Realizing fast and continuous generation of reactive oxygen species(ROSs)via iron-based advanced oxidation processes(AOPs)is significant in the environmental and biological fields.However,current AOPs assisted by co-c...Realizing fast and continuous generation of reactive oxygen species(ROSs)via iron-based advanced oxidation processes(AOPs)is significant in the environmental and biological fields.However,current AOPs assisted by co-catalysts still suffer from the poor mass/electron transfer and non-durable promotion effect,giving rise to the sluggish Fe^(2+)/Fe^(3+)cycle and low dynamic concentration of Fe^(2+)for ROS production.Herein,we present a three-dimensional(3D)macroscale co-catalyst functionalized with molybdenum disulfide(MoS_(2))to achieve ultra-efficient Fe^(2+)regeneration(equilibrium Fe^(2+)ratio of 82.4%)and remarkable stability(more than 20 cycles)via a circulating flow-through process.Unlike the conventional batch-type reactor,experiments and computational fluid dynamics simulations demonstrate that the optimal utilization of the 3D active area under the flow-through mode,initiated by the convectionenhanced mass/charge transfer for Fe^(2+)reduction and then strengthened by MoS_(2)-induced flow rotation for sufficient reactant mixing,is crucial for oxidant activation and subsequent ROS generation.Strikingly,the flow-through co-catalytic system with superwetting capabilities can even tackle the intricate oily wastewater stabilized by different surfactants without the loss of pollutant degradation efficiency.Our findings highlight an innovative co-catalyst system design to expand the applicability of AOPs based technology,especially in large-scale complex wastewater treatment.展开更多
Numerical calculations were conducted to simulate the flow and mass transfer in narrow membrane channels with and without flow disturbers. The channel consists of an impermeable solid wall and a membrane surface with ...Numerical calculations were conducted to simulate the flow and mass transfer in narrow membrane channels with and without flow disturbers. The channel consists of an impermeable solid wall and a membrane surface with a spacing of 2.0 mm. The flow disturbers studied include rectangular winglets, which are often used as longitudinal vortex generators to enhance heat transfer in heat exchanger applications, as well as square prism, triangular prism, and circular cylinder, which are used here to mimic the traditional spacer filaments for comparison of their abilities in enhancing the convective mass transfer near the membrane surface to alleviate the concentration polarization. The disturber performance was evaluated in terms of concentration polarization factor versus consumed pumping power, with a larger factor meaning a more serious concentration polarization.Calculations were carried out for Na Cl solution flow with Reynolds numbers ranging from 400 to 1000. The results show that the traditional flow disturbers can considerably reduce the concentration polarization but cause a substantial pressure drop, while the rectangular winglets can effectively reduce the concentration polarization with a much less pressure drop penalty. The rectangular winglets were optimized in geometry under equal pumping power condition.展开更多
Hollow fiber renewal liquid membrane(HFRLM) method was proposed based on the surface renewal theory for removal of aniline from waste water. The system of aniline + D2 EHPA in kerosene + HCl was used. Aqueous layer di...Hollow fiber renewal liquid membrane(HFRLM) method was proposed based on the surface renewal theory for removal of aniline from waste water. The system of aniline + D2 EHPA in kerosene + HCl was used. Aqueous layer diffusion in the feed phase is the rate-control step, and the influence of lumen side flow rate on the mass transfer is more significant than that on the shell side. The resistance of overall mass transfer is greatly reduced because of the mass transfer intensification in the renewal of liquid membrane on the lumen side. The driving force of mass transfer can be considered as a function of distribution equilibrium, and the overall mass transfer coefficient increases with the increase of p H in the feed solution, HCl concentration and D2 EHPA concentration, and decreases with the increase of initial aniline concentration. A mass transfer model is developed for HFRLM based on the surface renewal theory. The calculated results agree well with experimental results. The HFRLM process is a promising method for aniline wastewater treatment.展开更多
基金supported by National Natural Science Foundation of China(52003240)Zhejiang Provincial Natural Science Foundation of China(LQ21B070007)China Postdoctoral Science Foundation(2022M722818).
文摘Realizing fast and continuous generation of reactive oxygen species(ROSs)via iron-based advanced oxidation processes(AOPs)is significant in the environmental and biological fields.However,current AOPs assisted by co-catalysts still suffer from the poor mass/electron transfer and non-durable promotion effect,giving rise to the sluggish Fe^(2+)/Fe^(3+)cycle and low dynamic concentration of Fe^(2+)for ROS production.Herein,we present a three-dimensional(3D)macroscale co-catalyst functionalized with molybdenum disulfide(MoS_(2))to achieve ultra-efficient Fe^(2+)regeneration(equilibrium Fe^(2+)ratio of 82.4%)and remarkable stability(more than 20 cycles)via a circulating flow-through process.Unlike the conventional batch-type reactor,experiments and computational fluid dynamics simulations demonstrate that the optimal utilization of the 3D active area under the flow-through mode,initiated by the convectionenhanced mass/charge transfer for Fe^(2+)reduction and then strengthened by MoS_(2)-induced flow rotation for sufficient reactant mixing,is crucial for oxidant activation and subsequent ROS generation.Strikingly,the flow-through co-catalytic system with superwetting capabilities can even tackle the intricate oily wastewater stabilized by different surfactants without the loss of pollutant degradation efficiency.Our findings highlight an innovative co-catalyst system design to expand the applicability of AOPs based technology,especially in large-scale complex wastewater treatment.
基金Supported by Tsinghua University Initiative Scientific Research Program(20131089319)
文摘Numerical calculations were conducted to simulate the flow and mass transfer in narrow membrane channels with and without flow disturbers. The channel consists of an impermeable solid wall and a membrane surface with a spacing of 2.0 mm. The flow disturbers studied include rectangular winglets, which are often used as longitudinal vortex generators to enhance heat transfer in heat exchanger applications, as well as square prism, triangular prism, and circular cylinder, which are used here to mimic the traditional spacer filaments for comparison of their abilities in enhancing the convective mass transfer near the membrane surface to alleviate the concentration polarization. The disturber performance was evaluated in terms of concentration polarization factor versus consumed pumping power, with a larger factor meaning a more serious concentration polarization.Calculations were carried out for Na Cl solution flow with Reynolds numbers ranging from 400 to 1000. The results show that the traditional flow disturbers can considerably reduce the concentration polarization but cause a substantial pressure drop, while the rectangular winglets can effectively reduce the concentration polarization with a much less pressure drop penalty. The rectangular winglets were optimized in geometry under equal pumping power condition.
基金Supported by the Program for New Century Excellent Talents in University(NCET-100210)the National Natural Science Foundation of China(21076011 and 21276012)
文摘Hollow fiber renewal liquid membrane(HFRLM) method was proposed based on the surface renewal theory for removal of aniline from waste water. The system of aniline + D2 EHPA in kerosene + HCl was used. Aqueous layer diffusion in the feed phase is the rate-control step, and the influence of lumen side flow rate on the mass transfer is more significant than that on the shell side. The resistance of overall mass transfer is greatly reduced because of the mass transfer intensification in the renewal of liquid membrane on the lumen side. The driving force of mass transfer can be considered as a function of distribution equilibrium, and the overall mass transfer coefficient increases with the increase of p H in the feed solution, HCl concentration and D2 EHPA concentration, and decreases with the increase of initial aniline concentration. A mass transfer model is developed for HFRLM based on the surface renewal theory. The calculated results agree well with experimental results. The HFRLM process is a promising method for aniline wastewater treatment.
