The 1-aryloxyacetyl-4-(4-nitrophenyloxyacetyl)-thiosemicarbazides (3a-h) are synthe- sized via reaction of 4-nitrophenyloxyacetyl chloride with ammonium thiocyanate and aryloxyacetic hydrazides (2a-h) under phase tran...The 1-aryloxyacetyl-4-(4-nitrophenyloxyacetyl)-thiosemicarbazides (3a-h) are synthe- sized via reaction of 4-nitrophenyloxyacetyl chloride with ammonium thiocyanate and aryloxyacetic hydrazides (2a-h) under phase transfer catalysis and microwave irradiation in excellent yield.展开更多
Introduction Microwave irradiation has been very widely used in heating, cooking and brewing. Several papers which describe the use of domestic microwave ovens to perform rapid organic synthesis in solution have been ...Introduction Microwave irradiation has been very widely used in heating, cooking and brewing. Several papers which describe the use of domestic microwave ovens to perform rapid organic synthesis in solution have been published. The high heating efficiency gives rise to remarkable rate of reaction and dramatic reduction of reaction time. Nevertheless, its application seems to be limited to these procedures because of展开更多
A series of new diethers were obtained by alkylation of furoin under microwave irradiation (MWI) in phase transfer catalysis (PTC) conditions. The products of alkyl halides were synthesized in good yields (〉75%...A series of new diethers were obtained by alkylation of furoin under microwave irradiation (MWI) in phase transfer catalysis (PTC) conditions. The products of alkyl halides were synthesized in good yields (〉75%) within a few minutes, and the products of dihalides were synthesized in fair yields (about 45%). The yields are dramatically improved compared to conventional heating under the same conditions, in spite of similar profiles of rising in temperature.展开更多
The rapid alkylation of methyl N-benzylidene glycinate with halides under microwave irradiation using solid-liquid phase transfer condition without solvent has been achieved wilhin only one minute. After hydrolysis of...The rapid alkylation of methyl N-benzylidene glycinate with halides under microwave irradiation using solid-liquid phase transfer condition without solvent has been achieved wilhin only one minute. After hydrolysis of alkylated products the corresponding α-amino acids were obtained in overall yield 43.6~62.5%.展开更多
Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when...Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when the molar ratio of the reactants was n(ArOH)∶n(NaOH)∶n(ClCH 2CO 2H) =1∶2.5∶1.2 with microwave irradiation power of 640 W for 65—85 s.展开更多
A microwave irradiated magnetically separable nano cobalt ferrite catalyzed green method for the synthesis of 4-phenyl-4H-pyrano[3,2-h]quinolin-2-amine and 2-amino-4-phenyl-4H-pyrano[3,2-h] quinoline-3-carbonitrile de...A microwave irradiated magnetically separable nano cobalt ferrite catalyzed green method for the synthesis of 4-phenyl-4H-pyrano[3,2-h]quinolin-2-amine and 2-amino-4-phenyl-4H-pyrano[3,2-h] quinoline-3-carbonitrile derivatives through cyclization of aromatic aldehyde, acetonitrile/malononitrile and 8-hydoxyquinoline is developed and presented in this paper. The cubic magnetic cobalt ferrite nano particles were synthesized by sol-gel citrate precursor method and characterized by FT-IR, XRD, SEM and TEM techniques and the structures of the synthesized pyranoquinoline derivatives were assigned by IR, MASS and 1</sup>H NMR techniques. The reaction is carried out in a domestic microwave oven with a heat-resistant microwave safe glass container with a lid.展开更多
A rapid and efficient method was established for the synthesis of indoloquinolinone and its analogues using acid-promoted cyclization in the present of PPA. All the reactions were completed in good yields in lOmin und...A rapid and efficient method was established for the synthesis of indoloquinolinone and its analogues using acid-promoted cyclization in the present of PPA. All the reactions were completed in good yields in lOmin under microwave irradiation.展开更多
A high-efficiency synthesis method for a latent pigment of red pigment diketo-pyrrolo-pyrrole (Pig. Red 272:272DPP), which is important as a functional organic pigment, was investigated, and the investigation results ...A high-efficiency synthesis method for a latent pigment of red pigment diketo-pyrrolo-pyrrole (Pig. Red 272:272DPP), which is important as a functional organic pigment, was investigated, and the investigation results revealed that irradiation of microwaves (MWs) for several seconds to 272 DPP in NMP (N-methyl-2-pyrrolidone) solvent yielded DPP latent pigment (272DPP-BOC) at a high yield of 86.2%. Two kinds of latent-pigment crystals, namely, red and yellow, were obtained by recrystallization, and it was found that the fluorescence-emission properties of the two kinds differ significantly. Single-crystal X-ray structural analysis showed that the difference in the fluorescence-emission properties of the two types is derived from the difference in their crystal structures.展开更多
The title compound (C19H23NO3) was synthesized by the one-pot reaction ofp-methoxybenzaldehyde, Meldrum's acid, dimedone and CH3NH3Cl (NaOAc) in ethanol under microwave irradiation without catalyst and its crysta...The title compound (C19H23NO3) was synthesized by the one-pot reaction ofp-methoxybenzaldehyde, Meldrum's acid, dimedone and CH3NH3Cl (NaOAc) in ethanol under microwave irradiation without catalyst and its crystal structure was determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/c with a = 8.7462(10), b = 17.7367(19), c = 11.5959(14) A, β = 110.981(3)°, V= 1679.6(3) A^3, Z = 4, Dc = 1.239 g/cm^3,μ(MoKa) = 0.083 mm^-1, F(000) = 672 and Mr = 313.38. The structure was refined to R = 0.0530 and wR = 0.1216. X-ray analysis reveals that the dihedral angle between plane 1 (N(1), C(1), C(2), C(3)) and plane 2 (C(1), C(2), C(6), C(7), C(9)) is 3.64°, andt hat between plane 2 and plane 3 (C(11)~C(16)) is 85.33°.展开更多
A rapid way assisted by microwave irradiation was proposed to synthesize poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole](PBI) and poly(2,5-benzimidazole)(ab-PBI).Synthesis of PBI in polyphosphoric acid is cond...A rapid way assisted by microwave irradiation was proposed to synthesize poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole](PBI) and poly(2,5-benzimidazole)(ab-PBI).Synthesis of PBI in polyphosphoric acid is conducted for 20 h or even more.Under microwave irradiation,the polycondensations could be completed in polyphosphoric acid within 3 h from 3,3'-diaminobenzidine tetrahydrochloride(DAB·4HCl·2H2O) and isophthalic acid for PBI,and from 3,4-diaminobenzoic acids(DABA) for ab-PBI,respectively.The conditions for the polymerization including the power of microwave irradiation,temperature,heating time,and concentrations of the reactants in polyphosphoric acid were optimized.The inherent viscosity of the polymers in concentrated sulfuric acid at 30 ℃ was 0.9766 dL/g for PBI,and 0.6480 dL/g for ab-PBI,respectively.Characterization of the polymer products was made by nuclear magnetic resonance(1^H NMR),Fourier transform infrared spectra(FTIR) and thermogravimetric analysis(TGA).展开更多
The crystal structure N-methyl-9-(4-bromophenyl)-1,8-dioxo-1,2,3,4,5,6,7,8,9,10- decahydroacridine(C20H20BrNO2) was determined by single-crystal X-ray diffraction analysis. It belongs to P21/n space group, with a = ...The crystal structure N-methyl-9-(4-bromophenyl)-1,8-dioxo-1,2,3,4,5,6,7,8,9,10- decahydroacridine(C20H20BrNO2) was determined by single-crystal X-ray diffraction analysis. It belongs to P21/n space group, with a = 10.7999(18), b = 13.845(3), c = 11.4031(3) ?, β = 99.324(4)°, Dc = 1.525 g/cm3, Z = 4, λ = 0.71070 ?, μ(MoKα) = 2.455 mm-1, Mr = 386.28, V = 1682.5(5) ?3, F(000) = 792, the final R = 0.0463 and wR = 0.1053. In the crystal structure, the pyridine ring adopts a boat conformation, the two six-numbered rings fused with pyridine ring adopt twisting boat con- formation.展开更多
Novolacs were successfully synthesized using oxalic acid as the catalyst in a self-designed device based on a domestic microwave oven, The fundamental characteristics of the synthesis of novolacs under microwave irrad...Novolacs were successfully synthesized using oxalic acid as the catalyst in a self-designed device based on a domestic microwave oven, The fundamental characteristics of the synthesis of novolacs under microwave irradiation (MI) were investigated, and the properties of the resins polymerized and dehydrated under microwave irradiation and conventional heating (CH) were analyzed comparatively, The results show that MI reduced the polymerization and dehydration time greatly; and that the resins polymedzed and dehydrated under MI presented longer flow distances ( i. e., higher flowability) and shorter cure time than those obtained under CH.展开更多
Six new asymmetric thiocarbonohydrazones 3a-3f were synthesized from following steps: firstly hydrazine hydrate reacted with carbon disulfide to form thiocarbonohydrazide (1) under microwave irradiation. Then compo...Six new asymmetric thiocarbonohydrazones 3a-3f were synthesized from following steps: firstly hydrazine hydrate reacted with carbon disulfide to form thiocarbonohydrazide (1) under microwave irradiation. Then compound (1) reacted with ketone and different aldehydes step by step to give 3a-3f with excellent yields under solvent-free conditions using microwave irradiation. Their structures have been determined by elemental analysis, IR, MS and ^1H NMR data. 2009 Qing Han Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.展开更多
The synthesis and characterization of aluminum-pillared rectorite were studied. The synthesis was conducted with both conventional heating and microwave irradiation. Microwave irradiation was found to enhance the inte...The synthesis and characterization of aluminum-pillared rectorite were studied. The synthesis was conducted with both conventional heating and microwave irradiation. Microwave irradiation was found to enhance the intercalation and ion-exchange during synthesis, and to be able to produce the rectorite with a larger d_(001) and a better uniformity. The specific surface area is 180 m^2/g and basal spacing is 3.2 nm. The texture change and thermal and hydrothermal stability of cross-linked rectorite were examined using XRD, FTIR, nitrogen-adsorption and TGA. The experimental results show that the aluminum-pillared rectorite, after calcined at 800 ℃ for 3 hours, can keep the basal aluminum-silicate texture and would not disperse in water at room or an elevated temperature. The aluminum-pillared rectorite shows a high specific surface area, good thermal and hydrothermal stability, and is promising in applications as catalyst carriers and adsorbents for waste treatment.展开更多
zeolite was synthesized by using tetraethyl ammonium hydroxide as the template reagent andmicrowave radiation as the heat source. The effect of the sol composition and the radiation temperature onzeolite crystallinity...zeolite was synthesized by using tetraethyl ammonium hydroxide as the template reagent andmicrowave radiation as the heat source. The effect of the sol composition and the radiation temperature onzeolite crystallinity was investigated. The zeolite was tested and compared with the commercial product, whichwas produced by conventional hydrothermal synthesis method. The physico-chemical properties of the syn-thesized samples, the specific surface area of the samples synthesized under microwave irradiation and porevolume measured by X-ray diffraction apparatus, were better than the conventional samples. The etherificationexperiment on FCC light naphtha in the presence of transition metals modified Hβ-zeolite, which was synthe-sized firstly under microwave irradiation, was studied in a fixed-bed reactor. The effect of catalyst preparationconditions on its activity, stability and the effect of reaction temperature, methanol/tertiary-carbon olefin molarratio and liquid hourly space velocity on the etherification reaction were discussed. The experimental resultsshowed that the different metals modified Hβ-zeolite had different etherification performances. And theconversion of tertiary carbon-olefins of the molybdenum modified Hβzeolite, which was loaded at a concen-tration of 3 percents, was higher than that on 6.0 percent of Hβzeolite. The modified Hβzeolite catalystspossessed favorable prospects for its higher stability.展开更多
The N-cyclopropyl-9-(3,4-dicholophenyl)-1,2,3,4,5,6,7,8,9,10-decahydroacri- dine-1,8-dione was synthesized by the reaction of 1,3-cyclohexanedione, N-cyclopropylamine and 3,4-dicholoaldehyde in water and glycol under ...The N-cyclopropyl-9-(3,4-dicholophenyl)-1,2,3,4,5,6,7,8,9,10-decahydroacri- dine-1,8-dione was synthesized by the reaction of 1,3-cyclohexanedione, N-cyclopropylamine and 3,4-dicholoaldehyde in water and glycol under microwave irradiation. Its crystal structure was determined by single-crystal X-ray diffraction analysis. It possesses P212121 space group, with a = 9.9103(5), b = 13.3597(8), c = 14.5633(8) ?, V = 1928.16(18) ?3, Mr = 402.30, Z = 4, Dc = 1.386 g/cm3, λ = 0.7107 ?, μ(MoKα) = 0.354 mm?1 and F (000) = 840. The structure was refined to R = 0.0280 and wR = 0.0757. In the structure, the pyridine ring adopts a boat conformation.展开更多
The crystal structure of the title compound (C16H17NO5) has been determined by single-crystal X-ray diffraction.The crystal is of monoclinic,space group C2/c with a=18.520(2),b=7.8910(1),c=21.728(3)?,β=104.77(1)°...The crystal structure of the title compound (C16H17NO5) has been determined by single-crystal X-ray diffraction.The crystal is of monoclinic,space group C2/c with a=18.520(2),b=7.8910(1),c=21.728(3)?,β=104.77(1)°,V=3070.4(7)?^3,Mr=303.31,Z=8,Dc=1.312g/cm^3,λ=0.71073?,μ(MoKα)=0.098mm^-1 and F(000)=1280.The structure was refined to R=0.0486 and wR=0.1287.There exist intermolecular hydrogen bonds in the crystal.展开更多
Microwave irradiation of aromatic aldehyde and 2,4-thiazolidinedione provides a fast and high-yield access to 5-benzylidene-2,4-thiazolidinedione. Seven 3-alkyl-5-benzylidene-2,4-thiazolidinedione compounds were produ...Microwave irradiation of aromatic aldehyde and 2,4-thiazolidinedione provides a fast and high-yield access to 5-benzylidene-2,4-thiazolidinedione. Seven 3-alkyl-5-benzylidene-2,4-thiazolidinedione compounds were produced with high yield by reacting 5-benzylidene-2,4-thiazolidinedione with different alkylating agents under microwave irradiation.展开更多
Eighteen 1-aroyl-4-(2-iodobenzoyl)thiosemicarbazides and corresponding semicarbazides were synthesized in excellent yield under microwave irradiation in solvent and catalyst free condition.
基金Technological Innovation Engineering of Northwest Normal University (NWNU-KJCXGC-218) Natural Science Foundation of Gansu Province and Youth Foundation of Northwest Normal University.
文摘The 1-aryloxyacetyl-4-(4-nitrophenyloxyacetyl)-thiosemicarbazides (3a-h) are synthe- sized via reaction of 4-nitrophenyloxyacetyl chloride with ammonium thiocyanate and aryloxyacetic hydrazides (2a-h) under phase transfer catalysis and microwave irradiation in excellent yield.
文摘Introduction Microwave irradiation has been very widely used in heating, cooking and brewing. Several papers which describe the use of domestic microwave ovens to perform rapid organic synthesis in solution have been published. The high heating efficiency gives rise to remarkable rate of reaction and dramatic reduction of reaction time. Nevertheless, its application seems to be limited to these procedures because of
基金Natural Science Foundation of Jilin Province, China (No. 1999010540).
文摘A series of new diethers were obtained by alkylation of furoin under microwave irradiation (MWI) in phase transfer catalysis (PTC) conditions. The products of alkyl halides were synthesized in good yields (〉75%) within a few minutes, and the products of dihalides were synthesized in fair yields (about 45%). The yields are dramatically improved compared to conventional heating under the same conditions, in spite of similar profiles of rising in temperature.
文摘The rapid alkylation of methyl N-benzylidene glycinate with halides under microwave irradiation using solid-liquid phase transfer condition without solvent has been achieved wilhin only one minute. After hydrolysis of alkylated products the corresponding α-amino acids were obtained in overall yield 43.6~62.5%.
文摘Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when the molar ratio of the reactants was n(ArOH)∶n(NaOH)∶n(ClCH 2CO 2H) =1∶2.5∶1.2 with microwave irradiation power of 640 W for 65—85 s.
文摘A microwave irradiated magnetically separable nano cobalt ferrite catalyzed green method for the synthesis of 4-phenyl-4H-pyrano[3,2-h]quinolin-2-amine and 2-amino-4-phenyl-4H-pyrano[3,2-h] quinoline-3-carbonitrile derivatives through cyclization of aromatic aldehyde, acetonitrile/malononitrile and 8-hydoxyquinoline is developed and presented in this paper. The cubic magnetic cobalt ferrite nano particles were synthesized by sol-gel citrate precursor method and characterized by FT-IR, XRD, SEM and TEM techniques and the structures of the synthesized pyranoquinoline derivatives were assigned by IR, MASS and 1</sup>H NMR techniques. The reaction is carried out in a domestic microwave oven with a heat-resistant microwave safe glass container with a lid.
基金We thank the National Natural Science Foundation of China (No. 20472117) the NSFC/RGC Joint Research Scheme (No. 20710006, N_PolyU 508/06)+1 种基金 the Science Foundation of Guangzhou (No. 2006Z2-E402) the Sun Yat-sen University Opening Laboratory Fund for financial support of this study.
文摘A rapid and efficient method was established for the synthesis of indoloquinolinone and its analogues using acid-promoted cyclization in the present of PPA. All the reactions were completed in good yields in lOmin under microwave irradiation.
文摘A high-efficiency synthesis method for a latent pigment of red pigment diketo-pyrrolo-pyrrole (Pig. Red 272:272DPP), which is important as a functional organic pigment, was investigated, and the investigation results revealed that irradiation of microwaves (MWs) for several seconds to 272 DPP in NMP (N-methyl-2-pyrrolidone) solvent yielded DPP latent pigment (272DPP-BOC) at a high yield of 86.2%. Two kinds of latent-pigment crystals, namely, red and yellow, were obtained by recrystallization, and it was found that the fluorescence-emission properties of the two kinds differ significantly. Single-crystal X-ray structural analysis showed that the difference in the fluorescence-emission properties of the two types is derived from the difference in their crystal structures.
基金The project was supported by the National Natural Science Foundation of China (No. 20372057), the Natural Science Foundation of Jiangsu Province (No. BK2001142), the Open Foundation of Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University (JSK 011) and the Key Lab of Biotechnology for Medicinal Plants of Jiangsu Province (01AXL 14)
文摘The title compound (C19H23NO3) was synthesized by the one-pot reaction ofp-methoxybenzaldehyde, Meldrum's acid, dimedone and CH3NH3Cl (NaOAc) in ethanol under microwave irradiation without catalyst and its crystal structure was determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/c with a = 8.7462(10), b = 17.7367(19), c = 11.5959(14) A, β = 110.981(3)°, V= 1679.6(3) A^3, Z = 4, Dc = 1.239 g/cm^3,μ(MoKa) = 0.083 mm^-1, F(000) = 672 and Mr = 313.38. The structure was refined to R = 0.0530 and wR = 0.1216. X-ray analysis reveals that the dihedral angle between plane 1 (N(1), C(1), C(2), C(3)) and plane 2 (C(1), C(2), C(6), C(7), C(9)) is 3.64°, andt hat between plane 2 and plane 3 (C(11)~C(16)) is 85.33°.
基金Supported by the National High Technology Research and Development Program of China(No.2006AA03Z224)the Program of New Century Excellent Talents in Universities of China(No.NCET-04-0277)
文摘A rapid way assisted by microwave irradiation was proposed to synthesize poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole](PBI) and poly(2,5-benzimidazole)(ab-PBI).Synthesis of PBI in polyphosphoric acid is conducted for 20 h or even more.Under microwave irradiation,the polycondensations could be completed in polyphosphoric acid within 3 h from 3,3'-diaminobenzidine tetrahydrochloride(DAB·4HCl·2H2O) and isophthalic acid for PBI,and from 3,4-diaminobenzoic acids(DABA) for ab-PBI,respectively.The conditions for the polymerization including the power of microwave irradiation,temperature,heating time,and concentrations of the reactants in polyphosphoric acid were optimized.The inherent viscosity of the polymers in concentrated sulfuric acid at 30 ℃ was 0.9766 dL/g for PBI,and 0.6480 dL/g for ab-PBI,respectively.Characterization of the polymer products was made by nuclear magnetic resonance(1^H NMR),Fourier transform infrared spectra(FTIR) and thermogravimetric analysis(TGA).
基金This work was supported by the National Natural Science Foundation of China (No. 20372057) Natural Science Foundation of Jiangsu Province (No. BK2001142) the Suzhou University Organic Synthesis Open Laboratory of Jiangsu Province (No. S81091 11) and the Key Lab of Biotechnology for Medicinal Plants of Jiangsu Province (No. 01AXL 14)
文摘The crystal structure N-methyl-9-(4-bromophenyl)-1,8-dioxo-1,2,3,4,5,6,7,8,9,10- decahydroacridine(C20H20BrNO2) was determined by single-crystal X-ray diffraction analysis. It belongs to P21/n space group, with a = 10.7999(18), b = 13.845(3), c = 11.4031(3) ?, β = 99.324(4)°, Dc = 1.525 g/cm3, Z = 4, λ = 0.71070 ?, μ(MoKα) = 2.455 mm-1, Mr = 386.28, V = 1682.5(5) ?3, F(000) = 792, the final R = 0.0463 and wR = 0.1053. In the crystal structure, the pyridine ring adopts a boat conformation, the two six-numbered rings fused with pyridine ring adopt twisting boat con- formation.
文摘Novolacs were successfully synthesized using oxalic acid as the catalyst in a self-designed device based on a domestic microwave oven, The fundamental characteristics of the synthesis of novolacs under microwave irradiation (MI) were investigated, and the properties of the resins polymerized and dehydrated under microwave irradiation and conventional heating (CH) were analyzed comparatively, The results show that MI reduced the polymerization and dehydration time greatly; and that the resins polymedzed and dehydrated under MI presented longer flow distances ( i. e., higher flowability) and shorter cure time than those obtained under CH.
基金the Natural Science Foundation of Southwest University for Nationalities (No.08NQZ002) for financial support.
文摘Six new asymmetric thiocarbonohydrazones 3a-3f were synthesized from following steps: firstly hydrazine hydrate reacted with carbon disulfide to form thiocarbonohydrazide (1) under microwave irradiation. Then compound (1) reacted with ketone and different aldehydes step by step to give 3a-3f with excellent yields under solvent-free conditions using microwave irradiation. Their structures have been determined by elemental analysis, IR, MS and ^1H NMR data. 2009 Qing Han Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
文摘The synthesis and characterization of aluminum-pillared rectorite were studied. The synthesis was conducted with both conventional heating and microwave irradiation. Microwave irradiation was found to enhance the intercalation and ion-exchange during synthesis, and to be able to produce the rectorite with a larger d_(001) and a better uniformity. The specific surface area is 180 m^2/g and basal spacing is 3.2 nm. The texture change and thermal and hydrothermal stability of cross-linked rectorite were examined using XRD, FTIR, nitrogen-adsorption and TGA. The experimental results show that the aluminum-pillared rectorite, after calcined at 800 ℃ for 3 hours, can keep the basal aluminum-silicate texture and would not disperse in water at room or an elevated temperature. The aluminum-pillared rectorite shows a high specific surface area, good thermal and hydrothermal stability, and is promising in applications as catalyst carriers and adsorbents for waste treatment.
文摘zeolite was synthesized by using tetraethyl ammonium hydroxide as the template reagent andmicrowave radiation as the heat source. The effect of the sol composition and the radiation temperature onzeolite crystallinity was investigated. The zeolite was tested and compared with the commercial product, whichwas produced by conventional hydrothermal synthesis method. The physico-chemical properties of the syn-thesized samples, the specific surface area of the samples synthesized under microwave irradiation and porevolume measured by X-ray diffraction apparatus, were better than the conventional samples. The etherificationexperiment on FCC light naphtha in the presence of transition metals modified Hβ-zeolite, which was synthe-sized firstly under microwave irradiation, was studied in a fixed-bed reactor. The effect of catalyst preparationconditions on its activity, stability and the effect of reaction temperature, methanol/tertiary-carbon olefin molarratio and liquid hourly space velocity on the etherification reaction were discussed. The experimental resultsshowed that the different metals modified Hβ-zeolite had different etherification performances. And theconversion of tertiary carbon-olefins of the molybdenum modified Hβzeolite, which was loaded at a concen-tration of 3 percents, was higher than that on 6.0 percent of Hβzeolite. The modified Hβzeolite catalystspossessed favorable prospects for its higher stability.
基金This work was supported by the National Natural Science Foundation of China (No. 20372057), the Natural Science Foundation of the Jiangsu Province (No. BK2001142), the Suzhou University Organic Syntheses Open Laboratory of Jiangsu Province (No. S8109111) and the Key Lab of Biotechnology for Medicinal Plants of Jiangsu Province (No. 01AXL 14)
文摘The N-cyclopropyl-9-(3,4-dicholophenyl)-1,2,3,4,5,6,7,8,9,10-decahydroacri- dine-1,8-dione was synthesized by the reaction of 1,3-cyclohexanedione, N-cyclopropylamine and 3,4-dicholoaldehyde in water and glycol under microwave irradiation. Its crystal structure was determined by single-crystal X-ray diffraction analysis. It possesses P212121 space group, with a = 9.9103(5), b = 13.3597(8), c = 14.5633(8) ?, V = 1928.16(18) ?3, Mr = 402.30, Z = 4, Dc = 1.386 g/cm3, λ = 0.7107 ?, μ(MoKα) = 0.354 mm?1 and F (000) = 840. The structure was refined to R = 0.0280 and wR = 0.0757. In the structure, the pyridine ring adopts a boat conformation.
基金Supported by the Natural Science Foundation of Jiangsu province(No.BK2001142)the Natural Science Foundation of Jiangsu Education Department(No.01KJB150008)
文摘The crystal structure of the title compound (C16H17NO5) has been determined by single-crystal X-ray diffraction.The crystal is of monoclinic,space group C2/c with a=18.520(2),b=7.8910(1),c=21.728(3)?,β=104.77(1)°,V=3070.4(7)?^3,Mr=303.31,Z=8,Dc=1.312g/cm^3,λ=0.71073?,μ(MoKα)=0.098mm^-1 and F(000)=1280.The structure was refined to R=0.0486 and wR=0.1287.There exist intermolecular hydrogen bonds in the crystal.
文摘Microwave irradiation of aromatic aldehyde and 2,4-thiazolidinedione provides a fast and high-yield access to 5-benzylidene-2,4-thiazolidinedione. Seven 3-alkyl-5-benzylidene-2,4-thiazolidinedione compounds were produced with high yield by reacting 5-benzylidene-2,4-thiazolidinedione with different alkylating agents under microwave irradiation.
基金The authors thank the Scientific and Technological Innovation Engineering of Northwest Normal University(NWNU-KJCXGC-02-08)Natural Science Foundation of Gansu Province(ZS021-A25-006-Z)Environmental Protection Foundation of Gansu Province(GH2003-19)for the financial support of this work.
文摘Eighteen 1-aroyl-4-(2-iodobenzoyl)thiosemicarbazides and corresponding semicarbazides were synthesized in excellent yield under microwave irradiation in solvent and catalyst free condition.