NUCLEAR MAGNETIC RESONANCE STUDIES OF METAL COMPLEXES WITH ETHYLENEDIAMINE-N,N′-DIACETATE-N,N′-DI-β-PROPIONATE

The complexes of metals(Mg,Ca,Sr,Ba,La,Y and Lu)with ethylenediamine-N,N′-diacetate-N, N′-di-β-propionate have been studied by proton nuclear magnetic resonance(PMR).The interesting quartet spectral pattern of acetate protons and multiplet spectral pattern of protons of propionate groups for the complexes of metal ions of high charge density have been observed.The results show that the chemical bond for these complexes is predominantly ionic and the lability of metal-nitrogen bond as well as metal- oxygen bond decreases with increasing charge density of cations.

Terahertz Metamaterial Sensor Based on Electromagnetically Induced Transparency Effect

A terahertz metamaterial sensor adopting the metamaterial-based electromagnetically induced transparency（EIT） effect is presented for determining the 1,4-dioxane concentration in its aqueous solution. The metamaterial sensor, which consists of an EIT element unit with a cut-wire metallic resonator and two split-ring metallic resonators fabricated on a 490-μm thick silicon substrate, operates in a transmission geometry. The EIT peak was red-shifted and decreased with the increase of the water volume. A maximum redshift about 54 GHz of the EIT peak was detected between the 1,4-dioxane and water. The presented linear behavior and high sensitivity of the EIT peak depending on the water concentration pave a novel avenue for sensor applications.

Ultra-wideband RCS reduction using novel configured chessboard metasurface

A novel artificial magnetic conductor（AMC） metasurface is proposed with ultra-wideband 180？phase difference for radar cross section（RCS） reduction. It is composed of two dual-resonant AMC cells, which enable a broadband phase difference of 180°±30°from 7.9 GHz to 19.2 GHz to be achieved. A novel strategy is devised by dividing each rectangular grid in a chessboard configuration into four triangular grids, leading to a further reduction of peak bistatic RCS. Both fullwave simulation and measurement results show that the proposed metasurface presents a good RCS reduction property over an ultra-wideband frequency range.

Guest Editorial——TTA Special Section on Terahertz Functional Devices

Terahertz（THz）radiation has been extensively investigated in recent years due to its potential applications in communication,homeland security,safety inspection,sensing,and imaging.For a common THz system,three parts are quite important：THz sources,THz detectors,and THz functional devices.

New design of triplexer based on metal–insulator–metal plasmonic ring resonators

In this work, we propose a new design of all-optical triplexer based on of metal–insulator–metal（MIM） plasmonic waveguide structures and ring resonators. By adjusting the radii of ring resonators and the gap distance, certain wavelengths can be filtered out and the crosstalk of each channel can also be reduced. The numerical results show that the proposed MIM plasmonic waveguide structure can really function as an optical triplexer with respect to the three wavelengths, that is, 1310, 1490, and 1550 nm, respectively. It can be widely used as the fiber access network element for multiplexer–demultiplexer wavelength selective in fiber-to-the-home communication systems with transmission efficiency higher than 90%. It can also be a potential key component in the applications of the biosensing systems.

Advances in single-particle detection for DNA sensing

Rapid, accurate and sensitive detection of particular DNA sequence is critical in fundamental biomedical research and clinical diagnostics. However, conventional approaches for DNA assay often suffer from cumbersome procedures, long analysis time and insufficient sensitivity. Recently, single-particle detection technology has emerged as a powerful tool in the biosensing area due to its significant advantages of ultrahigh sensitivity, low sample-consumption and rapid analysis time. Especially, the introduction of novel nanomaterials has greatly promoted the development of single-particle detection and its applications for DNA sensing. In this review, we summarize the recent advance in single-particle detection strategies for DNA sensing, and focus mainly on metallic nanoparticle-and semiconductor quantum dot-based single-particle detection. We highlight the emerging trends in this field as well.

Highly sensitive and selective two-photon sensing of cartap using Au@Ag core-shell nanoparticles

A highly sensitive and selective two-photon sensing scheme for detection of cartap was developed by using Au@Ag bimetallic core-shell nanoparticles.Cartap was found to induce the aggregation of Au@Ag nanoparticles and up to 700-fold enhancement in two-photon photoluminescence.Huge enhancement in two-photon photoluminescence allows achieving a detection limit of as low as 0.0062 mg/kg,which is better than the conventional colorimetric methods.This two-photon sensing scheme has a broad dynamic range and displays excellent selectivity in detection of cartap against over other ten kinds of commonly used insecticides.

Topology and analysis of an N-stage cascaded polymer eight-port microring optical router with 7N channel wavelengths

Eight-port optical routers are widely used in cluster-mesh photonic networks-on-chip(No C). By using 24 groups of cross-coupling two-ring resonators, a 1-stage 8-port polymer optical router is proposed, which can optically route 7 channel wavelength data streams along definite path in two-dimensional(2D) plane. Under the selected 7 channel wavelengths, the insertion losses along all routing paths are within 0.02-0.58 d B, the maximum crosstalk of all routing operations is less than-39 d B, and the device footprint size is about 0.79 mm2. Then, a universal novel structure and routing scheme of N-stage cascaded 8-port optical router are presented, which contains 7N channel wavelengths. Because of the good scalability in wavelength, this device shows potential application of wideband signal routing in optical No C.

A novel terahertz device with multi-function of polarization and switch based on phase transition of VO_2

A terahertz(THz) polarizer and switch structure is proposed based on the phase transition of vanadium dioxide(VO_2). When VO_2 is in the insulation phase, the resonance frequencies of the proposed structure are 1.49 THz and 1.22 THz for the x- and y-polarization, respectively. It can perform as a THz polarizer with extinction ratios of 52.5 dB and 17 dB for the y- and x-polarization, respectively; When VO_2 transforms into metallic phase, the resonance frequency for x-polarization wave shifts from 1.49 THz to 1.22 THz, while that remains still for the y-polarization component. It means that the structure can work as a polarization-dependent THz switch with a high extinction ratio of 32 dB.