The magnetic properties and microstructure of sintered R-Fe-B(R, rare earth) magnets with nominal composition of((PrNd)(1-x)MMx)(30)Fe(bal)B1(x = 0, 0.1.0.2,0.3, 0.4, 0.5 and 0.7; MM, misch metal) prepar...The magnetic properties and microstructure of sintered R-Fe-B(R, rare earth) magnets with nominal composition of((PrNd)(1-x)MMx)(30)Fe(bal)B1(x = 0, 0.1.0.2,0.3, 0.4, 0.5 and 0.7; MM, misch metal) prepared using dual-alloy method were investigated. For x = 0.3, the maximum energy product((BH)(max)) of the sintered magnet is higher than 318.4 kJ·m^-3,but intrinsic coercivity(H(cj)) is lower than 351.8 kA·m^-1. The La and Ce contents are obviously different in some matrix-phase grains, which proves that the multi-hard magnetic phases(La, Ce-rich and La, Ce-lean) exist in the magnets. The coercivity is improved by the method of doping PrNd nanoparticles without sacrificing other magnetic properties. An enhancement in coercivity from 517.2 to 872.9 kA·m^-1 is achieved by doping 5 wt% PrNd nanoparticles. Meanwhile, it could exhibit better magnetic properties(remanence Br = 1.332 T.intrinsic coercivity H(cj)= 872.9 kA·m^-1 maximum energy product(BH)(max)=318.6 kJ·m^-3) and make the distribution of the intergranular phase become more homogeneous.展开更多
基金financially supported by the National Key Research and Development Program of China (No.2016YFB0700903)the National Natural Science Foundation of China (No.51571126)+3 种基金the Inner Mongolia Innovative Research Team(No.3400102)the Innovative Science and Technology Project of Inner Mongolia (No.4140300502)the Science and Technology Project of Baotou (Nos.2012R1006 and 2015C2006-13)the Science and Technology Innovation Project of University (No.2014QDL003)
文摘The magnetic properties and microstructure of sintered R-Fe-B(R, rare earth) magnets with nominal composition of((PrNd)(1-x)MMx)(30)Fe(bal)B1(x = 0, 0.1.0.2,0.3, 0.4, 0.5 and 0.7; MM, misch metal) prepared using dual-alloy method were investigated. For x = 0.3, the maximum energy product((BH)(max)) of the sintered magnet is higher than 318.4 kJ·m^-3,but intrinsic coercivity(H(cj)) is lower than 351.8 kA·m^-1. The La and Ce contents are obviously different in some matrix-phase grains, which proves that the multi-hard magnetic phases(La, Ce-rich and La, Ce-lean) exist in the magnets. The coercivity is improved by the method of doping PrNd nanoparticles without sacrificing other magnetic properties. An enhancement in coercivity from 517.2 to 872.9 kA·m^-1 is achieved by doping 5 wt% PrNd nanoparticles. Meanwhile, it could exhibit better magnetic properties(remanence Br = 1.332 T.intrinsic coercivity H(cj)= 872.9 kA·m^-1 maximum energy product(BH)(max)=318.6 kJ·m^-3) and make the distribution of the intergranular phase become more homogeneous.