Influence of Heating Rate on Double Reversible Transformation in CuZnAlMnNi Shape Memory Alloy

The influence of heating rate on double reversible transformation in CuZnAlMnNi shape memory alloy was investigated by differential scanning calorimetry. It was found that rapid heating inhibits X -->M transformation but is favorable to the reverse martensite transformation, giving rise to the approach of the two transformation peaks. With the decrease of heating rate, the two transformation peaks separate gradually.

Solution of an Inverse Problem of Heat Conduction of 45 Steel with Martensite Phase Transformation in High Pressure during Gas Quenching

In order to simulate thermal strains, thermal stresses, residual stresses and microstructure of the steel during gas quenching by means of the numerical method, it is necessary to obtain an accurate boundary condition of temperature field. The surface heat transfer coefficient is a key parameter. The explicit finite difference method, nonlinear estimation method and the experimental relation between temperature and time during gas quenching have been used to solve the inverse problem of heat conduction. The relationship between surface temperature and surface heat transfer coefficient of a cylinder has been given. The nonlinear surface heat transfer coefficients include the coupled effects between martensitic phase transformation and temperature.

Effects of high-pressure heat treatment on the solid-state phase transformation and microstructures of Cu_(61.13)Zn_(33.94)Al_(4.93) alloys

The phase transformation activation energy of the Cu61.13Zn33.94A14.93 alloys, which were treated at 4 GPa and 700 ℃ for 15 minutes, was calculated by means of differential scanning calorimetry curves obtained at various heating and cooling rates. Then, the effects of high-pressure heat treatments on the solid-state phase transformation and the microstructures of Cu61.13Zn33.94A14.93 alloys were investigated. The results show that high-pressure heat treatments can refine the grains and can change the preferred orientation from （111） to （200） of α phase. Compared with the as-cast alloy, the sample with high-pressure heat treatment has finer grains, lower β＇→β and/β→β＇ transformation temperature and activation energy. Furthermore, we found that high cooling rate favours the formation of fine needle-like α phase in the range of 5-20℃/min.

MICROSTRUCTURE TRANSFORMATION IN THE WELDING HEAT AFFECTED ZONE OF 800MPa GRADE ULTRA FINE STRUCTURED STEEL

The transformation behavior and microstructure development in the heat affected zone(HAZ)of 800MPa grade ultra fine structured steel was investigated.It was found that the HAZ has intermediate temperature transformation characteristics in a wide range of cooling rates,with the bainite sheaves consisting of bainite ferrite plates without carbide precipitation and retained austenite in the fast cooling regime.At relatively high cooling rates,which corresponded to low heat inputs,the hardness of the simulated HAZ was above that of the base metal.When the cooling rate was below 9C/s,the welding HAZ would have an obvious softening.The analysis of transformation rates in continuous cooling processes was completed by numerical differential method.The result indicated that the microstructure transformation rate of the HAZ in 800MPa grade ultra fine structured steel changed sharply to slow speeds when the cooling time t8/5 is longer than 7s.

Effect of heat treatment on the transformation behavior and temperature memory effect in TiNiCu wires

The effect of heat treatment on the phase transformation behavior of TiNiCu shape memory alloy wires and the temperature memory effect in this alloy were investigated by the resistance method. These results showed that with increasing annealing temperature and annealing time, the phase transformation temperatures of TiNiCu wires were shifted to higher temperatures in the heating and cooling process. It was also found that incomplete thermal cycles, upon heating the TiNiCu wires, which were arrested at a temperature between the start and finish temperatures of the reverse martensite transformation, could induce a kinetic stop in the next complete thermal cycle. The kinetic stop temperature was closely related to the previous arrested temperature. This phenomenon was defined as the temperature memory effect. The result of this study was consistent with the previous report on the phenomenon obtained using the differential scanning calorimetry method, indicating that temperature memory effect was a common phenomenon in shape memory alloys.

Water adsorption performance of UiO-66 modified by MgCl_(2) for heat transformation applications

UiO-66 is a potential material for adsorption heat transformation(AHT)with high specific surface area,and excellent thermal and chemical stability.However,the low water adsorption capacity of UiO-66 in the low relative pressure range(0<P/P_(0)<0.3)limits its application in AHT.We prepare the UiO-66 modified by MgCl_(2)through using the solvothermal method and impregnation method,and study their water vapor adsorption performances and heat storage capacities.Attributed to the extremely high saturated water uptake and excellent hydrophilicity of MgCl_(2),the water adsorption performance of UiO-66 is improved,although the introduction of MgCl_(2)reduces its specific surface area and pore volume.The water adsorption capacity at P/P_(0)=0.3 and the saturated water adsorption capacity of the UiO-66(with MgCl_(2)content of 0.57 wt%)modified by the solvothermal method are 0.27 g/g and 0.57 g/g at 298 K,respectively,which are 68.8%and 32.6%higher than the counterparts of pure UiO-66,respectively.Comparing with pure UiO-66,the water adsorption capacity of the UiO-66(with MgCl_(2)content of 1.02 wt%)modified by the impregnation method is increased by 56.3%and 14.0%at the same pressure,respectively.During 20 water adsorption/desorption cycles,the above two materials show high heat storage densities(~1293 J/g and 1378 J/g).Therein,the UiO-66 modified by the solvothermal method exhibits the excellent cyclic stability.These results suggest that the introduction of an appropriate amount of MgCl_(2)makes UiO-66more suitable for AHT applications.

THE NUMERICAL METHOD FOR ANALYSING THE TRANSIENT TEMPERATURE FIELD AND TRANSIENT PHASE TRANSFORMATION OF METAL MATERIALS IN HEAT TREATING

In this paper, the Kirchhoffs transformation is popularized to the nonlinear heat conduction problem which the heat conductivity can be expressd as a multinomial of temperature firstly, the boundary condition of heat conduction problem is determined by analytics.Secondly, the incubation peroid superposition and the linear combination law is employed to simulate the transient phasses transformation in the process of heat treatment of materials. That the begin time of phase transformation, the type of phase transformation and the amount of phase constitution is determined simply.Finally, the three-dimension Dual Reciprocity Boundary Element Method is usedto analysis the total process of various heat treatment of component, the results of numerical calculation of examples show that the method provided in this paper is effectivce.

Calculation of phase transformation latent heat based on cooling curves in end-quench test and its application in nickel-based superalloy

To obtain the phase transformation latent heat corresponding to different cooling rates with low test workload and cost,the Newton thermal analysis method and the improved Newtonian thermal analysis method were discussed based on the cooling curve obtained in the end-quench test.The validity of two methods was given by the latent heat calculation of 45^(#) steel.The results show that the relative error of latent heat is 5.20%through the improved Newtonian thermal analysis method,which is more accurate than the Newtonian thermal analysis method.Furthermore,the latent heat release of phase transformation of the self-designed CSU-A1 powder metallurgy nickel-based superalloy increases from 4.3 to 12.29 J/g when the cooling rate decreases from 50.15 to 33.40℃/min,because there is more sufficient time for the alloy microstructure to complete the phase transformation process when the cooling rate is smaller.

A Study on the Effects of Internal Heat Generation on the Thermal Performance of Solid and Porous Fins using Differential Transformation Method

In this study,the impacts of internal heat generation on heat transfer enhancement of porous fin is theoretical investigated using differential transform method.The parametric studies reveal that porosity enhances the fin heat dissipating capacity but the internal heat generation decreases the heat enhancement capacity of extended surface.Also,it is established that when the internal heat parameter increases to some certain values,some negative effects are recorded where the fin stores heat rather than dissipating it.This scenario defeats the prime purpose of the cooling fin.Additionally,it is established in the present study that the limiting value of porosity parameter for thermal stability for the passive device increases as internal heat parameter increases.This shows that although the internal heat parameter can help assist higher range and value of thermal stability of the fin,it produces negative effect which greatly defeats the ultimate purpose of the fin.The results in the work will help in fin design for industrial applications where internal heat generation is involved.

Effects of Heat Treatment and Thermal Cycling on Martensitic Transformation Behavior of Ni_(59)Al_(11)Mn_(30) High Temperature Shape Memory Alloy

A reversible martensitic transformation (MT) takes place during cooling and heating in the solution quenched and the solution quenched plus aged Ni59AlHMn30 alloy The MT temperature increases with increasing solution temperature. The excellent MT characteristics can be obtained from a process of lOOCTC solution quenched plus 400 °C aged. Follow this process, the MT start temperature (Ms) and the reverse MT finish temperature (Af) are 469*C and 548"C, respectively. The martensitic stabilization effect in the solution quenched and aged Ni59AlnMn3o alloy is observed as an increase in the Af temperature of the first reverse MT during thermal cycles. This stabilization effect vanishes from the second thermal cycle. Thermal cycling can enhance the stability of the reversible MT. The microstructure of the quenched NisgAlnMnjo alloy consists of martensite (M) and gamma phase. The volume fraction of gamma phase is about 40%. The substructure of M and gamma phase is twins and dislocations, respectively. The hardness of M is higher than that of gamma phase. After aging treatment the basic phases of alloy do not change, but the hardness of the phases increases.

Influence of Ni_4Ti_3 precipitates on phase transformation of NiTi shape memory alloy

Ni Ti shape memory alloy samples were aged for 2 h at 573, 723 and 873 K, respectively. Two R-phase variants are observed in the Ni Ti samples aged at 573 and 723 K, where the orientation relationship between the two R-phase variants and the B2 matrix is determined. In the Ni Ti samples aged at 573 and 723 K, fine and homogeneous Ni4Ti3 precipitates are coherent with the B2 austenite matrix. The Ni4Ti3 particles precipitate in the grain interior and at the grain boundaries, where the heterogeneous Ni4Ti3 precipitates are coherent, semi-coherent and incoherent with the B2 matrix in the Ni Ti sample aged at 873 K. As for the Ni Ti sample aged at 873 K, one-stage phase transformation from B19＇ martensite to B2 austenite occurs on heating, but two-stage phase transformation of B2-R-B19＇ arises on cooling. The Ni Ti sample aged at 723 K shows two-stage phase transformation of B2-R-B19＇ on cooling as well, but exhibits two-stage phase transformation of B19＇-R-B2 on heating. The Ni Ti sample aged at 573 K exhibits three-stage transformation on cooling due to local stress inhomogeneity and local composition inhomogeneity around the Ni4Ti3 precipitates.

FEM simulation and experimental verification of temperature field and phase transformation in deep cryogenic treatment

Combining with the low temperature material properties and the boiling heat transfer coefficient of specimen immersed in the liquid nitrogen, a numerical model based on metallo-thermo-mechanical couple theory was established to reproduce the deep cryogenic treatment （DCT） process of a newly developed cold work die steel Cr8Mo2SiV （SDC99）. Moreover, an experimental setup for rapid temperature measurement was designed to validate the simulation results. The investigation suggests that the differences in temperature and cooling rate between the surface and core of specimen are very significant. However, it should be emphasized that the acute temperature and cooling rate changes during DCT are mainly concentrated on the specimen surface region about 1/3 of the sample thickness. Subjected to DCT, the retained austenite of quenched specimen continues to transform to martensite and finally its phase volume fraction reduces to 2.3%. The predicted results are coincident well with the experimental data, which demonstrates that the numerical model employed in this study can accurately capture the variation characteristics of temperature and microstructure fields during DCT and provide a theoretical guidance for making the reasonable DCT procedure.

基于Transformer的3D点云目标检测算法

针对在三维目标检测中由于空间维度的增加基于锚框的方法难以部署的问题,研究了基于集合预测的点云目标检测算法。提出一种基于Transformer的3D点云目标检测算法,并结合自动驾驶场景下的点云特点,提出了改进空间调制注意力和热图初始化策略进行训练加速和查询初始化,在浅层网络下取得了良好的检测性能。在KITTI数据集上与其他算法进行比较,结果表明所提算法在性能上已经达到先进水平,进一步对算法中的主要组成部分进行了消融实验,验证了各个模块对检测效果的贡献。

Numerical manifold method for steady-state nonlinear heat conduction using Kirchhoff transformation

The numerical manifold method(NMM)introduces the mathematical and physical cover to solve both continuum and discontinuum problems in a unified manner.In this study,the NMM for solving steady-state nonlinear heat conduction problems is presented,and heat conduction problems consider both convection and radiation boundary conditions.First,the nonlinear governing equation of thermal conductivity,which is dependent on temperature,is transformed into the Laplace equation by introducing the Kirchhoff transformation.The transformation reserves linearity of both the Dirichlet and the Neumann boundary conditions,but the Robin and radiation boundary conditions remain nonlinear.Second,the NMM is employed to solve the Laplace equation using a simple iteration procedure because the nonlinearity focuses on parts of the problem domain boundaries.Finally,the temperature field is retrieved through the inverse Kirchhoff transformation.Typical examples are analyzed,demonstrating the advantages of the Kirchhoff transformation over the direct solution of nonlinear equations using the NewtonRaphson method.This study provides a new method for calculating nonlinear heat conduction.

A Study of the Extratropical Transformation of Typhoon Winnie (1997)

The complicated evolutive process of how a tropical cyclone transforms into an extratropical cyclone is still an unresolved issue to date, especially one which arises in a weakly baroclinic environment. Typhoon Winnie （1997） is studied during its extratropical transformation stage of extratropical transition （ET） with observational data and numerical simulations. Results show that Winnie experienced its extratropical transformation to the south of the subtropical high without intrusion of the mid-latitude baroclinic zone. This is significantly different from previous studies. Analyses reveal that the cold air, which appeared in the north edge of Winnie circulation, resulted from the precipitation drag and cooling effect of latent heat absorption associated with the intense precipitation there. The cooling only happened below 3 km and the greatest cooling was below 1 km. With the cold air and its advection by the circulation of Winnie, a front was formed in the lower troposphere. The front above is related not only to the cooling in the lower level but also to the warming effect of latent heat release in the middle-upper levels. The different temperature variation in the vertical caused the temperature gradient over Winnie and resulted in the baroclinicity.

Wood liquefaction with phenol by microwave heating and FTIR evaluation

We examined wood liquefaction using phenol and mixed acid catalysts with microwave heating, and compared that with similar processes that use oil bath heating. The reaction time for microwave heating to achieve a residue content was one sixth, one eighteenth, and one twenty-fourth of that from oil bath heating, respectively, for phenol to wood （P/W） ratios of 2.5/1, 2/1 and 1.5/1. A low P/W ratio tended to result in carbonization of liquefied wood due to an insufficient amount of phenol and localized microwave superheating. Fourier transform infrared spectroscopic （FTIR） evaluation of the liquefied residue, showed that the liquefaction rates of wood com- ponents differed. Hemicellulose was most susceptible to liquefaction, crystalline cellulose was most recalcitrant, and guaiacyl units the most prone to re-condensation. From FTIR, the chemical components and substitution patterns of bonded phenol were similar for both methods.

Transformation Plasticity─The Effect on Metallo-Thermo-Mechanical Simulation of Carburized Quenching Process

Theory of metallo-thermo-mechamics and the developed CAE code offer a powerful tool to simulate residual stresses and distortion during heat treatment processes, in which the transformation plasticity is one of factors to be considered being coupled with stress/strain and metallic structure. It is pointed out in this paper that, especially in the case of carburized quenching, transformation plasticity plays very important role on the distortion, which is verified by axisymmetric finite element, employing heat treatment simulation code "HEARTS". Simulated results with the careful consideration on the effect of transformation plasticity reveal to improve remarkably the accuracy of prediction of the displacement and the mode of distortion, compensating the discrepancy between experimental and calculated results. Attention is also paid on the difference in transformation plasticity and conventional plasticity in simulating the volume fraction, stress and strain in ring-shaped specimen during quenching. Moreover some discussions are made on practical use of the effect, and recent experimental results on the coefficient of transformation plasticity are presented.

Improvement of fuel consumption and maintenance of heating furnaces using a modified heating pattern

This article studies the transient heat conduction in a slab when passing through various sections of the furnace, and focuses on the thickness of the scale layer formed on the slab. The transient heat conduction behavior of a slab in various sections of the heating furnace is analyzed using the Laplace transformation method, including the pre-heating zone, the first heating zone, the second heating zone, and the soaking zone. The heating pattern of the furnace is then modified to reduce fuel consumption. The simulation results show that the scale layer formed on the slab significantly influences the quality of the hot rolled coil formed, and how the furnace parameters affect the efficiency of the furnace and the quality of the coil.

OSCILLATION AND VARIATION OF THE LAGUERRE HEAT AND POISSON SEMIGROUPS AND RIESZ TRANSFORMS

In this article, we study LP-boundedness properties of the oscillation and vari- ation operators for the heat and Poissson semigroup and Riesz transforms in the Laguerre settings. Also, we characterize Hardy spaces associated to Laguerre operators by using the variation operator of the heat semigroup.

Transformation, Deformation and Microstructure Characteristics of Ru_(50)Ta_(50) High Temperature Shape Memory Alloy

The basic martensitic transformation （MT） properties of Ru50Ta50 alloy, i.e. MT temperature （MTT）, temperature hysteresis （△T）, and MT heat （△H） were investigated in this paper. The effects of heat treatment and thermal cycling on MT behavior of Ru50Ta50 alloy, the deformation and microstructure characteristics of Ru50Ta50 alloy were also studied for its engineering application as high temperature actuator/sensor materials by means of differential scanning calorimetry, X-ray diffraction, transmission electron microscope, optical microscope, and hardness test. The results showed that a two-stage reversible MT takes place in Ru50Ta50 alloy. The two-stage MT starting temperatures （Ms^1, Ms^2） and the temperature hysteresis （△T1, △T2） are 1047, 784 and 11, 14℃, respectively. No significant effect of aging treatment and thermal cycling on MTT and AT of Ru50Ta50 alloy were observed, but △H decreases slowly with increasing thermal cycles. The hardness and brittleness of Ru50Ta50 alloy are high. The deformation mode of RuTa alloys is twinning.