Liquid metal welding enabling high loading binder/carbon-free layered oxide cathode toward high-performance liquid and solid-state battery

High loading cathode with high active material proportion is a practical demand but far below the desirable value to achieve high energy density lithium-ion batteries(LIBs).Normally,the Li^(+)/electron transport between active materials and electrolyte/c arbon,however,it is poor and areal resistance is extremely high for a high loading/thick cathode.In this manuscript,taking high-voltage lithium cobalt oxide LiCoO_(2)(LCO)as an example,we design a facile liquid metal welding method enabled by a low melting-point indium-tin oxide In_(2)O_(3)/SnO_(2)(ITO)during a thermal treatment process,the strongly adhesion active particles show robust mechanical property for the free-standing LCO cathode with a pellet architecture.We also demonstrate that the O_(2)atmosphere plays a critical role on the interfacial property,that is preventing the layered structure to rock-salt Co_(3)O_(4)as well as further enhancing the interfacial mechanical integration.As expected,the LCO-ITO free-standing cathode not only shows robust mechanical property with densely packed configuration but also provides a fast Li^(+)/electron pathway at the interface.Consequently,the LCO-ITO composite cathode exhibits excellent electrochemical cycling performance in both liquid and solid-state cells.For example,even at a high active material mass of 56 mg·cm^(-2),the LCO cathode still delivers a specific capacity of 151 mAh·g^(-1)and maintains132.5 mAh·g^(-1)(corresponding to 7.4 mAh·cm^(-2))after 80cycles.The LCO-ITO-O_(2)cathode is also applicable to a solidstate cell,which exhibits a high capacity of 100.4 mAh·g^(-1)after 200 cycles of long-term cycling.The excellent electrochemical of the LCO-ITO-O_(2)reveals the successful engineering mechanical architecture and interfacial carriers transport,which may be expected as an alternative approach to achieve high energy density LIBs.

Study on gas metal arc welding of two types of TMCP steels

Gas metal arc welding experiments were conducted on two types of steels with 0.41% carbon equivalent(Ceq) and 0.31% Cequsing WER70T wire and 20% CO_(2)and 80% Ar as shielding gas.The two types of steels show satisfactory weldability.The transition temperatures of 50% upper shelf energy(Tk0.5) for Charpy-V impact test of both the welded joints are below-40 ℃.However, the toughness of the fusion line zone and heat-affected zone(HAZ) of the two steel joints exhibits differences, with the toughness of 0.41% Ceqsteel being better than that of 0.31% Ceqsteel.The Tk0.5of the fusion line zone and the HAZ of 0.41% Ceqsteel is below-60℃,whereas that of 0.31% Ceqsteel is above-40℃.The welded joint of 0.41% Ceqsteel has low hardness fluctuation, while that of 0.31% Ceqsteel exhibits a narrow, softened zone, which has no obvious influence on the tested tensile strength.The coarse grain heat-affected zone(CGHAZ)microstructure of 0.41% Ceqsteel is bainite, while that of 0.31% Ceqsteel is bainite with ferrite and minor pearlite.

Ultrasonic vibration assisted tungsten inert gas welding of dissimilar metals 316L and L415

Ultrasonic vibration assisted tungsten inert gas welding was applied to joining stainless steel 316 L and low alloy high strength steel L415.The effect of ultrasonic vibration on the microstructure and mechanical properties of a dissimilar metal welded joint of 316 L and L415 was systematically investigated.The microstructures of both heat affected zones of L415 and weld metal were substantially refined,and the clusters ofδferrite in traditional tungsten inert gas(TIG)weld were changed to a dispersive distribution via the ultrasonic vibration.The ultrasonic vibration promoted the uniform distribution of elements and decreased the micro-segregation tendency in the weld.With the application of ultrasonic vibration,the average tensile strength and elongation of the joint was improved from 613 to 650 MPa and from 16.15%to31.54%,respectively.The content ofΣ3 grain boundaries around the fusion line zone is higher and the distribution is more uniform in the ultrasonic vibration assisted welded joint compared with the traditional one,indicating an excellent weld metal crack resistance.

Study on chaos in short circuit gas metal arc welding process

Based on the chaos theory, an idea is put forward to analyze the short circuit Gas Metal Arc Welding （ GMAW-S） process. The theory of phase space reconstruction and related algorithms such as mutual information and so on, are applied to analyze the chaos of the GMAW-S process. The largest Lyapunov exponents of some current time series are calculated, and the results indicate that chaos exists in the GMAW-S process. The research of the chaos in the GMAW-S process can be help to get new knowledge of the process.

Feature Extraction and Dimensionality Reduction of Arc Sound under Typical Penetration Status in Metal Inert Gas Welding

Arc sound is well known as the potential and available resource for monitoring and controlling of the weld penetration status,which is very important to the welding process quality control,so any attentions have been paid to the relationships between the arc sound and welding parameters.Some non-linear mapping models correlating the arc sound to welding parameters have been established with the help of neural networks.However,the research of utilizing arc sound to monitor and diagnose welding process is still in its infancy.A self-made real-time sensing system is applied to make a study of arc sound under typical penetration status,including partial penetration,unstable penetration,full penetration and excessive penetration,in metal inert-gas（MIG） flat tailored welding with spray transfer.Arc sound is pretreated by using wavelet de-noising and short-time windowing technologies,and its characteristics,characterizing weld penetration status,of time-domain,frequency-domain,cepstrum-domain and geometric-domain are extracted.Subsequently,high-dimensional eigenvector is constructed and feature-level parameters are successfully fused utilizing the concept of primary principal component analysis（PCA）.Ultimately,60-demensional eigenvector is replaced by the synthesis of 8-demensional vector,which achieves compression for feature space and provides technical supports for pattern classification of typical penetration status with the help of arc sound in MIG welding in the future.

Computer-based sensing and visualizing of metal transfer mode in gas metal arc welding

Using Xenon lamp lights to overcome the strong interference from the welding arc, a computer-based system is developed to sense and visualize the metal transfer in GMAW. This system combines through-the-arc sensing of the welding current and arc voltage with high speed imaging of the metal transfer. It can simultaneously display the metal transfer processes and waveforms of electrical welding parameters in real-time The metal transfer videos and waveforms of electrical welding parameters can be recorded. Metal transfers under various welding conditions have been investigated with the system developed.

Analysis of weld pool vibration characteristics in pulsed gas metal arc welding

Using highspeed camera image measuring and processing,the contour of the weld pool was extracted accurately in pulsed metal inert gas(P-MIG)welding.Based on this extraction method,time and frequency domain characteristics at different points along the contour of the weld pool were analyzed for one pulse one droplet and one pulse two droplets,respectively.The results show that,because of the wave super position that was created by the pulsed arc and droplet impacting the weld pool,the oscillation amplitude along the weld pool fluctuated and decreased with an increase in distance from the point to the arc center.The oscillation near the arc center was complex and intense for one pulse two droplets,and the amplitude were relatively small because the oscillation caused by the pulsed arc could be offset by the molten droplet impact.The weld pool oscillation that was caused by the pulsed arc was stronger than that caused by the droplet.

Digital control of pulsed gas metal arc welding inverter using TMS320LF2407A

A digital control of pulsed gas metal arc welding inverter was proposed. A control system consisting of analogue parts was replaced with a new digital control implemented in a TMS320LF2407A DSP chip. The design and constructional features of the whole digital control were presented. The resources of the DSP chip were efficiently utilized and the circuits are very concise, which can enhance the stability and reliability of welding inverter. Experimental results demonstrate that the developed digital control has the ability to accomplish the excellent pulsed gas metal arc welding process and the merits of the developed digital control are stable welding process, little spatter and perfect weld appearance.

Elucidation of Metallic Plume and Spatter Characteristics Based on SVM During High-Power Disk Laser Welding

During deep penetration laser welding,there exist plume（weak plasma） and spatters,which are the results of weld material ejection due to strong laser heating.The characteristics of plume and spatters are related to welding stability and quality.Characteristics of metallic plume and spatters were investigated during high-power disk laser bead-on-plate welding of Type 304 austenitic stainless steel plates at a continuous wave laser power of 10 kW.An ultraviolet and visible sensitive high-speed camera was used to capture the metallic plume and spatter images.Plume area,laser beam path through the plume,swing angle,distance between laser beam focus and plume image centroid,abscissa of plume centroid and spatter numbers are defined as eigenvalues,and the weld bead width was used as a characteristic parameter that reflected welding stability.Welding status was distinguished by SVM（support vector machine） after data normalization and characteristic analysis.Also,PCA（principal components analysis） feature extraction was used to reduce the dimensions of feature space,and PSO（particle swarm optimization） was used to optimize the parameters of SVM.Finally a classification model based on SVM was established to estimate the weld bead width and welding stability.Experimental results show that the established algorithm based on SVM could effectively distinguish the variation of weld bead width,thus providing an experimental example of monitoring high-power disk laser welding quality.

Laser Welding of Zr_(41)Ti_(14)Cu_(12)Ni_(10)Be_(23) Bulk Metallic Glass and Zirconium Metal

The laser bonding technology between the Zr41 Ti14 Cu12 Ni10 Be23 bulk metallic glass and zirconium metal was investigated under welding parameters of 1.3 kW and 7 m/min. The welded bead, microstructure, and micro-hardness of the welded joint were examined by Keyence, transmission electron microscopy, scanning electron microscopy, and Vickers hardness, respectively. The experimental results showed that the Zr41 Ti14 Cu12 Ni10 Be2 bulk metallic glass and zirconium metal were successfully bonded together. The Zr41 Ti14 Cu12 Ni10 Be2 in the base material zone maintained amorphous structure, and the welding fusion zone kept the hardness as high as as-received BMG. Therefore, the laser welding technology can be used to achieve successful bonding of bulk metallic glasses and crystallization metal.

Effects of Metal Absorber Thermal Conductivity on Clear Plastic Laser Transmission Welding

In our previous study, metals have been used as absorbers in the clear plastic laser transmission welding. The effects of metal thermal conductivity on the welding quality are investigated in the present work. Four metals with distinctly different thermal conductivities, i.e., titanium, nickel, molybdenum, and copper, are selected as light absorbers. The lap welding is conducted with an 808 nm diode laser and simulation experiments are also conducted. Nickel electroplating test is carried out to minimize the side-effects from different light absorptivities of different metals. The results show that the welding with an absorber of higher thermal conductivity can accommodate higher laser input power before smoking, which produces a wider and stronger welding seam.The positive role of the higher thermal conductivity can be attributed to the fact that a desirable thermal field distribution for the molecular diffusion and entanglement is produced from the case with a high thermal conductivity.

ACQUIRING AND PATTERN RECOGNITION OF SPECTRUM INFORMATION OF WELDING METAL TRANSFER

In order to recognize various metal transfer modes, by the creation of apattern recognition system for metal transfer mode, five kinds of spectrum signal in gas metal arcwelding (MIG, MAG and CO_2) are collected and taken as training samples. These samples arepretreated by computer. Several key characteristic parameters of the spectrum signal are creativelyextracted, and a corresponding recognition function and a minimum-distance-classifier areconstructed. The results show that using this method, the pattern recognition of several kinds ofmetal transfer mode for the metal gas arc welding can be done successfully. It has good accuracy andrecognition precision, basis for controlling the metal gas arc welding metal transferautomatically, and relative important parameters in welding process, such as the frequency ofdroplet transfer and the approximate diameter of each droplet, can also be obtained.

Determining chaotic invariant properties of short-circuiting gas metal arc welding from an observed time series

The experimental time series of welding current produced by carbon dioxide gas metal arc welding with shortcircuiting transfer were recorded and subsequently evaluated. Based on phase space reconstruction, the correlation dimeusions and Kolmogorov entropies of the corresponding system have been numerically calculated using the Grassberger-Procaccia algorithm at different time delays. It was found out that the time delay has little effect on the estimation of correlation dimension; conversely, it plays a key role in producing precise results on the estimation of Kolmogorov entropy.

Microstructure evolution in the weld metal region of a Ni-based Inconel 718 superalloy produced by tungsten inert gas welding

The microstructure evolution of the weld metal （WM） region in a Ni-based 718 superaUoy is discussed. The superalloy sheets were welded using the tungsten inert gas process at different heat inputs. The precipitates and dendrites in the WM of each joint were analyzed by optical microscopy, scanning electron microscopy, and energy dispersive spectroscopy （ EDS）. Statistics on the dendrite arm spacing and precipitates were obtained from the metallographs. Using the alloy composition determined by EDS and the phase diagram obtained using ThermoCalc, the equilibrium distribution coefficient of Nb, the temperature range of solid/liquid coexistence, and the distribution and morphology of Laves phase in different subregion of the WM were analyzed. There is lamellar segregation, regional segregation, and microsegregation in the WM. As the heat input increases, the arm spacing and the microsegregation increase. At a fixed heat input, the microsegregation rate is smallest in the crater, but with the macrosegregation seriously.

Gas metal arc welding of duplex stainless clad steel plates

The 2205 duplex stainless ＋ DH36 clad steel plate was welded by gas metal arc welding（GMAW）, and the welding performance of the clad steel plate was investigated. The results show that the adaptability of the welding procedure for the base metal of carbon steel, the transition layer, and the cladding material is excellent. The test results indicate that the phase proportion and component dilution of the GMAW-welded joints of clad steel plate can be effectively controlled to yield joints with good mechanical properties and corrosion resistance.

Experimental study on gas metal arc welding and laser hybrid welding of WYS700 steel

Gas metal arc welding, laser welding, and laser-metal active gas welding(MAG) hybrid welding methods were applied to WYS700 steel.Different welding procedures were performed and different welding technologies were compared.Macro metallographs of the welded joints were obtained, and the mechanical properties(such as tensile strength, bending property, and hardness) of the joints formed using the different welding technologies were determined.The results revealed that the joint of the WYS700 steel could be formed well through gas metal arc welding, laser welding, and laser-MAG hybrid welding.Furthermore, the softening of the welding heat affected zone can be effectively reduced to obtain good strength and plasticity by using a suitable welding procedure.Laser-MAG hybrid welding allows the realization of high efficiency and deep penetration for the welding of thick plates with specifications above 3 mm.

A novel single wire indirect arc metal inert gas welding process operated in streaming mode

Dilution of a pad weld must be limited to a certain critical level to improve its wear and/or corrosion properties.To do that,a novel single wire indirect arc metal inert gas welding process operated in streaming mode was realized.A metal inert gas welding torch,arranged perpendicular to a substrate in vertical position,is fixed with an auxiliary tungsten electrode horizontally.The arc is ignited between a wire through the torch and the auxiliary electrode.The substrate is not electrically connected.The welding current is set in the range of streaming mode.304 stainless steel was pad welded on Q235 substrates in vertical position by this process.Microstructures were analyzed with optical microscope.Dilution ratios were measured with stereo light microscope and calculated.The results show that,after eliminating interference of the massive torch setup,the dilution ratio of the pad weld with optimized parameters is 5.07%,much less than that with a metal inert gas welding process,which is 26.46%.The pad weld is bonded to the substrate without defects.Microstructures of the pad weld consist of columnar austenite and ferrite between the columns.The dilution ratio increases with increasing welding current or welding velocity,and decreases with increasing distance to the substrate.

Investigate Weld Quality of Gas Metal Arc Welding Process Through Online Monitoring of Input Parameters

Gas metal arc welding(GMAW)is also referred as the metal inert gas(MIG)welding which is a process of welding done by the formation of an electric arc between the consumable wire electrode and the workpiece.Through the welding process,a continuous flow of inert gas is supplied,and it avoids the weld being subjected to react with atmospheric air.The process can be automatic or semi-automatic where the main input parameters like current and the voltage can be direct and constant,respectively.Not only the current and voltage the welding quality depends on some more input parameters such as arc gap,velocity,and temperature.In this paper,we explain about a setup which is capable of real-time monitoring of input parameters mentioned above and selecting the best MIG welding parameters for the mild steel.The setup is composed of several sensors and microcontrollers for the collection and the measurement of the input parameters.The samples were categorized according to the federate and the voltage adjustment of the selected welding machine.Then the final objective was to identify the samples of the weld with different parameter changes which are monitored through the system.For the analysis,the samples were subjected to tensile and hardness tests,and microstructure tests to find the dependence of the input parameters which effect for the weld quality.Finally,the experimental results verified the effectiveness of the system for the selection of the quality weld.

STUDY ON METAL TRANSFER MODES OF SELF-SHIELDED FLUX-CORED WELDING WIRE

Metal transfer behavior of six kinds of self shielded flux cored wire(SSFCW) is studied using the apparatus of SSFCW high speed photography self made. Six kinds of metal transfer modes of SSFCW were obtained through observation for high speed photograph film and analysis. It is believed that the research is of magnificent for improving operative performance and mechanical properties of SSFCW and dynamics characteristic of welding power.

Microstructure and microtexture evolution of aluminum alloy 3003 under ultrasonic welding process for embedding SiC fibre

Ultrasonic welding process can be used for bonding metal foils which is the fundament of ultrasonic consolidation （UC）. UC process can be used to embed reinforcement fibres such as SiC fibres within an aluminum matrix materials. In this research we are investigating the phenomena occurring in the microstructure of the parts during ultrasonic welding process to obtain better understanding about how and why the process works. High-resolution electron backscatter diffraction （ EBSD ） is used to study the effects of the vibration on the evolution of microstructure in AA3003. The inverse pole figures （IPF） and the correlated misorientation angle distribution of the mentioned samples are obtained. The characteristics of the crystallographic orientation, the grain structure and the grain boundary are analyzed to find the effect of ultrasonic vibration on the microstructure and microtexture of the bond. The ultrasonic vibration will lead to exceptional refinement of grains to a micron level along the bond area and affect the crystallographic orientation. Ultrasonic vibration results in a very weak texture. Plastic flow occurs in the grain after welding process and there is additional plastic flow around the fibre which leads to the fibre embedding.