A series of novel aluminophosphates,named AlPO_4-CJ_n(n=2-5),has been synthesized hydrothermally from R-Al_2O_3-P_2O_5-H_2O systems(R= organic amine molecules),and characterized by means of X-ray powder diffraction,in...A series of novel aluminophosphates,named AlPO_4-CJ_n(n=2-5),has been synthesized hydrothermally from R-Al_2O_3-P_2O_5-H_2O systems(R= organic amine molecules),and characterized by means of X-ray powder diffraction,infrared,SEM,XPS,composition and thermal analyses.展开更多
Four new types of microporous beryllophosphates were hydrothermally synthesized using BeO - P_2O_5- R - MCl (or MCl_2) - H_20, R being HMDA (1, b-hexanediamine), EDA (ethylenediamine), or TBAOH (tetrabutytamine hydrox...Four new types of microporous beryllophosphates were hydrothermally synthesized using BeO - P_2O_5- R - MCl (or MCl_2) - H_20, R being HMDA (1, b-hexanediamine), EDA (ethylenediamine), or TBAOH (tetrabutytamine hydroxide), M alkali or alkali earth cation. By means of X-ray diffraction patterns (XRD), infrared (IR), TG-DT and elemental analyses we show that the crystalline beryllopbospbates have novel, unique framework structures, composed from basic units of tetrahedral P0_4 and Be0_4. These materials exhibit zeolite-like adsorption and ion-exchange properties.展开更多
A series of novet beryllophosphate zeolites,named BePO_4-CIn(n=4-7), are synthesized hydrothermally and characterized with X-ray powder diffraction,IR spectra,SEM,thermat analysis and ion-exchange.
文摘A series of novel aluminophosphates,named AlPO_4-CJ_n(n=2-5),has been synthesized hydrothermally from R-Al_2O_3-P_2O_5-H_2O systems(R= organic amine molecules),and characterized by means of X-ray powder diffraction,infrared,SEM,XPS,composition and thermal analyses.
文摘Four new types of microporous beryllophosphates were hydrothermally synthesized using BeO - P_2O_5- R - MCl (or MCl_2) - H_20, R being HMDA (1, b-hexanediamine), EDA (ethylenediamine), or TBAOH (tetrabutytamine hydroxide), M alkali or alkali earth cation. By means of X-ray diffraction patterns (XRD), infrared (IR), TG-DT and elemental analyses we show that the crystalline beryllopbospbates have novel, unique framework structures, composed from basic units of tetrahedral P0_4 and Be0_4. These materials exhibit zeolite-like adsorption and ion-exchange properties.
文摘A series of novet beryllophosphate zeolites,named BePO_4-CIn(n=4-7), are synthesized hydrothermally and characterized with X-ray powder diffraction,IR spectra,SEM,thermat analysis and ion-exchange.
