Tracing surface seawater mixing and nutrient transport by^(222)Rn on the northern coast of Beibu Gulf,China

The transport and diffusion of substances in seawater are limited by the mixing motion of water bodies,while the main forms of mixing in offshore water bodies are advection and eddy diffusion.The eddy diffusion process of water indicates the possible transport direction of dissolved substances.However,the complex environment in the coastal zone makes it difficult to quantitatively assess the water diffusion process.^(222)Rn is a useful tool to trace the diffusion process of water bodies.However,studies on the^(222)Rn distribution and its behavior in the Beibu Gulf are scarce.In this study,the activity distribution characteristics of^(222)Rn in surface seawater of the Guangxi shelf area of the Beibu Gulf were measured.Based on the one-dimensional,steady-state model,the vorticity diffusion coefficient of^(222)Rn in the horizontal direction was calculated as(0.42−2.13)×10^(8) m^(2)/d,and the offshore fluxes of^(222)Rn under the influence of water mixing were calculated as 2.00×10^(12) Bq/d.Correspondingly,the horizontal transport fluxes of silicate,phosphate,nitrite and nitrate were 6.28×10^(−3)mol/(m^(2)·d),0.10×10^(−3)mol/(m^(2)·d),0.20×10^(−3)mol/(m^(2)·d)and 4.15×10^(−3)mol/(m^(2)·d),respectively.These results indicate that the study of eddy current diffusion in offshore marine water facilitates a deeper understanding of the water mixing process and nutrient transport and migration.

Three Dimensional Baroclinic Numerical Model for Simulating Fresh and Salt Water Mixing in the Yangtze Estuary

For simulating fresh and salt water mixing in estuaries, a three dimensional nonlinear baroclinic numerical model is developed, in which the gradients of horizontal pressure contain die gradient of barotropic pressure arising from the gradient of tidal level and the gradient of baroclinic pressure due to the gradient of salinity. The Eulerian-Lagrangian method is employed to descretize both the momentum equations of tidal motion and the equation of salt water diffusion so as to improve the computational stability and accuracy. The methods to provide the boundary conditions and the initial conditions are proposed, and the criterion for computational stability of the salinity fields is presented. The present model is used for modeling fresh and salt water mixing in the Yangtze Estuary. Computations show that the salinity distribution has the characteristics of partial mixing pattern, and that the present model is suitable for simulation of fresh and salt water mixing in the Yangtze Estuary.

Warm water wake off northeast Vietnam in the South China Sea

Due to orographic blockage, a weak wind wake occurs in summer off northeast Vietnam in the South China Sea. Under the wind wake, warm water is observed from both high-resolution satellite data and hydrographic observations. The wake of warm water forms in June, continues to mature in July and August, starts to decay in September, and disappears in October. The warm water wake also shows robust diurnal variation – it intensifies during the day and weakens in the night. Warm water wakes can be generated through wind-induced mixing and thermal（latent heat flux） processes. In this paper, a mixed layer model is used to evaluate the relative importance of the two processes on seasonal and diurnal timescales, respectively. The results demonstrate that thermal processes make a greater contribution to the wake than wind-induced mixing processes on a seasonal timescale, while the warm water wake is dominated by wind-induced mixing processes on a diurnal timescale.

Volum etric Properties of Sodium Chlorobenzoatein N,N-Dim ethylform am ide/waterMixtures at 298.15K

Densities of sodium chlorobenzoate( o , m , p ) were measured in solutions up to 80 weight percent dimethylformamide(DMF) at 298 15 K with an oscillating tube densimeter. From these densities, apparent molar volumes of sodium chlorobenzoate in DMF H 2O mixtures were calculated, and partial molar volumes at infinite dilution were evaluated. Substituent and solvent effects on transfer volumes of each isomer from water to DMF H 2O mixed solvents were obtained. The results are explained in terms of solvent structure and solute solvent interaction.

Spatial and temporal variation of water mass mixing characteristic in the East China Sea

On the basis of the observation data of Kuroshio since 1984 and relative historical data in the East China Sea, spatial and temporal variation of water mass mixing characteristic in the observation area is analysed. The main results are as follows.

Rogoznica Lake(Croatia),a Unique Euxinic Seawater System on the Adriatic Coast

1 Introduction Rogoznica Lake is a typical example of euxinic saline lake,situated on the eastern Adriatic coast(43o32’N15o58’E).It is a karstic depression filled with seawater,

A Simple Mix Proportion Design Method Based on Frost Durability for Recycled High Performance Concrete Using Fully Coarse Recycled Aggregate

Durability design of recycled high performance concrete（RHPC） is fundamental for improving the use rate and level of concrete waste as coarse recycled aggregate（CRA）. We discussed a frostdurability-based mix proportion design method for RHPC using 100 % CRA and natural sand. Five groups of RHPC mixes with five strength grades（40, 50, 60, 70 and 80 MPa） were produced using CRA with four quality classes, and their workability, 28 d compressive strengths and frost resistances（measured by the compressive strength loss ratio and the relative dynamic modulus of elasticity） were tested. Relationships between the 28 d compressive strength, the frost resistance and the CRA quality characteristic parameter, water absorption, were then developed. The criterion of a CRA maximum water absorption limit value for RHPC was suggested, independent of its source and quality class. The results show that all RHPC mixes achieve the expected target workability, strength, and frost durability. The research results demonstrate that the application of the proposed method does not require trial testing prior to use.

Effect of hydration on the surface basicity and catalytic activity of Mg-rare earth mixed oxides for aldol condensation

Magnesium and rare earth mixed oxides（Mg3 REOx（RE=La, Y. Ce）） were prepared and characterized by Xray diffraction（XRD）, N_2 adsorption-desorption, infrared spectra and microcalorimetry of CO_2. The results reveal that the Mg_3 CeO_x catalyst is present in the form of Mg-Ce-O solid solution,while the Mg3 LaOx and Mg_3 YO_x catalysts are probably rare earth oxides dispersed on MgO surface. As a result, among the calcined Mg_3 REO_x catalysts, the Mg_3 CeO_x catalyst presents the highest rate constant for acetone aldolization, which is well correlated to its more homogeneous distribution of basic sites. In contrary, the Mg_3 YO_x catalyst exhibit the lowest catalytic activity for acetone aldolization. Upon hydration pre-treatment, the basic properties on the surface of the Mg_3 REO_x catalysts were changed markedly. The Mg_3 YO_x catalyst after hydration treatment shows the highest amount of basic sites on catalyst surface, and then exhibits the highest activity among the hydrated Mg_3 REO_x catalysts. These results make it possible to fine-tune basic sites for acetone aldolization.

Spatial and temporal variations of two cyanobacteria in the mesotrophic Miyun reservoir, China

Spatial variations in phytoplankton community within a large mesotrophic reservoir （Miyun reservoir, North China） were investigated in relation to variations in physico-chemical properties, nutrient concentrations, temperature and light conditions over a 5 month period in 2009. The dynamics of phytoplankton community was represented by the dominance of cyanobacteria through summer and fall, following with a short term dominance of chlorophyta in late fall, and a relatively high abundance of diatom in October; on the other hand, maximum phytoplankton biomass was recorded in the north shallow region of Miyun reservoir with a higher nutrients level. Particular attention was paid to the impacts of environmental conditions on the growth of two cyanobacteria genera, the toxin-producing Microcystis and the taste ＆ odor-producing Oscillatoria. Microcystis biomass was in general greatly affected by water temperature and mixing depth/local water depth ratio in this reservoir, while the Oscillatoria biomass in the surface and middle layers was greatly affected by total dissolved phosphorus, and that in the bottom layer was related with the Secchi depth/local water depth ratio. Abundant Oscillatoria biomass was observed only in late September when Microcystis biomass decreased and allowed sufficient light go through.

Mixing regime shapes the community assembly process,microbial interaction and proliferation of cyanobacterial species Planktothrix in a stratified lake

Lake mixing influences aquatic chemical properties and microbial community composition,and thus,we hypothesized that it would alter microbial community assembly and interac-tion.To clarify this issue,we explored the community assembly processes and cooccurrence networks in four seasons at two depths(epilimnion and hypolimnion)in a mesotrophic and stratified lake(Chenghai Lake),which formed stratification in the summer and turnover in the winter.During the stratification period,the epilimnion and hypolimnion went through contrary assembly processes but converged to similar assembly patterns in the mixing pe-riod.In a highly homogeneous selection environment,species with low niche breadth were filtered,resulting in decreased species richness.Water mixing in the winter homogenized the environment,resulting in a simpler microbial cooccurrence network.Interestingly,we observed a high abundance of the cyanobacterial genus Planktothrix in the winter,proba-bly due to nutrient redistribution and Planktothrix adaptivity to the winter environment in which mixing played important roles.Our study provides deeper fundamental insights into how environmental factors influence microbial community structure through community assembly processes.