Electromagnetic and Thermal Characteristics of Molybdenite Concentrate in Microwave Field

In modern metallurgical industry,microwave thermal technique has many advantages as one efficient energy treatment in an electromagnetic form,such as internal self-generated heat,easy access to control a volumetric heating process,and consensus on cleanliness,convenience and high efficiency of energy use.Both permittivity and permeability of molybdenite concentrate were measured for a further discussion about its electromagnetic heating coupling.A bidirectional coupling physics field in numerical modeling was undertaken to evaluate the microwave absorption potential and dielectric heating performance of molybdenite concentrate by the multi-physics finite element method.The electromagnetic morphology and the field distribution strength were described in the microwave reaction cavity.The electromagnetic field strength and the dissipation coefficient induced by temperature variation were represented throughout the whole heat chamber and at key parts of interest.Dependent temperature distribution was compared with that being obtained from a scenario by thermal conduction with a stable heat source.The molybdenite concentrate would be heated at surrounding temperature up to 593℃for 10 min by microwave energy that was transmitted by a rectangular waveguide.Scanning electron microscopy(SEM)patterns suggested that the polished and neat crystalline molybdenum trioxide(MoO_(3))products were achieved by the microwave heating process.The superiority via utilizing microwave thermal technique is expounded in the preparation strategy for molybdenum oxide or molybdenum metal.

A high rectification efficiency Si_(0.14)Ge_(0.72)Sn_(0.14)-Ge_(0.82)Sn_(0.18)-Ge quantum structure n-MOSFET for 2.45 GHz weak energy microwave wireless energy transmission

The design strategy and efficiency optimization of a Ge-based n-type metal-oxide-semiconductor field-effect transistor(n-MOSFET)with a Si_(0.14)Ge_(0.72)Sn_(0.14)-Ge_(0.82)Sn_(0.18)-Ge quantum structure used for 2.45 GHz weak energy microwave wireless energy transmission is reported.The quantum structure combined withδ-doping technology is used to reduce the scattering of the device and improve its electron mobility;at the same time,the generation of surface channels is suppressed by the Si_(0.14)Ge_(0.72)Sn_(0.14) cap layer.By adjusting the threshold voltage of the device to 91 mV,setting the device aspect ratio to 1μm/0.4μm and adopting a novel diode connection method,the rectification efficiency of the device is improved.With simulation by Silvaco TCAD software,good performance is displayed in the transfer and output characteristics.For a simple half-wave rectifier circuit with a load of 1 pf and 20 kΩ,the rectification efficiency of the device can reach 7.14%at an input power of-10 dBm,which is 4.2 times that of a Si MOSFET(with a threshold voltage of 80 mV)under the same conditions;this device shows a better rectification effect than a Si MOSFET in the range of-30 dBm to 6.9 dBm.

Scavenging Microwave Wireless Power:A Unified Model,Rectenna Design Automation,and Cutting-Edge Techniques

While sufficient review articles exist on inductive short-range wireless power transfer(WPT),long-haul microwave WPT(MWPT)for solar power satellites,and ambient microwave wireless energy harvesting(MWEH)in urban areas,few studies focus on the fundamental modeling and related design automation of receiver systems.This article reviews the development of MWPT and MWEH receivers,with a focus on rectenna design automation.A novel rectifier model capable of accurately modeling the rectification process under both high and low input power is presented.The model reveals the theoretical boundary of radio frequency-to-direct current(dc)power conversion efficiency and,most importantly,enables an automated system design.The automated rectenna design flow is sequential,with the minimal engagement of iterative optimization.It covers the design automation of every module(i.e.,rectifiers,matching circuits,antennae,and dc–dc converters).Scaling-up of the technique to large rectenna arrays is also possible,where the challenges in array partitioning and power combining are briefly discussed.In addition,several cutting-edge rectenna techniques for MWPT and MWEH are reviewed,including the dynamic range extension technique,the harmonics-based retro-directive technique,and the simultaneous wireless information and power transfer technique,which can be good complements to the presented automated design methodology.

Microwave-promoted pure host phase for red emission CaS:Eu^(2+) phosphor from single CaSO_4 precursor and the photoluminescence property

We report a novel approach to obtaining a classical blue-green excitable CaS：Eu2＋ phosphor with desired red emission by microwave （MW） firing procedure in the absence of adding elemental sulphur. The disturbing effect of MW electro- magnetic field on decomposition of CaSO4 into CaS activated by europium is distinctly observed to give pure host phase without adding any elemental sulphur and carbon. The host phase evolution is observed to be highly dependent on the variation of applied MW power from X-ray diffraction （XRD） patterns and the corresponding photoluminescence （PL）, and a maximum PL intensity at 1100 W of MW power is acquired for the obtained purer host phase. The non-thermal and non-equilibrium effects by MW are revealed to correlate with the interaction between polar structure of the host and applied electromagnetic field. The results demonstrate an optional procedure to prepare this red-emitting phosphor in an effective, environment-friendly and scalable approach for phosphor production in the application of bio-illumination for plant cultivation and artificial photosynthesis.

New Activated Carbon with High Thermal Conductivity and Its Microwave Regeneration Performance

Using a walnut shellas a carbon source and ZnCl_2 as an activating agent,we resolved the temperature gradient problems of activated carbon in the microwave desorption process.An appropriate amount of silicon carbide was added to prepare the composite activated carbon with high thermalconductivity while developing VOC adsorption-microwave regeneration technology.The experimentalresults show that the coefficient of thermalconductivity of SiC-AC is three times as much as those of AC and SY-6.When microwave power was 480 W in its microwave desorption,the temperature of the bed thermaldesorption was 10 ℃ to 30 ℃ below that of normalactivated carbon prepared in our laboratory.The toluene desorption activation energy was 16.05 k J·mol^（-1）,which was 15% less than the desorption activation energy of commercialactivated carbon.This study testified that the process could maintain its high adsorption and regeneration desorption performances.

Effect of rare earths on microwave absorbing properties of RE-Co alloys

The powders of RE2Co17（RE=Y, Ce, Nd, Ho, Er） and Ho x Co100–x（x=6, 8, 10, 12） alloys were prepared by the arc melting method and high-energy ball mill process. The compositions and morphologies of the alloys were characterized by X-ray diffraction（XRD） and scanning electron microscopy（SEM）, and the microwave absorbing properties were studied by a vector network analyzer. The results showed that the alloy of Y2Co17 had better absorbing properties at low frequencies and its lowest reflectivity value was –9.5 d B at 3.8 GHz. The lowest reflectivity value of Ho2Co17 alloy was –13.7 d B at 7.02 GHz and it obtained large absorbing bandwidth. Reflectivity value less than –5 d B was from 5.1 to 10.2 GHz. When x=6 and x=8, the alloys of Ho x Co100–x consisted of Ho2Co17 phase and Co phase. They had good radar absorbing properties. With increase in Ho content, the minimum reflectivity value worsened and the absorbing peak frequency shifted toward higher frequencies. But when x=12, the absorbing peak frequency shifted toward lower frequencies but the minimum reflectivity value worsened.