A group of theoretical models has been developed for analyzingtransient dynamic re- sponse to filled metallic cylindrical shellsimpacted by flat-nosed missiles at normal obliquity on the ba- sis ofthe analogy modeling...A group of theoretical models has been developed for analyzingtransient dynamic re- sponse to filled metallic cylindrical shellsimpacted by flat-nosed missiles at normal obliquity on the ba- sis ofthe analogy modeling method of beam-on-foundation. It can be used forsolving the global defor- mation and the local failure of cylindricalshells in the impact process. the ballistic limit speed and im- pactresponse history have been calculated by this group of theoreticalmodels, and the inner pressure effect on the ballistic limit speedand some parameters are discussed at length.展开更多
We prepared a kind of metal oxide-modified walnut-shell activated carbon(MWAC) by KOH chemical activation method and used for PH_3 adsorption removal. Meanwhile, the PH_3 adsorption equilibrium was investigated experi...We prepared a kind of metal oxide-modified walnut-shell activated carbon(MWAC) by KOH chemical activation method and used for PH_3 adsorption removal. Meanwhile, the PH_3 adsorption equilibrium was investigated experimentally and fitted by the Toth equation, and the isosteric heat of PH_3 adsorption was calculated by the Clausius-Clapeyron Equation. The exhausted MWAC was regenerated by water washing and air drying. Moreover, the properties of five different samples were characterized by N_2 adsorption isotherm, SEM/EDS, XPS, and FTIR. The results showed that the maximum PH_3 equilibrium adsorption capacity was 595.56 mg/g. The MWAC had an energetically heterogeneous surface due to values of isosteric heat of adsorption ranging from 43 to 90 kJ/mol. The regeneration method provided an effective way for both adsorption species recycling and exhausted carbon regeneration. The high removal efficiency and big equilibrium adsorption capacity for PH_3 adsorption on the MWAC were related to its large surface area and high oxidation activity in PH_3 adsorption-oxidation to H_3 PO_4 and P_2 O_5. Furthermore, a possible PH_3 adsorption mechanism was proposed.展开更多
Developing low-cost, high-performance catalysts is of fundamental significance for electrochemical energy conversion and storage. In recent years, metal@carbon core@shell nanocomposites have emerged as a unique class ...Developing low-cost, high-performance catalysts is of fundamental significance for electrochemical energy conversion and storage. In recent years, metal@carbon core@shell nanocomposites have emerged as a unique class of functional nanomaterials that show apparent electrocatalytic activity towards a range of reactions, such as hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, and CO2 reduction reaction, that are important in water splitting, fuel cells and metal-air batteries. The activity is primarily attributed to interfacial charge transfer from the metal core to the carbon shell that manipulate the electronic interactions between the catalyst surface and reaction intermediates, and varies with the structures and morphologies of the metal core(elemental composition, core size, etc.) and carbon shell(doping,layer thickness, etc.). Further manipulation can be achieved by the incorporation of a third structural component. A perspective is also included highlighting the current gap between theoretical modeling and experimental results, and technical challenges for future research.展开更多
Research on the expansion and fracture of explosively driven metal shells has been a key issue in weapon development and structural protection.It is important to study and predict the failure mode,fracture mechanism,a...Research on the expansion and fracture of explosively driven metal shells has been a key issue in weapon development and structural protection.It is important to study and predict the failure mode,fracture mechanism,and fragment distribution characteristics of explosively driven metal shells.In this study,we used the finite element-smoothed particle hydrodynamics(FE-SPH)adaptive method and the fluid-structure interaction method to perform a three-dimensional numerical simulation of the expansion and fracture of a metal cylindrical shell.Our method combined the advantages of the FEM and SPH,avoiding system mass loss,energy loss,and element distortion;in addition,the proposed method had a good simulation effect on the interaction between detonation waves and the cylindrical shell.The simulated detonation wave propagation,shell damage morphology,and fragment velocity distribution were in good agreement with theoretical and experimental results.We divided the fragments into three regions based on their shape characteristics.We analyzed the failure mode and formation process of fragments in different regions.The numerical results reproduced the phenomenon in which cracks initiated from the inner surface and extended to the outer surface of the cylindrical shell along the 45°or 135°shear direction.In addition,fragments composed of elements are identified,and the mass and characteristic lengths of typical fragments at a stable time are provided.Furthermore,the mass and size distribution characteristics of the fragments were explored,and the variation in the fitting results of the classical distribution function under different explosion pressures was examined.Finally,based on mathematical derivation,the distribution formula of fragment velocity was improved.The improved formula provided higher accuracy and could be used to analyze any metal cylindrical shells with different length-to-diameter ratios.展开更多
基金Shanxi Natural Science and Returnee Foundations(No.971004)
文摘A group of theoretical models has been developed for analyzingtransient dynamic re- sponse to filled metallic cylindrical shellsimpacted by flat-nosed missiles at normal obliquity on the ba- sis ofthe analogy modeling method of beam-on-foundation. It can be used forsolving the global defor- mation and the local failure of cylindricalshells in the impact process. the ballistic limit speed and im- pactresponse history have been calculated by this group of theoreticalmodels, and the inner pressure effect on the ballistic limit speedand some parameters are discussed at length.
基金Funded by the National Natural Science Foundation of China(51566017)
文摘We prepared a kind of metal oxide-modified walnut-shell activated carbon(MWAC) by KOH chemical activation method and used for PH_3 adsorption removal. Meanwhile, the PH_3 adsorption equilibrium was investigated experimentally and fitted by the Toth equation, and the isosteric heat of PH_3 adsorption was calculated by the Clausius-Clapeyron Equation. The exhausted MWAC was regenerated by water washing and air drying. Moreover, the properties of five different samples were characterized by N_2 adsorption isotherm, SEM/EDS, XPS, and FTIR. The results showed that the maximum PH_3 equilibrium adsorption capacity was 595.56 mg/g. The MWAC had an energetically heterogeneous surface due to values of isosteric heat of adsorption ranging from 43 to 90 kJ/mol. The regeneration method provided an effective way for both adsorption species recycling and exhausted carbon regeneration. The high removal efficiency and big equilibrium adsorption capacity for PH_3 adsorption on the MWAC were related to its large surface area and high oxidation activity in PH_3 adsorption-oxidation to H_3 PO_4 and P_2 O_5. Furthermore, a possible PH_3 adsorption mechanism was proposed.
基金National Science Foundation (CHE1710408) for partial support of the work
文摘Developing low-cost, high-performance catalysts is of fundamental significance for electrochemical energy conversion and storage. In recent years, metal@carbon core@shell nanocomposites have emerged as a unique class of functional nanomaterials that show apparent electrocatalytic activity towards a range of reactions, such as hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, and CO2 reduction reaction, that are important in water splitting, fuel cells and metal-air batteries. The activity is primarily attributed to interfacial charge transfer from the metal core to the carbon shell that manipulate the electronic interactions between the catalyst surface and reaction intermediates, and varies with the structures and morphologies of the metal core(elemental composition, core size, etc.) and carbon shell(doping,layer thickness, etc.). Further manipulation can be achieved by the incorporation of a third structural component. A perspective is also included highlighting the current gap between theoretical modeling and experimental results, and technical challenges for future research.
基金supported by the National Natural Science Foundation of China(Grant No.11872118,11627901)。
文摘Research on the expansion and fracture of explosively driven metal shells has been a key issue in weapon development and structural protection.It is important to study and predict the failure mode,fracture mechanism,and fragment distribution characteristics of explosively driven metal shells.In this study,we used the finite element-smoothed particle hydrodynamics(FE-SPH)adaptive method and the fluid-structure interaction method to perform a three-dimensional numerical simulation of the expansion and fracture of a metal cylindrical shell.Our method combined the advantages of the FEM and SPH,avoiding system mass loss,energy loss,and element distortion;in addition,the proposed method had a good simulation effect on the interaction between detonation waves and the cylindrical shell.The simulated detonation wave propagation,shell damage morphology,and fragment velocity distribution were in good agreement with theoretical and experimental results.We divided the fragments into three regions based on their shape characteristics.We analyzed the failure mode and formation process of fragments in different regions.The numerical results reproduced the phenomenon in which cracks initiated from the inner surface and extended to the outer surface of the cylindrical shell along the 45°or 135°shear direction.In addition,fragments composed of elements are identified,and the mass and characteristic lengths of typical fragments at a stable time are provided.Furthermore,the mass and size distribution characteristics of the fragments were explored,and the variation in the fitting results of the classical distribution function under different explosion pressures was examined.Finally,based on mathematical derivation,the distribution formula of fragment velocity was improved.The improved formula provided higher accuracy and could be used to analyze any metal cylindrical shells with different length-to-diameter ratios.
基金This work was supported by the National Natural Science Foundation of China （Grant Nos. 41172110 and 61107090） and Shandong Provincial Natural Science Foundation （Grant No. ZR2011BZ007）.
