Rapid Synthesis of Submicrometer-sized Red Phosphor CaS∶Cu^+,Eu^( 2+) in a Microwave Field

The red phosphor materials CaS∶Cu+,Eu 2+ were firstly synthesized in a microwave field, and characterized by XRD、SEM、fluorescent spectroscopy. The experimental results of XRD and SEM show that the phosphors of CaS∶Cu+,Eu 2+ possess a spherical crystallite structure, in the submicrometer(250～500 nm) size range. Compared to the conventional high temperature solid state reaction this new synthetic technique exhibits interesting features, such as rapid reactions without other protective atmosphere,phosphors with high purity, smaller particles,and higher efficient luminescence.

THE KINETICS OF FERRIC CHLORIDE LEACHING OF SPHALERITE IN THE MICROWAVE FIELD

The kinetics of ferric chloride leaching of sphalerite in the microwave field has being studied in this paper.According to the experimental data,the rate of dissolution of sphalerite microwave irradiation heating is faster than that with conventional heating.The dissolution of sphalerite in the microwave field was investigated in different condition of temperature,concentration of FeCl,and particle size and a nonisothermal kinetic equation has being obtained.

Spin Transport in a Rashba Ring-Quantum Dot System Pumped by Microwave Fields

We report a theoretical study on producing electrically spin-polarized current in the Rashba ring with parallel double dots embedded, which are subject to two time-dependent microwave fields. By means of the Keldysh Green＇s function method, we present an analytic result of the pumped current at adiabatic limit and demonstrate that the interplay between the quantum pumping effect and spin-dependent quantum interference can lead to an arbitrarily controllable spin-polarized current in the device. The magnitude and direction of the charge and spin current can be effectively modulated by system parameters such as the pumping phase difference, Rashba precession phase, and the dynamic phase difference of electron traveling in two arms of ring; moreover, the spin-polarization degree of the charge current can also be tuned in the range [-∞, ＋∞]. Our findings may shed light on the all-electric way to produce the controllable spin-polarized charge current in the field of spintronics.

Desulfurization of Nickel Pyrrhotite by Steam in the Microwave Field

Desulfurization of Ni pyrrhotite by steam in the microwave field was studied. According to the experimental data, the desulfurization rate by microwave heating is faster than that by conventional one. The desulfurization reaction is in a non-isothermal state and in a diffusion control because of the effect of chemical reaction heat, phase formation and intrinsic properties of materials of microwave absorbability. When the flow rate of steam was in the range of 180 similar to 220 mL/min, the temperature and desulfurization rate approached to a maximum and the activation energy to a minimum.

Extending microwave-frequency electric-field detection through single transmission peak method

The strength of microwave(MW)electric field can be observed with high precision by using the standard electromagnetically induced transparency and Aulter–Towns(EIT-AT)technique,when its frequency is resonant or nearly-resonant with the Rydberg transition frequency.As the detuning of MW field increases,one of the transmission peaks(single peak)is easier to measure due to its increased amplitude.It can be found that the central symmetry point of the two transmission peaks f_(1/2)is only related to the detuning of MW field△_(MW)and central symmetry point f_(0)of resonant MW field,satisfying the relation f_(1/2)=△_(MW)/2+f_(0).Thus,we demonstrate a single transmission peak method that the MW E-field can be determined by interval between the position of single peak and f_(1/2).We use this method to measure continuous frequencies in a band from-200 MHz to 200 MHz of the MW field.The experimental results and theoretical analysis are presented to describe the effectiveness of this method.For 50 MHz<△_(MW)<200 MHz,this method solves the problem that the AT splitting cannot be measured by using the standard EIT-AT techniques or multiple atomic-level Rydberg atom schemes.

NiB_(2)O_(4)(B=Mn or Co)catalysts for NH_(3)-SCR of NO_(x) at low-temperature in microwave field

Microwave-assisted selective catalytic reduction of nitrogen oxides(NOx)was investigated over Nibased metal oxides.The NiMn2O4 and NiCo_(2)O_(4) catalysts were synthesized by the co-precipitation method and their activities were evaluated as potential candidate catalysts for low-temperature NH_(3)-SCR in a microwave field.The physicochemical properties and structures of the catalysts were characterized by X-ray diffraction(XRD),Scanning electron microscope(SEM),N_(2)-physisorption,NO adsorption-desorption in the microwave field,H2-temperature programmed reduction(H2-TPR)and NH3-temperature programmed desorption(NH_(3)-TPD).The results verified that microwave radiation reduced the reaction temperature required for NH_(3)-SCR compared to conventional heating,which needed less energy.For the NiMn_(2)O_(4) catalyst,the catalytic efficiency exceeded 90%at 70°C and reached 96.8%at 110°C in the microwave field.Meanwhile,the NiMn_(2)O_(4) also exhibited excellent low-temperature NH3-SCR reaction performance under conventional heating conditions,which is due to the high BET specific surface area,more suitable redox property,good NO adsorption-desorption in the microwave field and rich acidic sites.

Transfer of quantum entangled states between superconducting qubits and microwave field qubits

Transferring entangled states between matter qubits and microwave-field(or optical-field)qubits is of fundamental interest in quantum mechanics and necessary in hybrid quantum information processing and quantum communication.We here propose a way for transferring entangled states between superconducting qubits(matter qubits)and microwave-field qubits.This proposal is realized by a system consisting of multiple superconducting qutrits and microwave cavities.Here,“qutrit”refers to a three-level quantum system with the two lowest levels encoding a qubit while the third level acting as an auxiliary state.In contrast,the microwave-field qubits are encoded with coherent states of microwave cavities.Because the third energy level of each qutrit is not populated during the operation,decoherence from the higher energy levels is greatly suppressed.The entangled states can be deterministically transferred because measurement on the states is not needed.The operation time is independent of the number of superconducting qubits or microwave-field qubits.In addition,the architecture of the circuit system is quite simple because only a coupler qutrit and an auxiliary cavity are required.As an example,our numerical simulations show that high-fidelity transfer of entangled states from two superconducting qubits to two microwave-field qubits is feasible with present circuit QED technology.This proposal is quite general and can be extended to transfer entangled states between other matter qubits(e.g.,atoms,quantum dots,and NV centers)and microwave-or optical-field qubits encoded with coherent states.

Vapor cell geometry effect on Rydberg atom-based microwave electric field measurement

The geometry effect of a vapor cell on the metrology of a microwave electric field is investigated. Based on the splitting of the electromagnetically induced transparency spectra of cesium Rydberg atoms in a vapor cell, high-resolution spatial distribution of the microwave electric field strength is achieved for both a cubic cell and a cylinder cell. The spatial distribution of the microwave field strength in two dimensions is measured with sub-wavelength resolution. The experimental results show that the shape of a vapor cell has a significant influence on the abnormal spatial distribution because of the Fabry-P6rot effect inside a vapor cell. A theoretical simulation is obtained for different vapor cell wall thicknesses and shows that a restricted wall thickness results in a measurement fluctuation smaller than 3% at the center of the vapor cell.

Optimal Microwave Radiation Field Parameters for Mercury Ion Microwave Frequency Standards

We propose a method to determine the optimal power of the microwave resonance transition that simultaneously improves the signal-to-noise ratio and reduces line width based on saturation broadening theory and experiment. Saturation broadening spectra of the ground state hyperfine transition of trapped 199Hg＋ ions are measured and analyzed. The value of the optimal microwave power is obtained by using the proposed method and is verified. Rabi oscillations decay spectra of trapped 199Hg＋ ions are observed and the optimal microwave irradiation time for the maximum transition signal intensity is determined. This work will help to improve the short-term frequency stability of the mercury ion microwave frequency standard.

Air breakdown induced by the microwave with two mutually orthogonal and heterophase electric field components

The air breakdown is easily caused by the high-power microwave, which can have two mutually orthogonal and heterophase electric field components. For this case, the electron momentum conservation equation is employed to deduce the electric field power and effective electric field for heating electrons. Then the formula of the electric field power is introduced into the global model to simulate the air breakdown. The breakdown prediction from the global model agrees well with the experimental data. Simulation results show that the electron temperature is sensitive to the phase difference between the two electron field components, while the latter can affect obviously the growth of the electron density at low electron temperature amplitudes. The ionization of nitrogen and oxygen induces the growth of electron density, and the density loss due to the dissociative attachment and dissociative recombination is obvious only at low electron temperatures.

Spontaneous emission from a microwave-driven four-level atom in an anisotropic photonic crystal

The spontaneous emission from a microwave-driven four-level atom embedded in an anisotropic photonic crystal is studied. Due to the modified density of state(DOS) in the anisotropic photonic band gap(PBG) and the coherent control induced by the coupling fields, spontaneous emission can be significantly enhanced when the position of the spontaneous emission peak gets close to the band gap edge. As a result of the closed-loop interaction between the fields and the atom,the spontaneous emission depends on the dynamically induced Autler–Townes splitting and its position relative to the PBG.Interesting phenomena, such as spectral-line suppression, enhancement and narrowing, and fluorescence quenching, appear in the spontaneous emission spectra, which are modulated by amplitudes and phases of the coherently driven fields and the effect of PBG. This theoretical study can provide us with more efficient methods to manipulate the atomic spontaneous emission.

Two methods to deal with an inhomogenous Rabi frequency in microwave transition

We analyse the influence of an inhomogenous microwave field on the coherence of atom ensembles. Two methods are proposed to suppress the dephasing generated by the inhomogenous Rabi frequency. One of them is realized by using a spin echo, and the other one is based on the identical spin rotation effect. The calculation results show that the contrast of a signal acquired in experiment can be improved by using the two methods. Their advantages and drawbacks are discussed. We hope they can be used to improve the contrast of experimental signals in situations where microwave fields are very inhomogenous. Finally, we discuss the case of a continuous working microwave field and show that the dipole force raised with the inhomogeneitv can be eased by slain flip.

The microwave scattering characteristics of sea ice in the Bohai Sea

Microwave remote sensing has become the primary means for sea-ice research, and has been supported by a great deal of field experiments and theoretical studies regarding sea-ice microwave scattering. However, these studies have been barely carried in the Bohai Sea. The sea-ice microwave scattering mechanism was first developed for the thin sea ice with slight roughness in the Bohai Sea in the winter of 2012, and included the backscattering coefficients which were measured on the different conditions of three bands（L, C and X）, two polarizations（HH and VV）, and incident angles of 20° to 60°, using a ground-based scatterometer and the synchronous physical parameters of the sea-ice temperature, density, thickness, salinity, and so on. The theoretical model of the sea-ice electromagnetic scattering is obtained based on these physical parameters. The research regarding the sea-ice microwave scattering mechanism is carried out through two means, which includes the comparison between the field microwave scattering data and the simulation results of the theoretical model, as well as the feature analysis of the four components of the sea-ice electromagnetic scattering. It is revealed that the sea-ice microwave scattering data and the theoretical simulation results vary in the same trend with the incident angles. Also, there is a visible variant in the sensitivity of every component to the different bands.For example, the C and X bands are sensitive to the top surface, the X band is sensitive to the scatterers, and the L and C bands are sensitive to the bottom surface, and so on. It is suggested that the features of the sea-ice surfaces and scatterers can be retrieved by the further research in the future. This experiment can provide an experimental and theoretical foundation for research regarding the sea-ice microwave scattering characteristics in the Bohai Sea.

Microwave coherent manipulation of cold atoms in optically induced fictitious magnetic traps on an atom chip

We propose a novel on-chip platform for controlling and manipulating cold atoms precisely and coherently. The scheme is achieved by producing optically induced fictitious magnetic traps（OFMTs） with 790 nm（for -（87）Rb） circularly polarized laser beams and state-dependent potentials simultaneously for two internal atomic states with microwave coplanar waveguides. We carry out numerical calculations and simulations for controlled collisional interactions between OFMTs and addressable single atoms＇ manipulation on our designed hybrid atom chips. The results show that our proposed platform is feasible and flexible, which has wide applications including collisional dynamics investigation, entanglement generation,and scalable quantum gates implementation.

Characterization of the current crowding effect on chip surface using a quantum wide-field microscope

We characterize the current crowding effect for microwave radiation on a chip surface based on a quantum wide-field microscope combining a wide-field reconstruction technique. A swept microwave signal with the power of 0–30 d Bm is supplied to a dumbbell-shaped microstrip antenna, and the significant differences in microwave magnetic-field amplitudes attributed to the current crowding effect are experimentally observed in a 2.20 mm ×1.22 mm imaging area. The normalized microwave magnetic-field amplitude along the horizontal geometrical center of the image area further demonstrates the feasibility of the characterization of the current crowding effect. The experiments indicate the proposal can be qualified for the characterization of the anomalous area of the radio-frequency chip surface.

Phase-dependent inversionless gain in a four-level atomic system with a closed interaction loop

A four-level atomic system with a closed interaction loop connected by two coherent driving fields and a microwave field is investigated. The results show that inversionless gain can be achieved on a higher frequency transition outside the closed interaction loop, and the gain behaviour can be modulated by the phase of the closed loop as well as the amplitude of the microwave field. The phase sensitivity property in such a scheme is similar to that in an analogous configuration with spontaneously generated coherence, but it is beyond the rigorous condition of near-degenerate levels with non-orthogonal dipole moments. Therefore this scheme is much more convenient in experimental realization.

Generation of Interstellar Class Ⅱ 7_2-8_1A^+ and 7_2-8_1A^-Methanol Masers

New methanol maser lines at 72 → 63A^-（86.6 GHz） and 72 → 63A^＋（86.9 GHz） together with two candidate methanol maser lines at 72 → 81A-（80.99GHz） and 72→81A^＋（111.29GHz） have been detected in W3（OH）. We use a pumping mechanism, i.e., methanol masers without population inversion, to explain the formation of weak methanol masers of 72 → 81A^＋ and 72→ 81A^-. We explain well why the line-shape of the transition 72 → 81A^＋ is not typical. A similar argument can be applied to the A-type level system 72A^-, 63A^- and 81A^-, as well as to the 72 → 81A^- 80.99 GHz masers.

Deployable Antenna with Compact Ortho-mode Transducer and Feeding Systems

The compact ortho-mode transducer (OMT) and compact conical corrugated horn(CCCH) are used as feeding system of the deployable dual polarizing antenna in this paper.A new stricture of double-septum in main wave guide OMT is proposed. The finite difference method in time domain (FDTD) in combination with genetic algorithms(GAs) is used to analysis and optimize this new OMT. The experiment results show that the voltage standing wave ratio (VSWR) of this OMT and feeding system is less than 1.17 in bandwidth; the isolation between the ortho-mode ports is less than -40dB; the cross-polar level of the feed can reach -35dB and the length of the main waveguide can be reduced 50% at least.