Variable strain rate tension tests for 4 metallic materials show that as the strain rate in creases the strain hardening exponent n decreases. The trend follows a two stage linear relation between n and Ig (?). When (...Variable strain rate tension tests for 4 metallic materials show that as the strain rate in creases the strain hardening exponent n decreases. The trend follows a two stage linear relation between n and Ig (?). When (?) < (?)cp, i.e. under quasi-static loading, n can be considered as a constant, but when (?)>(?)cp, n decreases rapidly till an ideal plastic state. n = 0. The characterizations and mechanisms of softening induced by high (?) are discussed.展开更多
The homogenized response of metal matrix composites(MMC) is studied using strain gradient plasticity.The material model employed is a rate independent formulation of energetic strain gradient plasticity at the micro...The homogenized response of metal matrix composites(MMC) is studied using strain gradient plasticity.The material model employed is a rate independent formulation of energetic strain gradient plasticity at the micro scale and conventional rate independent plasticity at the macro scale. Free energy inside the micro structure is included due to the elastic strains and plastic strain gradients. A unit cell containing a circular elastic fiber is analyzed under macroscopic simple shear in addition to transverse and longitudinal loading. The analyses are carried out under generalized plane strain condition. Micro-macro homogenization is performed observing the Hill-Mandel energy condition,and overall loading is considered such that the homogenized higher order terms vanish. The results highlight the intrinsic size-effects as well as the effect of fiber volume fraction on the overall response curves, plastic strain distributions and homogenized yield surfaces under different loading conditions. It is concluded that composites with smaller reinforcement size have larger initial yield surfaces and furthermore,they exhibit more kinematic hardening.展开更多
The toxicity of heavy metals (Hg2 + , Zn2 + ) and pesticides has been investigated by comparing the physiological properties in wild and tolerant strains of Synechococcus cedrorum 1191. The differential pattern of gro...The toxicity of heavy metals (Hg2 + , Zn2 + ) and pesticides has been investigated by comparing the physiological properties in wild and tolerant strains of Synechococcus cedrorum 1191. The differential pattern of growth, absorption spectra of pigments and nutrient uptake was observed in tolerant strain.展开更多
Various biaxial compressive strained GaSb p-channel metal-oxide-semiconductor field-effect transistors (MOSFETs) are experimentally and theoretically investigated, The biaxial compressive strained GaSb MOSFETs show ...Various biaxial compressive strained GaSb p-channel metal-oxide-semiconductor field-effect transistors (MOSFETs) are experimentally and theoretically investigated, The biaxial compressive strained GaSb MOSFETs show a high peak mobility of 638 cm2/V.s, which is 3.86 times of the extracted mobility of the fabricated GaSb MOSFETs without strain. Meanwhile, first principles calculations show that the hole effective mass of GaSb depends on the biaxial compressive strain. The biaxiai compressive strain brings a remarkable enhancement of the hole mobility caused by a significant reduction in the hole effective mass due to the modulation of the valence bands.展开更多
The electronic properties of TiO2-terminated BaTiO3(001) surface subjected to biaxial strain have been studied using first-principles calculations based on density functional theory. The Ti ions are always inward s...The electronic properties of TiO2-terminated BaTiO3(001) surface subjected to biaxial strain have been studied using first-principles calculations based on density functional theory. The Ti ions are always inward shifted either at compressive or tension strains, while the inward shift of the Ba ions occurs only for high compressive strain, implying an enhanced electric dipole moment in the case of high compressive strain. In particular, an insulator–metal transition is predicted at a compressive biaxial strain of 0.0475. These changes present a very interesting possibility for engineering the electronic properties of ferroelectric BaTiO3(001) surface.展开更多
Quasi-static and high strain rate mechanical behavior of the Zr_ 1.25Ti_ 13.75Ni_ 10Cu_ 12.5Be_ 22.5 bulk metallic glass was determined covering strain rates from 1.02×10 -4s -1 to 3.258×103s -1. By use ...Quasi-static and high strain rate mechanical behavior of the Zr_ 1.25Ti_ 13.75Ni_ 10Cu_ 12.5Be_ 22.5 bulk metallic glass was determined covering strain rates from 1.02×10 -4s -1 to 3.258×103s -1. By use of split hopkinson pressure bar(SHPB) equipment, it is found that the alloy fractures in the high strain rate period with a strength well below that of its quasi-static counterpart and thus a strain rate induced embrittlement happens. Considering the glassy nature of the alloy and with careful analysis of the fracture morphology, dynamic damage accumulated in the high speed deformation period is suggested to be the reason for this embrittlement.展开更多
Recently, two dimensional In Se attracts great attentions as potential hydrogen production photocatalysts.Here, comprehensive investigations on the hydrogen evolution reaction activity of In Se monolayer with3 d trans...Recently, two dimensional In Se attracts great attentions as potential hydrogen production photocatalysts.Here, comprehensive investigations on the hydrogen evolution reaction activity of In Se monolayer with3 d transition metal doping and biaxial strain were performed based on the density functional theory.Transition metal dopants significantly increase the bonding strength between H and Se, and then adjust the hydrogen adsorption free energy to 0.02 e V by Zn doping. The enhanced hydrogen evolution reaction activity results from less electron occupying H 1 s-Se 4 pzanti-bonding states, which is well correlated with the pzband center level. Importantly, the universal scalling law was proposed to descript the evolution of hydrogen adsorption free energy including both doping and strain effects. Moreover, with appropriate band alignment, optical absorption, and carriers separation ability, Zn doped In Se monolayer is considered as a promising candidate of visible-light photocatalyst for hydrogen production.展开更多
TiN_p/1N90Al composite was fabricated by powder metallurgy method with a reinforcement volume fraction of 15%. The tensile experiment, DSC and SEM were used to study the high strain rate superplasticity of the TiN_p/1...TiN_p/1N90Al composite was fabricated by powder metallurgy method with a reinforcement volume fraction of 15%. The tensile experiment, DSC and SEM were used to study the high strain rate superplasticity of the TiN_p/1N90Al composite. The DSC result shows that the incipient melting temperature of the TiN_p/1N90Al composite is 906K. The tensile tests were carried out over a range of deformation temperature from 918 to 928K and strain rate from 1.7 to 1.7×10 -3 s -1. The maximum elongation of 201% is realized at 923K with a strain rate of 1.7×10 -1 s -1. Otherwise all the elongations are higher than 100% in the strain rate range of 3.3×10 -2-6.7×10 -1 s -1 at the three deformation temperatures. The curves of m value of the TiN_p/1N90Al composite can be divided into two stages with the variation of strain rate at different deformation temperatures and the critical strain rate of 10 -1 s -1. When the strain rate is higher than 10 -1 s -1, the m values of the three curves are smaller than 0.3, but the m values of the three curves are about 0.37 when the strain rate is higher than 10 -1 s -1.展开更多
The corresponding positions of different metal plastic working processes in the plane stress state on a Mises yield ellipse are described.The paper points out that the forming of a workpiece inside its die is correspo...The corresponding positions of different metal plastic working processes in the plane stress state on a Mises yield ellipse are described.The paper points out that the forming of a workpiece inside its die is corresponding to a mass point moving along the ellipse and that its dimensional variation tendency in all directions can be judged according to a correspondence rule of the stress-strain order offered by the author.In addition,the paper also presents the corresponding three-dimensional positions of different metal plastic working processes on the Mises cylinder,from which the deformation force and technological plasticity required in different processes can be compared,and the dimensional variation tendency can be predicted.The analysis method used in this paper is not to calculate the variation of each stress component(σx,σy,σz) by convention,but to emphasize the variation of the stress state in the typical position,which is expressed correspondingly as the varying locus of points in principal stress space,and then based on the analysis the strain result is judged.展开更多
Ni/Au Schottky contacts on AlN/GaN and AlGaN/GaN heterostructures are fabricated. Based on the measured current-voltage and capacitance-voltage curves, the polarization sheet charge density and relative permittivity a...Ni/Au Schottky contacts on AlN/GaN and AlGaN/GaN heterostructures are fabricated. Based on the measured current-voltage and capacitance-voltage curves, the polarization sheet charge density and relative permittivity are analyzed and calculated by self-consistently solving Schrodinger's and Poisson's equations. It is found that the values of relative permittivity and polarization sheet charge density of AlN/GaN diode are both much smaller than the ones of AlGaN/GaN diode, and also much lower than the theoretical values. Moreover, by fitting the measured forward 1-V curves, the extracted dislocations existing in the barrier layer of the AlN/GaN diode are found to be much more than those of the AlGaN/GaN diode. As a result, the conclusion can be made that compared with AlGaN/GaN diode the Schottky metal has an enhanced influence on the strain of the extremely thinner AlN barrier layer, which is attributed to the more dislocations.展开更多
Instantaneous creep in face-centered cubic metals, 5N Al(99.999%), 2N Al (99%) and 4N Cu (99.99%) with different grain sizes, was firstly investigated by sudden stress-change experiments at ultra- low strain rat...Instantaneous creep in face-centered cubic metals, 5N Al(99.999%), 2N Al (99%) and 4N Cu (99.99%) with different grain sizes, was firstly investigated by sudden stress-change experiments at ultra- low strain rates ε ≤10-10 s-1 and temperature T 〈 0.32 Tn. The experimental results indicate that the observed instantaneous creep is strongly dependent on grain size, the concentration of impurity, and stacking fault energy. Creep in high-purity aluminum, 5N Al, with a very large grain size, d 〉 1600μm, shows non-viscous behavior, and is controlled by the recovery of dislocations in the boundary of dislocation cells. On the other hand, for 5N A1 with a small grain size, d=30μm, and low-purity aluminum, 2N A1, with d8= 25μm, creep shows viscous behavior and may be related to 'low temperature grain boundary sliding'. For high-purity copper, 4N Cu, with d= 40 grn and lower stacking fault energy, creep shows a non-viscous behavior, and is controlled by the recovery process of dislocations. For all of the samples, creep shows anelastic behavior.展开更多
The loading-unloading-reloading process could affect the tensile deformation of metals with the combined function of stress relaxation and work hardening, which has been reported in multiple experiments. Nevertheless,...The loading-unloading-reloading process could affect the tensile deformation of metals with the combined function of stress relaxation and work hardening, which has been reported in multiple experiments. Nevertheless, the effects of different unloading positions and unloading times have not been investigated. In this study, unloading-reloading tests on three materials (AL6061, HSLA and Q195) were conducted. The stress exhibits a rapid rise momentarily upon reloading and stabilizes afterward while the post stress-strain curve deviates up or down from the monotonic tensile curve. The ductility is enhanced by the unloading-reloading process in general. Different unloading positions and unloading times have different degrees of influence on the stretching of these metals. The effect of loading conditions on a medium manganese steel was further studied. The functions to modify the post stress-strain relationship after unloading-reloading were established.展开更多
文摘Variable strain rate tension tests for 4 metallic materials show that as the strain rate in creases the strain hardening exponent n decreases. The trend follows a two stage linear relation between n and Ig (?). When (?) < (?)cp, i.e. under quasi-static loading, n can be considered as a constant, but when (?)>(?)cp, n decreases rapidly till an ideal plastic state. n = 0. The characterizations and mechanisms of softening induced by high (?) are discussed.
基金supported by the Danish Research Council for Technology and Production Sciences in a project entitled Plasticity Across the Scales
文摘The homogenized response of metal matrix composites(MMC) is studied using strain gradient plasticity.The material model employed is a rate independent formulation of energetic strain gradient plasticity at the micro scale and conventional rate independent plasticity at the macro scale. Free energy inside the micro structure is included due to the elastic strains and plastic strain gradients. A unit cell containing a circular elastic fiber is analyzed under macroscopic simple shear in addition to transverse and longitudinal loading. The analyses are carried out under generalized plane strain condition. Micro-macro homogenization is performed observing the Hill-Mandel energy condition,and overall loading is considered such that the homogenized higher order terms vanish. The results highlight the intrinsic size-effects as well as the effect of fiber volume fraction on the overall response curves, plastic strain distributions and homogenized yield surfaces under different loading conditions. It is concluded that composites with smaller reinforcement size have larger initial yield surfaces and furthermore,they exhibit more kinematic hardening.
文摘The toxicity of heavy metals (Hg2 + , Zn2 + ) and pesticides has been investigated by comparing the physiological properties in wild and tolerant strains of Synechococcus cedrorum 1191. The differential pattern of growth, absorption spectra of pigments and nutrient uptake was observed in tolerant strain.
基金Project supported by the National Basic Research Program of China(Grant No.2011CBA00602)the National Science and Technology Major Project of the Ministry of Science and Technology of China(Grant No.2011ZX02708-002)
文摘Various biaxial compressive strained GaSb p-channel metal-oxide-semiconductor field-effect transistors (MOSFETs) are experimentally and theoretically investigated, The biaxial compressive strained GaSb MOSFETs show a high peak mobility of 638 cm2/V.s, which is 3.86 times of the extracted mobility of the fabricated GaSb MOSFETs without strain. Meanwhile, first principles calculations show that the hole effective mass of GaSb depends on the biaxial compressive strain. The biaxiai compressive strain brings a remarkable enhancement of the hole mobility caused by a significant reduction in the hole effective mass due to the modulation of the valence bands.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.1574091,51272078,and 51431006)the Natural Science Foundation of Guangdong Province of China(Grant No.2015A030313375)+1 种基金the Science and Technology Planning Project of Guangdong Province of China(Grant No.2015B090927006)the Program for International Innovation Cooperation Platform of Guangzhou City,China(Grant No.2014J4500016)
文摘The electronic properties of TiO2-terminated BaTiO3(001) surface subjected to biaxial strain have been studied using first-principles calculations based on density functional theory. The Ti ions are always inward shifted either at compressive or tension strains, while the inward shift of the Ba ions occurs only for high compressive strain, implying an enhanced electric dipole moment in the case of high compressive strain. In particular, an insulator–metal transition is predicted at a compressive biaxial strain of 0.0475. These changes present a very interesting possibility for engineering the electronic properties of ferroelectric BaTiO3(001) surface.
文摘Quasi-static and high strain rate mechanical behavior of the Zr_ 1.25Ti_ 13.75Ni_ 10Cu_ 12.5Be_ 22.5 bulk metallic glass was determined covering strain rates from 1.02×10 -4s -1 to 3.258×103s -1. By use of split hopkinson pressure bar(SHPB) equipment, it is found that the alloy fractures in the high strain rate period with a strength well below that of its quasi-static counterpart and thus a strain rate induced embrittlement happens. Considering the glassy nature of the alloy and with careful analysis of the fracture morphology, dynamic damage accumulated in the high speed deformation period is suggested to be the reason for this embrittlement.
基金supported by the National Natural Science Foundation of China(11804023)the Natural Science Foundation of Tianjin(18JCQNJC02700)。
文摘Recently, two dimensional In Se attracts great attentions as potential hydrogen production photocatalysts.Here, comprehensive investigations on the hydrogen evolution reaction activity of In Se monolayer with3 d transition metal doping and biaxial strain were performed based on the density functional theory.Transition metal dopants significantly increase the bonding strength between H and Se, and then adjust the hydrogen adsorption free energy to 0.02 e V by Zn doping. The enhanced hydrogen evolution reaction activity results from less electron occupying H 1 s-Se 4 pzanti-bonding states, which is well correlated with the pzband center level. Importantly, the universal scalling law was proposed to descript the evolution of hydrogen adsorption free energy including both doping and strain effects. Moreover, with appropriate band alignment, optical absorption, and carriers separation ability, Zn doped In Se monolayer is considered as a promising candidate of visible-light photocatalyst for hydrogen production.
文摘TiN_p/1N90Al composite was fabricated by powder metallurgy method with a reinforcement volume fraction of 15%. The tensile experiment, DSC and SEM were used to study the high strain rate superplasticity of the TiN_p/1N90Al composite. The DSC result shows that the incipient melting temperature of the TiN_p/1N90Al composite is 906K. The tensile tests were carried out over a range of deformation temperature from 918 to 928K and strain rate from 1.7 to 1.7×10 -3 s -1. The maximum elongation of 201% is realized at 923K with a strain rate of 1.7×10 -1 s -1. Otherwise all the elongations are higher than 100% in the strain rate range of 3.3×10 -2-6.7×10 -1 s -1 at the three deformation temperatures. The curves of m value of the TiN_p/1N90Al composite can be divided into two stages with the variation of strain rate at different deformation temperatures and the critical strain rate of 10 -1 s -1. When the strain rate is higher than 10 -1 s -1, the m values of the three curves are smaller than 0.3, but the m values of the three curves are about 0.37 when the strain rate is higher than 10 -1 s -1.
文摘The corresponding positions of different metal plastic working processes in the plane stress state on a Mises yield ellipse are described.The paper points out that the forming of a workpiece inside its die is corresponding to a mass point moving along the ellipse and that its dimensional variation tendency in all directions can be judged according to a correspondence rule of the stress-strain order offered by the author.In addition,the paper also presents the corresponding three-dimensional positions of different metal plastic working processes on the Mises cylinder,from which the deformation force and technological plasticity required in different processes can be compared,and the dimensional variation tendency can be predicted.The analysis method used in this paper is not to calculate the variation of each stress component(σx,σy,σz) by convention,but to emphasize the variation of the stress state in the typical position,which is expressed correspondingly as the varying locus of points in principal stress space,and then based on the analysis the strain result is judged.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.61306113,60876009,and 11174182)
文摘Ni/Au Schottky contacts on AlN/GaN and AlGaN/GaN heterostructures are fabricated. Based on the measured current-voltage and capacitance-voltage curves, the polarization sheet charge density and relative permittivity are analyzed and calculated by self-consistently solving Schrodinger's and Poisson's equations. It is found that the values of relative permittivity and polarization sheet charge density of AlN/GaN diode are both much smaller than the ones of AlGaN/GaN diode, and also much lower than the theoretical values. Moreover, by fitting the measured forward 1-V curves, the extracted dislocations existing in the barrier layer of the AlN/GaN diode are found to be much more than those of the AlGaN/GaN diode. As a result, the conclusion can be made that compared with AlGaN/GaN diode the Schottky metal has an enhanced influence on the strain of the extremely thinner AlN barrier layer, which is attributed to the more dislocations.
基金Funded by the Tianjin Research Program of Application Foundation and Advanced Technology(12JCYBJC32100)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministryin part by Grants-in-Aid from the Japan Society for the Promotion of Science(JSPS)
文摘Instantaneous creep in face-centered cubic metals, 5N Al(99.999%), 2N Al (99%) and 4N Cu (99.99%) with different grain sizes, was firstly investigated by sudden stress-change experiments at ultra- low strain rates ε ≤10-10 s-1 and temperature T 〈 0.32 Tn. The experimental results indicate that the observed instantaneous creep is strongly dependent on grain size, the concentration of impurity, and stacking fault energy. Creep in high-purity aluminum, 5N Al, with a very large grain size, d 〉 1600μm, shows non-viscous behavior, and is controlled by the recovery of dislocations in the boundary of dislocation cells. On the other hand, for 5N A1 with a small grain size, d=30μm, and low-purity aluminum, 2N A1, with d8= 25μm, creep shows viscous behavior and may be related to 'low temperature grain boundary sliding'. For high-purity copper, 4N Cu, with d= 40 grn and lower stacking fault energy, creep shows a non-viscous behavior, and is controlled by the recovery process of dislocations. For all of the samples, creep shows anelastic behavior.
文摘The loading-unloading-reloading process could affect the tensile deformation of metals with the combined function of stress relaxation and work hardening, which has been reported in multiple experiments. Nevertheless, the effects of different unloading positions and unloading times have not been investigated. In this study, unloading-reloading tests on three materials (AL6061, HSLA and Q195) were conducted. The stress exhibits a rapid rise momentarily upon reloading and stabilizes afterward while the post stress-strain curve deviates up or down from the monotonic tensile curve. The ductility is enhanced by the unloading-reloading process in general. Different unloading positions and unloading times have different degrees of influence on the stretching of these metals. The effect of loading conditions on a medium manganese steel was further studied. The functions to modify the post stress-strain relationship after unloading-reloading were established.
基金Fundamental Research Funds for the Central Universities,China(No.2232022D-13)Fundamental Research Funds for the Central Universities and Graduate Student Innovation Fund of Donghua University,China(No.CUSF-DH-D-2022034)。