Silicon photonic integrated circuits for telecommunication and data centers have been well studied in the past decade, and now most related efforts have been progressing toward commercialization. Scaling up the silico...Silicon photonic integrated circuits for telecommunication and data centers have been well studied in the past decade, and now most related efforts have been progressing toward commercialization. Scaling up the silicon-oninsulator(SOI)-based device dimensions in order to extend the operation wavelength to the short mid-infrared(MIR) range(2–4 μm) is attracting research interest, owing to the host of potential applications in lab-on-chip sensors, free space communications, and much more. Other material systems and technology platforms, including silicon-on-silicon nitride, germanium-on-silicon, germanium-on-SOI, germanium-on-silicon nitride, sapphireon-silicon, Si Ge alloy-on-silicon, and aluminum nitride-on-insulator are explored as well in order to realize low-loss waveguide devices for different MIR wavelengths. In this paper, we will comprehensively review silicon photonics for MIR applications, with regard to the state-of-the-art achievements from various device demonstrations in different material platforms by various groups. We will then introduce in detail of our institute's research and development efforts on the MIR photonic platforms as one case study. Meanwhile, we will discuss the integration schemes along with remaining challenges in devices(e.g., light source) and integration. A few application-oriented examples will be examined to illustrate the issues needing a critical solution toward the final production path(e.g., gas sensors). Finally, we will provide our assessment of the outlook of potential futureresearch topics and engineering challenges along with opportunities.展开更多
Mid-infrared(MIR) emissions of 2.4 and 3.5 μm from Tm3+:LiYF4 single crystals attributed to3H4 →3H5 and3H5 →3F4 transitions as well as MIR emissions of 4.2,4.3,and 4.5 μm from Nd3+:LiYF4 lasers attributed to...Mid-infrared(MIR) emissions of 2.4 and 3.5 μm from Tm3+:LiYF4 single crystals attributed to3H4 →3H5 and3H5 →3F4 transitions as well as MIR emissions of 4.2,4.3,and 4.5 μm from Nd3+:LiYF4 lasers attributed to4I15/2 →4I13/2,4I13/2 →4I11/2,and4I11/2 →4I9/2 transitions,respectively,are observed.LiYF4 single crystals possess high transmittance of over 85% in the 2.5-6 μm range.The large emission crosssections of Tm-doped crystals at 2.4 μm(1.9×10-20cm2) and Nd-doped crystals at 4.2 μm(0.84×10-20 cm2) as well as the high rare-earth doping concentrations,excellent optical transmission,and chemicalphysical properties of the resultant samples indicate that Nd3+and Tm3+singly doped crystals may be promising materials for application in MIR lasers.展开更多
We present the numerical results for the optimization of the pump-to-idler conversion efficiencies of nanosecond idler wavelength tunable cascaded optical parametric oscillators (OPO) in different wavelength tuning ...We present the numerical results for the optimization of the pump-to-idler conversion efficiencies of nanosecond idler wavelength tunable cascaded optical parametric oscillators (OPO) in different wavelength tuning ranges, where the primary signals from the OPO process are recycled to enhance the pump-to-idler conversion efficiencies via the simultaneous dif- ference frequency generation (DFG) process by monolithic aperiodically poled, magnesium oxide doped lithium niobate (APMgLN) crystals. The APMgLN crystals are designed with different chirp parameters for the DFG process to broaden their thermal acceptance bandwidths to different extents. The idler wavelength tuning of the cascaded OPO is realized by changing the temperature of the designed APMgLN crystal and the cascaded oscillation is achieved in a single pump pass singly resonant linear cavity. The pump-to-idler conversion efficiencies with respect to the pump pulse duration and ratio of OPO coefficient to DFG coefficient are calculated by numerically solving the coupled wave equations. The optimal work- ing conditions of the tunable cascaded OPOs pumped by pulses with energies of 350 p_J and 700 ~J are compared to obtain the general rules of optimization. It is concluded that the optimization becomes the interplay between the ratio of OPO coefficient to DFG coefficient and the pump pulse duration when the idler wavelength tuning range and the pump pulse energy are fixed. Besides, higher pump pulse energy is beneficial for reaching higher optimal pump-to-idler conversion efficiency as long as the APMgLN crystal is optimized according to this pump condition. To the best of our knowledge, this is the first numerical analysis of idler wavelength tunable cascaded OPOs based on chirp-assisted APMgLN crystals.展开更多
Biochemical reactions in vivo occur at the temperature usually lower than that in vitro,however the underlying mechanism still remains a challenge.Inspired by our recent studies of adenosine triphosphate(ATP)releasing...Biochemical reactions in vivo occur at the temperature usually lower than that in vitro,however the underlying mechanism still remains a challenge.Inspired by our recent studies of adenosine triphosphate(ATP)releasing photons to resonantly drive DNA replication in a quantum way,we propose a quantized chemical reaction driven by multiple mid-infrared(MIR)photons.The space confinement effect of enzymes on a reactant molecule increases the lifetime of excitation state of its bond vibration,providing a chance for the bond to resonantly absorb multiple photons.Although the energy of each MIR photon is significantly lower than that of chemical bond,the resonant absorption of multiple photons can break the appointed bond of confined molecules.Different from the traditional thermochemistry and photochemistry,the quantized chemical reactions could have a high energy efficiency and ultrahigh selectivity.In addition,we also suggest a quantum driving source for our quantum-confined superfluid reactions proposed previously.The quantized chemical reaction resonantly driven by multiple MIR photons holds great promise to develop novel approaches for the chemical engineering in future.展开更多
文摘Silicon photonic integrated circuits for telecommunication and data centers have been well studied in the past decade, and now most related efforts have been progressing toward commercialization. Scaling up the silicon-oninsulator(SOI)-based device dimensions in order to extend the operation wavelength to the short mid-infrared(MIR) range(2–4 μm) is attracting research interest, owing to the host of potential applications in lab-on-chip sensors, free space communications, and much more. Other material systems and technology platforms, including silicon-on-silicon nitride, germanium-on-silicon, germanium-on-SOI, germanium-on-silicon nitride, sapphireon-silicon, Si Ge alloy-on-silicon, and aluminum nitride-on-insulator are explored as well in order to realize low-loss waveguide devices for different MIR wavelengths. In this paper, we will comprehensively review silicon photonics for MIR applications, with regard to the state-of-the-art achievements from various device demonstrations in different material platforms by various groups. We will then introduce in detail of our institute's research and development efforts on the MIR photonic platforms as one case study. Meanwhile, we will discuss the integration schemes along with remaining challenges in devices(e.g., light source) and integration. A few application-oriented examples will be examined to illustrate the issues needing a critical solution toward the final production path(e.g., gas sensors). Finally, we will provide our assessment of the outlook of potential futureresearch topics and engineering challenges along with opportunities.
基金supported by the National Natural Science Foundation of China(Nos.51272109 and 50972061)the Natural Science Foundation of Zhejiang Province(No.R4100364)+1 种基金the Natural Science Foundation of Ningbo City(No.2012A610115)the K.C.Wong Magna Fund in Ningbo University
文摘Mid-infrared(MIR) emissions of 2.4 and 3.5 μm from Tm3+:LiYF4 single crystals attributed to3H4 →3H5 and3H5 →3F4 transitions as well as MIR emissions of 4.2,4.3,and 4.5 μm from Nd3+:LiYF4 lasers attributed to4I15/2 →4I13/2,4I13/2 →4I11/2,and4I11/2 →4I9/2 transitions,respectively,are observed.LiYF4 single crystals possess high transmittance of over 85% in the 2.5-6 μm range.The large emission crosssections of Tm-doped crystals at 2.4 μm(1.9×10-20cm2) and Nd-doped crystals at 4.2 μm(0.84×10-20 cm2) as well as the high rare-earth doping concentrations,excellent optical transmission,and chemicalphysical properties of the resultant samples indicate that Nd3+and Tm3+singly doped crystals may be promising materials for application in MIR lasers.
基金supported by the National Natural Science Foundation of China(Grant No.61505236)the Innovation Program of Shanghai Institute of Technical Physics,China(Grant No.CX-2)the Program of Shanghai Subject Chief Scientist,China(Grant No.14XD1404000)
文摘We present the numerical results for the optimization of the pump-to-idler conversion efficiencies of nanosecond idler wavelength tunable cascaded optical parametric oscillators (OPO) in different wavelength tuning ranges, where the primary signals from the OPO process are recycled to enhance the pump-to-idler conversion efficiencies via the simultaneous dif- ference frequency generation (DFG) process by monolithic aperiodically poled, magnesium oxide doped lithium niobate (APMgLN) crystals. The APMgLN crystals are designed with different chirp parameters for the DFG process to broaden their thermal acceptance bandwidths to different extents. The idler wavelength tuning of the cascaded OPO is realized by changing the temperature of the designed APMgLN crystal and the cascaded oscillation is achieved in a single pump pass singly resonant linear cavity. The pump-to-idler conversion efficiencies with respect to the pump pulse duration and ratio of OPO coefficient to DFG coefficient are calculated by numerically solving the coupled wave equations. The optimal work- ing conditions of the tunable cascaded OPOs pumped by pulses with energies of 350 p_J and 700 ~J are compared to obtain the general rules of optimization. It is concluded that the optimization becomes the interplay between the ratio of OPO coefficient to DFG coefficient and the pump pulse duration when the idler wavelength tuning range and the pump pulse energy are fixed. Besides, higher pump pulse energy is beneficial for reaching higher optimal pump-to-idler conversion efficiency as long as the APMgLN crystal is optimized according to this pump condition. To the best of our knowledge, this is the first numerical analysis of idler wavelength tunable cascaded OPOs based on chirp-assisted APMgLN crystals.
基金This work was supported by the National Key Research and Development Program of China(No.2018YFE0205501)the National Natural Science Foundation of China(Nos.21988102,51763019 and U1832125).
文摘Biochemical reactions in vivo occur at the temperature usually lower than that in vitro,however the underlying mechanism still remains a challenge.Inspired by our recent studies of adenosine triphosphate(ATP)releasing photons to resonantly drive DNA replication in a quantum way,we propose a quantized chemical reaction driven by multiple mid-infrared(MIR)photons.The space confinement effect of enzymes on a reactant molecule increases the lifetime of excitation state of its bond vibration,providing a chance for the bond to resonantly absorb multiple photons.Although the energy of each MIR photon is significantly lower than that of chemical bond,the resonant absorption of multiple photons can break the appointed bond of confined molecules.Different from the traditional thermochemistry and photochemistry,the quantized chemical reactions could have a high energy efficiency and ultrahigh selectivity.In addition,we also suggest a quantum driving source for our quantum-confined superfluid reactions proposed previously.The quantized chemical reaction resonantly driven by multiple MIR photons holds great promise to develop novel approaches for the chemical engineering in future.