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Seismic Response Analysis of Steel Structure Isolation System Under Long-Period Seismic Motion
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作者 Long Yu Mei Sheng +1 位作者 Huan Feng Jianan Hu 《Journal of Architectural Research and Development》 2024年第3期147-155,共9页
To analyze the seismic response of steel structure isolation systems under long-period seismic motion,a 9-story steel frame building was selected as the subject.Five steel structure finite element models were establis... To analyze the seismic response of steel structure isolation systems under long-period seismic motion,a 9-story steel frame building was selected as the subject.Five steel structure finite element models were established using SAP2000.Response spectrum analysis was conducted on the seismic motion to determine if it adhered to the characteristics of long-period seismic motion.Modal analysis of each structural model revealed that the isolation structure significantly prolonged the structural natural vibration period and enhanced seismic performance.Base reactions and floor displacements of various structures notably increased under long-period seismic motion compared to regular seismic activity.Placing isolation bearings in the lower part of the structure proved more effective under long-period seismic motion.In seismic design engineering,it is essential to consider the impact of long-period seismic motion on structures and the potential failure of isolation bearings. 展开更多
关键词 Long-period seismic motion Steel structure mid-story isolation structure isolation bearing Seismic performance
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Seismic response of a mid-story isolated structure considering SSI in mountainous areas under long-period earthquakes 被引量:1
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作者 Wan Feng Qin Shengwu +7 位作者 Liu Dewen Zhao Tiange Zheng Yanping Shan Hang Li Zhiang Peng Fusong Xu Jingran Lei Min 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第1期151-161,共11页
At present,there is not much research on mid-story isolated structures in mountainous areas.In this study,a model of a mid-story isolated structure considering soil-structure interaction(SSI)in mountainous areas is es... At present,there is not much research on mid-story isolated structures in mountainous areas.In this study,a model of a mid-story isolated structure considering soil-structure interaction(SSI)in mountainous areas is established along with a model that does not consider SSI.Eight long-period earthquake waves and two ordinary earthquake waves are selected as inputs for the dynamic time history analysis of the structure.The results show that the seismic response of a mid-story isolated structure considering SSI in mountainous areas can be amplified when compared with a structure that does not consider SSI.The structure response under long-period earthquakes is larger than that of ordinary earthquakes.The structure response under far-field harmonic-like earthquakes is larger than that of near-fault pulse-type earthquakes.The structure response under near-fault pulse-type earthquakes is larger than that of far-field non-harmonic earthquakes.When subjected to long-period earthquakes,the displacement of the isolated bearings exceeded the limit value,which led to instability and overturning of the structure.The structure with dampers in the isolated story could adequately control the nonlinear response of the structure,effectively reduce the displacement of the isolated bearings,and provide a convenient,efficient and economic method not only for new construction but also to retrofit existing structures. 展开更多
关键词 SSI in mountainous areas long-period earthquakes mid-story isolated structure structural dynamic analysis
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Study on the Influence of Aspect Ratio on the Seismic Response and Overturning Resistance of a New Staggered Story Isolated Structure
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作者 Tiange Zhao Dewen Liu 《World Journal of Engineering and Technology》 2024年第3期617-634,共18页
The aspect ratio of the structure has a significant impact on the overall stability of the ultra high-rise building. A large aspect ratio of the structure increases the risk of overturning and reduces the lateral stif... The aspect ratio of the structure has a significant impact on the overall stability of the ultra high-rise building. A large aspect ratio of the structure increases the risk of overturning and reduces the lateral stiffness of the structure, leading to significant tensile and compressive stresses in the isolated bearings. To study the effect of aspect ratio on the seismic response and overturning resistance of a new staggered story isolated structure, three models with different aspect ratios were established. Nonlinear time-history analysis of the three models was conducted using ETABS finite element software. The results indicate that the overturning moment and overturning resistance moment of the superstructure in the new staggered story isolated structure increase with an increasing aspect ratio. However, the increase in the overturning moment of the superstructure is much greater than the increase in the overturning resistance moment, resulting in a decrease in the overturning resistance ratio of the superstructure with an increasing aspect ratio. The overturning moment and overturning resistance moment of the substructure in the new staggered story isolated structure decrease with an increasing aspect ratio. However, the decrease in the overturning moment of the substructure is greater than the decrease in the overturning resistance moment, leading to an increase in the overturning resistance ratio of the substructure with an increasing aspect ratio. The decrease in the overturning resistance ratio of the superstructure in the new staggered story isolated structure is much greater than the increase in the overturning resistance ratio of the substructure. Therefore, as the aspect ratio of the overall structure increases, the overturning resistance ratio of the superstructure and the entire structure decreases. 展开更多
关键词 Aspect Ratio A New Staggered Story isolated structure Seismic Response Overturning Resistance Ratio isolated Bearing
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Seismic Response of Adjacent Structure to Inter-Story Isolated Structure
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作者 Bingxing Ma Dewen Liu +3 位作者 Zhuoxin Yang Jiayu Zhou Yong Ding Tao Ban 《World Journal of Engineering and Technology》 2024年第1期92-102,共11页
Currently, land resources are becoming more and more constrained and structures are getting closer to each other. To investigate the seismic response of inter-story isolated structure to adjacent structure, models con... Currently, land resources are becoming more and more constrained and structures are getting closer to each other. To investigate the seismic response of inter-story isolated structure to adjacent structure, models considering no soil-structure interaction (SSI), considering soil-structure interaction (SSI), and considering structure-soil-structure interaction (SSSI) were established. Nonlinear seismic response comparative analysis was conducted by varying the spacing between adjacent structure and inter-story isolated structure, as well as the weight of adjacent structure, under different earthquake inputs, in order to obtain the structural response characteristics. The results indicate that the inter-story drift and inter-story shear of the inter-story isolated structure without considering SSI are smaller than those considering SSI and SSSI. The inter-story drift and inter-story shear of the inter-story isolated structure considering SSSI are further affected compared to that of the inter-story isolated structure considering only SSI. As the spacing between adjacent structure and inter-story isolated structure increases, the influence of adjacent structure on inter-story isolated structure decreases. The variation in the spacing between the two structures has a negligible effect on the isolation layer of the inter-story isolated structure. With the increase in the weight of adjacent structure, the influence of adjacent structure on inter-story isolated structure becomes more significant. The increasing weight of adjacent structure has an increasing effect on the Isolation layer of the inter-story isolated structure. 展开更多
关键词 Soil-structure Interaction (SSI) structure-Soil-structure Interaction (SSSI) In-ter-Story isolation Adjacent structure
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High-Throughput Growth of Hexagonal Boron Nitride Film Using Porous-Structure Isolation Layer
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作者 Ruitao Jia Fangzhu Qing Xuesong Li 《Journal of Materials Science and Chemical Engineering》 CAS 2023年第3期45-51,共7页
Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitrid... Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitride films are limited to the size of growth chamber, which indicates a lower production efficiency. In this paper, the utilization efficiency of growth chamber is highly improved by alternately stacking multiple pieces of Cu foils and carbon fiber surface felt with porous structure. Uniform and continuous hexagonal boron nitride films are prepared on Cu foils through chemical vapor deposition utilizing ammonia borane as the precursor. This work develops a simple and practicable method for high-throughput preparation of hexagonal boron nitride films, which could contribute to the industrial application of hexagonal boron nitride. . 展开更多
关键词 Hexagonal Boron Nitride Chemical Vapor Deposition Porous structure isolation Layer High Throughput
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A Novel Radiation Tolerant SOI Isolation Structure
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作者 赵洪辰 海潮和 +2 位作者 韩郑生 钱鹤 司红 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第7期1291-1294,共4页
A novel radiation tolerant SOI isolation structure,consisting of thin SiO2/polysilicon/field SiO2 multilayers,is proposed. A device with this structure does not show obvious changes in subthreshold characteristics and... A novel radiation tolerant SOI isolation structure,consisting of thin SiO2/polysilicon/field SiO2 multilayers,is proposed. A device with this structure does not show obvious changes in subthreshold characteristics and leakage current,indicating a superior radiation tolerance to traditional LOCOS. 展开更多
关键词 isolation structure radiation tolerance SOI
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A bio-inspired spider-like structure isolator for low-frequency vibration 被引量:2
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作者 Guangdong SUI Shuai HOU +5 位作者 Xiaofan ZHANG Xiaobiao SHAN Chengwei HOU Henan SONG Weijie HOU Jianming LI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第8期1263-1286,共24页
This paper proposes a quasi-zero stiffness(QZS)isolator composed of a curved beam(as spider foot)and a linear spring(as spider muscle)inspired by the precise capturing ability of spiders in vibrating environments.The ... This paper proposes a quasi-zero stiffness(QZS)isolator composed of a curved beam(as spider foot)and a linear spring(as spider muscle)inspired by the precise capturing ability of spiders in vibrating environments.The curved beam is simplified as an inclined horizontal spring,and a static analysis is carried out to explore the effects of different structural parameters on the stiffness performance of the QZS isolator.The finite element simulation analysis verifies that the QZS isolator can significantly reduce the first-order natural frequency under the load in the QZS region.The harmonic balance method(HBM)is used to explore the effects of the excitation amplitude,damping ratio,and stiffness coefficient on the system’s amplitude-frequency response and transmissibility performance,and the accuracy of the analytical results is verified by the fourth-order Runge-Kutta integral method(RK-4).The experimental data of the QZS isolator prototype are fitted to a ninth-degree polynomial,and the RK-4 can theoretically predict the experimental results.The experimental results show that the QZS isolator has a lower initial isolation frequency and a wider isolation frequency bandwidth than the equivalent linear isolator.The frequency sweep test of prototypes with different harmonic excitation amplitudes shows that the initial isolation frequency of the QZS isolator is 3 Hz,and it can isolate 90%of the excitation signal at 7 Hz.The proposed biomimetic spider-like QZS isolator has high application prospects and can provide a reference for optimizing low-frequency or ultra-low-frequency isolators. 展开更多
关键词 bionic isolation structure curved beam nonlinear stiffness quasi-zero stiffness(QzS) low-frequency vibration isolator
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Influence of Vertical Irregularity on the Seismic Behavior of Base Isolated RC Structures with Lead Rubber Bearings under Pulse-Like Earthquakes
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作者 Ali Mahamied Amjad AYasin +2 位作者 Yazan Alzubi Jamal Al Adwan Issa Mahamied 《Structural Durability & Health Monitoring》 EI 2023年第6期501-519,共19页
Nowadays,an extensive number of studies related to the performance of base isolation systems implemented in regular reinforced concrete structures subjected to various types of earthquakes can be found in the literatu... Nowadays,an extensive number of studies related to the performance of base isolation systems implemented in regular reinforced concrete structures subjected to various types of earthquakes can be found in the literature.On the other hand,investigations regarding the irregular base-isolated reinforced concrete structures’performance when subjected to pulse-like earthquakes are very scarce.The severity of pulse-like earthquakes emerges from their ability to destabilize the base-isolated structure by remarkably increasing the displacement demands.Thus,this study is intended to investigate the effects of pulse-like earthquake characteristics on the behavior of low-rise irregular base-isolated reinforced concrete structures.Within the study scope,investigations related to the impact of the pulse-like earthquake characteristics,irregularity type,and isolator properties will be conducted.To do so,different values of damping ratios of the base isolation system were selected to investigate the efficiency of the lead rubber-bearing isolator.In general,the outcomes of the study have shown the significance of vertical irregularity on the performance of base-isolated structures and the considerable effect of pulse-like ground motions on the buildings’behavior. 展开更多
关键词 Reinforced concrete low-rise structure vertical irregularity the influence of pulse-like earthquake characteristics lead rubber bearing isolators nonlinear response history analysis
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Seismic isolation analysis of FPS bearings in spatial lattice shell structures 被引量:14
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作者 Yong-Chul Kim Xue Suduo +2 位作者 Zhuang Peng Zhao Wei Li Chenghao 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2010年第1期93-102,共10页
A theoretical model of a friction pendulum system (FPS) is introduced to examine its application for the seismic isolation of spatial lattice shell structures. An equation of motion of the lattice shell with FPS bea... A theoretical model of a friction pendulum system (FPS) is introduced to examine its application for the seismic isolation of spatial lattice shell structures. An equation of motion of the lattice shell with FPS bearings is developed. Then, seismic isolation studies are performed for both double-layer and single-layer lattice shell structures under different seismic input and design parameters of the FPS. The influence of frictional coefficients and radius of the FPS on seismic performance are discussed. Based on the study, some suggestions for seismic isolation design of lattice shells with FPS bearings are given and conclusions are made which could be helpful in the application of FPS. 展开更多
关键词 seismic isolation friction pendulum system spatial structure lattice shell parameter analysis
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Adaptive base-isolation of civil structures using variable amplification 被引量:3
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作者 Kenneth K. Walsh Makola M. Abdullah 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2006年第2期223-233,共11页
Semi-active dampers are used in base-isolation to reduce the seismic response of civil engineering structures. In the present study, a new semi-active damping system using variable amplification will be investigated f... Semi-active dampers are used in base-isolation to reduce the seismic response of civil engineering structures. In the present study, a new semi-active damping system using variable amplification will be investigated for adaptive baseisolation. It uses a novel variable amplification device (VAD) connected in series with a passive damper. The VAD is capable of producing multiple amplification factors, each corresponding to a different amplification state. Forces from the damper are amplified to the structure according to the current amplification state, which is selected via a semi-active control algorithm specifically tailored to the system's tmique damping characteristics. To demonstrate the effectiveness of the VAD-damper system for adaptive base-isolation, numerical simulations are conducted for three and seven-story base-isolated buildings subject to both far and near-field ground motions. The results indicate that the system can achieve significant reductions in response compared to the base-isolated buildings with no damper. The proposed system is also found to perform well compared to a typical semi-active damper. 展开更多
关键词 adaptive systems AMPLIFICATION BASE-isolation DAMPING earthquake resistant structures multistorybuildings seismic isolation structural control
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Shaking Table Model Test of Isolated Structure on Soft Site and Analysis on Its Isolation Efficiency 被引量:3
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作者 Yu Xu Zhuang Haiyang Zhu Chao 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2017年第2期169-176,共8页
Adopting a soft site model built on soft interlayer soil foundation,a shaking table test for soft interlayer soil-isolated structure interaction is conducted to investigate the seismic response of isolated structure o... Adopting a soft site model built on soft interlayer soil foundation,a shaking table test for soft interlayer soil-isolated structure interaction is conducted to investigate the seismic response of isolated structure on soft site,and analyze its isolation effect.Test results show that the test can reflect the earthquake response characteristics of isolated structure on soft site.It is on soft site that the dynamic characteristics of isolated structure,acceleration magnification factor(AMF)of isolated structure and isolation efficiency of the isolation layer differ from those on rigid foundation with an soil-structure interaction(SSI)effect,represented by the reduction in fundamental vibration frequency of isolated structure and the increase of damping ratio with changes of the SSI effect.SSI can either increase or decrease AMF of isolated structure on soft site,depending on the characteristics of earthquake motion input.Furthermore,the isolation efficiency of isolation layer on soft site is decreased with the SSI effect,which is related to the peak ground acceleration(PGA)and the characteristics of earthquake motion input. 展开更多
关键词 isolated structure shaking table model test soil-structure interaction(SSI) seismic response isolation efficiency
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A new isolation device using shape memory alloy and its application for long-span structures 被引量:3
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作者 Ding Youliang Chen Xin +1 位作者 Li Aiqun Zuo Xiaobao 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2011年第2期239-252,共14页
The key points to consider in determining the effectiveness of using structural isolation with shape memory alloys (SMA) are the constitutive model, the SMA isolation device and the analysis method. In this paper, a... The key points to consider in determining the effectiveness of using structural isolation with shape memory alloys (SMA) are the constitutive model, the SMA isolation device and the analysis method. In this paper, a simplified constitutive model based on the classic theory of plasticity is proposed to simulate the behavior of the superelasticity of the SMA, in which the martensite volume fraction is considered as one of the state variables. Comparisons between simulation results and experimental results are made and indicate that the proposed constitutive model yields stress-strain curves that are in good agreement with the experimental ones. Thus, the proposed model can correctly simulate the yield mechanism and energy dissipation capacity of the SMA. Next, in order to make full use of the superelasticity of SMA, a new SMA isolator composed of pre-tensioned SMA bars is presented. Then, a finite element analytical model is established to simulate the behavior of the SMA isolator according to its configuration and simplified constitutive model. Finally, a simplified design method for long-span structures installed with SMA isolators is proposed, which is further used to investigate the isolation effects of a space grid structure. Results show that the SMA isolator can reduce the seismic responses of the structure effectively, which indicates the effectiveness of the proposed SMA isolation method. 展开更多
关键词 shape memory alloy super-elasticity constitutive model seismic response structural isolation space gridstructure
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Isolation, Crystal Structure and Antitussive Activity of 9S,9aS-neotuberostemonine 被引量:2
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作者 吴旖 叶青美 +3 位作者 刘敬 徐未 朱自荣 江仁望 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2018年第4期571-576,共6页
The title compound 9S,9aS-neotuberostemonine (1) was isolated from the 95%ethanol extract of the roots of Stemona tuberosa. The crystal structure of 1, C22H33NO4, wasdetermined by single-crystal X-ray diffraction an... The title compound 9S,9aS-neotuberostemonine (1) was isolated from the 95%ethanol extract of the roots of Stemona tuberosa. The crystal structure of 1, C22H33NO4, wasdetermined by single-crystal X-ray diffraction analysis. The crystal belongs to orthorhombicsystem, space group P212121, with a-9.0115(11), b = 10.612(4), c = 22.074(3) A, V= 2110.9(8)S^3, Z= 4, Mr= 375.49, Dc= 1.182 g/cm3, λ= 0.71079 A,μ= 0.080 cm^-1, F(000) = 816, S = 1.019,R = 0.0579 and wR = 0.1358. A total of 3109 unique reflections were collected, of which 2902were observed (I〉 2σ(I)). The absolute configuration of 1 could be assigned by referring to theconserved configuration of the methyl groups at C(13) and C(20). In the solid state, the moleculeswere linked into a chain along the a-axis through weak hydrogen bond C(ll)-H(11A)…O(2).Compound 1 shows significant inhibition of cough by 24%, 44% and 65% at doses of 50, 100 and150 mg/kg, respectively. 展开更多
关键词 9S 9aS-neotuberostemonine isolation crystal structure ANTITUSSIVE
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A Multi-level Approach for Complex Fault Isolation Based on Structured Residuals 被引量:4
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作者 叶鲁彬 石向荣 梁军 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第3期462-472,共11页
In industrial processes,there exist faults that have complex effect on process variables.Complex and simple faults are defined according to their effect dimensions.The conventional approaches based on structured resid... In industrial processes,there exist faults that have complex effect on process variables.Complex and simple faults are defined according to their effect dimensions.The conventional approaches based on structured residuals cannot isolate complex faults.This paper presents a multi-level strategy for complex fault isolation.An extraction procedure is employed to reduce the complex faults to simple ones and assign them to several levels.On each level,faults are isolated by their different responses in the structured residuals.Each residual is obtained insensitive to one fault but more sensitive to others.The faults on different levels are verified to have different residual responses and will not be confused.An entire incidence matrix containing residual response characteristics of all faults is obtained,based on which faults can be isolated.The proposed method is applied in the Tennessee Eastman process example,and the effectiveness and advantage are demonstrated. 展开更多
关键词 MULTI-LEVEL structured residuals principal component analysis complex fault isolation Tennessee Eastman process
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ISOLATION AND STRUCTURES OF FOUR CYCLODIPEPTIDES 被引量:2
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作者 Jing Yu SU Yong Li ZHONG +2 位作者 Long Mei ZENG Wei SHEN Qi Wen WANG 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第2期139-140,共2页
Three novel interesting polychlorinated cyclodipeptides,designated dyssmide A(1),B(2),C(3)and a known compound,2,3-dihydrodyeamide C(4)were isolated from the sponge Dysidea sp.Their structures were elucidated by spect... Three novel interesting polychlorinated cyclodipeptides,designated dyssmide A(1),B(2),C(3)and a known compound,2,3-dihydrodyeamide C(4)were isolated from the sponge Dysidea sp.Their structures were elucidated by spectroscopic methods. 展开更多
关键词 CCI IR isolation AND structureS OF FOUR CYCLODIPEPTIDES
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ISOLATION, STRUCTURE ELUCIDATION AND SYNTHESIS OF A NEW PRENYLATED FLAVONOL, MAACKIAFLAVONOL, FROM MAACKIA TENUIFOLIA 被引量:2
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作者 Jian Hua SHEN, Lan WANG and Bing Nan ZHOU State Key Laboratory for New Drug Research, Shanghai Institute of Materia Medica, Academia Sinica, Shanghai 200031 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第8期629-630,共2页
A new prenylated flavonol, maackiaflavonol, was isolated from the ethanol extract of the roots of Maackia tenuifolia. Its structure was elucidated as 7-hydrox-8-prenylflavonol by means of spectroscopic analysis (UV, I... A new prenylated flavonol, maackiaflavonol, was isolated from the ethanol extract of the roots of Maackia tenuifolia. Its structure was elucidated as 7-hydrox-8-prenylflavonol by means of spectroscopic analysis (UV, IR, MS, NMR and 1H-1H COSY) and confirmed by total synthesis. 展开更多
关键词 isolation MAACKIAFLAVONOL structure ELUCIDATION AND SYNTHESIS OF A NEW PRENYLATED FLAVONOL FROM MAACKIA TENUIFOLIA
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ISOLATION AND STRUCTURE ELUCIDATION OF A NOVEL STEROL FROM THE SOUTH CHINA SEA SPONGE DYSIDEA SP. 被引量:3
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作者 Yong Li ZHONG Jing Yu SU Long Mei ZENG Department of Chemistry,Zhongshan University,Guangzhou,510275 Wei SHEN Qi Wen WANG State Key Laboratory of Bioorganic and Natural Products Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Science,Shanghai,200032 《Chinese Chemical Letters》 SCIE CAS CSCD 1992年第12期981-982,共2页
A novel and unusual sterol with unsaturation in the△^(5(14)) position,5α-cholesta-8(14),24(25)-diene-3β,6α-diol 1,was isolated from the South China Ses sponge Dysidea sp.The structure and relative stereochemistry ... A novel and unusual sterol with unsaturation in the△^(5(14)) position,5α-cholesta-8(14),24(25)-diene-3β,6α-diol 1,was isolated from the South China Ses sponge Dysidea sp.The structure and relative stereochemistry of 1 was established by spectral analysis and comparison to the spectral data of known sterols. 展开更多
关键词 isolation AND structure ELUCIDATION OF A NOVEL STEROL FROM THE SOUTH CHINA SEA SPONGE DYSIDEA SP 二七 SEA
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Research and development of seismic base isolation technique for civil engineering structures 被引量:1
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作者 Zhu Hongping Mei Shilong +2 位作者 Li Li Ye Kun Yuan Yong 《Engineering Sciences》 EI 2010年第1期16-21,共6页
Base isolation is one of the most promising alternatives among the structure control methods. In recent decades, base isolation has been seriously considered for civil structures, such as buildings and bridges, subjec... Base isolation is one of the most promising alternatives among the structure control methods. In recent decades, base isolation has been seriously considered for civil structures, such as buildings and bridges, subjected to ground motion. The research achievements and development of seismic base isolation technique for civil structures in Huazhong University of Science and Technology (HUST) are introduced. The achievements include project applications, experimental research results and theoretical innovation. 展开更多
关键词 seismic base isolation civil structures DEVELOPMENT APPLICATION
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Isolation and Structure Elucidation of an Antifungal Antibiotics A73 Produced by a Soil Fungus Strain No.131
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作者 YANG Jun QI Xiu-lan +2 位作者 SHAO Gang YAO Xin-sheng Susumu Kitanaka 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1999年第1期85-88,共4页
IntroductionMorphologicaldeformationofmyceliaorconidiaofmicroorganisms,suchascurling,sweling,hyper-divergenc... IntroductionMorphologicaldeformationofmyceliaorconidiaofmicroorganisms,suchascurling,sweling,hyper-divergency,beadformation,a... 展开更多
关键词 Antifungal antibiotics isolation structure elucidation A73
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Isolation and Crystal Structure of 4β,6α,9α-Trimethy-2-carboxyltricyclo[6.3.0.0^(4,5)]undec-2-ene
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作者 施树云 吴迪瑶 赵昱 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第9期1045-1048,共4页
The title compound, 4β,6α,9α-trimethy-2-carboxyltricyclo[6.3.0.0^(4,5)]undec-2-ene, is a sesquiterpene which was first isolated from Ligularia caloxantha and characterized by MS and NMR. In addition, the structur... The title compound, 4β,6α,9α-trimethy-2-carboxyltricyclo[6.3.0.0^(4,5)]undec-2-ene, is a sesquiterpene which was first isolated from Ligularia caloxantha and characterized by MS and NMR. In addition, the structure was determined by X-ray single-crystal diffraction. It crystallizes in orthorhombie, space group P212121 with a = 8.197(2), b = 14.876(3), c = 22.281(6) A, α = β = γ = 90°, V = 2716.9(11) ]A^3, Z = 8, C15H22O2, Mr = 234.34, Dc = 1.146 g/cm^3, μ(MoKa) = 0.074 mm^-1, F(000) = 1024, the final R = 0.0384 and wR = 0.0856 for 6200 independent reflections (Rint = 0.066) and 2538 observed ones (I 〉 2σ(I)). In the molecule, there are three fused five-membered rings; while in this crystal form, the asymmetric unit contains two molecules of the same hand and they are linked together by two intermolecular O-H...O hydrogen bonds to form a dimer. 展开更多
关键词 Ligularia caloxantha isolation crystal structure 9α.trimethy-2-carboxyltricyclo[6.3.0.0^(4 5)]undec-2-ene
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