A novel utilization way of the sludge from wet calcium-based flue gas desulfurization (FGD) processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calc...A novel utilization way of the sludge from wet calcium-based flue gas desulfurization (FGD) processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calcium sulfate by a hydrothermal salt solution method at atmospheric pressure. Experimental study has been carried out in a batch reactor. Qualitative and quantitative analyses were made by DSC/TG thermal analysis, SEM, XRD, metalloscope and chemical analysis. The experimental results showed that the modification of FGD gypsum was controlled by the dissolution and recrystallization mechanisms. With the introduction of FGD gypsum the salt solution was supersaturated, then crystal nucleus of α-hemihydrate calcium sulfate were produced in the solution. With the submicroscopic structure of FGD gypsum crystal changed, the crystal nucleus grew up into α-hemihydrate calcium sulfate crystals. Thus ,the modification of FGD gypsum was fulfilled.展开更多
For simulating fresh and salt water mixing in estuaries, a three dimensional nonlinear baroclinic numerical model is developed, in which the gradients of horizontal pressure contain die gradient of barotropic pressure...For simulating fresh and salt water mixing in estuaries, a three dimensional nonlinear baroclinic numerical model is developed, in which the gradients of horizontal pressure contain die gradient of barotropic pressure arising from the gradient of tidal level and the gradient of baroclinic pressure due to the gradient of salinity. The Eulerian-Lagrangian method is employed to descretize both the momentum equations of tidal motion and the equation of salt water diffusion so as to improve the computational stability and accuracy. The methods to provide the boundary conditions and the initial conditions are proposed, and the criterion for computational stability of the salinity fields is presented. The present model is used for modeling fresh and salt water mixing in the Yangtze Estuary. Computations show that the salinity distribution has the characteristics of partial mixing pattern, and that the present model is suitable for simulation of fresh and salt water mixing in the Yangtze Estuary.展开更多
The industrial products or wastewater rich in the mixed salts(Cl-/SO4^2-) not only causes the environmental damage, but also induces waste of resource. In this study, an ED stack with monovalent selective AEMs and con...The industrial products or wastewater rich in the mixed salts(Cl-/SO4^2-) not only causes the environmental damage, but also induces waste of resource. In this study, an ED stack with monovalent selective AEMs and conventional CEMs was employed to separate the Cl-and SO42-from simulated wastewater. The effect of current density and mass fraction percentage was investigated in order to optimize the experimental conditions during ED process. It was found that at a concentration ratio between NaCl and Na2SO4 of 95/5(wt%/wt%) and a current density of40 m A·cm^-2, a current efficiency of 72%, an energy consumption of 1.6 k W·h·kg^-1 Na Cl and a Cl-/SO4^2-concentration(67.5/3.5 g·L^-1) were obtained. Hence, it is appropriate and effective to separate Cl-and SO42-by ED using the monovalent selective AEMs.展开更多
Using field hydrological data, the relationship between the mixing of salt water and fresh water and the tidal range/ high tidal level in the Changjiang (Yangtze) River estuary is discussed, and the transporting and c...Using field hydrological data, the relationship between the mixing of salt water and fresh water and the tidal range/ high tidal level in the Changjiang (Yangtze) River estuary is discussed, and the transporting and concentrating of suspended sediment in the estuary were also analysed in respect to the circulation, flocculation and stratified interface resulting from mixing.The calculation results by two-dimentional box model have confirmed the effects of the circulation on the concentrating of suspended sediment in the estuary. The conclusions derived from this work have deepened the understanding on the mixing in the Changjiang River estuary and are of significance in bo’th theory and practice.展开更多
Because the lack of detailed study of biological decolorization in high salt dye wastewater, it is still difficult to evaluate the biological treatment on high-salinity dye wastewater. The experiments were carried out...Because the lack of detailed study of biological decolorization in high salt dye wastewater, it is still difficult to evaluate the biological treatment on high-salinity dye wastewater. The experiments were carried out to study the salt-tolerant bacteria, which is useful in the treatment of high-salinity colored wastewater. Simulated wastewater containing 5-150 g/L salt (NaCI) and 50-2000 mg/L Reactive Brilliant Red K-2BP was treated with three salt-tolerant mixed cultures (CAS, TAS, DSAS), which were under a gradually acclimated procedure. With the increase of concentrations of salt and dye, the decolorization became low. The abilities of decolorization of dyes wastewater by three mixed cultures (CAS, TAS, DSAS) were studied, CAS and DSAS mixed cultures showed more active for the treatment of high-salinity colored wastewater than TAS mixed cultures. The results suggested that there might be a simple process for the high salt wastewater treatment, which could be incorporated into conventional activated sludge plants.展开更多
Complex salt Co_2Cl_5(py)_5 (py=pyridine) was obtained by the reaction of CoCl_2·6H_2O with Bu_4NMnO_4 in pyridine in the presence of benzoic acid. It is monoclinic and crystallizes in space group P2_1/n, fw=690....Complex salt Co_2Cl_5(py)_5 (py=pyridine) was obtained by the reaction of CoCl_2·6H_2O with Bu_4NMnO_4 in pyridine in the presence of benzoic acid. It is monoclinic and crystallizes in space group P2_1/n, fw=690.64, a=28.652(5), b=14.108(4), c=7.424(3) ;β=90.09(1); V=3001(2)~3; Z=4, Dc=1.53g/cm^3. Final R factor is 0.041. The structure consists of a discrete cation [Co~ⅢCl_2(py)_4]^+ and an anion [Co~Ⅱ Cl_3(py)]^-. The Co~Ⅲ ion is coordinated by two Cl^- and four pyridine nitrogen atoms to form an octahedral geometry, and Co~Ⅱ is coordinated by three Cl^- and one pyridine nitrogen atom to form the apices of a tetrahedron. The variable-temperature magnetic susceptility measurement shows no magnet-exchange interaction between Co~Ⅲ and Co~Ⅱ ions.展开更多
Located in Yunlong Dali, Nuodeng salt-village has thousands of years deep in Bai history, culture of the precipitation, the rich historical and cultural heritage of the Bai nationality. In Bai settlement formation and...Located in Yunlong Dali, Nuodeng salt-village has thousands of years deep in Bai history, culture of the precipitation, the rich historical and cultural heritage of the Bai nationality. In Bai settlement formation and development history, its diverse natural appearances and rich cultural styles have the dual characteristics in natural and cultural heritage. Nuodeng salt-village is a connection between central plains culture and South Asia culture, also a complete ecological museum. By this time, this essay put Jinan springs under the view of mixed heritage based on the background of its history and geography, to identify the natural and cultural value of Nuodeng salt-village by comparison and conclude the heritage protection planning accordingly.展开更多
The enthalpies of mixing for the PbCl_2-NaCl-BaCl_2 ternary molten salt mixtures have been measured along four iso-αPbCl_2 Iines by using a SETARAM calorimeter at 873 K.The results show that the molar enthalpy of mix...The enthalpies of mixing for the PbCl_2-NaCl-BaCl_2 ternary molten salt mixtures have been measured along four iso-αPbCl_2 Iines by using a SETARAM calorimeter at 873 K.The results show that the molar enthalpy of mixing between iso-αPbCl_2 liquid binary subsystems PbCl_2-NaCl and PbCl_2-BaCl_2 is near zero.approximately fitting the partial ideal solution model.展开更多
The effect of two dissolved inorganic salts,cadmium chloride CdCl2 and ammonium chloride NH4Cl,on the excess enthalpy of mixing(HE) of the binary system methanol + benzene measured at 303.15 K using an iso-thermal dis...The effect of two dissolved inorganic salts,cadmium chloride CdCl2 and ammonium chloride NH4Cl,on the excess enthalpy of mixing(HE) of the binary system methanol + benzene measured at 303.15 K using an iso-thermal displacement calorimeter with vapor space is investigated in the present work. Compared to the salt-free system,a decreasing trend in the endothermicity of HE values is significant with the addition of CdCl2 salt but the decrease in the HE values is insignificantly smaller with the addition of NH4Cl salt. The experimental values of the enthalpy of mixing are fitted into a Redlich-Kister equation and the deviations in the values and the parameters are reported. The importance of the solute-solvent interactions and the solvent-solvent interactions are demonstrated from the increasing excess enthalpy of mixing values in the positive direction with the increase of salt concentration.展开更多
Salt desert,saline-alkaline dust storm and saline-alkaline mixed dust storm are significant but ignored problems for a long time.After many years of observations and researches,the author believes that salt desert,sal...Salt desert,saline-alkaline dust storm and saline-alkaline mixed dust storm are significant but ignored problems for a long time.After many years of observations and researches,the author believes that salt desert,saline-alkaline dust展开更多
文摘A novel utilization way of the sludge from wet calcium-based flue gas desulfurization (FGD) processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calcium sulfate by a hydrothermal salt solution method at atmospheric pressure. Experimental study has been carried out in a batch reactor. Qualitative and quantitative analyses were made by DSC/TG thermal analysis, SEM, XRD, metalloscope and chemical analysis. The experimental results showed that the modification of FGD gypsum was controlled by the dissolution and recrystallization mechanisms. With the introduction of FGD gypsum the salt solution was supersaturated, then crystal nucleus of α-hemihydrate calcium sulfate were produced in the solution. With the submicroscopic structure of FGD gypsum crystal changed, the crystal nucleus grew up into α-hemihydrate calcium sulfate crystals. Thus ,the modification of FGD gypsum was fulfilled.
基金The project is financially supported by the Research Fund of the College of Harbor,Waterway and Coastal Engineering,Hohai University.
文摘For simulating fresh and salt water mixing in estuaries, a three dimensional nonlinear baroclinic numerical model is developed, in which the gradients of horizontal pressure contain die gradient of barotropic pressure arising from the gradient of tidal level and the gradient of baroclinic pressure due to the gradient of salinity. The Eulerian-Lagrangian method is employed to descretize both the momentum equations of tidal motion and the equation of salt water diffusion so as to improve the computational stability and accuracy. The methods to provide the boundary conditions and the initial conditions are proposed, and the criterion for computational stability of the salinity fields is presented. The present model is used for modeling fresh and salt water mixing in the Yangtze Estuary. Computations show that the salinity distribution has the characteristics of partial mixing pattern, and that the present model is suitable for simulation of fresh and salt water mixing in the Yangtze Estuary.
基金Supported by the National Key Research and Development Plan(Nos.2017YFC0403700 and 2017YFD0400604)
文摘The industrial products or wastewater rich in the mixed salts(Cl-/SO4^2-) not only causes the environmental damage, but also induces waste of resource. In this study, an ED stack with monovalent selective AEMs and conventional CEMs was employed to separate the Cl-and SO42-from simulated wastewater. The effect of current density and mass fraction percentage was investigated in order to optimize the experimental conditions during ED process. It was found that at a concentration ratio between NaCl and Na2SO4 of 95/5(wt%/wt%) and a current density of40 m A·cm^-2, a current efficiency of 72%, an energy consumption of 1.6 k W·h·kg^-1 Na Cl and a Cl-/SO4^2-concentration(67.5/3.5 g·L^-1) were obtained. Hence, it is appropriate and effective to separate Cl-and SO42-by ED using the monovalent selective AEMs.
文摘Using field hydrological data, the relationship between the mixing of salt water and fresh water and the tidal range/ high tidal level in the Changjiang (Yangtze) River estuary is discussed, and the transporting and concentrating of suspended sediment in the estuary were also analysed in respect to the circulation, flocculation and stratified interface resulting from mixing.The calculation results by two-dimentional box model have confirmed the effects of the circulation on the concentrating of suspended sediment in the estuary. The conclusions derived from this work have deepened the understanding on the mixing in the Changjiang River estuary and are of significance in bo’th theory and practice.
文摘Because the lack of detailed study of biological decolorization in high salt dye wastewater, it is still difficult to evaluate the biological treatment on high-salinity dye wastewater. The experiments were carried out to study the salt-tolerant bacteria, which is useful in the treatment of high-salinity colored wastewater. Simulated wastewater containing 5-150 g/L salt (NaCI) and 50-2000 mg/L Reactive Brilliant Red K-2BP was treated with three salt-tolerant mixed cultures (CAS, TAS, DSAS), which were under a gradually acclimated procedure. With the increase of concentrations of salt and dye, the decolorization became low. The abilities of decolorization of dyes wastewater by three mixed cultures (CAS, TAS, DSAS) were studied, CAS and DSAS mixed cultures showed more active for the treatment of high-salinity colored wastewater than TAS mixed cultures. The results suggested that there might be a simple process for the high salt wastewater treatment, which could be incorporated into conventional activated sludge plants.
文摘Complex salt Co_2Cl_5(py)_5 (py=pyridine) was obtained by the reaction of CoCl_2·6H_2O with Bu_4NMnO_4 in pyridine in the presence of benzoic acid. It is monoclinic and crystallizes in space group P2_1/n, fw=690.64, a=28.652(5), b=14.108(4), c=7.424(3) ;β=90.09(1); V=3001(2)~3; Z=4, Dc=1.53g/cm^3. Final R factor is 0.041. The structure consists of a discrete cation [Co~ⅢCl_2(py)_4]^+ and an anion [Co~Ⅱ Cl_3(py)]^-. The Co~Ⅲ ion is coordinated by two Cl^- and four pyridine nitrogen atoms to form an octahedral geometry, and Co~Ⅱ is coordinated by three Cl^- and one pyridine nitrogen atom to form the apices of a tetrahedron. The variable-temperature magnetic susceptility measurement shows no magnet-exchange interaction between Co~Ⅲ and Co~Ⅱ ions.
文摘Located in Yunlong Dali, Nuodeng salt-village has thousands of years deep in Bai history, culture of the precipitation, the rich historical and cultural heritage of the Bai nationality. In Bai settlement formation and development history, its diverse natural appearances and rich cultural styles have the dual characteristics in natural and cultural heritage. Nuodeng salt-village is a connection between central plains culture and South Asia culture, also a complete ecological museum. By this time, this essay put Jinan springs under the view of mixed heritage based on the background of its history and geography, to identify the natural and cultural value of Nuodeng salt-village by comparison and conclude the heritage protection planning accordingly.
文摘The enthalpies of mixing for the PbCl_2-NaCl-BaCl_2 ternary molten salt mixtures have been measured along four iso-αPbCl_2 Iines by using a SETARAM calorimeter at 873 K.The results show that the molar enthalpy of mixing between iso-αPbCl_2 liquid binary subsystems PbCl_2-NaCl and PbCl_2-BaCl_2 is near zero.approximately fitting the partial ideal solution model.
基金Supported by Basic Science Research Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education,Science and Technology(R11-2005-065)DST-SERC,New Delhi,India(100/IFD/9726/2009-2010 dated 2/2/2010)
文摘The effect of two dissolved inorganic salts,cadmium chloride CdCl2 and ammonium chloride NH4Cl,on the excess enthalpy of mixing(HE) of the binary system methanol + benzene measured at 303.15 K using an iso-thermal displacement calorimeter with vapor space is investigated in the present work. Compared to the salt-free system,a decreasing trend in the endothermicity of HE values is significant with the addition of CdCl2 salt but the decrease in the HE values is insignificantly smaller with the addition of NH4Cl salt. The experimental values of the enthalpy of mixing are fitted into a Redlich-Kister equation and the deviations in the values and the parameters are reported. The importance of the solute-solvent interactions and the solvent-solvent interactions are demonstrated from the increasing excess enthalpy of mixing values in the positive direction with the increase of salt concentration.
文摘Salt desert,saline-alkaline dust storm and saline-alkaline mixed dust storm are significant but ignored problems for a long time.After many years of observations and researches,the author believes that salt desert,saline-alkaline dust