In Situ Analyses of Trace Elements, U–Pb and Lu–Hf Isotopes in Zircons from the Tongshankou Granodiorite Porphyry in Southeast Hubei Province, Middle-Lower Yangtze River Metallogenic Belt, China

The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.

Intensification of the East Asian Monsoon in Southern China at about300-400 kaBP Inferred from Eolian Deposits in the Middle-lower Reaches of the Yangtze River

In the East Asian monsoon region, eolian deposits widely distributed in the middle-lower reaches of the Yantgze River are among the best materials available for studies on Quaternary climate change in the subtropical zone of Southern China. Typical eolian deposits in this region include upper Xiashu Loess （XL） and underlying Vermiculated Red Soil （VRS） layers. In this paper, chronological and paleoclimatic studies are conducted on an eolian deposit sequence near Jiujiang （J J） city in northern Jiangxi province. A magnetostratigraphic study, combined with optically stimulated luminescence （OSL） dating, is conducted on the JJ section and provides further evidence that eolian deposits in the middle-lower reaches of the Yangtze River have been formed since the late Early Pleistocene, and that the boundary age between the XL and VRS layers is about 300-400 kaBP. In grain-size records of the JJ section, the median grain-size and content of the 〉30μn size fraction increase sharply after 300-400 kaBP, representing an East Asian winter monsoon intensification event. Further pollen analysis reveals differing pollen assemblages before and after 300-400 kaBP： there is an evident increase in plants adapted to grow in a warm humid environment after 300-400 kaBP, implying an increase in precipitation caused by intensification of the East Asian summer monsoon. Global ice volume and uplift of the Tibet Plateau （TP） are regarded as crucial factors influencing variations of the East Asian monsoon on a long-term scale. The deep-sea JlSO record, which reflects variations in global ice volume, shows no obvious change after 300-400 kaBP. Moreover, the influence of global ice volume changes on the East Asian summer and winter monsoons is inverse; the global ice volume increase （decrease） implies a strengthened （weakened） winter monsoon and weakened （strengthened） summer monsoon. We therefore interpret the coupled intensifications of the East Asian summer and winter monsoons at about 300-400 kaBP to the uplift of the TP in the Middle Pleistocene. This climate event is also documented in eolian deposits from the southern margin of the Chinese Loess Plateau （CLP） and from the desert-loess transitional belt. However, it is not recorded in the loess-paleosol sequences from the central part of the CLP, thereby indicating differing climate responses to TP uplift in different regions, which requires further study.

Discovery of Lorandite TlAsS_2 at the Distal Au-Tl Deposit in a Skarn system,Fengshan Area,Middle-Lower Yangtze River,Eastern China

Thallium has been used geochemical exploration of gold deposits. However, as an indicator element in searching for hydrothermal the T1 minerals and mineralization are rare in nature. Lorandite T1AsS2, a relatively uncommon mineral, has been dominantly discovered in some Carlin gold deposits, and minor Sb- Hg, U and Pb-Zn-Ag deposits.

Preliminary study on the depositional model in the wavedominated delta evolution during the Anthropocene:a case study of the Hanjiang River Delta in China

The deltas serve as the primary interactive zone where terrestrial and marine environments converge,playing a pivotal role in the coastal deposition.In the Holocene,climate changes and sea level fluctuation are the principal driving factors in the evolution of deltas.However,human activities such as the construction of dams and reservoirs in the Anthropocene have significantly altered sediment transport in rivers,leading to depositional pattern variation during deltaic evolution.In this study,we have conducted a comparative analysis of the morphological variations(1986-2021)in the barrier system of the Hanjiang River Delta(HRD)using satellite remote sensing(SRS)method.Additionally,we have examined the lithological changes and facies alterations observed in eight boreholes on the present barrier spit.Our findings indicate that the intensification of anthropogenic activities led to a significant reduction in the sediment flux of the Hanjiang River(HR),resulting in depocenter landward migration at the estuary.SRS analysis reveals their periodical morphological characteristics and spatial variations of estuarine sandbars(1986-1992),barrier islands-lagoons(1993-2009),and barrier spits(2010-2021)during 1986 to 2021.The stratigraphy of boreholes demonstrates a south-to-north facies transition from lagoon to lagoon-barrier spit and barrier spit in vertical lithology.Therefore,the depositional evolution of the HRD barrier system is categorized into three phases:estuarine sandbar-barrier island phase(1986-1998);barrier island-lagoon phase(1999-2009);and barrier spit phase(2010-2021).During the estuarine sandbar-barrier island phase,fluvial processes played a predominate role in the deposition.Consequently,with a significant decrease in river sediment load,the dominant factors driving depositional processes shifted towards wave action and alongshore current.Based on the conceptual model in the Holocene,we propose a modified depositional model of wave-dominated deltas during Anthropocene that encompasses three evolutionary phases:estuarine sandbars and delta front platforms,barrier island-lagoon formation and landward migration of barrier spits.This pattern highlights that human-induced reduction in river sediment flux has led to a seaward deltaic progradation driven by barrier landward migration.

Impact of Water-Sediment Regulation on Variations of Amino Acids in the Middle-Lower Yellow River, China

In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analyzed their specific amino acids(AA),DOC,POC,and bacteria abundance.Summarized by 14 specific AA,the total hydrolysable AA(THAA),particulate AA(PAA),and sediment AA(SAA)varied in ranges of 2.29-9.05μmol L^-1,5.22-22.96μmol L^-1,and 81.7-137.19μg g^-1 dry weight.After the regulation,dissolved free AA(DFAA)decreased by 29%while DCAA increased by 72%.These variations suggested that DFAA were further degraded,while DCAA molecules were further activated.Meanwhile,PAA increased almost 4 times as many as those before regulation,and SAA increased as well.After regulation,the amounts of bioactive amino acids(Asp,Glu and Gly)increased in THAA but decreased in PAA,with little changes in SAA.The ratios of Asp/Gly in different phases increased after regulation,indicating the AA contributions were promoted by calcareous organisms rather than by siliceous organisms.Multiple correlation analysis showed that PAA was primary representatives of AA and organic carbon,followed by DCAA and POC.Moreover,bacterial reproduction played a key role in shaping the AA compositions and properties,followed by the redox condition and acid-base balance.The results of this study provided a clear evidence for the effects of water-sediment regulation on regional biogeochemistry of organic carbon in the middle-lower Yellow River.

Cathodoluminescence and Trace Element Composition of Scheelite from the Middle-Lower Yangtze River Metallogenic Belt(MLYB): Implications for Mineralization and Exploration

The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovered in the MLYB during recent decades.The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood.We investigate four sets of scheelite samples from tungsten,iron and copper deposits,using CL imaging and LA-ICP-MS techniques to reveal internal zonation patterns and trace element compositions.The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies.The oxygen fugacity of ore-forming fluid increased in Donggushan,while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan,Guilinzheng and Gaojiabang.The scheelites from the Donggushan,Ruanjiawan,Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE,with Nb/La ratios ranging from 1.217 to 52.455,indicating that the four tungsten deposits are enriched in the volatile fluorine.A plot of(La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type,porphyry and skarn tungsten deposits.This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.

Molybdenite Re-Os,titanite and garnet U-Pb dating of the Magushan skarn Cu-Mo deposit,Xuancheng district,Middle-Lower Yangtze River Metallogenic Belt

The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age of an ore deposit is important for understanding the timing of mineralization relative to other geological events in a region and to fully place the formation of a mineral deposit within the geological context of other processes that occur within the study area.Here,we present new molybdenite Re-Os and titanite and andradite garnet U-Pb ages for the Magushan deposit and use these data to outline possible approaches for identifying genetic relationships in geologically complex areas.The spatial and paragenetic relationships between the intrusions,alteration,and mineralization within the study area indicates that the formation of the Magushan deposit is genetically associated with the porphyritic granodiorite.However,this is not always the case,as some areas contain complexly zoned plutons with multiple phases of intrusion or mineralization may be distal from or may not have any clear spatial relationship to a pluton.This means that it may not be possible to determine whether the mineralization formed as a result of single or multiple magmatic/hydrothermal events.As such,the approaches presented in this study provide an approach that allows the identification of any geochronological relationships between mineralization and intrusive events in areas more complex than the study area.Previously published zircon U-Pb data for the mineralization-related porphyritic granodiorite in this area yielded an age of 134.2±1.2 Ma(MSWD=1.4)whereas the Re-Os dating of molybdenite from the study area yielded an isochron age of 137.7±2.5 Ma(MSWD=0.43).The timing of the mineralizing event in the study area was further examined by the dating of magmatic accessory titanite and skarn-related andradite garnet,yielding U-Pb ages of 136.3±2.5 Ma(MSWD=3.2)and 135.9±2.7 Ma(MSWD=2.5),respectively.The dating of magmatic and hydrothermal activity within the Magushan area yields ages around 136 Ma,strongly suggesting that the mineralization in this area formed as a result of the emplacement of the intrusion.The dates presented in this study also provide the first indication of the timing of mineralization within the Xuancheng district.providing evidence of a close genetic relationship between the formation of the mineralization within the Xuancheng district and the Early Cretaceous magmatism that occurred in this area.This in turn suggests that other Early Cretaceous intrusive rocks within this region are likely to be associated with mineralization and should be considered highly prospective for future mineral exploration.This study also indicates that the dating of garnet and titanite can also provide reliable geochronological data and evidence of the timing of mineralization and magmatism,respectively,in areas lacking other dateable minerals(e.g.,molybdenite)or where the relationship between mineralization and magmatism is unclear,for example in areas with multiple stages of magmatism,with complexly zoned plutons,and with distal skarn mineralization.

A PREDICTION ABOUT THE EFFECT OF THE BUILDING OF SHUIKOU HYDROPOWER STATION ON THE ECOLOGICAL ENVIRONMENT OF THE MIDDLE-LOWER REACHES OF THE MINJIANG RIVER

The building of Shuikou Hydropower Station in the Minjiang River is the largest one in the region of east China. Its install capacity is 1.4 million kw., and its generated energy of planning is 4.95 billion kwh each year. In accordance with a comprehensive survey of the valley of the middle-lower reaches of the Minjiang River and the characteristic of hydrography and in association with the specific type of the hydrography station, we can be sure that no harm will be done to the ecological environment when a hydropower station is built at Shuikou. Not only the deposition of silt within the reservoir must not be very serious, it is also more favorable than before for the irrigation of farmland on plains in the lower reaches of the Minjiang River and inland navigation.In addition, after the completion of the power station, the ecological environment will be the same as before both at the Minjiang River estuary and beyond it.

Flood and Waterlogging Disaster Damage Evaluation in Middle-Lower Yangtze River by 3S technology

The evaluation method, model and process for the flood and waterlogging disaster condition by GIS,RS and GPS technology and the method for setting up disaster condition database, dyke database and historical disaster damage database are presented. An index of flood damage degree(FDD) used to evaluate the relative degree of disaster loss and divide flood and waterlogging area is suggested. The value of flood damage degree can be calculated as follows :taking the various disaster losses of sample area in a base year as standard value and computing the ratios of various disaster loss values in different areas and years to the standard flood disaster loss values, then summing up the weighted ratios. The computed results are the value of flood damage degree in the every year. The macroscopic flood disaster distribution can be evaluated by the values of flood loss degree.

Tectonodynamic Adjustment of Crustal Materials in the Middle-Lower Reaches of the Yangtze River

Under the tectonodynamic process, crustal materials tend to experience two modes of adjustment: (1) structural (physical) adjustment, manifested by folding, faulting, uplifting, downwarping, etc.: (2) compositional adjustment, represented by element migration, concentration and dispersion, crystalline and dynamic differentiation of crystals, metamorphism, etc. (Yang Kaiqing. 1986; Yang Kaiqing et al., 1986). The dynamic adjustment of crustal materials in the middle-lower reaches of the Yangtze mainly occurred in the Mesozoic under the conditions of intense collision between the North China (Dabie) massif and the Yangtze massif. The structural adjustment refers to various types of deformation within the two massifs and the intensive shortening of the stratigraphic coyer of the Yangtze massif, whereas the compositional adjustment implies the structural remelting of the basement and the ore. and rock- forming processes in the two massifs.

Detrital Zircon Ages of Hanjiang River:Constraints on Evolution of Northern Yangtze Craton,South China

Clastic sedimentary rocks are natural samples of the exposed continental crust over large areas. The Hanjiang （汉江） River drains the northern Yangtze craton, including the South Qinling （秦岭） belt and the northern parts of the Yangtze craton. Detrital zircons from this river thus provide an ideal sample for studying the formation and evolution of the northern Yangtze craton. Here we report laser ablation inductively coupled plasma mass spectrometer U-Pb ages of 122 detrital zircons from one sand sample of the Hanjiang River. The 110 concordant zircons reveal four major age groups of 768, 444, 212, and 124 Ma, which well correlate with known magmatic events in the northern Yangtze craton. A minor group is present at 1 536 Ma, which is less known in the study area. Only seven zircons have ages of 〉1 750 Ma. Our results show that the Early Paleozoic, Late Triassic, and Early Cretaceous are important episodes of zircon growth and crustal growth/reworking in addition to the previously documented Neoproterozoic event. Our results suggest very limited exposures of Paleoproterozoic and Archean rocks in the northern parts of the Yangtze craton.

Large-scale Migration of Fluids toward Foreland Basins during Collisional Orogeny: Evidence from Triassic Anhydrock Sequences and Regional Alteration in the Middle-Lower Yangtze Area

The middle-lower Yangtze area underwent a series of complex tectonic evolution, such as Hercynian extensional rifting, Indosinian foreland basining, and Yanshanian transpression-transtension, resulting in a large distinctive Cu-Fe-Au metallogenic belt. In the tectonic evolution, large-scale migration and convergence of fluids toward foreland basins induced during the collisional orogeny of the Yangtze and North China continental blocks were of vital importance for the formation of the metallogenic belt. Through geological surveys of the middle-lower Yangtze area, three lines of evidence of large-scale fluid migration are proposed: (1) The extensive dolomitic and silicic alteration penetrating Cambrian-Triassic strata generally occurs in a region sandwiched between the metallogenic belt along the Yangtze River and the Dabie orogenic belt, and in the alteration domain alternately strong and weak alteration zones extend in a NW direction and are controlled by the fault system of the Dabie orogenic belt; it might record the locus of the activities of long-distance migrating fluids. (2) The textures and structures of very thick Middle-Lower Triassic anhydrock sequences in restricted basins along the river reveal the important contribution of the convergence of regional hot brine in restricted basins and the chemical deposition or their formation. (3) Early-Middle Triassic syndepositional iron carbonate sequences and Fe-Cu-Pb-Zn massive sulfide deposits alternate with anhydrock sequences or are separated from the latter, but all of them occur in the same stratigraphic horizon and are intimately associated with each other, being the product of syndeposition of high-salinity hot brine. According to the geological surveys, combined with previous data, the authors propose a conceptual model of fluid migration-convergence and mineralization during the Dabie collisional orogeny.

Cosmogenic 26Al/10Be Burial Dating of the Birth of the Present Hanjiang River

Objective Structural lows and major rift systems provide the basis for the creation of large rivers.The uplift of the Qinling and Daba Mountains structural belts and Tibetan Plateau would have provided the basis for the origin and northwest–southeast flow of the ancient Hanjiang River(Lu et al.,2018).After a long-term evolution,the present pattern of Hanjiang River has been formed.Five to six river terraces in the Hanzhong and Yunxian basins along the flanks of Hanjiang River valleys had been identified and some terraces had been dated by using optically stimulated luminescence(OSL),paleomagnetic,and electron spin resonance(ESR)dating methods,and correlating the pedostratigraphy and magnetic susceptibility with the Luochuan loess section by our team(Sun et al.,2016,2017).These terraces are composed of fluvial deposits overlaid with eolian deposits,and record the evolution history of the Hanjiang River.(Fig.1).This study is aimed to deduce the birth time of the present Hanjiang River by using 26Al/10Be burial dating method to date the highest fluvial terraces of the Hanjiang River.

GLOBAL WARMING EFFECTS ON THE HANJIANG RIVER HYDROLOGICAL REGIMES

The paper, based on a semi-conceptual hydrological model, analysed global warming effects on the Hanjiang River hydrological regimes and water resources, including soil moisture, evaporation, runoff and the transferable water quantity from the Danjiangkou Reservoir according to Middle Route of China's South-to-North Water Transfer Project.

水动力学模型的实时组合校正方法研究

受降雨分布不均、地形复杂多变及模型结构等因素限制,水动力学模型的水位模拟精度难以进一步提升。为此,基于一维水动力学模型运行结果,建立了涵盖KNN、SVR、LSTM、GRU等多种智能算法的实时校正模型,并将KNN校正法与WF算法串联耦合,提出了具有降噪功效的KNN-WF校正方法,在此基础上,为充分挖掘各校正算法在不同水位区间的校正优势,提出了一种基于M分位数的水位分级组合校正方法,以均方根误差、决定系数和峰值相对误差综合比较分析各校正方法的校正效果。汉江流域应用结果表明,KNN-WF校正法能有效避免KNN校正结果中存在的噪声和锯齿状峰值,校正后的水位过程与实测水位过程更加吻合,分级组合校正方法能实现不同水位区间的精细化校正从而提升整体校正效果。

The Greening Situation and Developing Countermeasures along the Han River——Taking Chaozhou Downtown Part as an Example

Hanjiang is the main river in Chaozhou. The urban sections on both sides of it are large-scale landscape zones which combine the natural landscape and the cultural landscape. Aiming at better manifesting the geographical features and pro-moting the sustainable development of the ecological environment on both sides of the Hanjiang River, the research, with the reach between the Jinshan River and the Hanjiang River as an example, pointed out the existing problems and put forward some constructive suggestions based on a thorough survey on the plant species and the rationality of plant configuration and the afforstation managements, in order to provide reference for the decision-maker of the further planning and construction of this area.

韩江流域生态文明建设的实践探索

2020年,习近平总书记到潮州市视察时作出“让韩江秀水长清”的重要指示。近年来,粤东地区通过抓好顶层设计、强化组织引领,坚持精准施策、提高治理能力,基本实现建设与宣传并重、生态与经济共赢,韩江流域生态文明建设呈现持续向好的发展态势。为进一步贯彻落实习近平总书记的重要指示,积极践行习近平生态文明思想的粤东实践,必须高度重视并严格遵循人与自然是生命共同体原则、经济发展与生态保护协同共进原则、生态文明建设系统推进原则,在“六个必须坚持”科学方法的指导下探索韩江流域生态文明建设的实践路径。

中国式现代化视域下韩江流域生态文明建设:理念、方法与路径

人与自然和谐共生是中国式现代化的中国特色和本质要求。推进韩江流域生态文明建设,必须坚持以习近平生态文明思想为根本遵循、以绿美广东建设提升行动为抓手、以韩江流域生态资源禀赋为出发点,坚持习近平生态文明思想的世界观、方法论,通过持续植绿扩绿护绿做大“绿蛋糕”,减污节约降碳做优“绿蛋糕”,畅通“生态美、产业兴、百姓富”的转化通道,把“绿蛋糕”转化为“金蛋糕”,在书写中国式现代化建设中绘出韩江流域美丽画卷。

3-D isotropic and anisotropic tomography of P-wave travel times from the Anhui airgun experiment in the Yangtze River

The Middle-Lower Yangtze River is a typical transition region between the nearly NW-oriented Tethys and NE-trending Pacific tectonic regimes.Structures of different periods and directions overlap strongly during these processes.The NE-trending Yangtze River compound structural belt and NW-trending Tongling-Hangzhou structural belt both control the magmatic activities and distributions of the metallogenic belts in the area.Here,we obtain 3-D high-resolution isotropic and azimuthally anisotropic velocity structures at depths of 1–10 km using the first arrivals from airgun sources.The velocity maps correspond well with the tectonic structures,with high-velocity anomalies distributed in ore-concentrated districts and low-velocity anomalies distributed along the Yangtze River.The fast directions are generally consistent with the fault strike,indicating that the azimuthal anisotropy is mainly dominated by the fault and fracture trends in the upper crust.The complicated fast directions near the Luzong and Tongling ore deposits reveal complex deformations in the upper crust,which are mainly caused by the intersection of the Yangtze River compound and Tongling-Hangzhou structural belts.The magma intrusion beneath the two ore deposits(Luzong and Tongling)are connected at depths of 5–10 km.

气候变暖背景下汉江流域降水和气温时空变化特征

为探究气候变暖背景下汉江流域降水和气温的时空发展规律,基于汉江流域及其周边地区29个气象站点逐日降水(P_(re))、最高气温(T_(max))、最低气温(T_(min))和平均气温(T_(ave))的观测资料,利用线性拟合、Mann-Kendall突变检验和空间插值等方法,分析1960~2019年汉江流域降水和气温的时空变化特征,以及对变暖停滞现象(Hiatus)的响应。结果表明:①在全球变暖背景下,汉江流域气候表现出降水不显著减少(p>0.05)、气温显著上升(p<0.05)的暖干化趋势。1960~2019年汉江流域P_(re)变化幅度夏季(0.582 mm/a)>秋季(-0.477 mm/a)>春季(-0.403 mm/a)>全年(-0.184 mm/a)>冬季(0.125 mm/a);全年升温幅度呈T_(min)(0.028℃/a)>T_(max)(0.025℃/a)>T_(ave)(0.022℃/a),四季T_(max)、T_(min)和T_(ave)一致呈上升趋势,多数升温趋势通过了显著性检验(p<0.05),但升温幅度存在明显差异。②汉江流域全年和夏季P_(re)均未发生突变,春、秋季P_(re)在1970年代中后期发生突变下降,冬季P_(re)在1984年突变增加;除夏季T_(max)和T_(ave)外,其余时序气温集中在1990年代中后期至2000年代前期发生了突变上升。③汉江流域全年P_(re)自东南向北递减,四季P_(re)空间分布规律各异,全年和四季T_(max)、T_(min)和T_(ave)皆自南向北递减;全年及四季P_(re)、T_(max)、T_(min)和T_(ave)变化趋势具有较强的空间异质性。④1998~2012年汉江流域出现Hiatus现象,尤其以冬季最为明显;停滞后春夏季快速增温,秋冬季依旧呈降温趋势。研究成果对于制定汉江流域防灾减灾、供水保障应对策略具有重要的科学意义。