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Novel Properties of Supramolecular Complexes Formed by Pairing Cationic Porphyrin and Anionic Metal-Oxo Cluster
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作者 Shu Qing LIU Ji Qing XU Hao Ran SUN Department of Chemistry, Jilin University, Changchun 130023 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第9期831-834,共4页
MTBPyP (meso-tetrakis(4-N-benzylpyridyl)porphyrin, M=H-2, Zn) bearing positive charge has been shown to associate with SiW12O404- in water solution. The spectral evolution and Job's plots analyses reveal that the ... MTBPyP (meso-tetrakis(4-N-benzylpyridyl)porphyrin, M=H-2, Zn) bearing positive charge has been shown to associate with SiW12O404- in water solution. The spectral evolution and Job's plots analyses reveal that the relatively stable aggregates contain equal numbers of MTBPyP4(+) and SiW12O404-. 展开更多
关键词 cationic porphyrin anionic metal-ore cluster ion pair supramolecular complex
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