A microwave-assisted general method for the synthesis of 2-aminovinyl benzimidazoles has been developed.Treatment of the 1,2-phenylenediamines and N-arylated/N,N-dialkylated 3-aminoacroleins with bis（cyclopentadienyl...A microwave-assisted general method for the synthesis of 2-aminovinyl benzimidazoles has been developed.Treatment of the 1,2-phenylenediamines and N-arylated/N,N-dialkylated 3-aminoacroleins with bis（cyclopentadienyl）zirconium（IV） dichloride（Cp2Zr Cl2） as the catalyst under microwave irradiation for 3–5 min followed by in situ Mn O2 oxidation afforded thirteen 2-aminovinyl benzimidazoles in good yields.展开更多
基金the National Natural Science Foundation of China (Nos.21262014 to Q.Sun and 21003018 to H.-B.Sun)Key Project of Chinese Ministry of Education (No.212092)Research Funds (Nos.ky2012zy08 and 2013QNBJRC001) from JXSTNU for financial support
文摘A microwave-assisted general method for the synthesis of 2-aminovinyl benzimidazoles has been developed.Treatment of the 1,2-phenylenediamines and N-arylated/N,N-dialkylated 3-aminoacroleins with bis（cyclopentadienyl）zirconium（IV） dichloride（Cp2Zr Cl2） as the catalyst under microwave irradiation for 3–5 min followed by in situ Mn O2 oxidation afforded thirteen 2-aminovinyl benzimidazoles in good yields.
