Metal ions, such as Cr<sup>6+</sup>, V<sup>5+</sup>, Ce<sup>4+</sup>, Co<sup>3+</sup>, Mn<sup>3+</sup>, coupled with some organic compounds, have been report...Metal ions, such as Cr<sup>6+</sup>, V<sup>5+</sup>, Ce<sup>4+</sup>, Co<sup>3+</sup>, Mn<sup>3+</sup>, coupled with some organic compounds, have been reported to be useful as a redox system for initiating vinyl polymerization. The organic compounds commonly used are alcohols, aldehydes, ketons, α-hydroxy acids, amines, etc. Samal et al. reported that Ce<sup>4+</sup> coupled with thioacetamide, succinamide and acetamide can initiate acryionitrile to polymerize. Feng et al. found展开更多
基金Project supported by the National Natural Science Foundation of China
文摘Metal ions, such as Cr<sup>6+</sup>, V<sup>5+</sup>, Ce<sup>4+</sup>, Co<sup>3+</sup>, Mn<sup>3+</sup>, coupled with some organic compounds, have been reported to be useful as a redox system for initiating vinyl polymerization. The organic compounds commonly used are alcohols, aldehydes, ketons, α-hydroxy acids, amines, etc. Samal et al. reported that Ce<sup>4+</sup> coupled with thioacetamide, succinamide and acetamide can initiate acryionitrile to polymerize. Feng et al. found
