The possibility of using a centrifugal-gravity concentrator to reject Mg-bearing minerals and minimize metal losses in the flotation of base metals was evaluated. Sample characterization, batch scoping tests, pilot-sc...The possibility of using a centrifugal-gravity concentrator to reject Mg-bearing minerals and minimize metal losses in the flotation of base metals was evaluated. Sample characterization, batch scoping tests, pilot-scale tests, and regrind-flotation tests were conducted on a Ni flotation tailings stream. Batch tests revealed that the Mg grade decreased dramatically in the concentrate products. Pilot-scale testing of a continuous centrifugal concentrator(Knelson CVD6) on the flotation tailings revealed that a concentrate with a low mass yield, low Mg content, and high Ni upgrade ratio could be achieved. Under optimum conditions, a concentrate at 6.7% mass yield was obtained with 0.85% Ni grade at 12.9% Ni recovery and with a low Mg distribution(1.7%). Size partition curves demonstrated that the CVD also operated as a size classifier, enhancing the rejection of talc fines. Overall, the CVD was capable of rejecting Mg-bearing minerals. Moreover, an opportunity exists for the novel use of centrifugal-gravity concentration for scavenging flotation tailings and/or after comminution to minimize amount of Mg-bearing minerals reporting to flotation.展开更多
The effect of reagents used in separating chalcopyrite from pyrite on the cake moisture of the copper concentrate at Daye Iron Mine Mineral Processing Plant was investigated. The results showed that the dosage of lime...The effect of reagents used in separating chalcopyrite from pyrite on the cake moisture of the copper concentrate at Daye Iron Mine Mineral Processing Plant was investigated. The results showed that the dosage of lime used for depressing pyrite was the main factor that increased the filter cake moisture of copper concentrate. With increasing the dosage of lime, the cake moisture of copper concentrate increased sharply. The cause was concluded to be the addition of lime to the pulp, which resulted in the formation of floc and a high pH value. The collector Z-200#, used for collecting chalcopyrite, had, as well, an adverse effect on the cake moisture of copper concentrate, but its effect was inferior in respect to that of lime. The cake moisture of copper concentrate can be decreased by changing the method with which lime is added and the pH value of pulp is regulated. The experiment results showed that the sulfuric acid was the best regulator. When the clarified liquor of lime was used as a depressant and the pH value of the pulp was regulated to 6.5€*7.0 by adding sulfuric acid, the cake moisture of copper concentrate was reduced from 15.49% to 13.13%. The examination of chalcopyrite surface by using ESCA (Electron Spectroscopy for Chemical Analysis) showed that calcium sulfate and iron hydroxide had formed on the surface of chalcopyrite when lime was added to the pulp. The formation of calcium sulfate and iron hydroxide on its surface increased the hydrophilicity of chalcopyrite so that its cake moisture increased. The addition of sulfuric acid to the pulp not only removed the calcium sulfate, but also reduced the concentration of iron hydroxide on the surface of chalcopyrite so that the cake moisture of copper concentrate was decreased.展开更多
A hybrid process consisting of flotation and magnetic separation has been developed to concentrate multi-phase rare earth minerals associated with a carbonatite ore that contains a significant amount of niobium. The d...A hybrid process consisting of flotation and magnetic separation has been developed to concentrate multi-phase rare earth minerals associated with a carbonatite ore that contains a significant amount of niobium. The deposit is known to contain at least 15 different rare earth minerals identified as silicocarbonatite, magnesiocarbonatite, ferrocarbonatites, calciocarbonatite, REE/Nb ferrocarbonatite, phosphates and niobates. Although no collector exists to float all the different rare earth minerals, the hydroxamic acid-based collectors have shown adequate efficiency in floating most of these minerals. 92% recovery of total rare earth oxide (TREO) and niobium in 45% mass was possible at d<sub>80</sub> of <65 microns grind size. It was also possible to reduce the mass pull to 28%, but TREO and Nb’s recovery dropped to 85%. Calcination of the concentrate followed by quenching and fine grinding to <25 μm allowed upgrading the flotation concentrate by magnetic separation. It was demonstrated that at least 87% TREO and 85% Nb could be recovered in 16% of the feed mass. The paper discusses the overall concept of the flowsheet and the experimental strategies that led to this process.展开更多
Bubble surface area flux(S_b) is one of the main design parameter in flotation column that typically employed to describe the gas dispersion properties, and it has a strong correlation with the flotation rate constant...Bubble surface area flux(S_b) is one of the main design parameter in flotation column that typically employed to describe the gas dispersion properties, and it has a strong correlation with the flotation rate constant. There is a limited information available in the literature regarding the effect of particle type,density, wettability and concentration on Sb. In this paper, computational fluid dynamics(CFD) simulations are performed to study the gas–liquid–solid three-phase flow dynamics in flotation column by employing the Eulerian–Eulerian formulation with k-e turbulence model. The model is developed by writing Fortran subroutine and incorporating then into the commercial CFD code AVL FIRE, v.2014.This paper studies the effects of superficial gas velocities and particle type, density, wettability and concentration on Sband bubble concentration in the flotation column. The model has been validated against published experimental data. It was found that the CFD model was able to predict, where the response variable as indicated by R-Square value of 0.98. These results suggest that the developed CFD model is reasonable to describe the flotation column reactor. From the CFD results, it is also found that Sb decreased with increasing solid concentration and hydrophobicity, but increased with increasing superficial gas velocity. For example, approximately 28% reduction in the surface area flux is observed when coal concentration is increased from 0 to 10%, by volume. While for the same solid concentration and gas flow rate, the bubble surface area flux is approximately increased by 7% in the presences of sphalerite.A possible explanation for this might be that increasing solid concentration and hydrophobicity promotes the bubble coalescence rate leading to the increase in bubble size. Also, it was found that the bubble concentration would decrease with addition of hydrophobic particle(i.e., coal). For instance, under the same operating conditions, approximately 23% reduction in the bubble concentration is predicted when the system was working with hydrophobic particles. The results presented are useful for understanding flow dynamics of three-phase system and provide a basis for further development of CFD model for flotation column.展开更多
Nanobubbles play a potential role in the application of the flotation of fine particles.In this work,the identification of nanoentities was performed with a contact mode atomic force microscope(AFM).Moreover,the influ...Nanobubbles play a potential role in the application of the flotation of fine particles.In this work,the identification of nanoentities was performed with a contact mode atomic force microscope(AFM).Moreover,the influences of setpoint ratio and amplitude of the cantilever and the responses of the formed surface nanobubbles to the fluctuation of pH,salt concentration,and surfactant concentration in the slurry were respectively studied.Nanobubbles were reported on the highly oriented pyrolytic graphite(HOPG)surface as the HOPG was immersed in de-ionized water under ambient temperature.The coalescence of nanobubbles occurred under contact mode,which provides strong evidence of the gaseous nature of these nanostructures on HOPG.The measuring height of the surface nanobubbles decreased with the setpoint ratio.The changes in the pH and concentration of methyl isobutyl carbinol(MIBC)show a negligible influence on the lateral size and height of the preex-isting surface nanobubbles.The addition of LiCl results in a negligible change of the lateral size;however,an obvious change is noticed in the height of surface nanobubbles.The results are expected to provide a valuable reference in understanding the properties of surface nanobubbles and in the design of nanobubble-assisted flotation processes.展开更多
The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved.Meanwhile,it is believed that frother transport between phases is perhaps the most impor...The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved.Meanwhile,it is believed that frother transport between phases is perhaps the most important reason for the interactive nature of the phenomena occurring in the bulk and froth phases in flotation,as frother adsorbed in the surface of rising bubbles is removed from the bulk phase and then released into the froth as a fraction of the bubbles burst.This causes the increased concentration in the froth compared to the bulk concentration,named as frother partitioning.Partitioning reflects the adsorption of frother on bubbles and how to influence bubble size is not known.There currently exists no such a topic aiming to link these two key parameters.To fill this vacancy,the correspondence between bubble size and frother partitioning was examined.Bubble size was measured by sampling-for-imaging(SFI)technique.Using total organic carbon(TOC)analysis to measure the frother partitioning between froth and bulk phases was determined.Measurements have shown,with no exceptions including four different frothers,higher frother concentration is in the bulk than in the froth.The results also show strong partitioning giving an increase in bubble size which implies there is a compelling relationship between these two,represented by CFroth/CBulk and D32.The CFroth/CBulkand D32 curves show similar exponential decay relationships as a function of added frother in the system,strongly suggesting that the frother concentration gradient between the bulk solution and the bubble interface is the driving force contributing to bubble size reduction.展开更多
This work aims to provide a relationship of how the key operational variables of frother type and impeller speed affect the size of bubble(D32). The study was performed using pilot-scale equipment(0.8 m3) that is up t...This work aims to provide a relationship of how the key operational variables of frother type and impeller speed affect the size of bubble(D32). The study was performed using pilot-scale equipment(0.8 m3) that is up to two orders of magnitude larger than equipment used for studies performed to date by others, and incorporated the key process variables of frother type and impeller speed. The results show that each frother family exhibits a unique CCC95-HLB relationship dependent on n(number of C-atoms in alkyl group) and m(number of propylene oxide group). Empirical models were developed to predict CCC95 from HLB associated with other two parameters α and β. The impeller speed-bubble size tests show that D32 is unaffected by increased impeller tip speed across the range of 4.6 to 9.2 m/s(representing the industrial operating range), although D32 starts to increase below 4.6 m/s. The finding is valid for both coalescing and non-coalescing conditions. The results suggest that the bubble size and bubble size distribution(BSD) being created do not change with increasing impeller speed in the quiescent zone of the flotation.展开更多
In this paper, prediction of copper and molybdenum grades and their recoveries of an industrial flotation plant are investigated using the Artificial Neural Networks (ANN) model. Process modeling has done based on 92 ...In this paper, prediction of copper and molybdenum grades and their recoveries of an industrial flotation plant are investigated using the Artificial Neural Networks (ANN) model. Process modeling has done based on 92 datasets collected at different operational conditions and feed characteristics. The prominent parameters investigated in this network were pH, collector, frother and F-Oil concentration, size percentage of feed passing 75 microns, moisture content in feed, solid percentage, and grade of copper, molybdenum, and iron in feed. A multilayer perceptron neural network, with 10:10:10:4 structure (two hidden layers), was used to estimate metallurgical performance. To obtain the optimal hidden layers and nodes in a layer, a trial and error procedure was done. In training and testing phases, it achieved quite correlations of 0.98 and 0.93 for Copper grade, of 0.99 and 0.92 for Copper recovery, of 0.99 and 0.92 for Molybdenum grade and of 0.99 and 0.94 for Molybdenum recovery prediction, respectively. The proposed neural network model can be applied to determine the most beneficial operational conditions for the expected Copper and Molybdenum grades and their recovery in final concentration of the industrial copper flotation process.展开更多
The flotability and mechanism of tantalite-niobite minerals which have different contents of Ta, Nb, Fe Mn using styrenephosphonic acid (SPA) were investigated. The optimum pH value in pulp is less than 5, flotability...The flotability and mechanism of tantalite-niobite minerals which have different contents of Ta, Nb, Fe Mn using styrenephosphonic acid (SPA) were investigated. The optimum pH value in pulp is less than 5, flotability varies with the different contents of mineral, and flotability of minerals with higher Nb2O5 content is better than that with higher Ta2O5 content. In wide range of pH in solution, the Fe, Mn on the surface are the main active species for flotation. Research using Auger electron spectroscopy, infrared spectroscopy and ultraviolet spectroscopy for determining surface conditions has been done. SPA interacts with Fe, Mn ions on the surface by a chemical bond force. On the outer layer of the collector, which is a non-uniform multilayer, adsorption of SPA on surface is both chemico-adsorption and physico-adsorption, but chemico-adsorption is dominant.展开更多
A low-grade gold ore from Ilesha-Itagunmodi, south western Nigeria was panned, dried and ball-milled before sieving into fractions. The morphological, mineralogical and chemical composition was studied by optical micr...A low-grade gold ore from Ilesha-Itagunmodi, south western Nigeria was panned, dried and ball-milled before sieving into fractions. The morphological, mineralogical and chemical composition was studied by optical micro-scopy (Reflected and Transmission), X-ray diffraction (XRD) and Energy Dispersive X-ray fluorescence (XRF), respectively. The sieved fractions were subjected to chemical analysis (AAS). The +106 μm sieve had the highest concentration of the mineral and was then selected for the upgrade through froth flotation using standard reagents. In this paper a report on a 2k factorial experiment that provides an understanding of the impact of operational variables on the quantity of gold mineral obtained from the ore during froth flotation is presented. Analysis results showed that Ilesha-Itagunmodi gold ore is non-refractory with fine grain particles, amenable to froth flotation and contained about 20 other associated minerals, gold had a concentration of about 0.0024%. A com-bination of P-Xanthate and amine glycol collectors at a pH of 9.2 only produced a considerable increase in gold yield. This translated to about 87.13% increase in recovery of gold from the ore. Analysis of variance (ANOVA) was carried out and the model equation obtained was subsequently optimised to obtain a model equation that could be used in predicting the recoverable quantity of gold, indicating that F11,1-values for Collector concentration, Frother concentration, pH and Conditioning time were 156.86, 6.96, 43.81, and 56.77 respectively. A model with an F value of 88.41 was obtained which indicated that the model was significant. The model equation obtained was subsequently optimised to be able to predict the recoverable quantity of gold. A “Pred R-Squared” value of 0.9365 (93.65%) was also obtained and is in reasonable agreement with the “Adj R-Squared” value of 0.9534 (95.34%). It was established that Ilesha placer gold ore is amenable to froth flotation using standard reagents.展开更多
针对浮选过程变量滞后、耦合特征及建模样本数量少所导致精矿品位难以准确预测的问题,提出了一种基于改进麻雀搜索算法(Improved Sparrow Search Algorithm,ISSA)优化混核最小二乘支持向量机(Hybrid Kernel Least Squares Support Vecto...针对浮选过程变量滞后、耦合特征及建模样本数量少所导致精矿品位难以准确预测的问题,提出了一种基于改进麻雀搜索算法(Improved Sparrow Search Algorithm,ISSA)优化混核最小二乘支持向量机(Hybrid Kernel Least Squares Support Vector Machine,HKLSSVM)的浮选过程精矿品位预测方法.首先采集浮选现场载流X荧光品位分析仪数据作为建模变量并进行预处理,建立基于最小二乘支持向量机(Least Squares Support Vector Machine,LSSVM)的预测模型,以此构建新型混合核函数,将输入空间映射至高维特征空间,再引入改进麻雀搜索算法对模型参数进行优化,提出基于ISSA-HKLSSVM方法实现精矿品位预测,最后开发基于LabVIEW的浮选精矿品位预测系统对本文提出方法实际验证.实验结果表明,本文提出方法对于浮选过程小样本建模具有良好拟合能力,相比现有方法提高了预测准确率,可实现精矿品位的准确在线预测,为浮选过程的智能调控提供实时可靠的精矿品位反馈信息.展开更多
文摘The possibility of using a centrifugal-gravity concentrator to reject Mg-bearing minerals and minimize metal losses in the flotation of base metals was evaluated. Sample characterization, batch scoping tests, pilot-scale tests, and regrind-flotation tests were conducted on a Ni flotation tailings stream. Batch tests revealed that the Mg grade decreased dramatically in the concentrate products. Pilot-scale testing of a continuous centrifugal concentrator(Knelson CVD6) on the flotation tailings revealed that a concentrate with a low mass yield, low Mg content, and high Ni upgrade ratio could be achieved. Under optimum conditions, a concentrate at 6.7% mass yield was obtained with 0.85% Ni grade at 12.9% Ni recovery and with a low Mg distribution(1.7%). Size partition curves demonstrated that the CVD also operated as a size classifier, enhancing the rejection of talc fines. Overall, the CVD was capable of rejecting Mg-bearing minerals. Moreover, an opportunity exists for the novel use of centrifugal-gravity concentration for scavenging flotation tailings and/or after comminution to minimize amount of Mg-bearing minerals reporting to flotation.
文摘The effect of reagents used in separating chalcopyrite from pyrite on the cake moisture of the copper concentrate at Daye Iron Mine Mineral Processing Plant was investigated. The results showed that the dosage of lime used for depressing pyrite was the main factor that increased the filter cake moisture of copper concentrate. With increasing the dosage of lime, the cake moisture of copper concentrate increased sharply. The cause was concluded to be the addition of lime to the pulp, which resulted in the formation of floc and a high pH value. The collector Z-200#, used for collecting chalcopyrite, had, as well, an adverse effect on the cake moisture of copper concentrate, but its effect was inferior in respect to that of lime. The cake moisture of copper concentrate can be decreased by changing the method with which lime is added and the pH value of pulp is regulated. The experiment results showed that the sulfuric acid was the best regulator. When the clarified liquor of lime was used as a depressant and the pH value of the pulp was regulated to 6.5€*7.0 by adding sulfuric acid, the cake moisture of copper concentrate was reduced from 15.49% to 13.13%. The examination of chalcopyrite surface by using ESCA (Electron Spectroscopy for Chemical Analysis) showed that calcium sulfate and iron hydroxide had formed on the surface of chalcopyrite when lime was added to the pulp. The formation of calcium sulfate and iron hydroxide on its surface increased the hydrophilicity of chalcopyrite so that its cake moisture increased. The addition of sulfuric acid to the pulp not only removed the calcium sulfate, but also reduced the concentration of iron hydroxide on the surface of chalcopyrite so that the cake moisture of copper concentrate was decreased.
文摘A hybrid process consisting of flotation and magnetic separation has been developed to concentrate multi-phase rare earth minerals associated with a carbonatite ore that contains a significant amount of niobium. The deposit is known to contain at least 15 different rare earth minerals identified as silicocarbonatite, magnesiocarbonatite, ferrocarbonatites, calciocarbonatite, REE/Nb ferrocarbonatite, phosphates and niobates. Although no collector exists to float all the different rare earth minerals, the hydroxamic acid-based collectors have shown adequate efficiency in floating most of these minerals. 92% recovery of total rare earth oxide (TREO) and niobium in 45% mass was possible at d<sub>80</sub> of <65 microns grind size. It was also possible to reduce the mass pull to 28%, but TREO and Nb’s recovery dropped to 85%. Calcination of the concentrate followed by quenching and fine grinding to <25 μm allowed upgrading the flotation concentrate by magnetic separation. It was demonstrated that at least 87% TREO and 85% Nb could be recovered in 16% of the feed mass. The paper discusses the overall concept of the flowsheet and the experimental strategies that led to this process.
基金the Higher Committee for Education Development in Iraq (HCED) for their financial support
文摘Bubble surface area flux(S_b) is one of the main design parameter in flotation column that typically employed to describe the gas dispersion properties, and it has a strong correlation with the flotation rate constant. There is a limited information available in the literature regarding the effect of particle type,density, wettability and concentration on Sb. In this paper, computational fluid dynamics(CFD) simulations are performed to study the gas–liquid–solid three-phase flow dynamics in flotation column by employing the Eulerian–Eulerian formulation with k-e turbulence model. The model is developed by writing Fortran subroutine and incorporating then into the commercial CFD code AVL FIRE, v.2014.This paper studies the effects of superficial gas velocities and particle type, density, wettability and concentration on Sband bubble concentration in the flotation column. The model has been validated against published experimental data. It was found that the CFD model was able to predict, where the response variable as indicated by R-Square value of 0.98. These results suggest that the developed CFD model is reasonable to describe the flotation column reactor. From the CFD results, it is also found that Sb decreased with increasing solid concentration and hydrophobicity, but increased with increasing superficial gas velocity. For example, approximately 28% reduction in the surface area flux is observed when coal concentration is increased from 0 to 10%, by volume. While for the same solid concentration and gas flow rate, the bubble surface area flux is approximately increased by 7% in the presences of sphalerite.A possible explanation for this might be that increasing solid concentration and hydrophobicity promotes the bubble coalescence rate leading to the increase in bubble size. Also, it was found that the bubble concentration would decrease with addition of hydrophobic particle(i.e., coal). For instance, under the same operating conditions, approximately 23% reduction in the bubble concentration is predicted when the system was working with hydrophobic particles. The results presented are useful for understanding flow dynamics of three-phase system and provide a basis for further development of CFD model for flotation column.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.51722405 and 51974310).
文摘Nanobubbles play a potential role in the application of the flotation of fine particles.In this work,the identification of nanoentities was performed with a contact mode atomic force microscope(AFM).Moreover,the influences of setpoint ratio and amplitude of the cantilever and the responses of the formed surface nanobubbles to the fluctuation of pH,salt concentration,and surfactant concentration in the slurry were respectively studied.Nanobubbles were reported on the highly oriented pyrolytic graphite(HOPG)surface as the HOPG was immersed in de-ionized water under ambient temperature.The coalescence of nanobubbles occurred under contact mode,which provides strong evidence of the gaseous nature of these nanostructures on HOPG.The measuring height of the surface nanobubbles decreased with the setpoint ratio.The changes in the pH and concentration of methyl isobutyl carbinol(MIBC)show a negligible influence on the lateral size and height of the preex-isting surface nanobubbles.The addition of LiCl results in a negligible change of the lateral size;however,an obvious change is noticed in the height of surface nanobubbles.The results are expected to provide a valuable reference in understanding the properties of surface nanobubbles and in the design of nanobubble-assisted flotation processes.
基金Project supported by the Collaborative Research and Development Program of Natural Sciences and Engineering Research Council of Canada
文摘The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved.Meanwhile,it is believed that frother transport between phases is perhaps the most important reason for the interactive nature of the phenomena occurring in the bulk and froth phases in flotation,as frother adsorbed in the surface of rising bubbles is removed from the bulk phase and then released into the froth as a fraction of the bubbles burst.This causes the increased concentration in the froth compared to the bulk concentration,named as frother partitioning.Partitioning reflects the adsorption of frother on bubbles and how to influence bubble size is not known.There currently exists no such a topic aiming to link these two key parameters.To fill this vacancy,the correspondence between bubble size and frother partitioning was examined.Bubble size was measured by sampling-for-imaging(SFI)technique.Using total organic carbon(TOC)analysis to measure the frother partitioning between froth and bulk phases was determined.Measurements have shown,with no exceptions including four different frothers,higher frother concentration is in the bulk than in the froth.The results also show strong partitioning giving an increase in bubble size which implies there is a compelling relationship between these two,represented by CFroth/CBulk and D32.The CFroth/CBulkand D32 curves show similar exponential decay relationships as a function of added frother in the system,strongly suggesting that the frother concentration gradient between the bulk solution and the bubble interface is the driving force contributing to bubble size reduction.
基金Project supported by the Collaborative Research and Development Program of NSERC(Natural Sciences and Engineering Research Council of Canada) with Industrial Sponsorship from Vale,Teck Cominco,Xstrata Process Support,Agnico-Eagle,Shell Canada,Barrick Gold,COREM,SGS Lakefield Research and Flottec
文摘This work aims to provide a relationship of how the key operational variables of frother type and impeller speed affect the size of bubble(D32). The study was performed using pilot-scale equipment(0.8 m3) that is up to two orders of magnitude larger than equipment used for studies performed to date by others, and incorporated the key process variables of frother type and impeller speed. The results show that each frother family exhibits a unique CCC95-HLB relationship dependent on n(number of C-atoms in alkyl group) and m(number of propylene oxide group). Empirical models were developed to predict CCC95 from HLB associated with other two parameters α and β. The impeller speed-bubble size tests show that D32 is unaffected by increased impeller tip speed across the range of 4.6 to 9.2 m/s(representing the industrial operating range), although D32 starts to increase below 4.6 m/s. The finding is valid for both coalescing and non-coalescing conditions. The results suggest that the bubble size and bubble size distribution(BSD) being created do not change with increasing impeller speed in the quiescent zone of the flotation.
文摘In this paper, prediction of copper and molybdenum grades and their recoveries of an industrial flotation plant are investigated using the Artificial Neural Networks (ANN) model. Process modeling has done based on 92 datasets collected at different operational conditions and feed characteristics. The prominent parameters investigated in this network were pH, collector, frother and F-Oil concentration, size percentage of feed passing 75 microns, moisture content in feed, solid percentage, and grade of copper, molybdenum, and iron in feed. A multilayer perceptron neural network, with 10:10:10:4 structure (two hidden layers), was used to estimate metallurgical performance. To obtain the optimal hidden layers and nodes in a layer, a trial and error procedure was done. In training and testing phases, it achieved quite correlations of 0.98 and 0.93 for Copper grade, of 0.99 and 0.92 for Copper recovery, of 0.99 and 0.92 for Molybdenum grade and of 0.99 and 0.94 for Molybdenum recovery prediction, respectively. The proposed neural network model can be applied to determine the most beneficial operational conditions for the expected Copper and Molybdenum grades and their recovery in final concentration of the industrial copper flotation process.
文摘The flotability and mechanism of tantalite-niobite minerals which have different contents of Ta, Nb, Fe Mn using styrenephosphonic acid (SPA) were investigated. The optimum pH value in pulp is less than 5, flotability varies with the different contents of mineral, and flotability of minerals with higher Nb2O5 content is better than that with higher Ta2O5 content. In wide range of pH in solution, the Fe, Mn on the surface are the main active species for flotation. Research using Auger electron spectroscopy, infrared spectroscopy and ultraviolet spectroscopy for determining surface conditions has been done. SPA interacts with Fe, Mn ions on the surface by a chemical bond force. On the outer layer of the collector, which is a non-uniform multilayer, adsorption of SPA on surface is both chemico-adsorption and physico-adsorption, but chemico-adsorption is dominant.
文摘A low-grade gold ore from Ilesha-Itagunmodi, south western Nigeria was panned, dried and ball-milled before sieving into fractions. The morphological, mineralogical and chemical composition was studied by optical micro-scopy (Reflected and Transmission), X-ray diffraction (XRD) and Energy Dispersive X-ray fluorescence (XRF), respectively. The sieved fractions were subjected to chemical analysis (AAS). The +106 μm sieve had the highest concentration of the mineral and was then selected for the upgrade through froth flotation using standard reagents. In this paper a report on a 2k factorial experiment that provides an understanding of the impact of operational variables on the quantity of gold mineral obtained from the ore during froth flotation is presented. Analysis results showed that Ilesha-Itagunmodi gold ore is non-refractory with fine grain particles, amenable to froth flotation and contained about 20 other associated minerals, gold had a concentration of about 0.0024%. A com-bination of P-Xanthate and amine glycol collectors at a pH of 9.2 only produced a considerable increase in gold yield. This translated to about 87.13% increase in recovery of gold from the ore. Analysis of variance (ANOVA) was carried out and the model equation obtained was subsequently optimised to obtain a model equation that could be used in predicting the recoverable quantity of gold, indicating that F11,1-values for Collector concentration, Frother concentration, pH and Conditioning time were 156.86, 6.96, 43.81, and 56.77 respectively. A model with an F value of 88.41 was obtained which indicated that the model was significant. The model equation obtained was subsequently optimised to be able to predict the recoverable quantity of gold. A “Pred R-Squared” value of 0.9365 (93.65%) was also obtained and is in reasonable agreement with the “Adj R-Squared” value of 0.9534 (95.34%). It was established that Ilesha placer gold ore is amenable to froth flotation using standard reagents.
文摘针对浮选过程变量滞后、耦合特征及建模样本数量少所导致精矿品位难以准确预测的问题,提出了一种基于改进麻雀搜索算法(Improved Sparrow Search Algorithm,ISSA)优化混核最小二乘支持向量机(Hybrid Kernel Least Squares Support Vector Machine,HKLSSVM)的浮选过程精矿品位预测方法.首先采集浮选现场载流X荧光品位分析仪数据作为建模变量并进行预处理,建立基于最小二乘支持向量机(Least Squares Support Vector Machine,LSSVM)的预测模型,以此构建新型混合核函数,将输入空间映射至高维特征空间,再引入改进麻雀搜索算法对模型参数进行优化,提出基于ISSA-HKLSSVM方法实现精矿品位预测,最后开发基于LabVIEW的浮选精矿品位预测系统对本文提出方法实际验证.实验结果表明,本文提出方法对于浮选过程小样本建模具有良好拟合能力,相比现有方法提高了预测准确率,可实现精矿品位的准确在线预测,为浮选过程的智能调控提供实时可靠的精矿品位反馈信息.