Hydrophobically associative polyacrylamide （HAPAM） were prepared in aqueous solution by radical copolymerization of novel cationic surface-active monomer, dimethylhexadecyl（3-acrylamidopropyl）ammonium bromide （DM...Hydrophobically associative polyacrylamide （HAPAM） were prepared in aqueous solution by radical copolymerization of novel cationic surface-active monomer, dimethylhexadecyl（3-acrylamidopropyl）ammonium bromide （DMHAB）, with acrylamide （AM） in the presence of DMHAB/CTAB mixed micelles. The length of hydrophobic microblock （NH） in HAPAM is controlled by the molar fraction of DMHAB in mixed micelles, which can be mediated by the ratio of CTAB to DMHAB. The results of steady-state fluorescence probe and viscometry experiments showed the ability of HAPAM association was determined by the length of the hydrophobic microblock. HAPAM with tunable association ability are promising materials for thickening agent.展开更多
The interaction of poly(sodium sulfodecyl methacrylate) (PSSM) with cetyltrimethyl ammonium bromide (CTAB)was studied. It was found that the precipitate formed from PSSM and CTAB will be dissolved by excessive CTAB, r...The interaction of poly(sodium sulfodecyl methacrylate) (PSSM) with cetyltrimethyl ammonium bromide (CTAB)was studied. It was found that the precipitate formed from PSSM and CTAB will be dissolved by excessive CTAB, resultingin the appearance of two maxima of the solution viscosity at the molar ratio (CTAB/-SO_3^-) of≈ 0.68 and≈1.30,respectively. The first one is related closely to the aggregation of polymer chains via CTAB molecules and the second oneshould be ascribed to the formation of the mixed micelles comprising surfactant and the polymer's hydrophobic chains. Theeffect of NaCl on the viscosity, the transmittance of the aqueous solution and the solubility of oil-soluble dye (dimethyl yellow) in the mixed system were also investigated.展开更多
文摘Hydrophobically associative polyacrylamide （HAPAM） were prepared in aqueous solution by radical copolymerization of novel cationic surface-active monomer, dimethylhexadecyl（3-acrylamidopropyl）ammonium bromide （DMHAB）, with acrylamide （AM） in the presence of DMHAB/CTAB mixed micelles. The length of hydrophobic microblock （NH） in HAPAM is controlled by the molar fraction of DMHAB in mixed micelles, which can be mediated by the ratio of CTAB to DMHAB. The results of steady-state fluorescence probe and viscometry experiments showed the ability of HAPAM association was determined by the length of the hydrophobic microblock. HAPAM with tunable association ability are promising materials for thickening agent.
基金This work was supported by the National Natural Science Foundation of China (Contract No: 39870227 & 50173002).
文摘The interaction of poly(sodium sulfodecyl methacrylate) (PSSM) with cetyltrimethyl ammonium bromide (CTAB)was studied. It was found that the precipitate formed from PSSM and CTAB will be dissolved by excessive CTAB, resultingin the appearance of two maxima of the solution viscosity at the molar ratio (CTAB/-SO_3^-) of≈ 0.68 and≈1.30,respectively. The first one is related closely to the aggregation of polymer chains via CTAB molecules and the second oneshould be ascribed to the formation of the mixed micelles comprising surfactant and the polymer's hydrophobic chains. Theeffect of NaCl on the viscosity, the transmittance of the aqueous solution and the solubility of oil-soluble dye (dimethyl yellow) in the mixed system were also investigated.
