Enhanced gas separation performance of mixed matrix hollow fiber membranes containing post-functionalized S-MIL-53

Mixed matrix hollow fiber membranes（MMHFMs）filled with metal-organic frameworks（MOFs）have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem-1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53（S-MIL-53）and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO2/N2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.

Photon statistics of pulse-pumped four-wave mixing in fiber with weak signal injection

We study the photon statistics of pulse-pumped four-wave mixing in fibers with weak coherent signal injection by measuring the intensity correlation functions of individual signal and idler fields. The experimental results show that the intensity correlation function of individual signal（idler） field g_（s（i））^（2） decreases with the intensity of signal injection. After applying narrow band filter in signal（idler） band, the value of g_（s（i））^（2） decreases from 1.9 ± 0.02（1.9 ± 0.02） to 1.03 ± 0.02（1.05 ± 0.02） when the intensity of signal injection varies from 0 to 120 photons/pulse. The results indicate that the photon statistics changes from Bose–Einstein distribution to Poisson distribution. We calculate the intensity correlation functions by using the multi-mode theory of four-wave mixing in fibers. The theoretical curves well fit the experimental results.Our investigation will be useful for mitigating the crosstalk between quantum and classical channels in a dense wavelength division multiplexing network.

Economics and Performance of 10 Gb/s Metro Transport Over Mixed Fiber Plant of G.655 NZDF and G.652.C Zero Water-Peak Fibers

Using lower-cost lasers, 30% savings are possible for 10-Gb/s uncompensated metro transmission over NZDF, compared to G.652 fiber. We present WDM transmission results for a mixed plant of NZDF rings interconnected to G.652.C-fiber access laterals.

Multi-wavelength erbium-doped fiber laser using four-wave mixing effect in doped fiber

We demonstrate a multi-wavelength erbium-doped fiber laser （EDFL） using erbium gain and four-wave mixing （FWM） effect in a piece of erbium-doped fiber （EDF） with high erbium ion concentration. The EDF has a pump absorption rate of 24.6 dB/m at 979 nm and is bi-directionally pumped by 980-nm laser diodes. FWM effect redistributes the energy of different oscillating lines and causes multi-wavelength operation. The laser generates more than 22 lines of optical comb with a line spacing of approximately 0.10 nm at the 1569-nm region using only 1.5-m-long EDF.

Canonical logic units using bidirectional four-wave mixing in highly nonlinear fiber

All-optical canonical logic units at 40 Gb/s using bidirectional four-wave mixing(FWM) in highly nonlinear fiber are proposed and experimentally demonstrated. Clear temporal waveforms and correct pattern streams are successfully observed in the experiment. This scheme can reduce the amount of nonlinear devices and enlarge the computing capacity compared with general ones. The numerical simulations are made to analyze the relationship between the FWM efficiency and the position of two interactional signals.