In order to ensure consistent argon flow in the stopper gas channel and improve argon bubble performance in the slab casting mould,two patented new technologies CSC（Clean Stream Cartridge） and SHP（Slot Hole Plug） ...In order to ensure consistent argon flow in the stopper gas channel and improve argon bubble performance in the slab casting mould,two patented new technologies CSC（Clean Stream Cartridge） and SHP（Slot Hole Plug） were applied in the argon purging stopper designs.The novel stopper designs can maintain a stable back pressure and argon flow in the argon line during long sequence casting,eliminate pressure increasing at the start of the casting,even distribute gas bubbles in the mould leading to improved mould flux melting and lubrication,reduce mould level fluctuation and so on.展开更多
The influence of fluorine on the structure of CaO Si（）e-Al2Oa Na2O-CaF2 continuous-casting-type slag was measured by Raman spectroscopy, and the degree of polymerization of mould flux and the structural behavior of ...The influence of fluorine on the structure of CaO Si（）e-Al2Oa Na2O-CaF2 continuous-casting-type slag was measured by Raman spectroscopy, and the degree of polymerization of mould flux and the structural behavior of F- in the melt were investigated by classifying and quantifying the structural species of F ions. The results exhibit that the main structural units of Si O tetrahedra are Q1, Q1 and Q2, and the actual measured number of non bridging oxygen ions in the [SiO4 ]-tetrahedra （denoted by NBO/T） in creases from 2. 73 to 3.44 with increasing the molar ratio of F to （F＋O） （denoted by XF/X（F-O ） from 0.06 to 0. 19. It means that the degree of polymerization o1 meh structure decreases with an increase in XE/X（F＋O）. In addition, most of F- ions were distributed in Si-O tetrahedra and Al-O tetrahedra. With increasing XF/X（F＋O）, the complex structural units Al-Otetrahedra are gradually replaced hy discrete structural units A1F4 because of the breakage of Al-O bonds in Al-Otetrahedra by F ions, and the SiO （bridging oxygen） bonds of SiO tetrahedra are broken to form [SiOnF1-n]-tetrahedra by F ions coordinating with Si4 ＋ .展开更多
文摘In order to ensure consistent argon flow in the stopper gas channel and improve argon bubble performance in the slab casting mould,two patented new technologies CSC（Clean Stream Cartridge） and SHP（Slot Hole Plug） were applied in the argon purging stopper designs.The novel stopper designs can maintain a stable back pressure and argon flow in the argon line during long sequence casting,eliminate pressure increasing at the start of the casting,even distribute gas bubbles in the mould leading to improved mould flux melting and lubrication,reduce mould level fluctuation and so on.
基金the National Natural Science Foundation of China for providing financial support(Nos.51374060 and 51374059)
文摘The influence of fluorine on the structure of CaO Si（）e-Al2Oa Na2O-CaF2 continuous-casting-type slag was measured by Raman spectroscopy, and the degree of polymerization of mould flux and the structural behavior of F- in the melt were investigated by classifying and quantifying the structural species of F ions. The results exhibit that the main structural units of Si O tetrahedra are Q1, Q1 and Q2, and the actual measured number of non bridging oxygen ions in the [SiO4 ]-tetrahedra （denoted by NBO/T） in creases from 2. 73 to 3.44 with increasing the molar ratio of F to （F＋O） （denoted by XF/X（F-O ） from 0.06 to 0. 19. It means that the degree of polymerization o1 meh structure decreases with an increase in XE/X（F＋O）. In addition, most of F- ions were distributed in Si-O tetrahedra and Al-O tetrahedra. With increasing XF/X（F＋O）, the complex structural units Al-Otetrahedra are gradually replaced hy discrete structural units A1F4 because of the breakage of Al-O bonds in Al-Otetrahedra by F ions, and the SiO （bridging oxygen） bonds of SiO tetrahedra are broken to form [SiOnF1-n]-tetrahedra by F ions coordinating with Si4 ＋ .
