In the present work, the glass formation of Zr59Nb5Cu18Ni8Al10 (numbers indicate at %) alloy with diameter of 2 mm was prepared through water-cooled copper mold casting and in a ribbon form by the single roller melt-s...In the present work, the glass formation of Zr59Nb5Cu18Ni8Al10 (numbers indicate at %) alloy with diameter of 2 mm was prepared through water-cooled copper mold casting and in a ribbon form by the single roller melt-spinning method. This study is primarily devoted to evaluating the results obtained with the two methods of the development. The thermal stability was evaluated by differential scanning calorimetry (DSC) at a heating rate of 10℃/mn. The characteristic data of the bulk metallic glass are presented, including glass transition temperature (Tg) and crystallization temperature (Tx). The microstructure and constituent phases of the alloy composite have been analyzed by using X-ray diffraction, and observed by Scanning Electron Microscopy (SEM). The mechanical properties of bulk Zr59Nb5Cu18Ni8Al10 were alloy measured by compression tests at room temperature.展开更多
Cu46Zr46A14.8Ti3.2 bulk metallic glass （BMG） was successfully synthesized by copper-mold casting and the mechanical properties at room temperature were measured by compression tests. The structure and thermal charac...Cu46Zr46A14.8Ti3.2 bulk metallic glass （BMG） was successfully synthesized by copper-mold casting and the mechanical properties at room temperature were measured by compression tests. The structure and thermal characteristics were analyzed by XRD and DSC, and the fracture surface morphology was examined by SEM. The glassy alloy with 4 mm in diameter shows an high fracture strength of 1 960 MPa, with an improvement of about 20% compared to the ultimate compression fracture strength of the Cu46Zr46A18 BMG, which suggests that the Ti addition improves the compression fracture strength. The different degrees of the adiabatic heating induce four types of fracture features： a vein-like structure, an elongated and striated vein pattern, melting and smooth regions. The elongated and striated vein patterns as well as the melting region show that enormous strain energy is released, which causes significant adiabatic heating. Furthernaore, many micro-cracks observed in the smooth region are caused by the strong shear force. In addition, the strong shear force leads to many shear bands as well as the melting in the lateral surface.展开更多
文摘In the present work, the glass formation of Zr59Nb5Cu18Ni8Al10 (numbers indicate at %) alloy with diameter of 2 mm was prepared through water-cooled copper mold casting and in a ribbon form by the single roller melt-spinning method. This study is primarily devoted to evaluating the results obtained with the two methods of the development. The thermal stability was evaluated by differential scanning calorimetry (DSC) at a heating rate of 10℃/mn. The characteristic data of the bulk metallic glass are presented, including glass transition temperature (Tg) and crystallization temperature (Tx). The microstructure and constituent phases of the alloy composite have been analyzed by using X-ray diffraction, and observed by Scanning Electron Microscopy (SEM). The mechanical properties of bulk Zr59Nb5Cu18Ni8Al10 were alloy measured by compression tests at room temperature.
基金Project(NCET-10-0360) supported by the Program for New Century Excellent Talents in University,ChinaProject supported by the Fundamental Research Funds for the Central Universities,China
文摘Cu46Zr46A14.8Ti3.2 bulk metallic glass （BMG） was successfully synthesized by copper-mold casting and the mechanical properties at room temperature were measured by compression tests. The structure and thermal characteristics were analyzed by XRD and DSC, and the fracture surface morphology was examined by SEM. The glassy alloy with 4 mm in diameter shows an high fracture strength of 1 960 MPa, with an improvement of about 20% compared to the ultimate compression fracture strength of the Cu46Zr46A18 BMG, which suggests that the Ti addition improves the compression fracture strength. The different degrees of the adiabatic heating induce four types of fracture features： a vein-like structure, an elongated and striated vein pattern, melting and smooth regions. The elongated and striated vein patterns as well as the melting region show that enormous strain energy is released, which causes significant adiabatic heating. Furthernaore, many micro-cracks observed in the smooth region are caused by the strong shear force. In addition, the strong shear force leads to many shear bands as well as the melting in the lateral surface.
