Highway frost heave and thawing settlement caused by water migration towards the freezing front and ice lens development is widespread in the alpine meadow area of the southeast QinghaiTibet Plateau(QTP). A laboratory...Highway frost heave and thawing settlement caused by water migration towards the freezing front and ice lens development is widespread in the alpine meadow area of the southeast QinghaiTibet Plateau(QTP). A laboratory experiment on a highway reconstruction and expansion project in the QTP was carried out in this work to analyze the effects of fine particle content, initial water content, and the number of freeze-thaw cycles(FTCs) on frost depth, temperature gradient(Grad T), total water intake, and water intake flux. Based on the results of the laboratory experiment, a modified model of migration potential related to fine particle content, freeze-thaw history, and freezing time was established. The results show that, with the increase of fine particle content, the frost depth of soil decreases, the curve of total water intake over time is transformed from an Sshape to an arch, and the curve of water intake flux over time is transformed from a peak shape to descending shape. The variation trend of migration potential with freezing time and the freeze-thaw history is the same as that of water intake flux with freezing time and freeze-thaw history. The variation trend of soil intake flux can be used as a reference to determine the variation trend of soil migration potential. This study provides a reference for the design and construction of highway subgrade in the alpine meadow area of the QTP.展开更多
Na superionic conductor(NASICON)-type La_(0.33)Ti_(2)(PO_(4))_(3)(LaTP) is firstly proposed as sodium/potassium storage materials.The density functional theory(DFT) calculations show that LaTP has good electronic char...Na superionic conductor(NASICON)-type La_(0.33)Ti_(2)(PO_(4))_(3)(LaTP) is firstly proposed as sodium/potassium storage materials.The density functional theory(DFT) calculations show that LaTP has good electronic character and low Na^(+)/K^(+)migration barriers.The flexible La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofiber film is synthesized via electrostatic spinning and investigated as free-standing electrode applied to sodium-ion batteries(SIBs) and potassiumion batteries(PIBs) in this work.The low band gap and Na^(+)/K^(+) migration barriers of LaTP,unique morphology,and complete conductive carbon net allow the La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofibers film to deliver high capacity(296.3 mAh·g^(-1) for SIBs and 235.8 mAh·g^(-1) for PIBs),excellent rate performance(142.5 mAh·g^(-1) for SIBs and50.5 mAh·g^(-1) for PIBs at 1.00 A·g^(-1)),and superior cyclability above 1000 cycles.The full-cell tests show that the material has a good application prospect,indicating a promising flexible anode material for SIBs and PIBs.展开更多
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.310821173701)Natural Science Basic Research Program of Shaanxi(Grant No.2020JQ-379)。
文摘Highway frost heave and thawing settlement caused by water migration towards the freezing front and ice lens development is widespread in the alpine meadow area of the southeast QinghaiTibet Plateau(QTP). A laboratory experiment on a highway reconstruction and expansion project in the QTP was carried out in this work to analyze the effects of fine particle content, initial water content, and the number of freeze-thaw cycles(FTCs) on frost depth, temperature gradient(Grad T), total water intake, and water intake flux. Based on the results of the laboratory experiment, a modified model of migration potential related to fine particle content, freeze-thaw history, and freezing time was established. The results show that, with the increase of fine particle content, the frost depth of soil decreases, the curve of total water intake over time is transformed from an Sshape to an arch, and the curve of water intake flux over time is transformed from a peak shape to descending shape. The variation trend of migration potential with freezing time and the freeze-thaw history is the same as that of water intake flux with freezing time and freeze-thaw history. The variation trend of soil intake flux can be used as a reference to determine the variation trend of soil migration potential. This study provides a reference for the design and construction of highway subgrade in the alpine meadow area of the QTP.
基金financially supported by the National Natural Science Foundation of China (No. 52072325)the Key Research Foundation of Education Bureau of Hunan Province, China (No. 20A486)+2 种基金Hunan 2011 Collaborative Innovation Center of Chemical Engineering and Technology with Environmental Benignity and Effective Resource Utilization, Program for Innovative Research Cultivation Team in University of Ministry of Education of China (No. 1337304)the 111 Project (No. B12015)the Natural Science Foundation of Shandong Province (No. ZR2020MB045)。
文摘Na superionic conductor(NASICON)-type La_(0.33)Ti_(2)(PO_(4))_(3)(LaTP) is firstly proposed as sodium/potassium storage materials.The density functional theory(DFT) calculations show that LaTP has good electronic character and low Na^(+)/K^(+)migration barriers.The flexible La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofiber film is synthesized via electrostatic spinning and investigated as free-standing electrode applied to sodium-ion batteries(SIBs) and potassiumion batteries(PIBs) in this work.The low band gap and Na^(+)/K^(+) migration barriers of LaTP,unique morphology,and complete conductive carbon net allow the La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofibers film to deliver high capacity(296.3 mAh·g^(-1) for SIBs and 235.8 mAh·g^(-1) for PIBs),excellent rate performance(142.5 mAh·g^(-1) for SIBs and50.5 mAh·g^(-1) for PIBs at 1.00 A·g^(-1)),and superior cyclability above 1000 cycles.The full-cell tests show that the material has a good application prospect,indicating a promising flexible anode material for SIBs and PIBs.
