The development of zinc ion batteries (ZIBs) with large capacity,high rate,and durable cathode material is a crucial and urgent task.Ni Co_(2)O_(4)(NCO) has received ever-growing interest as a potential cathode materi...The development of zinc ion batteries (ZIBs) with large capacity,high rate,and durable cathode material is a crucial and urgent task.Ni Co_(2)O_(4)(NCO) has received ever-growing interest as a potential cathode material for ZIBs,owing to the high theoretical capacity,rich source,cost-effective,and versatile redox nature.However,due to the slow dynamics of the NCO electrodes,its practical application in highperformance systems is severely limited.Herein,we report an electron density modulated NCO nanosheets (N-NCO NSs) with high-kinetics Zn^(2+)-storage capability as an additive-free cathode for flexible all-solid-state (ASS) ZIBs.By virtue of the enhanced electronic conductivity,improved reaction kinetics,and increased active sites,the optimized N-NCO NSs electrode delivers a high capacity of 357.7 m Ah g^(-1)at 1.0 A g^(-1)and a superior rate capacity of 201.4 m Ah g^(-1)at 20 A g^(-1).More importantly,a flexible ASS ZIBs device is manufactured using a solid polymer electrolyte of a poly (vinylidene fluoride hexafluoropropylene)(PVDF-HFP) film.The flexible ASS ZIBs device shows superb durability with 80.2%capacity retention after 20,000 cycles and works well in the range of-20–70℃.Furthermore,the flexible ASS ZIBs achieves an impressive energy density as high as 578.1 W h kg^(-1)with a peak power density of 33.6 k W kg^(-1),substantially outperforming those latest ZIBs.This work could provide valuable insights for constructing high-kinetics and high-capability cathodes with long-term stability for flexible ASS ZIBs.展开更多
During assembly process,the miniature part needs to be fixed in its assembly position.In some occasions where adhesive is used,the joining force is not established due to the adhesive curing process,in that case the l...During assembly process,the miniature part needs to be fixed in its assembly position.In some occasions where adhesive is used,the joining force is not established due to the adhesive curing process,in that case the locking of parts is required.Manual locking is difficult to meet the increasing demand for mass production.To solve this problem and realize fully automatic assembly,a novel gripper module was designed and corresponding locking method was proposed.Thanks to the functional integration,the gripper module is capable of manipulating and locking the part.This module is integrated into the assembly system and plays a crucial role in automatic assembly.The locking method for automatic assembly is based on the integration of the part picking up and the locking unit releasing.After being placed accurately at its desired position,the miniature part can be automatically locked by releasing the locking unit.The innovative structure and mechanism of the gripper module convert the spring force into the locking force of the miniature part,ensuring non-rigid locking and suitable small locking force.Locking principle,flexibility and limitations of the proposed method were clarified in detail.Moreover,an effective compensation strategy was used to achieve accurate and stable pickup of the part,which increased the reliability of the assembly process.During automatic locking,the disturbances to the part due to the eccentric load were analyzed.The effectiveness of the gripper module and proposed method was verified by experiment.Experimental results indicated that the modular system integrated with the gripper module could meet the requirements of fully automatic assembly.Manual locking is replaced by automatic locking,and workers are liberated from tedious manual operations.The improvement of automation level enables assembly equipment to be applied to mass production scenarios.展开更多
基金the Basic and Applied Basic Research Project of Guangdong Province(2019A1515110827)the Science and Technology Planning Project of Guangzhou(202102080169)+3 种基金the Education Commission of Guangdong Province(2019GKTSCX015)the Advanced Functional Materials Scientific Research and Technical Service Team(X20190197)Guangdong Training Programs of Scientific and Technological Innovation for Undergraduates(pdjh2021a0715)the Innovation Training Program for Undergraduate of Hainan Normal University(2021024)。
文摘The development of zinc ion batteries (ZIBs) with large capacity,high rate,and durable cathode material is a crucial and urgent task.Ni Co_(2)O_(4)(NCO) has received ever-growing interest as a potential cathode material for ZIBs,owing to the high theoretical capacity,rich source,cost-effective,and versatile redox nature.However,due to the slow dynamics of the NCO electrodes,its practical application in highperformance systems is severely limited.Herein,we report an electron density modulated NCO nanosheets (N-NCO NSs) with high-kinetics Zn^(2+)-storage capability as an additive-free cathode for flexible all-solid-state (ASS) ZIBs.By virtue of the enhanced electronic conductivity,improved reaction kinetics,and increased active sites,the optimized N-NCO NSs electrode delivers a high capacity of 357.7 m Ah g^(-1)at 1.0 A g^(-1)and a superior rate capacity of 201.4 m Ah g^(-1)at 20 A g^(-1).More importantly,a flexible ASS ZIBs device is manufactured using a solid polymer electrolyte of a poly (vinylidene fluoride hexafluoropropylene)(PVDF-HFP) film.The flexible ASS ZIBs device shows superb durability with 80.2%capacity retention after 20,000 cycles and works well in the range of-20–70℃.Furthermore,the flexible ASS ZIBs achieves an impressive energy density as high as 578.1 W h kg^(-1)with a peak power density of 33.6 k W kg^(-1),substantially outperforming those latest ZIBs.This work could provide valuable insights for constructing high-kinetics and high-capability cathodes with long-term stability for flexible ASS ZIBs.
基金supported by LiaoNing Revitalization Talent Program(Grant No.2002020)the Major Project of Basic Scientific Research of Chinese Ministry(Grant No.JCYK2016205A003).
文摘During assembly process,the miniature part needs to be fixed in its assembly position.In some occasions where adhesive is used,the joining force is not established due to the adhesive curing process,in that case the locking of parts is required.Manual locking is difficult to meet the increasing demand for mass production.To solve this problem and realize fully automatic assembly,a novel gripper module was designed and corresponding locking method was proposed.Thanks to the functional integration,the gripper module is capable of manipulating and locking the part.This module is integrated into the assembly system and plays a crucial role in automatic assembly.The locking method for automatic assembly is based on the integration of the part picking up and the locking unit releasing.After being placed accurately at its desired position,the miniature part can be automatically locked by releasing the locking unit.The innovative structure and mechanism of the gripper module convert the spring force into the locking force of the miniature part,ensuring non-rigid locking and suitable small locking force.Locking principle,flexibility and limitations of the proposed method were clarified in detail.Moreover,an effective compensation strategy was used to achieve accurate and stable pickup of the part,which increased the reliability of the assembly process.During automatic locking,the disturbances to the part due to the eccentric load were analyzed.The effectiveness of the gripper module and proposed method was verified by experiment.Experimental results indicated that the modular system integrated with the gripper module could meet the requirements of fully automatic assembly.Manual locking is replaced by automatic locking,and workers are liberated from tedious manual operations.The improvement of automation level enables assembly equipment to be applied to mass production scenarios.
