Coordination behavior between zinc salts and L-α-methionine

The solubility properties of ZnCl\-2/ZnAc\-2/ZnSO\-4MetH\-2O systems at 25℃ in the whole cocentration range have been investigated by phase equilibrium method. The results indicate that ZnAc\-2 and ZnSO\-4 systems are both simple systems, which do not exist any compound; there are 2 complexes formed in ZnCl\-2 system: Zn（Met）Cl\-2 and Zn（Met）\-2Cl\-2·2H\-2O. Under the direction of phase equilibrium result, 2 solid complexes have been prepared in water and characterized by chemical analysis, IR, Xray diffraction. Their combustion energies have also been determined by means of a RBCtype1 rotatingbomb calorimeter, and their standard enthalpies of formation, Δ f, coor（s）H O-, have been calculated which are （-828.32±3.00） kJ·mol -1 and （-1 117.08±6.15） kJ·mol -1, respectively.

Zn(Met)Ac_2·H_2O固态配合物的制备及标准生成焓

在水 丙酮混合溶剂中合成了Zn(Met)Ac2 ·H2 O固态配合物 ,通过化学分析、元素分析、IR、DSC和TG DTG对其组成、结构及热稳定性进行了表征。得出其脱水过程和分解过程的焓变分别为 15 30J/ g和35 7 80J/ g。用转动弹热量计测得其恒容燃烧能ΔcE为 (- 6 4 72 11± 2 2 0 )kJ/mol,计算得其标准燃烧焓ΔcH0m 和标准生成焓ΔfH0m 分别为 (- 6 4 75 2 1± 2 2 0 )kJ/mol和 (- 4 2 9 0 4± 2 5 9)kJ/mol。