Microencapsulation phase change material slurry(MEPCMS) becomes a potential working fluid for cooling high energy density miniaturized components,thanks to the latent heat absorption of particles in the heat transfer ...Microencapsulation phase change material slurry(MEPCMS) becomes a potential working fluid for cooling high energy density miniaturized components,thanks to the latent heat absorption of particles in the heat transfer process.In this work,the Discrete Phase Model(DPM) based on the Euler-Lagrangian method is used to numerically investigate the convective heat transfer characteristics of MEPCMS flowing through a rectangular minichannel with constant heat flux.The results show that particles of MEPCMS are mainly subjected to drag force during the flow.Even so,they can migrate from the high-temperature region to the low-temperature region driven by the thermophoretic force,affecting the particle distribution and phase change process.Moreover,the Nux of the MEPCMS fluctuates due to particle phase change with varying specific heat capacities.Specifically,the value increases first,then decreases,and eventually increases again until it approaches the fully developed value of the pure base fluid as the particles gradually melt.Furthermore,the heat transfer performance of the MEPCMS is influenced by the combination of fluid inlet temperature fluid inlet velocity(v),and mass concentration(c_(m)) of MEPCM particles.The result shows that the maximum reduction of the maximum bottom wall temperature difference(ΔT_(w)) is 23.98% at T_(in)=293.15 K,v=0.15 m·s^(-1),c_(m)=10%.展开更多
Due to its core phase change characteristics,microencapsulated phase change material(MPCM)can make many base fluids have better heat transfer characteristics.In this paper,the flow boiling heat transfer characteristic...Due to its core phase change characteristics,microencapsulated phase change material(MPCM)can make many base fluids have better heat transfer characteristics.In this paper,the flow boiling heat transfer characteristics of fluorinated liquid-based microencapsulated phase change material suspension(MPCMS)through vertical transparent quartz channel were studied.The effects of MPCM core phase change temperature and suspension flow velocity on boiling heat transfer coefficient and critical heat flux were discussed,respectively.The results show that the appropriate concentration of MPCMS can enhance both the boiling heat transfer coefficient and the critical heat flux.The strengthening effect becomes weak with the increase of suspension flow velocity.The maximum strengthening rates of critical heat flux appear at 0.05 m/s,which are 25%(MPCMS(70℃)),16%(MPCMS(58℃))and 10%(MPCMS(28℃)).The phase change temperature of the MPCM core has important effects on the boiling heat transfer coefficient and the critical heat flux.The results showed that the MPCM with core phase change temperature higher than the boiling temperature of base fluid has the best enhancement effect.Different bubble behavior in vertical tube with different heat flux can be observed by high-speed photography system.The particle core phase change in MPCMS inhibits the aggregation of bubbles and forms many small bubbles to enhance heat transfer.The work lays a foundation for further exploring the industrial application of MPCMS.展开更多
The specific heat capacity of working fluid is an important influence factor on heat transfer characteristic of the pulsating heat pipe(PHP).Due to the relatively large specific heat capacity of micro encapsulated pha...The specific heat capacity of working fluid is an important influence factor on heat transfer characteristic of the pulsating heat pipe(PHP).Due to the relatively large specific heat capacity of micro encapsulated phase change material(MEPCM) suspension,a heat transfer performance experimental facility of the PHP was established.The heat transfer characteristic with MEPCM suspension of different mass concentrations(0.5% and 1.0%) and ultra-pure water were compared experimentally.It was found that when the PHP uses MEPCM suspension as its working fluid,operating stability is impoverished under lower heating power and the operating stability is better under higher heating power.At the inclination angle of 90°,the temperature at heating side decreases compared to ultra-pure water and the temperature at heating side decreases with the raising of MEPCM suspension mass concentration.The heat transfer characteristic of the PHP is positively correlated with the inclination angle and the 90° is optimum.The unfavorable effect of the inclination angle decreases with heating power increasing.When the inclination angle is 90°,the PHP with MEPCM suspension at 1.0% of mass concentration has the lowest thermal transfer resistance and followed by ultra-pure water and MEPCM suspension at 0.5% of mass concentration has the highest thermal transfer resistance.When the inclination angles are 60° and30°,the effect of gravity on the flow direction is reduced to 86.6% and 50% of that on the inclination angle of 90°,respectively,and the promoting effect of gravity on the working fluid is further weakened as the inclination angle further decreases.Due to the high viscosity of MEPCM suspension,the PHP with ultra-pure water has the lowest heat transfer resistance.When the inclination angles is 60°,the thermal resistance with MEPCM suspension at0.5% of the mass concentration is lower than that at 1.0% at the heating power below 230 W.The thermal resistance of MEPCM suspension tends to be similar for heating power of 230-250 W.At the heating power above 270 W,the thermal resistance with MEPCM suspension at 1.0% of the mass concentration is lower than that at 0.5%.展开更多
This short communication reports our recent work on the synthesis and characterisation ofmicrocapsules of phase change materials using silica as the shell material through a one-step method. The method uses no surfact...This short communication reports our recent work on the synthesis and characterisation ofmicrocapsules of phase change materials using silica as the shell material through a one-step method. The method uses no surfactants or dispersants for stabilising the capsules. The results show that the one-step method allows the tuning of the size and polydispersity of the capsules, and the use of different core materials. Analyses of the capsules show that they contain about 65% phase change materials. The results also suggest no need for a stabilising agent due to self-stabilisation by the amine groups. Further work is underway to investigate the mechanical and thermal properties of the microcapsules and the scale-up of the method.展开更多
An experimental investigation was conducted on the laminar flow frictional characteristics of suspensions with microencapsulated phase change material (MEPCM) in water flowing through rectangular copper minichannels. ...An experimental investigation was conducted on the laminar flow frictional characteristics of suspensions with microencapsulated phase change material (MEPCM) in water flowing through rectangular copper minichannels. The MEPCM was provided at an average particle size of 4.97 μm, and was mixed with distilled water to form suspen- sions with various mass concentrations ranging from 0 to 20%. The experiment was per- formed to explore the effect of MEPCM mass concentration on friction factor and pressure drop in the minichannels. The Reynolds number ranged from 200 to 2000 to provide laminar and transitional flows. It was found that the experimental data for the suspensions with 0 and 5% concentration agree well with the existing theoretical data for an incom- pressible, fully developed, laminar Newtonian flow. For the suspensions with mass con- centrations higher than 10%, there is an obvious increase in friction factor and pressure drop in comparison with laminar Newtonian flow.展开更多
This paper presents a novel concept for designing solar-absorbing metamaterial microcapsules of phase change materials(PCMs)integrated with thermo-regulating smart textiles intended for coats or garments,especially fo...This paper presents a novel concept for designing solar-absorbing metamaterial microcapsules of phase change materials(PCMs)integrated with thermo-regulating smart textiles intended for coats or garments,especially for wear in space or cold weather on earth.The metamaterial is a periodically nanostructured metal-dielectric-metal thin film and can acquire surface plasmons to trap or absorb solar energy at subwavelength scales.This kind of metamaterial microencapsulation is not only able to take advantage of latent heat that can be stored or released from the PCMs over a tunable temperature range,but also has other advantages over conventional polymer microencapsulation of PCMs,such as enhanced thermal conductivity,improved flame-retardant capabilities,and usage as an extra solar power resource.The thermal analysis for this kind of microencapsulation has been done and can be used as a guideline for designing integrated thermo-regulating smart textiles in the future.These metamaterial microcapsules may open up new routes to enhancing thermo-regulating textiles with novel properties and added value.展开更多
Aiming to identify the validity of fabricating microencapsulated phase change material(PCM) with polymethylmethacrylate(PMMA) by ultraviolet curing emulsion polymerization method using iron(III) chloride as photoiniti...Aiming to identify the validity of fabricating microencapsulated phase change material(PCM) with polymethylmethacrylate(PMMA) by ultraviolet curing emulsion polymerization method using iron(III) chloride as photoinitiator,SA/PMMA microcapsules were prepared and various techniques were employed to determine the ignition mechanism,structural characteristics and thermal properties of the composite.The results shown that the microcapsules containing SA with maximum percentage of 52.20 wt% formed by radical mechanism and only physical interactions existed in the components both in the prepared process and subsequent use.The phase change temperatures and latent heats of the microencapsulated SA were measured as 55.3 °C and 102.1 J·g^(-1) for melting,and 48.8 °C and 102.8 J·g^(-1) for freezing,respectively.Thermal gravimetric analysis revealed that SA/PMMA has good thermal durability in working temperature range.The results of accelerated thermal cycling test are all shown that the SA/PMMA have excellent thermal reliability and chemical stability although they were subjected 1000 melting/freezing cycles.In summary,the comparable thermal storage ability and good thermal reliability facilitated SA/PMMA to be considered as a viable candidate for thermal energy storage.The successful fabrication of SA/PMMA capsules indicates that ferric chloride is a prominent candidate for synthesizing PMMA containing PCM composite.展开更多
基金the financial support of the National Natural Science Foundation of China (No.U20A20299)the Natural Science Foundation of Guangdong Province (No.2019A1515012119)。
文摘Microencapsulation phase change material slurry(MEPCMS) becomes a potential working fluid for cooling high energy density miniaturized components,thanks to the latent heat absorption of particles in the heat transfer process.In this work,the Discrete Phase Model(DPM) based on the Euler-Lagrangian method is used to numerically investigate the convective heat transfer characteristics of MEPCMS flowing through a rectangular minichannel with constant heat flux.The results show that particles of MEPCMS are mainly subjected to drag force during the flow.Even so,they can migrate from the high-temperature region to the low-temperature region driven by the thermophoretic force,affecting the particle distribution and phase change process.Moreover,the Nux of the MEPCMS fluctuates due to particle phase change with varying specific heat capacities.Specifically,the value increases first,then decreases,and eventually increases again until it approaches the fully developed value of the pure base fluid as the particles gradually melt.Furthermore,the heat transfer performance of the MEPCMS is influenced by the combination of fluid inlet temperature fluid inlet velocity(v),and mass concentration(c_(m)) of MEPCM particles.The result shows that the maximum reduction of the maximum bottom wall temperature difference(ΔT_(w)) is 23.98% at T_(in)=293.15 K,v=0.15 m·s^(-1),c_(m)=10%.
基金This work was supported by the Scientific Instrument Developing Project of the Chinese Academy of Sciences(Grant No.YJKYYQ20200016)the National Natural Science Foundation of China(Grant No.52106117).
文摘Due to its core phase change characteristics,microencapsulated phase change material(MPCM)can make many base fluids have better heat transfer characteristics.In this paper,the flow boiling heat transfer characteristics of fluorinated liquid-based microencapsulated phase change material suspension(MPCMS)through vertical transparent quartz channel were studied.The effects of MPCM core phase change temperature and suspension flow velocity on boiling heat transfer coefficient and critical heat flux were discussed,respectively.The results show that the appropriate concentration of MPCMS can enhance both the boiling heat transfer coefficient and the critical heat flux.The strengthening effect becomes weak with the increase of suspension flow velocity.The maximum strengthening rates of critical heat flux appear at 0.05 m/s,which are 25%(MPCMS(70℃)),16%(MPCMS(58℃))and 10%(MPCMS(28℃)).The phase change temperature of the MPCM core has important effects on the boiling heat transfer coefficient and the critical heat flux.The results showed that the MPCM with core phase change temperature higher than the boiling temperature of base fluid has the best enhancement effect.Different bubble behavior in vertical tube with different heat flux can be observed by high-speed photography system.The particle core phase change in MPCMS inhibits the aggregation of bubbles and forms many small bubbles to enhance heat transfer.The work lays a foundation for further exploring the industrial application of MPCMS.
基金financially supported by National Natural Science Foundation of China (Grant No.52000008)supported by R&D Program of Beijing Municipal Education Commission(Grant No.KM202310016008)+1 种基金Beijing Natural Science Foundation (Grant No.3192042)the Fundamental Research Funds for Beijing University of Civil Engineering and Architecture (Grant No.X20058)。
文摘The specific heat capacity of working fluid is an important influence factor on heat transfer characteristic of the pulsating heat pipe(PHP).Due to the relatively large specific heat capacity of micro encapsulated phase change material(MEPCM) suspension,a heat transfer performance experimental facility of the PHP was established.The heat transfer characteristic with MEPCM suspension of different mass concentrations(0.5% and 1.0%) and ultra-pure water were compared experimentally.It was found that when the PHP uses MEPCM suspension as its working fluid,operating stability is impoverished under lower heating power and the operating stability is better under higher heating power.At the inclination angle of 90°,the temperature at heating side decreases compared to ultra-pure water and the temperature at heating side decreases with the raising of MEPCM suspension mass concentration.The heat transfer characteristic of the PHP is positively correlated with the inclination angle and the 90° is optimum.The unfavorable effect of the inclination angle decreases with heating power increasing.When the inclination angle is 90°,the PHP with MEPCM suspension at 1.0% of mass concentration has the lowest thermal transfer resistance and followed by ultra-pure water and MEPCM suspension at 0.5% of mass concentration has the highest thermal transfer resistance.When the inclination angles are 60° and30°,the effect of gravity on the flow direction is reduced to 86.6% and 50% of that on the inclination angle of 90°,respectively,and the promoting effect of gravity on the working fluid is further weakened as the inclination angle further decreases.Due to the high viscosity of MEPCM suspension,the PHP with ultra-pure water has the lowest heat transfer resistance.When the inclination angles is 60°,the thermal resistance with MEPCM suspension at0.5% of the mass concentration is lower than that at 1.0% at the heating power below 230 W.The thermal resistance of MEPCM suspension tends to be similar for heating power of 230-250 W.At the heating power above 270 W,the thermal resistance with MEPCM suspension at 1.0% of the mass concentration is lower than that at 0.5%.
基金supported by UK EPSRC under grants EP/F023014/1 and EP/F000464/1a collaborative research fund from the Institute of Process Engineering of Chinese Academy of Sciences
文摘This short communication reports our recent work on the synthesis and characterisation ofmicrocapsules of phase change materials using silica as the shell material through a one-step method. The method uses no surfactants or dispersants for stabilising the capsules. The results show that the one-step method allows the tuning of the size and polydispersity of the capsules, and the use of different core materials. Analyses of the capsules show that they contain about 65% phase change materials. The results also suggest no need for a stabilising agent due to self-stabilisation by the amine groups. Further work is underway to investigate the mechanical and thermal properties of the microcapsules and the scale-up of the method.
基金partly supported by Deutscher Akademischer Austausch Dienst(German DAAD scholarship),Chinese Scholarship Councilthe National Natural Science Foundation of China(Grant Nos.50436020 and 50176004).
文摘An experimental investigation was conducted on the laminar flow frictional characteristics of suspensions with microencapsulated phase change material (MEPCM) in water flowing through rectangular copper minichannels. The MEPCM was provided at an average particle size of 4.97 μm, and was mixed with distilled water to form suspen- sions with various mass concentrations ranging from 0 to 20%. The experiment was per- formed to explore the effect of MEPCM mass concentration on friction factor and pressure drop in the minichannels. The Reynolds number ranged from 200 to 2000 to provide laminar and transitional flows. It was found that the experimental data for the suspensions with 0 and 5% concentration agree well with the existing theoretical data for an incom- pressible, fully developed, laminar Newtonian flow. For the suspensions with mass con- centrations higher than 10%, there is an obvious increase in friction factor and pressure drop in comparison with laminar Newtonian flow.
文摘This paper presents a novel concept for designing solar-absorbing metamaterial microcapsules of phase change materials(PCMs)integrated with thermo-regulating smart textiles intended for coats or garments,especially for wear in space or cold weather on earth.The metamaterial is a periodically nanostructured metal-dielectric-metal thin film and can acquire surface plasmons to trap or absorb solar energy at subwavelength scales.This kind of metamaterial microencapsulation is not only able to take advantage of latent heat that can be stored or released from the PCMs over a tunable temperature range,but also has other advantages over conventional polymer microencapsulation of PCMs,such as enhanced thermal conductivity,improved flame-retardant capabilities,and usage as an extra solar power resource.The thermal analysis for this kind of microencapsulation has been done and can be used as a guideline for designing integrated thermo-regulating smart textiles in the future.These metamaterial microcapsules may open up new routes to enhancing thermo-regulating textiles with novel properties and added value.
基金Supported by the National Natural Science Foundation of China(51562023)the Natural Science Foundation of Gansu Provence(145RJZA185)the National science and technology support project(2014BAA01B01)
文摘Aiming to identify the validity of fabricating microencapsulated phase change material(PCM) with polymethylmethacrylate(PMMA) by ultraviolet curing emulsion polymerization method using iron(III) chloride as photoinitiator,SA/PMMA microcapsules were prepared and various techniques were employed to determine the ignition mechanism,structural characteristics and thermal properties of the composite.The results shown that the microcapsules containing SA with maximum percentage of 52.20 wt% formed by radical mechanism and only physical interactions existed in the components both in the prepared process and subsequent use.The phase change temperatures and latent heats of the microencapsulated SA were measured as 55.3 °C and 102.1 J·g^(-1) for melting,and 48.8 °C and 102.8 J·g^(-1) for freezing,respectively.Thermal gravimetric analysis revealed that SA/PMMA has good thermal durability in working temperature range.The results of accelerated thermal cycling test are all shown that the SA/PMMA have excellent thermal reliability and chemical stability although they were subjected 1000 melting/freezing cycles.In summary,the comparable thermal storage ability and good thermal reliability facilitated SA/PMMA to be considered as a viable candidate for thermal energy storage.The successful fabrication of SA/PMMA capsules indicates that ferric chloride is a prominent candidate for synthesizing PMMA containing PCM composite.
