Numerical Experiments for the influence of the Transition Zone Migration on Summer Climate in North China

As the position of the transition zone changes obviously, that is, as the transition zone migrates to the north or the south from present position, it affects water or heat balance between the land and the atmosphere in a considerable degree and has a profound influence on climate in North China. The experiment results in this paper indicate whether in the dry case or in the wet case of the large-scale climatological background field, the surface air temperature in a wide range of the transition zone migration and its surrounding decreases as the transition zone migrates northward. Moreover, the net upward fluxes of the surface long wave radiation and the sensible heat decrease, and the evaporation to the atmosphere increases. As the transition zone migrates southward, the results are opposite. This kind of significant thermal forcing between the land and the atmosphere can excite secondary circulation or circulation cells, which interact with the large-scale circulation systems, changing the atmospheric motion, affecting the water vapor transportation and consequently having an effect on the precipitation.

Inhibiting Voltage Decay in Li-Rich Layered Oxide Cathode:From O3-Type to O2-Type Structural Design

Li-rich layered oxide(LRLO)cathodes have been regarded as promising candidates for next-generation Li-ion batteries due to their exceptionally high energy density,which combines cationic and anionic redox activities.However,continuous voltage decay during cycling remains the primary obstacle for practical applications,which has yet to be fundamentally addressed.It is widely acknowledged that voltage decay originates from the irreversible migration of transition metal ions,which usually further exacerbates structural evolution and aggravates the irreversible oxygen redox reactions.Recently,constructing O2-type structure has been considered one of the most promising approaches for inhibiting voltage decay.In this review,the relationship between voltage decay and structural evolution is systematically elucidated.Strategies to suppress voltage decay are systematically summarized.Additionally,the design of O2-type structure and the corresponding mechanism of suppressing voltage decay are comprehensively discussed.Unfortunately,the reported O2-type LRLO cathodes still exhibit partially disordered structure with extended cycles.Herein,the factors that may cause the irreversible transition metal migrations in O2-type LRLO materials are also explored,while the perspectives and challenges for designing high-performance O2-type LRLO cathodes without voltage decay are proposed.

Effects of bisphenol compounds on the growth and epithelial mesenchymal transition of MCF-7 CV human breast cancer cells

Bisphenol-A（BPA） has been considered as an endocrine disrupting chemical（EDC） because it can exert estrogenic properties.For bisphenol-S（BPS） and bisphenol-F（BPF） that are BPA analogs and substitutes,their risk to estrogendependent cancer has been reported rarely compared with the numerous cases of BPA.In this study,we examined whether BPA,BPS,and BPF can lead to the proliferation,migration,and epithelial mesenchymal transition（EMT） of MCF-7 clonal variant（MCF-7 CV） breast cancer cells expressing estrogen receptors（ERs）.In a cell viability assay,BPA,BPS,and BPF significantly increased proliferation of MCF-7 CV cells compared to control（DMSO） as did17β-estradiol（E2）.In Western blotting assay,BPA,BPS,and BPF enhanced the protein expression of cell cycle progression genes such as cyclin D1 and E1.In addition,MCF-7 CV cells lost cell to cell contacts and acquired fibroblast-like morphology by the treatment of BPA,BPS,or BPF for 24 hours.In cell migration assay,BPA,BPS,and BPF accelerated the migration capability of MCF-7 CV cells as did E2.In relation with the EMT process,BPA,BPS,and BPF increased the protein expression of N-cadherin,while they decreased the protein expression of Ecadherin.When BPA,BPS,and BPF were co-treated with ICI 182,780,an ER antagonist,proliferation effects were reversed,the expression of cyclin D1 and cyclin E1 was downregulated,and the altered cell migration and expression of N-cadherin and E-cadherin by BPA,BPS,and BPF were restored to the control level.Thus,these results imply that BPS and BPF also have the risk of breast cancer progression as much as BPA in the induction of proliferation and migration of MCF-7 CV cells by regulating the protein expression of cell cycle-related genes and EMT markers via the ER-dependent pathway.

Facile construction of a multilayered interface for a durable lithium‐rich cathode

Layered lithium-rich manganese-based oxide(LRMO)has the limitation of inevitable evolution of lattice oxygen release and layered structure transformation.Herein,a multilayer reconstruction strategy is applied to LRMO via facile pyrolysis of potassium Prussian blue.The multilayer interface is visually observed using an atomic-resolution scanning transmission electron microscope and a high-resolution transmission electron microscope.Combined with the electrochemical characterization,the redox of lattice oxygen is suppressed during the initial charging.In situ X-ray diffraction and the high-resolution transmission electron microscope demonstrate that the suppressed evolution of lattice oxygen eliminates the variation in the unit cell parameters during initial(de)lithiation,which further prevents lattice distortion during long cycling.As a result,the initial Coulombic efficiency of the modified LRMO is up to 87.31%,and the rate capacity and long-term cycle stability also improved considerably.In this work,a facile surface reconstruction strategy is used to suppress vigorous anionic redox,which is expected to stimulate material design in high-performance lithium ion batteries.

Crust and upper mantle structures beneath Northeast China from receiver function studies

P-wave and S-wave receiver function analyses have been performed along a profile consisted of 27 broadband seismic stations to image the crustal and upper mantle discontinuities across Northeast China. The results show that the average Moho depth varies from about 37 km beneath the Daxing＇anling orogenic belt in the west to about 33 km beneath the Songliao Basin, and to about 35 km beneath the Changbai mountain region in the east. Our results reveal that the Moho is generally flat beneath the Daxing＇anling region and a remarkable Moho offset （about 4 km） exists beneath the basin-mountain boundary, the Daxing＇anling-Taihang Gravity Line. Beneath the Tanlu faults zone, which seperates the Songliao Basin and Changbai region, the Moho is uplift and the crustal thick- ness changes rapidly. We interpret this feature as that the Tanlu faults might deeply penetrate into the upper mantle, and facilitate the mantle upwelling along the faults during the Cenozoic era. The average depth of the lithosphereasthenosphere boundary （LAB） is - 80 km along the profile which is thinner than an average thickness of a continental lithosphere. The LAB shows an arc-like shape in the basin, with the shallowest part approximately beneath the center of the basin. The uplift LAB beneath the basin might be related to the extensive lithospheric stretching in the Mesozoic. In the mantle transition zone, a structurally complicated 660 km discontinuity with a maximum 35 km depression beneath the Changbai region is observed. The 35 km depression is roughly coincident with the location of the stagnant western pacific slab on top of the 660 km discontinuity revealed by the recent P wave tomography.

A NUMERICAL EXPERIMENT STUDY FOR INFLUENCE OF THE TRANSITION ZONE MIGRATION ON SUMMER DROUGHT IN NORTH CHINA

In this paper, the summer climate of 1991 is taken as a case to study the influence of the transition zone migration on summer drought in North China by using the regional climate model (RegCM2). The results show that the transition zone migrates inland, the summer monsoon rainband of 1991 also moves inland. The intensive rainband in the Changjiang River Valley during the Meiyu period moves north. The precipitation in North China increases and the surface air temperature decreases. As a consequence, it results in a good circle between ecosystem and climate. The transition zone migration changes flux transfers between land and atmosphere, and excites secondary circulation or circulation cells around it. All those are closely related with the variation of precipitation.