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Damage effects and mechanism of the silicon NPN monolithic composite transistor induced by high-power microwaves 被引量:4
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作者 Hui Li Chang-Chun Chai +2 位作者 Yu-Qian Liu Han Wu in-Tang Yang 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第8期633-639,共7页
A two-dimensional model of the silicon NPN monolithic composite transistor is established for the first time by utilizing the semiconductor device simulator, Sentaurus-TCAD. By analyzing the internal distributions of ... A two-dimensional model of the silicon NPN monolithic composite transistor is established for the first time by utilizing the semiconductor device simulator, Sentaurus-TCAD. By analyzing the internal distributions of electric field, current density, and temperature of the device, a detailed investigation on the damage process and mechanism induced by high-power microwaves (HPM) is performed. The results indicate that the temperature elevation occurs in the negative half-period and the temperature drop process is in the positive half-period under the HPM injection from the output port. The damage point is located near the edge of the base-emitter junction of T2, while with the input injection it exists between the base and the emitter of T2. Comparing these two kinds of injection, the input injection is more likely to damage the device than the output injection. The dependences of the damage energy threshold and the damage power threshold causing the device failure on the pulse-width are obtained, and the formulas obtained have the same form as the experimental equations, which demonstrates that more power is required to destroy the device if the pulse-width is shorter. Furthermore, the simulation result in this paper has a good coincidence with the experimental result. 展开更多
关键词 monolithic composite transistor high-power microwaves damage effects pulse-width effects
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Microwaves Scattering by Underdense Inhomogeneous Plasma Column 被引量:3
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作者 张林 欧阳吉庭 《Plasma Science and Technology》 SCIE EI CAS CSCD 2016年第3期266-272,共7页
The scattering characteristics of microwaves (MWs) by an underdense inhomoge- neous plasma column have been investigated. The plasma column is generated by hollow cathode discharge (HCD) in a glass tube filled wit... The scattering characteristics of microwaves (MWs) by an underdense inhomoge- neous plasma column have been investigated. The plasma column is generated by hollow cathode discharge (HCD) in a glass tube filled with low pressure argon. The plasma density in the column can be varied by adjusting the discharge current. The scattering power of X-band MWs by the column is measured at different discharge currents and receiving angles. The results show that the column can affect the properties of scattering wave significantly regardless of its plasma frequency much lower than the incident wave frequency. The power peak of the scattering wave shifts away from 0° to about ±15° direction. The finite-different time-domain (FDTD) method is employed to analyze the wave scattering by plasma column with different electron density distributions. The reflected MW power from a metal plate located behind the column is also measured to investi- gate the scattering effect on reducing MW refiectivity of a metal target. This study is expected to deepen the understanding of plasma-electromagnetic wave interaction and expand the applications concerning plasma antenna and plasma stealth. 展开更多
关键词 glow discharge plasma microwaves scattering FDTD method
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Inspections of Mobile Phone Microwaves Effects on Proteins Secondary Structure by Means of Fourier Transform Infrared Spectroscopy 被引量:2
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作者 Emanuele Calabrò Salvatore Magazù 《Journal of Electromagnetic Analysis and Applications》 2010年第11期607-617,共11页
In this study the effects of microwaves on the secondary structure of three typical proteins have been investigated. A set of samples of lysozyme, bovine serum albumin and myoglobin in D2O solutions were exposed for 8... In this study the effects of microwaves on the secondary structure of three typical proteins have been investigated. A set of samples of lysozyme, bovine serum albumin and myoglobin in D2O solutions were exposed for 8 hours to mobile phone microwaves at 900 MHz at a magnetic field intensity around 16 mA/m. The relative effects on the secondary structure of the proteins were studied by means of Fourier Transform Infrared Spectroscopy. An increase of the amide I band intensity in the secondary structure of the proteins was observed after the microwaves exposure. Furthermore, a weak shift of the amide I mode of bovine serum albumin and a heavier shift of the amide I of myoglobin occurred after the exposure. In addition, a clear increasing of the β-sheet components with respect to the α-helix content was observed in the spectra of bovine serum albumin and myoglobin after the exposure, suggesting the hypothesis of the formation of aggregates. 展开更多
关键词 Mobile PHONE microwaves PROTEIN Infrared SPECTRUM SECONDARY Structure AMIDE I
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Modulation of heat shock protein response in SH-SY5Y by mobile phone microwaves 被引量:1
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作者 Emanuele Calabrò Salvatore Condello +4 位作者 Monica Currò Nadia Ferlazzo Daniela Caccamo Salvatore Magazù Riccardo Ientile 《World Journal of Biological Chemistry》 CAS 2012年第2期34-40,共7页
AIM: To investigate putative biological damage caused by GSM mobile phone frequencies by assessing electromagnetic fields during mobile phone working. METHODS: Neuron-like cells, obtained by retinoicacid-induced diffe... AIM: To investigate putative biological damage caused by GSM mobile phone frequencies by assessing electromagnetic fields during mobile phone working. METHODS: Neuron-like cells, obtained by retinoicacid-induced differentiation of human neuroblastoma SH-SY5Y cells, were exposed for 2 h and 4 h to microwaves at 1800 MHz frequency bands. RESULTS: Cell stress response was evaluated by MTT assay as well as changes in the heat shock protein expression (Hsp20, Hsp27 and Hsp70) and caspase-3 activity levels, as biomarkers of apoptotic pathway. Under our experimental conditions, neither cell viability nor Hsp27 expression nor caspase-3 activity was significantly changed. Interestingly, a significant decrease in Hsp20 expression was observed at both times of exposure, whereas Hsp70 levels were significantly increased only after 4 h exposure. CONCLUSION: The modulation of the expression of Hsps in neuronal cells can be an early response to radiofrequency microwaves. 展开更多
关键词 APOPTOSIS ELECTROMAGNETIC field Heat shock PROTEINS microwaves SH-SY5Y DIFFERENTIATED cells
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An Experimental Research to Study the Microwaves transmission Characteristics of Ablating Material in Arc-Heated Plasma Flow
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作者 程梅莎 董永晖 张嘉祥 《Plasma Science and Technology》 SCIE EI CAS CSCD 2001年第2期743-747,共5页
in this paper, an experimental research the effect of ablating material on the reflection and the transmission of microwaves in arc-heated plasma flow is presented by using the C band microwave measuring system. The ... in this paper, an experimental research the effect of ablating material on the reflection and the transmission of microwaves in arc-heated plasma flow is presented by using the C band microwave measuring system. The results show that the ablating material with accidented surface and its high temperature have remarkably affected the reflection and the transmission of microwaves. The experiment proves that the system has outstanding precision and reliability. 展开更多
关键词 An Experimental Research to Study the microwaves transmission Characteristics of Ablating Material in Arc-Heated Plasma Flow Arc high
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Determination of Material Properties like Permittivity and Density with Microwaves
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作者 Christoph Sklarczyk 《Journal of Modern Physics》 2014年第6期335-340,共6页
With the help of electromagnetic waves in deci-, centi- and millimeter-wave range (microwaves) it is possible to determine the properties of non-metallic objects like permittivity or density in a nondestructive and if... With the help of electromagnetic waves in deci-, centi- and millimeter-wave range (microwaves) it is possible to determine the properties of non-metallic objects like permittivity or density in a nondestructive and if necessary in a contactless way. Depending on the type of the test object the measurement can be carried out both with low-cost narrowband or more expensive wideband devices and sensors. To get the characteristic value in most cases it is necessary to calibrate the test device with the help of reference materials. It is recommendable to sustain a constant distance (lift-off or standoff) between the antenna of the sensor and the test object. The paper deals with the characterization of asphalt, especially the determination of its density. 展开更多
关键词 NONDESTRUCTIVE microwaves PERMITTIVITY DENSITY SENSOR
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Effects on the Behavior and Neuroimmunity of Pulsed Microwaves with Different Peak Densities
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作者 YANG Zhen Zhong WU Da Wei +2 位作者 MA Hong Bo FEI Jin Xue ZHAO Ya Li 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 2018年第12期893-897,共5页
Pulsed microwaves are widely used inradar,navigation, and communication. The average power density is low at narrow pulse widths or large pulse intervals,but pulsed microwaves at certain peak densities exert numerous ... Pulsed microwaves are widely used inradar,navigation, and communication. The average power density is low at narrow pulse widths or large pulse intervals,but pulsed microwaves at certain peak densities exert numerous biological effects, including 展开更多
关键词 Effects on the Behavior and Neuroimmunity of Pulsed microwaves with Different Peak Densities
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Antioxidant Capacity in Vanilla Extracts Obtained by Applying Focused Microwaves
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作者 Adalith Rojas-López María P.Canizares-Macías 《Food and Nutrition Sciences》 2013年第8期244-253,共10页
ORAC method and a continuous flow injection method based on Folin-Ciocalteau reaction (FI-FC) were used for determining the antioxidant activity in extracts obtained by using focused microwaves. Analysis of the antiox... ORAC method and a continuous flow injection method based on Folin-Ciocalteau reaction (FI-FC) were used for determining the antioxidant activity in extracts obtained by using focused microwaves. Analysis of the antioxidant capacity (AC) of the main compounds of vanilla (vanillin, p-hydroxybenzaldehyde, p-hydroxybenzoic acid and vanillic acid) was also carried out. Vanilla extracts obtained by using focused microwaves had a higher AC (between 72% and 117%) than the obtained by conventional methods. Vanillin had a linear correlation with the antioxidant capacity of the extracts and it is the most influential compound in the antioxidant power. The AC calculated by the ORAC method and the FI-FC method had a ratio 2:1 because of different kinetics and reaction mechanisms of the antioxidants with the reagents, so it is necessary more than one method to establish the antioxidant power in food. On base on the results of the present study microwaves energy can be used to obtain vanilla extracts to improve the AC of them. 展开更多
关键词 Focused microwaves VANILLA Antioxidant Capacity ORAC Method Flow Injection Folin-Ciocalteau
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Influence of wet activation of used inorganic binder on cyclically refreshed water glass moulding sands hardened by microwaves 被引量:3
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作者 Mateusz Stachowicz Kazimierz Granat 《China Foundry》 SCIE 2016年第6期427-432,共6页
The paper presents the research results of using an innovative method to reclaim the waste moulding sands containing water glass. Two of the examined processes are connected with "dry" or "wet" act... The paper presents the research results of using an innovative method to reclaim the waste moulding sands containing water glass. Two of the examined processes are connected with "dry" or "wet" activation of inorganic binder in waste moulding sand mixtures physically hardened by microwave radiation. The sand mixtures consisting of high-silica sand and water-glass with average molar module 2.5, were subjected to the following cyclical process: mixing the components, compacting, microwave heating, cooling-down, thermally loading the mould to 800 °C, cooling-down to ambient temperature, and knocking-out. After being knocked-out, the waste moulding sands were subjected to either dry or wet activation of the binder. To activate thermally treated inorganic binder, each of the examined processes employed the surface phenomenon usually associated to mechanical reclamation. The study also covered possible use of some elements of wet reclamation to rehydrate waste binder. To evaluate the effectiveness of the two proposed methods of waste binder activation, selected strength and technological parameters were measured. After each subsequent processing cycle, the permeability, tensile strength and bending strength were determined. In addition, the surface of activated sand grains was examined with a scanning electron microscope. Analysis of the results indicates that it is possible to re-activate the used binder such as sodium silicate, and to stabilize the strength parameters in both activation processes. Permeability of the refreshed moulding sands strongly depends on the surface condition of high-silica grains. The wet activation process by wetting and buffering knocked-out moulding sands in closed humid environment makes it possible to reduce the content of refreshing additive in water-glass. The moulding sands cyclically prepared in both processes do not require the addition of fresh high-silica sand. The relatively high quality achieved in the refreshed moulding sands allows them to be reused for manufacture of next moulds. Thus, the two proposed methods for cyclically processing used moulding sands containing sodium silicate, subject to microwave hardening, are suitable for economic and ecological circulation moulding mixtures. 展开更多
关键词 moulding sand RECLAMATION water-glass microwave heating REFRESHING
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The Interaction of C-Band Microwaves with Large Plasma Sheets
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作者 DING Liang HUO Wenqing +1 位作者 YANG Xinjie XU Yuemin 《Plasma Science and Technology》 SCIE EI CAS CSCD 2012年第1期9-13,共5页
A large plasma sheet 60 cm×60 cm×2 cm in size was generated using a hollow cathode, and measurements were conducted for interactions including transmission, reflection and absorption. With different discharg... A large plasma sheet 60 cm×60 cm×2 cm in size was generated using a hollow cathode, and measurements were conducted for interactions including transmission, reflection and absorption. With different discharge parameters, plasma sheets can vary and influence microwave strength. Microwave reflection decreases when the discharge current rises, and the opposite occurs in transmission. The C-band microwave is absorbed when it is propagated through large plasma sheets at higher pressure. When plasma density and collision frequency are fitted with incident microwave frequency, a large amount of microwave energy is consumed. Reflection, transmission and absorption all exist simultaneously. Plasma sheets are an attractive alternative to microwave steering at low pressure, and the microwave reflection used in receiving radar can be altered by changing the discharge parameters. 展开更多
关键词 hollow cathode discharge microwave effect large plasma sheet density distribution
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The Characteristics of Columniform Surface Wave Plasma Excited Around a Quartz Rod by 2.45 GHz Microwaves
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作者 吴忠航 梁荣庆 +1 位作者 永津雅章 昌锡江 《Plasma Science and Technology》 SCIE EI CAS CSCD 2016年第10期987-991,共5页
A novel surface wave plasma (SWP) source excited with cylindrical Teflon waveguide has been developed in our previous work. The plasma characteristics have been simply studied. In this work, our experimental device ... A novel surface wave plasma (SWP) source excited with cylindrical Teflon waveguide has been developed in our previous work. The plasma characteristics have been simply studied. In this work, our experimental device has been significantly improved by replacing the Teflon waveguide with a quartz rod, and then better microwave coupling and higher gas purity can be obtained during plasma discharge. The plasma spatial distributions, both in radial and axial directions, have been measured and the effect of gas pressure has been investigated. Plasma density profiles indicate that this plasma source can produce uniform plasma in an axial direction at low pressure, which shows its potential in plasma processing on a curved surface such as an inner tube wall. A simplified circular waveguide model has been used to explain the principle of plasma excitation. The distinguishing features and potential application of this kind of plasma source with a hardware improvement have been shown. 展开更多
关键词 2.45 GHz microwave surface wave plasma circular waveguide plasmadiagnosis
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Upper Hybrid Resonance of Microwaves with a Large Magnetized Plasma Sheet
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作者 HUO Wenqing GUO Shijie +1 位作者 DING Liang XU Yuemin 《Plasma Science and Technology》 SCIE EI CAS CSCD 2013年第10期979-984,共6页
A large magnetized plasma sheet with size of 60 cm×60 cm×2 cm was generated by a linear hollow cathode discharge under the confinement of a uniform magnetic field generated by a Helmholtz Coil. The microwave... A large magnetized plasma sheet with size of 60 cm×60 cm×2 cm was generated by a linear hollow cathode discharge under the confinement of a uniform magnetic field generated by a Helmholtz Coil. The microwave transmission characteristic of the plasma sheet was measured for different incident frequencies, in cases with the electric field polarization of the incident microwave either perpendicular or parallel to the magnetic field. In this measurement, parameters of the plasma sheet were changed by varying the discharge current and magnetic field intensity. In the experiment, upper hybrid resonance phenomena were observed when the electric field polarization of the incident wave was perpendicular to the magnetic field. These resonance phenomena cannot be found in the case of parallel polarization incidence. This result is consistent with theoretical consideration. According to the resonance condition, the electron density values at the resonance points are calculated under various experimental conditions. This kind of resonance phenomena can be used to develop a specific method to diagnose the electron density of this magnetized plasma sheet apparatus. Moreover, it is pointed out that the operating parameters of the large plasma sheet in practical applications should be selected to keep away from the upper hybrid resonance point to prevent signals from polarization distortion. 展开更多
关键词 magnetized plasma sheet upper hybrid resonance MICROWAVE
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Absorption of Microwaves in Low Intensity Eucalyptus Litter Fire
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作者 Douglas Letsholathebe Kgakgamatso Mphale 《Journal of Electromagnetic Analysis and Applications》 2015年第8期217-224,共8页
A fuel bed was constructed where various vegetation species could be used as combustion fuel. The fuel bed was equipped with a thermocouple to measure fire temperature and a two-port automatic network analyser to meas... A fuel bed was constructed where various vegetation species could be used as combustion fuel. The fuel bed was equipped with a thermocouple to measure fire temperature and a two-port automatic network analyser to measure microwave scattering parameters in flame medium. The parameters are then used to determine microwave propagation characteristics in fire. The measurements have implications on radio wave communication during wildfire suppression and in remote sensing. The attenuation data also provide an estimation of vegetation fire ionisation and conductivity. Eucalyptus litter fire with a maximum flame temperature of 976 K was set on the fuel bed and X-band microwaves (7.00 - 9.50 GHz) were caused to propagate through the flame. Attenuation of 0.35 - 0.90 dB was measured for microwaves in the frequency range. For the low intensity fire, conductivity was measured to range from 0.00021 - 0.00055 mho/m and electron density was to be the range of 1.83 - 2.24 × 1015 m-3. 展开更多
关键词 WILDFIRE Microwave ATTENUATION WEAKLY Ionised Gas Remote Sensing Electric CONDUCTIVITY
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Developing a Novel Approach for Sludge Treatment Using Microwaves Technology
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作者 David Yu Wendy Li 《Journal of Geoscience and Environment Protection》 2020年第5期195-203,共9页
The purpose of this research is to find a method that can improve the cost and efficiency of sludge treatment. Currently, large amounts of sludge are produced every day, but sludge treatment is neither efficient nor p... The purpose of this research is to find a method that can improve the cost and efficiency of sludge treatment. Currently, large amounts of sludge are produced every day, but sludge treatment is neither efficient nor profitable. To improve the sludge treatment process, we proposed the method of using microwave technology to treat sludge. We hypothesized that using microwave technology, we can reduce the volume of the sludge up to 90%, and can save more energy and time comparing to the traditional methods that we are currently using to treat the sludge. To prove our hypothesis, we designed an experiment to compare the solid-liquid boundary height and the solid-liquid mass ratio of the sludge treated by the conventional method and the microwave technology. Prime temperature and time found for dewatering sludge are 70 Celsius degrees and five minutes. The results were rather surprising, as microwave heating demonstrated no significant advantage over conventional heating. The solid-liquid boundary height of sludge heated by conventional and by microwave methods are 22.34 mL and 22.56 mL;the solid-liquid mass ratio of sludge using conventional heating and microwave heating at 70 Celsius degrees are 14.28% and 14.55% (by separation with filter press), or 9.82% and 9.89% (by centrifugation). In conclusion, the difference is negligible. 展开更多
关键词 MUNICIPAL SEWER SLUDGE SLUDGE DEWATERING Microwave Treatment INTRACELLULAR Water Thermal CONDITIONING Solid Liquid Separation
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Mechanically reprogrammable Pancharatnam-Berry metasurface for microwaves 被引量:9
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作者 Quan Xu Xiaoqiang Su +9 位作者 Xueqian Zhang Lijuan Dong Lifeng Liu Yunlong Shi Qiu Wang Ming Kang Andrea Alù Shuang Zhang Jiaguang Han Weili Zhang 《Advanced Photonics》 SCIE EI CSCD 2022年第1期69-79,共11页
Metasurfaces have enabled the realization of several optical functionalities over an ultrathin platform,fostering the exciting field of flat optics.Traditional metasurfaces are achieved by arranging a layout of static... Metasurfaces have enabled the realization of several optical functionalities over an ultrathin platform,fostering the exciting field of flat optics.Traditional metasurfaces are achieved by arranging a layout of static meta-atoms to imprint a desired operation on the impinging wavefront,but their functionality cannot be altered.Reconfigurability and programmability of metasurfaces are the next important step to broaden their impact,adding customized on-demand functionality in which each meta-atom can be individually reprogrammed.We demonstrate a mechanical metasurface platform with controllable rotation at the meta-atom level,which can implement continuous Pancharatnam–Berry phase control of circularly polarized microwaves.As the proof-of-concept experiments,we demonstrate metalensing,focused vortex beam generation,and holographic imaging in the same metasurface template,exhibiting versatility and superior performance.Such dynamic control of electromagnetic waves using a single,low-cost metasurface paves an avenue towards practical applications,driving the field of reprogrammable intelligent metasurfaces for a variety of applications. 展开更多
关键词 reprogrammable metasurfaces Pancharatnam-Berry phase mechanical metasurfaces microwaves
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Structural and microwave absorption properties of CoFe_(2)O_(4)/residual carbon composites
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作者 Yuanchun Zhang Shengtao Gao +3 位作者 Xingzhao Zhang Dacheng Ma Chuanlei Zhu Jun He 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期221-232,共12页
Electromagnetic interference,which necessitates the rapid advancement of substances with exceptional capabilities for bsorbing electromagnetic waves,is of urgent concern in contemporary society.In this work,CoFe_(2)O_... Electromagnetic interference,which necessitates the rapid advancement of substances with exceptional capabilities for bsorbing electromagnetic waves,is of urgent concern in contemporary society.In this work,CoFe_(2)O_(4)/residual carbon from coal gasification fine slag(CFO/RC)composites were created using a novel hydrothermal method.Various mechanisms for microwave absorption,including conductive loss,natural resonance,interfacial dipole polarization,and magnetic flux loss,are involved in these composites.Consequently,compared with pure residual carbon materials,this composite offers superior capabilities in microwave absorption.At 7.76GHz,the CFO/RC-2 composite achieves an impressive minimum reflection loss(RL_(min))of-43.99 dB with a thickness of 2.44 mm.Moreover,CFO/RC-3 demonstrates an effective absorption bandwidth(EAB)of up to 4.16 GHz,accompanied by a thickness of 1.18mm.This study revealed the remarkable capability of the composite to diminish electromagnetic waves,providing a new generation method for microwave absorbing materials of superior quality. 展开更多
关键词 coal gasification slag residual carbon hydrothermal method microwave absorption CoFe_(2)O_(4)
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Focusing microwaves into subwavelength dimensions with a half-cylindrical hyperlens based on split ring resonators
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作者 郑国兴 李子乐 +7 位作者 袁桂山 张瑞瑛 何平安 董小春 崔钧 赵江南 鄖建平 李松 《Chinese Optics Letters》 SCIE EI CAS CSCD 2014年第8期64-67,共4页
Hyperlenses based on metamaterials can be applied to subwavelength imaging in the lightwave band. In this letter, we demonstrate both through simulations and experimentally verified results that our proposed half- cyl... Hyperlenses based on metamaterials can be applied to subwavelength imaging in the lightwave band. In this letter, we demonstrate both through simulations and experimentally verified results that our proposed half- cylindrical shaped hyperlens can be used for super-resolution microwave focusing in a TE mode. Based on split ring resonators, the hyperlens satisfies a hyperbolic dispersion relationship. Simulations demonstrate that the focused spot size and position are insensitive to the rotation angle of the hyperlens around its geometric center. Experimental results show that a focused spot size 1/3 of the vacuum wavelength is achieved in the microwave band. 展开更多
关键词 ring Focusing microwaves into subwavelength dimensions with a half-cylindrical hyperlens based on split ring resonators
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Multicomponent One-pot Diastereoselective Synthesis of Biologically Important Scaffold under Microwaves 被引量:9
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作者 DANDIA, Anshu SINGH, Ruby SARAWGI, Pritima KHATURIA, Sarita 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2006年第7期950-954,共5页
A simple and fast three-component diastereoselective synthesis of biologically important spiro scaffold 4 was carried out in reasonable purity starting from readily available 1H-indole-2,3-dione 1, ethyl cyanoacetate ... A simple and fast three-component diastereoselective synthesis of biologically important spiro scaffold 4 was carried out in reasonable purity starting from readily available 1H-indole-2,3-dione 1, ethyl cyanoacetate 2 and 4-hydroxycoumarin 3 under microwave in high yield (88%-92%) and short time. 展开更多
关键词 multi-component reaction microwave spiro derivative
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Pb(Ⅱ) removal from water using Fe-coated bamboo charcoal with the assistance of microwaves 被引量:6
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作者 Zengsheng Zhang Xuejiang Wang +4 位作者 Yin Wang Siqing Xia Ling Chen Yalei Zhang Jianfu Zhao 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2013年第5期1044-1053,共10页
Bamboo charcoal(BC) was used as starting material to prepare iron-modified bamboo charcoal(Fe-MBC) by its impregnation in FeCl 3 and HNO 3 solutions simultaneously,followed by microwave heating.The material can be... Bamboo charcoal(BC) was used as starting material to prepare iron-modified bamboo charcoal(Fe-MBC) by its impregnation in FeCl 3 and HNO 3 solutions simultaneously,followed by microwave heating.The material can be used as an adsorbent for Pb(Ⅱ) contaminants removal in water.The composites were prepared with Fe molar concentration of 0.5,1.0 and 2.0 mol/L and characterized by means of N 2 adsorption-desorption isotherms,X-ray diffraction spectroscopy(XRD),scanning electron microscopy coupled with energy dispersive X-ray spectrometry(SEM-EDS),Fourier transform infrared(FT-IR) and point of zero charge(pH pzc) measurements.Nitrogen adsorption analyses showed that the BET specific surface area and total pore volume increased with iron impregnation.The adsorbent with Fe molar concentration of 2 mol/L(2Fe-MBC) exhibited the highest surface area and produced the best pore structure.The Pb(Ⅱ) adsorption process of 2Fe-MBC and BC were evaluated in batch experiments and 2Fe-MBC showed an excellent adsorption capability for removal Pb(Ⅱ).The adsorption of Pb(Ⅱ) strongly depended on solution pH,with maximum values at pH 5.0.The ionic strength had a significant effect on the adsorption at pH 〈 6.0.The adsorption isotherms followed the Langmuir isotherm model well,and the maximum adsorption capacity for Pb(Ⅱ) was 200.38 mg/g for 2Fe-MBC.The adsorption processes were well fitted by a pseudo second-order kinetic model.Thermodynamic parameters showed that the adsorption of Pb(Ⅱ) onto Fe-MBC was feasible,spontaneous,and exothermic under the studied conditions,and the ion exchange mechanism played an significant role.These results have important implications for the design of low-cost and effective adsorbents in the removal of Pb(Ⅱ) from wastewater. 展开更多
关键词 ADSORPTION bamboo charcoal microwave assistance KINETICS adsorption isotherms
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Microwaves spark emission spectroscopy for the analysis of cations:A simple form of atomic emission spectroscopy
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作者 Zahid Hussain Khalid Mohammed Khan +2 位作者 Khadim Hussain Sadam Hussain Shahnaz Perveen 《Chinese Chemical Letters》 SCIE CAS CSCD 2011年第9期1084-1086,共3页
A novel method for the cation analysis was investigated. The analysis is based on the sparking of the salts of metals in a microwave oven after placing in a graphite cell. The graphite cell absorbs microwaves and prod... A novel method for the cation analysis was investigated. The analysis is based on the sparking of the salts of metals in a microwave oven after placing in a graphite cell. The graphite cell absorbs microwaves and produces high temperature which converts the salt into light emitting species. The colour of light was found to dependent on the nature of cation, however, the intensity of the emitted light was found to be depending upon the form and shape of the graphite assembly in addition to the concentration of the salt. This communication presents explanation for all these observations and for the systematic and quantitative analysis using microwave spark emission technique. 展开更多
关键词 Microwave spark Cation analysis Spark colour Graphite cell Atomic emission
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