In order to study the physical and chemical reaction after CO2 injected into coal beds at different condition.The physical and chemistry reaction among CO2,H2O and coal was studied,and the influence on permeability an...In order to study the physical and chemical reaction after CO2 injected into coal beds at different condition.The physical and chemistry reaction among CO2,H2O and coal was studied,and the influence on permeability and porosity of coal beds was carried out.The experimental method was used,so did the basic theory of mineralogy,coal petrology,geochemistry,analytical geochemistry and physical chemistry.In this experiment,the changes of mineral and permeability of coal and water quality were observed through CO2 solution reacting with different coal samples.The differences could be found out by comparing the properties and microcrystalline structure before and after the reaction.There are three results were carried out:First,the content of carbonate in coal beds decreases because of the dissolution reaction between carbonate minerals and CO2 solution,and precipitation is formed by reaction of chlorite and orthoclase.Second,the result that permeability and porosity of coal beds are improved after the reaction is proposed.Third,the initial permeability of different coal samples plays a great role on the reaction,and the improvement of permeability is not obvious in the samples which have too low or too high permeability,and the improvement is good in medium permeability(0.2–3 mD).展开更多
A series of water absorption tests on dried soft rock have been conducted by the intelligent testing system for water absorption tests in deep soft rock, including tests of water absorption with and without pres- sure...A series of water absorption tests on dried soft rock have been conducted by the intelligent testing system for water absorption tests in deep soft rock, including tests of water absorption with and without pres- sure. The results show that the water absorbing capacity of rock with a certain pressure is larger than that of rock without pressure： however, the relationship between the water absorbing percentage and the time can be expressed by w（t） = a（l - e^-bt）. In hi-logarithmic coordinates, the hydrophilic relationship with time in tests with pressure could be characterized by linearity, while they present concave or convex in tests without pressure. Based on the hypothesis that each influential factor is irrelevant and they have a linear correlation with the water absorbing capacity, we calculated the weight coefficient of each factor according to experimental results under different conditions. The calculations demonstrate that the effec- tive porosity, content of smectite and kaolinite are all positively correlated with the water absorption capacity of rock; meanwhile, the fractal dimension of the effective pores presents a negative correlation with the water absorption capacity of rock. The water absorption capacity with pressure increases with increasing illite, chlorite and chlorite/smectite formation and a decrease in illite/smectite formation and the fractal dimension of the effective pores, while it is opposite in tests without pressure. The weight coefficient of smectite is smallest among positive factors, and the fractal dimension of the effective pores is the smallest amongst the negative factors.展开更多
基金supported by the China National Major Scientifc and Technological Special Project for ‘‘Physical and Chemical Reaction between CO2 and Coal and Rock after Infuse CO2 into Deep Coal Bed’’ during the Twelfth Five-Year Plan Period(No.2011ZX05042-03)
文摘In order to study the physical and chemical reaction after CO2 injected into coal beds at different condition.The physical and chemistry reaction among CO2,H2O and coal was studied,and the influence on permeability and porosity of coal beds was carried out.The experimental method was used,so did the basic theory of mineralogy,coal petrology,geochemistry,analytical geochemistry and physical chemistry.In this experiment,the changes of mineral and permeability of coal and water quality were observed through CO2 solution reacting with different coal samples.The differences could be found out by comparing the properties and microcrystalline structure before and after the reaction.There are three results were carried out:First,the content of carbonate in coal beds decreases because of the dissolution reaction between carbonate minerals and CO2 solution,and precipitation is formed by reaction of chlorite and orthoclase.Second,the result that permeability and porosity of coal beds are improved after the reaction is proposed.Third,the initial permeability of different coal samples plays a great role on the reaction,and the improvement of permeability is not obvious in the samples which have too low or too high permeability,and the improvement is good in medium permeability(0.2–3 mD).
文摘A series of water absorption tests on dried soft rock have been conducted by the intelligent testing system for water absorption tests in deep soft rock, including tests of water absorption with and without pres- sure. The results show that the water absorbing capacity of rock with a certain pressure is larger than that of rock without pressure： however, the relationship between the water absorbing percentage and the time can be expressed by w（t） = a（l - e^-bt）. In hi-logarithmic coordinates, the hydrophilic relationship with time in tests with pressure could be characterized by linearity, while they present concave or convex in tests without pressure. Based on the hypothesis that each influential factor is irrelevant and they have a linear correlation with the water absorbing capacity, we calculated the weight coefficient of each factor according to experimental results under different conditions. The calculations demonstrate that the effec- tive porosity, content of smectite and kaolinite are all positively correlated with the water absorption capacity of rock; meanwhile, the fractal dimension of the effective pores presents a negative correlation with the water absorption capacity of rock. The water absorption capacity with pressure increases with increasing illite, chlorite and chlorite/smectite formation and a decrease in illite/smectite formation and the fractal dimension of the effective pores, while it is opposite in tests without pressure. The weight coefficient of smectite is smallest among positive factors, and the fractal dimension of the effective pores is the smallest amongst the negative factors.
