4V alloy fabricated by SLM before and after sandblasting were studied. After sandblasting, the mechanical properties of the two porous metallic biomaterials were slightly improved, and the self-corrosion potential and pitting potential were more negative;meanwhile, the self-corrosion current density and passive current density increased, indicating that its corrosion performance decreased, and the passive film stability of sandblasted samples got worse.
基金provided by the NSERC Discovery grant # 341960-2013Canada Research Chairs Program to N.O. Scholarships to Erin Mann from NSERC CREATE and Memorial University of Newfoundland
文摘Mercury(Hg) in the Arctic is a significant concern due to its bioaccumulative and neurotoxic properties, and the sensitivity of Arctic environments. Previous research has found high levels of Hg in snowpacks with high chloride(Cl-) concentrations. We hypothesised that Cl- would increase Hg retention by decreasing Hg photoreduction to Hg(0) in melted Arctic snow. To test this, changes in Hg photoreduction kinetics in melted Alert, NU snow were quantified with changing Cl- concentration and UV intensity. Snow was collected and melted in Teflon bottles in May 2014, spiked with 0–10 μg/g Cl-, and irradiated with 3.52–5.78 W·m-2 UV(280–400 nm)radiation in a Luz Chem photoreactor. Photoreduction rate constants(k)(0.14–0.59 hr-1) had positive linear relationships with [Cl-], while photoreduced Hg amounts(Hg(Ⅱ)red) had negative linear relationships with [Cl-](1287–64 pg in 200 g melted snow). Varying UV and[Cl-] both altered Hg(Ⅱ)red amounts, with more efficient Hg stabilisation by Cl- at higher UV intensity, while k can be predicted by Cl- concentration and/or UV intensity, depending on experimental parameters. Overall, with future projections for greater snowpack Cl- loading,our experimental results suggest that more Hg could be delivered to Arctic aquatic ecosystems by melted snow(smaller Hg(Ⅱ)red expected), but the Hg in the melted snow that is photoreduced may do so more quickly(larger k expected).
基金Supported by Youth Program of National Natural Science Foundation of China(Grant No.51905008)Beijing Postdoctoral Research Foundation of China(Grant No.2021-zz-064)+2 种基金Shandong Provincial Major Science and Technology Innovation Project of China(Grant No.2020JMRH0504)Jinan Innovation Team Project of China(Grant No.2021GXRC066)Quancheng Scholars Construction Project of China(Grant No.D03032).
文摘The twin-body plasma arc has the decoupling control ability of heat transfer and mass transfer,which is beneficial to shape and property control in wire arc additive manufacturing.In this paper,with the wire feeding speed as a characteristic quantity,the wire melting control ability of twin-body plasma arc was studied by adjusting the current separation ratio(under the condition of a constant total current),the wire current/main current and the position of the wire in the arc axial direction.The results showed that under the premise that the total current remains unchanged(100 A),as the current separation ratio increased,the middle and minimum melting amounts increased approximately synchronously under the effect of anode effect power,the first melting mass range remained constant;the maximum melting amount increased twice as fast as the middle melting amount under the effect of the wire feeding speed,and the second melting mass range was expanded.When the wire current increased,the anode effect power and the plasma arc power were both factors causing the increase in the wire melting amount;however,when the main current increased,the plasma arc power was the only factor causing the increase in the wire melting amount.The average wire melting increment caused by the anode effect power was approximately 2.7 times that caused by the plasma arc power.The minimum melting amount was not affected by the wire-torch distance under any current separation ratio tested.When the current separation ratio increased and reached a threshold,the middle melting amount remained constant with increasing wire-torch distance.When the current separation ratio continued to increase and reached the next threshold,the maximum melting amount remained constant with the increasing wire-torch distance.The effect of the wire-torch distance on the wire melting amount reduced with the increase in the current separation ratio.Through this study,the decoupling mechanism and ability of this innovative arc heat source is more clearly.
基金supported by the National Natural Science Foundation of China(Nos.41472065 and 42073059).
文摘The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.