A fiber optic 2-cholrophenol（2-CP） sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-...A fiber optic 2-cholrophenol（2-CP） sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-CP concentration can be determined by utilizing a lock-in amplifier to measure the change in the fluorescence lifetime of an oxygen-sensitive membrane, in which the tris（2,2′-bipyridyl） ruthenium（II） chloride complexes（Ru（II）（byp）3Cl2） were immobilized in cellulose acetate（CA） via simple hybridized approach. The experimental results show the good linear relationship between the phase delay of sensitive membrane and 2-CP concentration in its detection range of 1×10-7 to 1×10-5 mol/L and 1×10-5 to 1×10-4 mol/L. The detection limit of the sensor is 7×10-8 mol/L（S/N=3） and the response time is 5 min. Our experimental measurements confirmed good response characteristics of the as-prepared fiber optic 2-CP sensor, as well as its capability to detect the 2-CP concentration in practical water samples.展开更多
To reduce the cost and achieve high diffraction efficiency, a modified moir@ technique for fabricating a large- aperture multi-level Fresnel membrane optic by a novel design of alignment marks is proposed. The modifie...To reduce the cost and achieve high diffraction efficiency, a modified moir@ technique for fabricating a large- aperture multi-level Fresnel membrane optic by a novel design of alignment marks is proposed. The modified moire fringes vary more sensitively with the actual misalignment. Hence, the alignment accuracy is significantly improved. Using the proposed method, a 20 μm thick, four-level Fresnel diffractive polyimide membrane optic with a 200 mm diameter is made, which exhibits over 62% diffraction efficiency into the ＋1 order, and an efficiency root mean square of 0.051.展开更多
Membrane diffractive optical elements formed by fabricating microstructures on the substrates have two important characteristics,ultra-light mass(surface mass density<0.1 kg/m2)and loose surface shape tolerances(su...Membrane diffractive optical elements formed by fabricating microstructures on the substrates have two important characteristics,ultra-light mass(surface mass density<0.1 kg/m2)and loose surface shape tolerances(surface accuracy requirements are on the order of magnitude of centimeter).Large-aperture telescopes using a membrane diffractive optical element as the primary lens have super large aperture,light weight,and low cost at launch.In this paper,the research and development on space-based diffractive telescopes are classified and summarized.First,the imaging theory and the configuration of diffractive-optics telescopes are discussed.Then,the developments in diffractive telescopes are introduced.Finally,the development prospects for this technology used as a high-resolution space reconnaissance system in the future are summarized,and the critical and relevant work that China should carry out is put forward.展开更多
基金Funded by the National Natural Science Foundation of China(No.61377092)
文摘A fiber optic 2-cholrophenol（2-CP） sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-CP concentration can be determined by utilizing a lock-in amplifier to measure the change in the fluorescence lifetime of an oxygen-sensitive membrane, in which the tris（2,2′-bipyridyl） ruthenium（II） chloride complexes（Ru（II）（byp）3Cl2） were immobilized in cellulose acetate（CA） via simple hybridized approach. The experimental results show the good linear relationship between the phase delay of sensitive membrane and 2-CP concentration in its detection range of 1×10-7 to 1×10-5 mol/L and 1×10-5 to 1×10-4 mol/L. The detection limit of the sensor is 7×10-8 mol/L（S/N=3） and the response time is 5 min. Our experimental measurements confirmed good response characteristics of the as-prepared fiber optic 2-CP sensor, as well as its capability to detect the 2-CP concentration in practical water samples.
基金supported by the National Natural Science Foundation of China under Grant No.11375175
文摘To reduce the cost and achieve high diffraction efficiency, a modified moir@ technique for fabricating a large- aperture multi-level Fresnel membrane optic by a novel design of alignment marks is proposed. The modified moire fringes vary more sensitively with the actual misalignment. Hence, the alignment accuracy is significantly improved. Using the proposed method, a 20 μm thick, four-level Fresnel diffractive polyimide membrane optic with a 200 mm diameter is made, which exhibits over 62% diffraction efficiency into the ＋1 order, and an efficiency root mean square of 0.051.
基金Project supported by the National Natural Science Foundation of China(No.11874091)。
文摘Membrane diffractive optical elements formed by fabricating microstructures on the substrates have two important characteristics,ultra-light mass(surface mass density<0.1 kg/m2)and loose surface shape tolerances(surface accuracy requirements are on the order of magnitude of centimeter).Large-aperture telescopes using a membrane diffractive optical element as the primary lens have super large aperture,light weight,and low cost at launch.In this paper,the research and development on space-based diffractive telescopes are classified and summarized.First,the imaging theory and the configuration of diffractive-optics telescopes are discussed.Then,the developments in diffractive telescopes are introduced.Finally,the development prospects for this technology used as a high-resolution space reconnaissance system in the future are summarized,and the critical and relevant work that China should carry out is put forward.
