In this paper,a frictional contact problem between an electro-elastic body and an electrically conductive foundation is studied.The contact is modeled by normal compliance with finite penetration and a version of Coul...In this paper,a frictional contact problem between an electro-elastic body and an electrically conductive foundation is studied.The contact is modeled by normal compliance with finite penetration and a version of Coulomb’s law of dry friction in which the coefficient of friction depends on the slip.In addition,the effects of the electrical conductivity of the foundation are taken into account.This model leads to a coupled system of the quasi-variational inequality of the elliptic type for the displacement and the nonlinear variational equation for the electric potential.The existence of a weak solution is proved by using an abstract result for elliptic variational inequalities and a fixed point argument.Then,a finite element approximation of the problem is presented.Under some regularity conditions,an optimal order error estimate of the approximate solution is derived.Finally,a successive iteration technique is used to solve the problem numerically and a convergence result is established.展开更多
LiMn2O4 spinel cathode materials were modified with 2 wt.%Li-M-PO4(M=Co,Ni,Mn) by polyol synthesis method.The phosphate surface-modified LiMn2O4 cathode materials were physically characterized by X-ray diffraction(...LiMn2O4 spinel cathode materials were modified with 2 wt.%Li-M-PO4(M=Co,Ni,Mn) by polyol synthesis method.The phosphate surface-modified LiMn2O4 cathode materials were physically characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM) and energy dispersive X-ray spectroscopy(EDS).The charge-discharge test showed that the cycling and rate capacities of LiMn2O4 cathode materials were significantly enhanced by stabilizing the electrode surface with phosphate.展开更多
β-Sialon based composites were successfully prepared from fly ash and carbon black under nitrogen atmosphere by carbothermal reduction-nitridation process. Effects of heating temperature and raw materials composition...β-Sialon based composites were successfully prepared from fly ash and carbon black under nitrogen atmosphere by carbothermal reduction-nitridation process. Effects of heating temperature and raw materials composition on synthesis process were investigated, and the formation process of the composites was also discussed. The phase composition and microstructure of the composites were characterized by X-ray diffraction and scanning electronic microscopy. The results show that increasing heating temperature or mass ratio of carbon black to fly ash can promote the formation of β-Sialon. The β-Sialon based composites can be synthesized at 1723 K for 6 h while heating the sample with mass ratio of carbon black to fly ash of 0.56. The as-received β-Sialon in the composites exists as granular with an average particle size of 2-3 μm. The preparation process of β-Sialon based composites includes the formation of O′-Sialon, X-Sialon and β-Sialon as well as the conversion processes of O′-Sialon and X-Sialon to β-Sialon.展开更多
Layered intercalated functional materials of layered double hydroxide type are an important class of functional materials developed in recent years. Based on long term studies on these materials in the State Key Labor...Layered intercalated functional materials of layered double hydroxide type are an important class of functional materials developed in recent years. Based on long term studies on these materials in the State Key Laboratory of Chemical Resource Engineering in Beiiing University of Chemical Technology, the orinciole for the design of controlled intercalation processes in the light of tuture production processing requirements has been developed. Intercalation assembly methods and technologies have been invented to control the intercalation process for preparing layered intercalated materials with various structures and functions.展开更多
We presented Mathematical apparatus of the choice of optimum parameters of technical, technological systems and materials on the basis of vector optimization. We have considered the formulation and solution of three t...We presented Mathematical apparatus of the choice of optimum parameters of technical, technological systems and materials on the basis of vector optimization. We have considered the formulation and solution of three types of tasks presented below. First, the problem of selecting the optimal parameters of technical systems depending on the functional characteristics of the system. Secondly, the problem of selecting the optimal parameters of the process depending on the technological characteristics of the process. Third, the problem of choosing the optimal structure of the material depending on the functional characteristics of this material. The statement of all problems is made in the form of vector problems of mathematical (nonlinear) programming. The theory and the principle of optimality of the solution of vector tasks it is explained in work of https://rdcu.be/bhZ8i. The implementation of the methodology is shown on a numerical example of the choice of optimum parameters of the technical, technological systems and materials. On the basis of mathematical methods of solution of vector problems we developed the software in the MATLAB system. The numerical example includes: input data (requirement specification) for modeling;transformation of mathematical models with uncertainty to the model under certainty;acceptance of an optimal solution with equivalent criteria (the solution of numerical model);acceptance of an optimal solution with the given priority of criterion.展开更多
Supporting sustainable green energy systems,there is a big demand gap for grid energy storage.Sodiumion storage,especially sodium-ion batteries(SIBs),have advanced significantly and are now emerging as a feasible alte...Supporting sustainable green energy systems,there is a big demand gap for grid energy storage.Sodiumion storage,especially sodium-ion batteries(SIBs),have advanced significantly and are now emerging as a feasible alternative to the lithium-ion batteries equivalent in large-scale energy storage due to their natural abundance and prospective inexpensive cost.Among various anode materials of SIBs,beneficial properties,such as outstanding stability,great abundance,and environmental friendliness,make sodium titanates(NTOs),one of the most promising anode materials for the rechargeable SIBs.Nevertheless,there are still enormous challenges in application of NTO,owing to its low intrinsic electronic conductivity and collapse of structure.The research on NTOs is still in its infancy;there are few conclusive reviews about the specific function of various modification methods.Herein,we summarize the typical strategies of optimization and analysis the fine structures and fabrication methods of NTO anodes combined with the application of in situ characterization techniques.Our work provides effective guidance for promoting the continuous development,equipping NTOs in safety-critical systems,and lays a foundation for the development of NTO-anode materials in SIBs.展开更多
xLi2MnO3·(1-x)Li(Ni1/3Co1/3Mn1/3)O2 (x=0.25, 0.40, 0.55) compounds were prepared by low-heating solid state reaction. In the voltage range of 2.70-4.35 V, the discharge capacity of the electrode decreased w...xLi2MnO3·(1-x)Li(Ni1/3Co1/3Mn1/3)O2 (x=0.25, 0.40, 0.55) compounds were prepared by low-heating solid state reaction. In the voltage range of 2.70-4.35 V, the discharge capacity of the electrode decreased with the increase of x, with a better cyclability. However, when cycled between 2.7 and 4.6 V, the cathodes delivered much larger capacities and their capacities increased with the introduction of Li2MnO3. Moreover, it was found that the discharge capacity gradually increased with the cycle number. The reason for this phenomenon was discussed. It was found that the relatively low cut-off potential made the activation of the Li2MnO3 component in the compound a gradual process, which caused the increasing capacity.展开更多
The transient mass transter processes in the natural drying of wood particle materials were experimental;y studied A new theory tio determme the mass transfer parameters in the Materials was developed in terms of grad...The transient mass transter processes in the natural drying of wood particle materials were experimental;y studied A new theory tio determme the mass transfer parameters in the Materials was developed in terms of gradient transformation method(GTM).By making use of GTM.Thewater vapour diffusion coefficient and the surtaee emission coefficent of wood chip were expermentally determined both in air phase and in solid phase.It Was found that the internal resistance to water vapour diffusion in the air phase of wood partiele aggregates is around ten to the third power as large as that in common air The drag coefficient was given to quantify the effect The phenomenon of undersurface diffusion in wood partiele bed was quantitatively modelled.The dimensionless Fourier snumber and the Biot's number for mass transfer were theoretically derived.The study showed that Biot's number for the problem investigated was the ratio of the characteristie length of wood partiele bed to the penetrating depth of the undersurface.An analytical solution of the nonlinear goveming equation for water transport process in the aggregates of wood chip was obtained by introducing the variable coefficients measured in the study into the governing equation.The comparison between the analytical solution and the observed moisture content of wood chip showed that the deviation was less than ±7%.The thermophysieal properties of wood particle materials are little known at present.The knowledge provided in the paper will be and in the handling.researeh or engineering application of wood chip.wood shavingsete.展开更多
One-dimensional carbon nano-materials (ODCNMs) synthesized from ethanol flames exhibit various agglomerated morphologies, such as "chrysanthemum-like", "hairball-like" or "orange-peel-like", "vertically alig...One-dimensional carbon nano-materials (ODCNMs) synthesized from ethanol flames exhibit various agglomerated morphologies, such as "chrysanthemum-like", "hairball-like" or "orange-peel-like", "vertically aligned" and "wrinkling-pileup". The present work studied the agglomerating process and the growth mechanism by using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It is thought that the size and distribution of the catalyst particles produced from pretreatment of the substrates play a key role during the formation of agglomerations. It is expected that the steady growth of ODCNMs in flames will be improved through the preparation of the catalysts.展开更多
A new material with heat-resistant and adiabatic characteristics and high strength was prepared using the combustion synthesis method by mixed powders of CrO3, Al, Al2O3, and NaF in atmospheric gas. The reaction dynam...A new material with heat-resistant and adiabatic characteristics and high strength was prepared using the combustion synthesis method by mixed powders of CrO3, Al, Al2O3, and NaF in atmospheric gas. The reaction dynamic process of the Al-CrO3-NaF-Al2O3-N2-O2 new material system by the combustion synthesis method was discussed based on the observation results by SEM, EDS, and XRD in combination with the combustion front quenching method (CFQM) and the relation curves between reaction free enthalpies and the corresponding temperatures. The combustion synthesis mechanism and the formation reasons of the phase in the combustion product were analyzed.展开更多
La0.7Sr0.3MnO3(LSMO) nanorods were synthesized by a method combining sol-gel with molten salts at 950 ℃ for 10 h, which employed KCl+NaCl(mass ratio 4:1) as eutectic molten salts. The morphologies and magnetic ...La0.7Sr0.3MnO3(LSMO) nanorods were synthesized by a method combining sol-gel with molten salts at 950 ℃ for 10 h, which employed KCl+NaCl(mass ratio 4:1) as eutectic molten salts. The morphologies and magnetic properties of the resulting LSMO nanorods were investigated by X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), and vibrating sample magnetometer(VSM) measurements. It was found that the obtained perovskite manganite LSMO was a uniform nanorod with a diameter of about 50 nm and a length of longer than 500 rim. The Curie temperature(To) of the LSMO nanorod used here was 262 K, much lower than that of bulky single crystal LSMO(360 K). The low Curie temperature might be a result of the great disorder near the grain boundary, which could be observed clearly from the TEM picture.展开更多
Microwave synthesis method was applied to the fast preparation of LiCoO2. The structure of the synthesized oxides was analyzed by using X-ray diffraction. Only single-phase LiCoO2 was obtained. Electrochemical behavio...Microwave synthesis method was applied to the fast preparation of LiCoO2. The structure of the synthesized oxides was analyzed by using X-ray diffraction. Only single-phase LiCoO2 was obtained. Electrochemical behaviors of LiCoO2 were investigated by charge-discharge cycling properties in the voltage range of 3.004.35 V((vs Li).) The results show that the prepared LiCoO2 powders calcinated at 900 ℃ for 120 min exhibit an initial charge and discharge capacity of 168 and 162 mA·h·g-1 at 0.1C current rate, respectively, as compared to 159 and 154 (mA·h·g-1) of LiCoO2 synthesized by conventional means. In addition, more than 95% of the capacity is retained (even) after 10 cycles. But with the increase of calcinating time, its electrochemical properties deteriorate. Compared with the conventional method, the microwave heating method is simple, fast, and with high energy efficiency.展开更多
This paper applies the stochastic finite element method to analyse the statistics of stresses in earth dams and assess the safety and reliability of the dams. Formulations of the stochastic finite element method are b...This paper applies the stochastic finite element method to analyse the statistics of stresses in earth dams and assess the safety and reliability of the dams. Formulations of the stochastic finite element method are briefly reviewed and the procedure for assessing dam's strength and stability is described. As an example, a detailed analysis for an actual dam Nululin dam is performed. A practical method for studying built-dams based on the prototype observation data is described.展开更多
This book records a collection of 42 selected papers presented at UK-China Particle Technology Forum Ⅲ held at Birmingham, UI〈, on 2011-7-3/6. The prior Forum Ⅱ was held in Guiyang, China in 2009, and Forum Ⅰ in L...This book records a collection of 42 selected papers presented at UK-China Particle Technology Forum Ⅲ held at Birmingham, UI〈, on 2011-7-3/6. The prior Forum Ⅱ was held in Guiyang, China in 2009, and Forum Ⅰ in Leeds, UK in 2007. This Forum Ⅲ was classified in this book into four topics totaling 42 presentations, each represented in this review by the first two papers, as follows:展开更多
文摘In this paper,a frictional contact problem between an electro-elastic body and an electrically conductive foundation is studied.The contact is modeled by normal compliance with finite penetration and a version of Coulomb’s law of dry friction in which the coefficient of friction depends on the slip.In addition,the effects of the electrical conductivity of the foundation are taken into account.This model leads to a coupled system of the quasi-variational inequality of the elliptic type for the displacement and the nonlinear variational equation for the electric potential.The existence of a weak solution is proved by using an abstract result for elliptic variational inequalities and a fixed point argument.Then,a finite element approximation of the problem is presented.Under some regularity conditions,an optimal order error estimate of the approximate solution is derived.Finally,a successive iteration technique is used to solve the problem numerically and a convergence result is established.
基金financially supported by the National High-Tech Research and Development(863) Program of China(No.2006AA11A160)the National Natural Science Foundation of China(No.50604018)
文摘LiMn2O4 spinel cathode materials were modified with 2 wt.%Li-M-PO4(M=Co,Ni,Mn) by polyol synthesis method.The phosphate surface-modified LiMn2O4 cathode materials were physically characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM) and energy dispersive X-ray spectroscopy(EDS).The charge-discharge test showed that the cycling and rate capacities of LiMn2O4 cathode materials were significantly enhanced by stabilizing the electrode surface with phosphate.
基金Project (51074038) supported by the National Natural Science Foundation of ChinaProject (N100302002) supported by the Fundamental Research Funds for the Central Universities, China
文摘β-Sialon based composites were successfully prepared from fly ash and carbon black under nitrogen atmosphere by carbothermal reduction-nitridation process. Effects of heating temperature and raw materials composition on synthesis process were investigated, and the formation process of the composites was also discussed. The phase composition and microstructure of the composites were characterized by X-ray diffraction and scanning electronic microscopy. The results show that increasing heating temperature or mass ratio of carbon black to fly ash can promote the formation of β-Sialon. The β-Sialon based composites can be synthesized at 1723 K for 6 h while heating the sample with mass ratio of carbon black to fly ash of 0.56. The as-received β-Sialon in the composites exists as granular with an average particle size of 2-3 μm. The preparation process of β-Sialon based composites includes the formation of O′-Sialon, X-Sialon and β-Sialon as well as the conversion processes of O′-Sialon and X-Sialon to β-Sialon.
基金Supported by the National Key Technologies R&D Program (2011BAE28B01) and the National Natural Science Foundation of China (21276016).
文摘Layered intercalated functional materials of layered double hydroxide type are an important class of functional materials developed in recent years. Based on long term studies on these materials in the State Key Laboratory of Chemical Resource Engineering in Beiiing University of Chemical Technology, the orinciole for the design of controlled intercalation processes in the light of tuture production processing requirements has been developed. Intercalation assembly methods and technologies have been invented to control the intercalation process for preparing layered intercalated materials with various structures and functions.
文摘We presented Mathematical apparatus of the choice of optimum parameters of technical, technological systems and materials on the basis of vector optimization. We have considered the formulation and solution of three types of tasks presented below. First, the problem of selecting the optimal parameters of technical systems depending on the functional characteristics of the system. Secondly, the problem of selecting the optimal parameters of the process depending on the technological characteristics of the process. Third, the problem of choosing the optimal structure of the material depending on the functional characteristics of this material. The statement of all problems is made in the form of vector problems of mathematical (nonlinear) programming. The theory and the principle of optimality of the solution of vector tasks it is explained in work of https://rdcu.be/bhZ8i. The implementation of the methodology is shown on a numerical example of the choice of optimum parameters of the technical, technological systems and materials. On the basis of mathematical methods of solution of vector problems we developed the software in the MATLAB system. The numerical example includes: input data (requirement specification) for modeling;transformation of mathematical models with uncertainty to the model under certainty;acceptance of an optimal solution with equivalent criteria (the solution of numerical model);acceptance of an optimal solution with the given priority of criterion.
基金supported by projects from the National Natural Science Foundation of China(U20A20145)the Open Project of State Key Laboratory of Environment-friendly Energy Materials(20kfhg07)+6 种基金Distinguished Young Foundation of Sichuan Province(2020JDJQ0027)2020 Strategic Cooperation Project between Sichuan University and the Zigong Municipal People's Government(2020CDZG-09)State Key Laboratory of Polymer Materials Engineering(sklpme2020-3-02)Sichuan Provincial Department of Science and Technology(2020YFG0471,2020YFG0022,2022YFG0124)Sichuan Province Science and Technology Achievement Transfer and Transformation Project(21ZHSF0111)Sichuan University Postdoctoral Interdisciplinary Innovation Fund(2021SCU12084)Start-up funding of Chemistry and Chemical Engineering Guangdong Laboratory(2122010)。
文摘Supporting sustainable green energy systems,there is a big demand gap for grid energy storage.Sodiumion storage,especially sodium-ion batteries(SIBs),have advanced significantly and are now emerging as a feasible alternative to the lithium-ion batteries equivalent in large-scale energy storage due to their natural abundance and prospective inexpensive cost.Among various anode materials of SIBs,beneficial properties,such as outstanding stability,great abundance,and environmental friendliness,make sodium titanates(NTOs),one of the most promising anode materials for the rechargeable SIBs.Nevertheless,there are still enormous challenges in application of NTO,owing to its low intrinsic electronic conductivity and collapse of structure.The research on NTOs is still in its infancy;there are few conclusive reviews about the specific function of various modification methods.Herein,we summarize the typical strategies of optimization and analysis the fine structures and fabrication methods of NTO anodes combined with the application of in situ characterization techniques.Our work provides effective guidance for promoting the continuous development,equipping NTOs in safety-critical systems,and lays a foundation for the development of NTO-anode materials in SIBs.
基金supported by the National Natural Science Foundation of China(No.50472093,50702007)
文摘xLi2MnO3·(1-x)Li(Ni1/3Co1/3Mn1/3)O2 (x=0.25, 0.40, 0.55) compounds were prepared by low-heating solid state reaction. In the voltage range of 2.70-4.35 V, the discharge capacity of the electrode decreased with the increase of x, with a better cyclability. However, when cycled between 2.7 and 4.6 V, the cathodes delivered much larger capacities and their capacities increased with the introduction of Li2MnO3. Moreover, it was found that the discharge capacity gradually increased with the cycle number. The reason for this phenomenon was discussed. It was found that the relatively low cut-off potential made the activation of the Li2MnO3 component in the compound a gradual process, which caused the increasing capacity.
文摘The transient mass transter processes in the natural drying of wood particle materials were experimental;y studied A new theory tio determme the mass transfer parameters in the Materials was developed in terms of gradient transformation method(GTM).By making use of GTM.Thewater vapour diffusion coefficient and the surtaee emission coefficent of wood chip were expermentally determined both in air phase and in solid phase.It Was found that the internal resistance to water vapour diffusion in the air phase of wood partiele aggregates is around ten to the third power as large as that in common air The drag coefficient was given to quantify the effect The phenomenon of undersurface diffusion in wood partiele bed was quantitatively modelled.The dimensionless Fourier snumber and the Biot's number for mass transfer were theoretically derived.The study showed that Biot's number for the problem investigated was the ratio of the characteristie length of wood partiele bed to the penetrating depth of the undersurface.An analytical solution of the nonlinear goveming equation for water transport process in the aggregates of wood chip was obtained by introducing the variable coefficients measured in the study into the governing equation.The comparison between the analytical solution and the observed moisture content of wood chip showed that the deviation was less than ±7%.The thermophysieal properties of wood particle materials are little known at present.The knowledge provided in the paper will be and in the handling.researeh or engineering application of wood chip.wood shavingsete.
基金Supported by the Scientific Research Foundationfor the Returned Overseas Chinese Scholars of Chinese Ministry Edu-cation (200233)
文摘One-dimensional carbon nano-materials (ODCNMs) synthesized from ethanol flames exhibit various agglomerated morphologies, such as "chrysanthemum-like", "hairball-like" or "orange-peel-like", "vertically aligned" and "wrinkling-pileup". The present work studied the agglomerating process and the growth mechanism by using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It is thought that the size and distribution of the catalyst particles produced from pretreatment of the substrates play a key role during the formation of agglomerations. It is expected that the steady growth of ODCNMs in flames will be improved through the preparation of the catalysts.
基金the National High-Tech Research and Development Program of China (863 Program) (No. 2006AA03Z351).
文摘A new material with heat-resistant and adiabatic characteristics and high strength was prepared using the combustion synthesis method by mixed powders of CrO3, Al, Al2O3, and NaF in atmospheric gas. The reaction dynamic process of the Al-CrO3-NaF-Al2O3-N2-O2 new material system by the combustion synthesis method was discussed based on the observation results by SEM, EDS, and XRD in combination with the combustion front quenching method (CFQM) and the relation curves between reaction free enthalpies and the corresponding temperatures. The combustion synthesis mechanism and the formation reasons of the phase in the combustion product were analyzed.
基金Supported by the National Natural Science Foundation of China (No.20801016)Natural Science Foundation of Heilong-jiang Province, China(No.B2007-8)+1 种基金Research Fund for the Doctoral Program of Higher Education of China for New Teach-ers(No.20070217060)Basic Research Fund of Harbin Engineering University, China(No.HEUFT05019)
文摘La0.7Sr0.3MnO3(LSMO) nanorods were synthesized by a method combining sol-gel with molten salts at 950 ℃ for 10 h, which employed KCl+NaCl(mass ratio 4:1) as eutectic molten salts. The morphologies and magnetic properties of the resulting LSMO nanorods were investigated by X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), and vibrating sample magnetometer(VSM) measurements. It was found that the obtained perovskite manganite LSMO was a uniform nanorod with a diameter of about 50 nm and a length of longer than 500 rim. The Curie temperature(To) of the LSMO nanorod used here was 262 K, much lower than that of bulky single crystal LSMO(360 K). The low Curie temperature might be a result of the great disorder near the grain boundary, which could be observed clearly from the TEM picture.
文摘Microwave synthesis method was applied to the fast preparation of LiCoO2. The structure of the synthesized oxides was analyzed by using X-ray diffraction. Only single-phase LiCoO2 was obtained. Electrochemical behaviors of LiCoO2 were investigated by charge-discharge cycling properties in the voltage range of 3.004.35 V((vs Li).) The results show that the prepared LiCoO2 powders calcinated at 900 ℃ for 120 min exhibit an initial charge and discharge capacity of 168 and 162 mA·h·g-1 at 0.1C current rate, respectively, as compared to 159 and 154 (mA·h·g-1) of LiCoO2 synthesized by conventional means. In addition, more than 95% of the capacity is retained (even) after 10 cycles. But with the increase of calcinating time, its electrochemical properties deteriorate. Compared with the conventional method, the microwave heating method is simple, fast, and with high energy efficiency.
文摘This paper applies the stochastic finite element method to analyse the statistics of stresses in earth dams and assess the safety and reliability of the dams. Formulations of the stochastic finite element method are briefly reviewed and the procedure for assessing dam's strength and stability is described. As an example, a detailed analysis for an actual dam Nululin dam is performed. A practical method for studying built-dams based on the prototype observation data is described.
文摘This book records a collection of 42 selected papers presented at UK-China Particle Technology Forum Ⅲ held at Birmingham, UI〈, on 2011-7-3/6. The prior Forum Ⅱ was held in Guiyang, China in 2009, and Forum Ⅰ in Leeds, UK in 2007. This Forum Ⅲ was classified in this book into four topics totaling 42 presentations, each represented in this review by the first two papers, as follows: