High temperature H_(2)S selective oxidation on a copper-substituted hexaaluminate catalyst: A facile process for treating low concentration acid gas

H_(2)S selective catalytic oxidation technology is a prospective way for the treatment of low concentration acid gas with simple process operation and low investment. However, undesirable results such as large formation of SO_(2) and catalyst deactivation inevitably occur, due to the temperature rise of fixed reaction bed caused by the exothermic reaction. Catalyst with high activity in wide operating temperature window, especially in high temperature range, is urgently needed. In this paper, a series of copper-substituted hexaaluminate catalysts (LaCu_(x), x = 0, 0.5, 1, 1.5, 2, 2.5) were prepared and investigated for the H_(2)S selective oxidation reaction at high temperature conditions (300-550℃). The LaCu_(1) catalyst exhibited excellent catalytic performance and great stability, which was attributed to the best reductive properties and proper pore structure. Besides, two facile deep processing paths were proposed to eliminate the remaining H_(2)S and SO_(2) in the tail gas.

北湖污水厂改良A^(2)/O膜生物池混合液回流系统优化

北湖污水处理厂有40×10^(4) m^(3)/d规模的污水采用高浓度改良A^(2)/O生物池+MBR组合工艺处理。为充分发挥其污泥浓度高、节省占地、出水水质好、自动化程度高的优点,消除其受混合液回流方式限制引发回流条件不好而导致生物脱氮除磷效果差的弊端,该工程提出一种混合液回流系统的优化设计方案,即采用改良A^(2)/O生物池混合液导流/分流装置。该装置由分流导流板系统、混合液导入系统及混合液导出系统组成,通过对导入及导出点所在的同一平面位置进行竖向分隔,形成两个相对独立的空间,在不同高度空间内实现不同分区之间的混合液导入与导出,从而构建出高效的混合液回流系统。该解决方案构思巧妙,简单易行,可广泛应用于各种具有推流结构形式、同步脱氮除磷及多级回流需求的生物池中,例如UCT工艺、VIP工艺、A^(2)/O及其各种变形工艺。该装置可节约能耗,提高生物脱氮除磷效果,北湖污水厂混合液回流能耗为0.0017 kW·h/m^(3),节能50%~85%,平均脱氮率为73%,最高达93%。