Mixed matrix membranes(MMMs)could combine the advantages of both polymeric membranes and porousfillers,making them an effective alternative to conventional polymer membranes.However,interfacial incompatibility issues,s...Mixed matrix membranes(MMMs)could combine the advantages of both polymeric membranes and porousfillers,making them an effective alternative to conventional polymer membranes.However,interfacial incompatibility issues,such as the presence of interfacial voids,hardening of polymer chains,and blockage of micropores by polymers between common MMMsfillers and the polymer matrix,currently limit the gas sep-aration performance of MMMs.Ternary phase MMMs(consisting of afiller,an additive,and a matrix)made by adding a third compound,usually functionalized additives,can overcome the structural problems of binary phase MMMs and positively impact membrane separation performance.This review introduces the structure and fabrication processes for ternary MMMs,categorizes various nanofillers and the third component,and summarizes and analyzes in detail the CO_(2) separation performance of newly developed ternary MMMs based on both rubbery and glassy polymers.Based on this separation data,the challenges of ternary MMMs are also discussed.Finally,future directions for ternary MMMs are proposed.展开更多
Efficiently enriching low-concentration CH4 is pivotal for enhancing the utilization of unconventional energy sources and mitigating greenhouse gas emissions.This study focuses on modifying the overall performance of ...Efficiently enriching low-concentration CH4 is pivotal for enhancing the utilization of unconventional energy sources and mitigating greenhouse gas emissions.This study focuses on modifying the overall performance of CH_(4)/N_(2)separation membranes.A novel mixed matrix membrane(MMM)with a reinforced substrate structure was developed through a straightforward dip-coating technique.This MMM incorporates a polytetrafluoroethylene(PTFE)porous membrane as the supporting framework,while a composite of block polymer(styrene-butadiene-styrene)and metal-organic framework(Ni-MOF-74)forms the selective separation layer.Comprehensive characterization of Ni-MOF-74 and the fabricatedmembranes was conducted using X-rays diffraction,scanning electron microscope,Brunauer-Emmett-Teller analysis,and gas permeance tests.The findings indicate a robust integration of the PTFE porous support with the membrane layer,enhancing the mechanical stability of theMMM.Under optimal conditions,the mechanical strength of the PM20 membrane(containing 20%Ni-MOF-74)was observed to be 37.7 MPa,representing remarkable increase compared to the non-reinforcedMMM.Additionally,thePM20membrane exhibited an impressive CH4 permeation rate of 92 barrer(1 barrer﹦3.35×10^(-16)mol·m·m^(-2)·s^(-1)·Pa^(-1))alongside a CH_(4)/N_(2)selectivity of 4.18.These results underscore the MMM's substantial performance and its promising potential in methane enrichment applications.展开更多
In this paper, poly(amide-6-b-ethylene oxide) (Pebax1657)/SAPO-34 mixed matrix membranes (MMMs) were prepared by solvent-evaporation method with acetic acid as a novel solvent. CO2, N2, CH4 and H2 permeation pro...In this paper, poly(amide-6-b-ethylene oxide) (Pebax1657)/SAPO-34 mixed matrix membranes (MMMs) were prepared by solvent-evaporation method with acetic acid as a novel solvent. CO2, N2, CH4 and H2 permeation properties were investigated, and the physical properties of Pebax/SAPO-34 MMMs were characterized by XRD and SEM. At low SAPO-34 content, it was homogeneously distributed in the Pebax ma- trix, and then precipitated and agglomerated at high SAPO-34 content. The crystallinity of Pebax phase in Pebax/SAPO-34 MMMs decreased initially and then rebounded as a result of phase separation. With the increase of transmembrane pressure difference, CO2 permeability was en- hanced due to the effect of pressure-induced plasticization. Owing to the happening of stratification, the CO2 permeability of Pebax/SAPO-34 MMMs (50 wt% SAPO-34) increased to 338 Barrer from 111 Barrer of pristine Pebax, while the selectivities of CO2/CH4 and CO2/N2 were almost unchanged. Compared with the pristine Pebax, the gas separation performances of Pebax/SAPO-34 MMMs were remarkably enhanced.展开更多
Recent advances on mixed matrix membrane for CO<sub>2</sub> separation are reviewed in this paper. To improve CO<sub>2</sub> separation performance of polymer membranes, mixed matrix membranes ...Recent advances on mixed matrix membrane for CO<sub>2</sub> separation are reviewed in this paper. To improve CO<sub>2</sub> separation performance of polymer membranes, mixed matrix membranes (MMMs) are developed. The concept of MMM is illustrated distinctly. Suitable polymer and inorganic or organic fillers for MMMs are summarized. Possible interface morphologies between polymer and filler, and the effect of interface morphologies on gas transport properties of MMMs are summarized. The methods to improve compatibility between polymer and filler are introduced. There are eight methods including silane coupling, Grignard treatment, incorporation of additive, grafting, in situ polymerization, polydopamine coating, particle fusion approach and polymer functionalization. To achieve higher productivity for industrial application, mixed matrix composite membranes are developed. The recent development on hollow fiber and flat mixed matrix composite membrane is reviewed in detail. Last, the future trend of MMM is forecasted.展开更多
The industrial products or wastewater rich in the mixed salts(Cl-/SO4^2-) not only causes the environmental damage, but also induces waste of resource. In this study, an ED stack with monovalent selective AEMs and con...The industrial products or wastewater rich in the mixed salts(Cl-/SO4^2-) not only causes the environmental damage, but also induces waste of resource. In this study, an ED stack with monovalent selective AEMs and conventional CEMs was employed to separate the Cl-and SO42-from simulated wastewater. The effect of current density and mass fraction percentage was investigated in order to optimize the experimental conditions during ED process. It was found that at a concentration ratio between NaCl and Na2SO4 of 95/5(wt%/wt%) and a current density of40 m A·cm^-2, a current efficiency of 72%, an energy consumption of 1.6 k W·h·kg^-1 Na Cl and a Cl-/SO4^2-concentration(67.5/3.5 g·L^-1) were obtained. Hence, it is appropriate and effective to separate Cl-and SO42-by ED using the monovalent selective AEMs.展开更多
Mixed matrix hollow fiber membranes(MMHFMs)filled with metal-organic frameworks(MOFs)have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and ...Mixed matrix hollow fiber membranes(MMHFMs)filled with metal-organic frameworks(MOFs)have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem-1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53(S-MIL-53)and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO2/N2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.展开更多
A mixture of nine biphenyl nitrile compounds with high hydrophobicity and similar structures was successfully separated by microemulsion electrokinetic chromatography (MEEKC) within 30 min. The buffer system containe...A mixture of nine biphenyl nitrile compounds with high hydrophobicity and similar structures was successfully separated by microemulsion electrokinetic chromatography (MEEKC) within 30 min. The buffer system contained 100 mmol/L sodium dodecyl sulfate (SDS), 80 mmol/L sodium cholate (SC), 0.81% heptane, 7.5% n-butanol, 10% acetonitrile and 10 mmol/L borate. The addition of SC, organic modifiers, sample preparation and temperature all showed remarkable effect on the separation. Meanwhile, the MEEKC method was briefly compared with micellar electrokinetic chromatography (MEKC) method.展开更多
Speaker separation in complex acoustic environment is one of challenging tasks in speech separation.In practice,speakers are very often unmoving or moving slowly in normal communication.In this case,the spatial featur...Speaker separation in complex acoustic environment is one of challenging tasks in speech separation.In practice,speakers are very often unmoving or moving slowly in normal communication.In this case,the spatial features among the consecutive speech frames become highly correlated such that it is helpful for speaker separation by providing additional spatial information.To fully exploit this information,we design a separation system on Recurrent Neural Network(RNN)with long short-term memory(LSTM)which effectively learns the temporal dynamics of spatial features.In detail,a LSTM-based speaker separation algorithm is proposed to extract the spatial features in each time-frequency(TF)unit and form the corresponding feature vector.Then,we treat speaker separation as a supervised learning problem,where a modified ideal ratio mask(IRM)is defined as the training function during LSTM learning.Simulations show that the proposed system achieves attractive separation performance in noisy and reverberant environments.Specifically,during the untrained acoustic test with limited priors,e.g.,unmatched signal to noise ratio(SNR)and reverberation,the proposed LSTM based algorithm can still outperforms the existing DNN based method in the measures of PESQ and STOI.It indicates our method is more robust in untrained conditions.展开更多
Highly selective separation of CO_2 from its methane-containing binary gas mixture can be achieved by using Poly(ether-block-amide)(PEBAX)mixed matrix membranes(MMMs).According to FESEM and AFM analyses,silica-based n...Highly selective separation of CO_2 from its methane-containing binary gas mixture can be achieved by using Poly(ether-block-amide)(PEBAX)mixed matrix membranes(MMMs).According to FESEM and AFM analyses,silica-based nanoparticles were homogenously integrated within the polymer matrix,facilitating penetration of CO_2 through the membrane while acting as barrier for methane gas.The membrane containing 4.6 wt% fumed silica(FS)(PEBAX/4.6 wt%FS)exhibits astonishing selectivity results where binary gas mixture of CO_2/CH_4 was used as feed gas.As detected by gas chromatography,in the permeate side,data showed a significant increase of CO_2 permeance,while CH_4 transport through the mixed matrix membrane was not detectable.Moreover,PEBAX/4.6 wt%FS greatly exceeds the Robeson limit.According to data reported on CO_2/CH_4 gas pair separation in the literature,the results achieved in this work are beyond those data reported in the literature,particularly when PEBAX/4.6 wt%FS membrane was utilized.展开更多
In this paper, we applied RobustICA to speech separation and made a comprehensive comparison to FastICA according to the separation results. Through a series of speech signal separation test, RobustICA reduced the sep...In this paper, we applied RobustICA to speech separation and made a comprehensive comparison to FastICA according to the separation results. Through a series of speech signal separation test, RobustICA reduced the separation time consumed by FastICA with higher stability, and speeches separated by RobustICA were proved to having lower separation errors. In the 14 groups of speech separation tests, separation time consumed by RobustICA was 3.185 s less than FastICA by nearly 68%. Separation errors of FastICA had a float between 0.004 and 0.02, while the errors of RobustlCA remained around 0.003. Furthermore, compared to FastICA, RobustlCA showed better separation robustness. Experimental results showed that RohustICA was successful to apply to the speech signal separation, and showed superiority to FastlCA in speech separation.展开更多
Since the minimum-boiling azeotropes of C2-C8 alcohols with water and high-water content(up to 95%(mass))in the Fischer-Tropsch aqueous by-products,the separation is energy-intensive and challenging.The energy-saving ...Since the minimum-boiling azeotropes of C2-C8 alcohols with water and high-water content(up to 95%(mass))in the Fischer-Tropsch aqueous by-products,the separation is energy-intensive and challenging.The energy-saving strategy for the complete separation of the Fischer-Tropsch aqueous by-products has received massive attention in recent decades.In this study,a stripper-sidestream decanter process is proposed by exploiting homogeneous azeotropes(C2-C3 alcohols-water)and heterogeneous azeotropes(C4-C8 alcohols-water).The introduction of the stripping column for pre-dehydration avoids the revaporization of the mixture,and energy carried by the overhead vapor is conserved instead of being removed in a condenser.The precise fraction cutting of C1-C3 alcohol-water mixture,C4-C8 alcohols,and water is realized by the sidestream distillation column.The C4-C8 alcohols rich mixture withdrawn from the sidestream flows into the decanter to break the distillation boundary,where the organic phase returns to the sidestream distillation column to obtain the dehydrated C4-C8 alcohols,and the aqueous phase enters the stripping column.Steady-state optimization based on total annual cost(TAC)minimization shows that the stripper-sidestream decanter process reduces TAC by 17.00%and saves energy by 21.27%compared with the conventional three-column distillation process.Further,a control structure of the process is established,and dynamic simulations show that the control structure combining a differential controller with a low-selector exhibits robust co ntrol.This study provides a novel design scheme and deepens the insights into the efficient separation of aqueous by-products of the Fischer-Tropsch synthesis.展开更多
Traditional separation methods have limited ability to handle the speech separation problem in high reverberant and low signal-to-noise ratio(SNR)environments,and thus achieve unsatisfactory results.In this study,a co...Traditional separation methods have limited ability to handle the speech separation problem in high reverberant and low signal-to-noise ratio(SNR)environments,and thus achieve unsatisfactory results.In this study,a convolutional neural network with temporal convolution and residual network(TC-ResNet)is proposed to realize speech separation in a complex acoustic environment.A simplified steered-response power phase transform,denoted as GSRP-PHAT,is employed to reduce the computational cost.The extracted features are reshaped to a special tensor as the system inputs and implements temporal convolution,which not only enlarges the receptive field of the convolution layer but also significantly reduces the network computational cost.Residual blocks are used to combine multiresolution features and accelerate the training procedure.A modified ideal ratio mask is applied as the training target.Simulation results demonstrate that the proposed microphone array speech separation algorithm based on TC-ResNet achieves a better performance in terms of distortion ratio,source-to-interference ratio,and short-time objective intelligibility in low SNR and high reverberant environments,particularly in untrained situations.This indicates that the proposed method has generalization to untrained conditions.展开更多
Deep Attractor Network(DANet) is the state-of-the-art technique in speech separation field, which uses Bidirectional Long Short-Term Memory(BLSTM), but the complexity of the DANet model is very high. In this paper, a ...Deep Attractor Network(DANet) is the state-of-the-art technique in speech separation field, which uses Bidirectional Long Short-Term Memory(BLSTM), but the complexity of the DANet model is very high. In this paper, a simplified and powerful DANet model is proposed using Bidirectional Gated neural network(BGRU) instead of BLSTM. The Gaussian Mixture Model(GMM) other than the k-means was applied in DANet as a clustering algorithm to reduce the complexity and increase the learning speed and accuracy. The metrics used in this paper are Signal to Distortion Ratio(SDR), Signal to Interference Ratio(SIR), Signal to Artifact Ratio(SAR), and Perceptual Evaluation Speech Quality(PESQ) score. Two speaker mixture datasets from TIMIT corpus were prepared to evaluate the proposed model, and the system achieved 12.3 dB and 2.94 for SDR and PESQ scores respectively, which were better than the original DANet model. Other improvements were 20.7% and 17.9% in the number of parameters and time training respectively. The model was applied on mixed Arabic speech signals and the results were better than that in English.展开更多
Speech separation is an active research topic that plays an important role in numerous applications,such as speaker recognition,hearing pros-thesis,and autonomous robots.Many algorithms have been put forward to improv...Speech separation is an active research topic that plays an important role in numerous applications,such as speaker recognition,hearing pros-thesis,and autonomous robots.Many algorithms have been put forward to improve separation performance.However,speech separation in reverberant noisy environment is still a challenging task.To address this,a novel speech separation algorithm using gate recurrent unit(GRU)network based on microphone array has been proposed in this paper.The main aim of the proposed algorithm is to improve the separation performance and reduce the computational cost.The proposed algorithm extracts the sub-band steered response power-phase transform(SRP-PHAT)weighted by gammatone filter as the speech separation feature due to its discriminative and robust spatial position in formation.Since the GRU net work has the advantage of processing time series data with faster training speed and fewer training parameters,the GRU model is adopted to process the separation featuresof several sequential frames in the same sub-band to estimate the ideal Ratio Masking(IRM).The proposed algorithm decomposes the mixture signals into time-frequency(TF)units using gammatone filter bank in the frequency domain,and the target speech is reconstructed in the frequency domain by masking the mixture signal according to the estimated IRM.The operations of decomposing the mixture signal and reconstructing the target signal are completed in the frequency domain which can reduce the total computational cost.Experimental results demonstrate that the proposed algorithm realizes omnidirectional speech sep-aration in noisy and reverberant environments,provides good performance in terms of speech quality and intelligibility,and has the generalization capacity to reverberate.展开更多
In the design of hearing aids(HA),the real-time speech-enhancement is done.The digital hearing aids should provide high signal-to-noise ratio,gain improvement and should eliminate feedback.In generic hearing aids the ...In the design of hearing aids(HA),the real-time speech-enhancement is done.The digital hearing aids should provide high signal-to-noise ratio,gain improvement and should eliminate feedback.In generic hearing aids the perfor-mance towards different frequencies varies and non uniform.Existing noise can-cellation and speech separation methods drops the voice magnitude under the noise environment.The performance of the HA for frequency response is non uni-form.Existing noise suppression methods reduce the required signal strength also.So,the performance of uniform sub band analysis is poor when hearing aid is con-cern.In this paper,a speech separation method using Non-negative Matrix Fac-torization(NMF)algorithm is proposed for wavelet decomposition.The Proposed non-uniformfilter-bank was validated by parameters like band power,Signal-to-noise ratio(SNR),Mean Square Error(MSE),Signal to Noise and Dis-tortion Ratio(SINAD),Spurious-free dynamic range(SFDR),error and time.The speech recordings before and after separation was evaluated for quality using objective speech quality measures International Telecommunication Union-Telecommunication standard ITU-T P.862.展开更多
This research investigates the permeability of CO2 and N2 as well as selectivity of CO2 over N2 of polysulfone (PSF) mixed matrix membranes filled with zeolite 4Å particles. The membranes were prepared by sol...This research investigates the permeability of CO2 and N2 as well as selectivity of CO2 over N2 of polysulfone (PSF) mixed matrix membranes filled with zeolite 4Å particles. The membranes were prepared by solution-casting method and utilized to determine the permeation rates of N2 and CO2. It was characterized by FTIR and the gas separation performance was analysed by Design of Expert (DOE) method. FTIR result revealed the intensity of peak for sulfone S=O vibration at 1322 cm-1;it was related to O=S=O bound of polysulfone in the sample. The single concentration variable has low outcome, however the mixture concentration interaction was effectively to lead better selectivity of CO2 over N2. In terms of interaction between mixture concentrations, interaction between PSF and N-Methyl-2-pyrrolidone (NMP) has considerable effect on the permeability of CO2 with the highest F value of 0.46 membrane. NMP exhibited a high degree of polarity and hydrogen bonding which led to effect of selective skin and permeation rate. The model regression equations were developed as the potential use for screening the permeability of CO2 and N2 based on the deviation effect of polymer concentration.展开更多
Speech recognition rate will deteriorate greatly in human-machine interaction when the speaker's speech mixes with a bystander's voice. This paper proposes a time-frequency approach for Blind Source Seperation...Speech recognition rate will deteriorate greatly in human-machine interaction when the speaker's speech mixes with a bystander's voice. This paper proposes a time-frequency approach for Blind Source Seperation (BSS) for intelligent Human-Machine Interaction(HMI). Main idea of the algorithm is to simultaneously diagonalize the correlation matrix of the pre-whitened signals at different time delays for every frequency bins in time-frequency domain. The prososed method has two merits: (1) fast convergence speed; (2) high signal to interference ratio of the separated signals. Numerical evaluations are used to compare the performance of the proposed algorithm with two other deconvolution algorithms. An efficient algorithm to resolve permutation ambiguity is also proposed in this paper. The algorithm proposed saves more than 10% of computational time with properly selected parameters and achieves good performances for both simulated convolutive mixtures and real room recorded speeches.展开更多
Tarnavas established mixed weighted power mean inequality in 1999. A separation of weighted power mean inequslity was derived in this paper. As its applications, some separations of other inequalities were given.
The electromagnetic separation method is a new approach to treat ship-based marine oily wastewater,in which oil droplets are dispersed in seawater(oil-seawater mixed flow).In order to clarify the separation process an...The electromagnetic separation method is a new approach to treat ship-based marine oily wastewater,in which oil droplets are dispersed in seawater(oil-seawater mixed flow).In order to clarify the separation process and determine the separation characteristics,the flow field and volume fraction of the oil droplets of the oil-seawater mixed flow under an applied electromagnetic field with different operating conditions were investigated by 2D numerical simulations with the Eulerian model.The results show that:(1)the downward Lorentz force causes seawater to flow downwards and the oil droplets to move upwards due to the electromagnetic separation force in the effective section of the separation channel;(2)the volume fraction of the oil droplets at the top of the outlet section increases with the current density,magnetic field,and the diameter of the oil droplet and decreases with the inlet velocity of the oily seawater.The results provide useful guidance for the design of electromagnetic separation devices of the oil-seawater mixed flow.展开更多
To enhance the performance of the polyphenylene sulfone(PPSU) membrane,a novel mixed matrix membrane with hydrophilicity and antifouling properties was prepared.Using PPSU as the ba sic membrane material,polyvinyl pyr...To enhance the performance of the polyphenylene sulfone(PPSU) membrane,a novel mixed matrix membrane with hydrophilicity and antifouling properties was prepared.Using PPSU as the ba sic membrane material,polyvinyl pyrrolidone(PVP) as the porogen,N-Methyl pyrrolidone(NMP) as the solvent,and MOF-CAU-1(Al_(4)(OH)_(2)(OCH_(3))_4(H_2 N-BDC)_(3)·xH_(2) O) as the filler,PPSU/CAU-1 mixed matrix membrane(MMM) was prepared by an immersion precipitation and phase transformation technique.By changing the amount of MOF-CAU-1,the properties and performance of the MMM membrane were investigated in terms of hydrophilicity,pore morphology,surface roughness,and dye removal.The results show that the highest pure water flux of the mixed reached 47.9 L·m^(-2)·h^(-1), when the CAU-1 addition amount was 1.0 wt%, which was 23% higher than that of the pure PPSU membrane.Both the rejection rate and the antifouling performance of the MMM membrane also noticeably improved.展开更多
基金support from Sichuan Science and Technology Program(2021YFH0116)National Natural Science Foundation of China(No.52170112)DongFang Boiler Co.,Ltd.(3522015).
文摘Mixed matrix membranes(MMMs)could combine the advantages of both polymeric membranes and porousfillers,making them an effective alternative to conventional polymer membranes.However,interfacial incompatibility issues,such as the presence of interfacial voids,hardening of polymer chains,and blockage of micropores by polymers between common MMMsfillers and the polymer matrix,currently limit the gas sep-aration performance of MMMs.Ternary phase MMMs(consisting of afiller,an additive,and a matrix)made by adding a third compound,usually functionalized additives,can overcome the structural problems of binary phase MMMs and positively impact membrane separation performance.This review introduces the structure and fabrication processes for ternary MMMs,categorizes various nanofillers and the third component,and summarizes and analyzes in detail the CO_(2) separation performance of newly developed ternary MMMs based on both rubbery and glassy polymers.Based on this separation data,the challenges of ternary MMMs are also discussed.Finally,future directions for ternary MMMs are proposed.
基金financial support from the National Natural Science Foundation of China(52174229 and 52174230)the Natural Science Foundation of Liaoning Province(2022-KF-13-05)+1 种基金Fushun Revitalization Talents Program(FSYC202107010)the program funded by Liaoning Province Education Administration(LJKZ0411).
文摘Efficiently enriching low-concentration CH4 is pivotal for enhancing the utilization of unconventional energy sources and mitigating greenhouse gas emissions.This study focuses on modifying the overall performance of CH_(4)/N_(2)separation membranes.A novel mixed matrix membrane(MMM)with a reinforced substrate structure was developed through a straightforward dip-coating technique.This MMM incorporates a polytetrafluoroethylene(PTFE)porous membrane as the supporting framework,while a composite of block polymer(styrene-butadiene-styrene)and metal-organic framework(Ni-MOF-74)forms the selective separation layer.Comprehensive characterization of Ni-MOF-74 and the fabricatedmembranes was conducted using X-rays diffraction,scanning electron microscope,Brunauer-Emmett-Teller analysis,and gas permeance tests.The findings indicate a robust integration of the PTFE porous support with the membrane layer,enhancing the mechanical stability of theMMM.Under optimal conditions,the mechanical strength of the PM20 membrane(containing 20%Ni-MOF-74)was observed to be 37.7 MPa,representing remarkable increase compared to the non-reinforcedMMM.Additionally,thePM20membrane exhibited an impressive CH4 permeation rate of 92 barrer(1 barrer﹦3.35×10^(-16)mol·m·m^(-2)·s^(-1)·Pa^(-1))alongside a CH_(4)/N_(2)selectivity of 4.18.These results underscore the MMM's substantial performance and its promising potential in methane enrichment applications.
基金supported by the National Science and Technology Planning Project(No.2011BAC08B00)the National High Technology Research and Development Program of China(863 Program)(No.2012AA03A611)
文摘In this paper, poly(amide-6-b-ethylene oxide) (Pebax1657)/SAPO-34 mixed matrix membranes (MMMs) were prepared by solvent-evaporation method with acetic acid as a novel solvent. CO2, N2, CH4 and H2 permeation properties were investigated, and the physical properties of Pebax/SAPO-34 MMMs were characterized by XRD and SEM. At low SAPO-34 content, it was homogeneously distributed in the Pebax ma- trix, and then precipitated and agglomerated at high SAPO-34 content. The crystallinity of Pebax phase in Pebax/SAPO-34 MMMs decreased initially and then rebounded as a result of phase separation. With the increase of transmembrane pressure difference, CO2 permeability was en- hanced due to the effect of pressure-induced plasticization. Owing to the happening of stratification, the CO2 permeability of Pebax/SAPO-34 MMMs (50 wt% SAPO-34) increased to 338 Barrer from 111 Barrer of pristine Pebax, while the selectivities of CO2/CH4 and CO2/N2 were almost unchanged. Compared with the pristine Pebax, the gas separation performances of Pebax/SAPO-34 MMMs were remarkably enhanced.
基金Supported by the National Natural Science Foundation of China(21436009)the Program of Introducing Talents of Discipline to Universities(B06006)
文摘Recent advances on mixed matrix membrane for CO<sub>2</sub> separation are reviewed in this paper. To improve CO<sub>2</sub> separation performance of polymer membranes, mixed matrix membranes (MMMs) are developed. The concept of MMM is illustrated distinctly. Suitable polymer and inorganic or organic fillers for MMMs are summarized. Possible interface morphologies between polymer and filler, and the effect of interface morphologies on gas transport properties of MMMs are summarized. The methods to improve compatibility between polymer and filler are introduced. There are eight methods including silane coupling, Grignard treatment, incorporation of additive, grafting, in situ polymerization, polydopamine coating, particle fusion approach and polymer functionalization. To achieve higher productivity for industrial application, mixed matrix composite membranes are developed. The recent development on hollow fiber and flat mixed matrix composite membrane is reviewed in detail. Last, the future trend of MMM is forecasted.
基金Supported by the National Key Research and Development Plan(Nos.2017YFC0403700 and 2017YFD0400604)
文摘The industrial products or wastewater rich in the mixed salts(Cl-/SO4^2-) not only causes the environmental damage, but also induces waste of resource. In this study, an ED stack with monovalent selective AEMs and conventional CEMs was employed to separate the Cl-and SO42-from simulated wastewater. The effect of current density and mass fraction percentage was investigated in order to optimize the experimental conditions during ED process. It was found that at a concentration ratio between NaCl and Na2SO4 of 95/5(wt%/wt%) and a current density of40 m A·cm^-2, a current efficiency of 72%, an energy consumption of 1.6 k W·h·kg^-1 Na Cl and a Cl-/SO4^2-concentration(67.5/3.5 g·L^-1) were obtained. Hence, it is appropriate and effective to separate Cl-and SO42-by ED using the monovalent selective AEMs.
基金the financial support from the National Natural Science Foundation of China(No.21436009)
文摘Mixed matrix hollow fiber membranes(MMHFMs)filled with metal-organic frameworks(MOFs)have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem-1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53(S-MIL-53)and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO2/N2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.
文摘A mixture of nine biphenyl nitrile compounds with high hydrophobicity and similar structures was successfully separated by microemulsion electrokinetic chromatography (MEEKC) within 30 min. The buffer system contained 100 mmol/L sodium dodecyl sulfate (SDS), 80 mmol/L sodium cholate (SC), 0.81% heptane, 7.5% n-butanol, 10% acetonitrile and 10 mmol/L borate. The addition of SC, organic modifiers, sample preparation and temperature all showed remarkable effect on the separation. Meanwhile, the MEEKC method was briefly compared with micellar electrokinetic chromatography (MEKC) method.
基金This work is supported by the National Nature Science Foundation of China(NSFC)under Grant Nos.61571106,61501169,41706103the Fundamental Research Funds for the Central Universities under Grant No.2242013K30010.
文摘Speaker separation in complex acoustic environment is one of challenging tasks in speech separation.In practice,speakers are very often unmoving or moving slowly in normal communication.In this case,the spatial features among the consecutive speech frames become highly correlated such that it is helpful for speaker separation by providing additional spatial information.To fully exploit this information,we design a separation system on Recurrent Neural Network(RNN)with long short-term memory(LSTM)which effectively learns the temporal dynamics of spatial features.In detail,a LSTM-based speaker separation algorithm is proposed to extract the spatial features in each time-frequency(TF)unit and form the corresponding feature vector.Then,we treat speaker separation as a supervised learning problem,where a modified ideal ratio mask(IRM)is defined as the training function during LSTM learning.Simulations show that the proposed system achieves attractive separation performance in noisy and reverberant environments.Specifically,during the untrained acoustic test with limited priors,e.g.,unmatched signal to noise ratio(SNR)and reverberation,the proposed LSTM based algorithm can still outperforms the existing DNN based method in the measures of PESQ and STOI.It indicates our method is more robust in untrained conditions.
基金financial support of Research Institute of Petroleum Industry
文摘Highly selective separation of CO_2 from its methane-containing binary gas mixture can be achieved by using Poly(ether-block-amide)(PEBAX)mixed matrix membranes(MMMs).According to FESEM and AFM analyses,silica-based nanoparticles were homogenously integrated within the polymer matrix,facilitating penetration of CO_2 through the membrane while acting as barrier for methane gas.The membrane containing 4.6 wt% fumed silica(FS)(PEBAX/4.6 wt%FS)exhibits astonishing selectivity results where binary gas mixture of CO_2/CH_4 was used as feed gas.As detected by gas chromatography,in the permeate side,data showed a significant increase of CO_2 permeance,while CH_4 transport through the mixed matrix membrane was not detectable.Moreover,PEBAX/4.6 wt%FS greatly exceeds the Robeson limit.According to data reported on CO_2/CH_4 gas pair separation in the literature,the results achieved in this work are beyond those data reported in the literature,particularly when PEBAX/4.6 wt%FS membrane was utilized.
基金National Natural Science Foundation of Chinagrant number:61271082,61201029,61102094
文摘In this paper, we applied RobustICA to speech separation and made a comprehensive comparison to FastICA according to the separation results. Through a series of speech signal separation test, RobustICA reduced the separation time consumed by FastICA with higher stability, and speeches separated by RobustICA were proved to having lower separation errors. In the 14 groups of speech separation tests, separation time consumed by RobustICA was 3.185 s less than FastICA by nearly 68%. Separation errors of FastICA had a float between 0.004 and 0.02, while the errors of RobustlCA remained around 0.003. Furthermore, compared to FastICA, RobustlCA showed better separation robustness. Experimental results showed that RohustICA was successful to apply to the speech signal separation, and showed superiority to FastlCA in speech separation.
文摘Since the minimum-boiling azeotropes of C2-C8 alcohols with water and high-water content(up to 95%(mass))in the Fischer-Tropsch aqueous by-products,the separation is energy-intensive and challenging.The energy-saving strategy for the complete separation of the Fischer-Tropsch aqueous by-products has received massive attention in recent decades.In this study,a stripper-sidestream decanter process is proposed by exploiting homogeneous azeotropes(C2-C3 alcohols-water)and heterogeneous azeotropes(C4-C8 alcohols-water).The introduction of the stripping column for pre-dehydration avoids the revaporization of the mixture,and energy carried by the overhead vapor is conserved instead of being removed in a condenser.The precise fraction cutting of C1-C3 alcohol-water mixture,C4-C8 alcohols,and water is realized by the sidestream distillation column.The C4-C8 alcohols rich mixture withdrawn from the sidestream flows into the decanter to break the distillation boundary,where the organic phase returns to the sidestream distillation column to obtain the dehydrated C4-C8 alcohols,and the aqueous phase enters the stripping column.Steady-state optimization based on total annual cost(TAC)minimization shows that the stripper-sidestream decanter process reduces TAC by 17.00%and saves energy by 21.27%compared with the conventional three-column distillation process.Further,a control structure of the process is established,and dynamic simulations show that the control structure combining a differential controller with a low-selector exhibits robust co ntrol.This study provides a novel design scheme and deepens the insights into the efficient separation of aqueous by-products of the Fischer-Tropsch synthesis.
基金This work is supported by the National Key Research and Development Program of China under Grant 2020YFC2004003 and Grant 2020YFC2004002the National Nature Science Foundation of China(NSFC)under Grant No.61571106.
文摘Traditional separation methods have limited ability to handle the speech separation problem in high reverberant and low signal-to-noise ratio(SNR)environments,and thus achieve unsatisfactory results.In this study,a convolutional neural network with temporal convolution and residual network(TC-ResNet)is proposed to realize speech separation in a complex acoustic environment.A simplified steered-response power phase transform,denoted as GSRP-PHAT,is employed to reduce the computational cost.The extracted features are reshaped to a special tensor as the system inputs and implements temporal convolution,which not only enlarges the receptive field of the convolution layer but also significantly reduces the network computational cost.Residual blocks are used to combine multiresolution features and accelerate the training procedure.A modified ideal ratio mask is applied as the training target.Simulation results demonstrate that the proposed microphone array speech separation algorithm based on TC-ResNet achieves a better performance in terms of distortion ratio,source-to-interference ratio,and short-time objective intelligibility in low SNR and high reverberant environments,particularly in untrained situations.This indicates that the proposed method has generalization to untrained conditions.
文摘Deep Attractor Network(DANet) is the state-of-the-art technique in speech separation field, which uses Bidirectional Long Short-Term Memory(BLSTM), but the complexity of the DANet model is very high. In this paper, a simplified and powerful DANet model is proposed using Bidirectional Gated neural network(BGRU) instead of BLSTM. The Gaussian Mixture Model(GMM) other than the k-means was applied in DANet as a clustering algorithm to reduce the complexity and increase the learning speed and accuracy. The metrics used in this paper are Signal to Distortion Ratio(SDR), Signal to Interference Ratio(SIR), Signal to Artifact Ratio(SAR), and Perceptual Evaluation Speech Quality(PESQ) score. Two speaker mixture datasets from TIMIT corpus were prepared to evaluate the proposed model, and the system achieved 12.3 dB and 2.94 for SDR and PESQ scores respectively, which were better than the original DANet model. Other improvements were 20.7% and 17.9% in the number of parameters and time training respectively. The model was applied on mixed Arabic speech signals and the results were better than that in English.
基金This work is supported by Nanjing Institute of Technology(NIT)fund for Research Startup Projects of Introduced talents under Grant No.YKJ202019Nature Sci-ence Research Project of Higher Education Institutions in Jiangsu Province under Grant No.21KJB510018+1 种基金National Nature Science Foundation of China(NSFC)under Grant No.62001215NIT fund for Doctoral Research Projects under Grant No.ZKJ2020003.
文摘Speech separation is an active research topic that plays an important role in numerous applications,such as speaker recognition,hearing pros-thesis,and autonomous robots.Many algorithms have been put forward to improve separation performance.However,speech separation in reverberant noisy environment is still a challenging task.To address this,a novel speech separation algorithm using gate recurrent unit(GRU)network based on microphone array has been proposed in this paper.The main aim of the proposed algorithm is to improve the separation performance and reduce the computational cost.The proposed algorithm extracts the sub-band steered response power-phase transform(SRP-PHAT)weighted by gammatone filter as the speech separation feature due to its discriminative and robust spatial position in formation.Since the GRU net work has the advantage of processing time series data with faster training speed and fewer training parameters,the GRU model is adopted to process the separation featuresof several sequential frames in the same sub-band to estimate the ideal Ratio Masking(IRM).The proposed algorithm decomposes the mixture signals into time-frequency(TF)units using gammatone filter bank in the frequency domain,and the target speech is reconstructed in the frequency domain by masking the mixture signal according to the estimated IRM.The operations of decomposing the mixture signal and reconstructing the target signal are completed in the frequency domain which can reduce the total computational cost.Experimental results demonstrate that the proposed algorithm realizes omnidirectional speech sep-aration in noisy and reverberant environments,provides good performance in terms of speech quality and intelligibility,and has the generalization capacity to reverberate.
文摘In the design of hearing aids(HA),the real-time speech-enhancement is done.The digital hearing aids should provide high signal-to-noise ratio,gain improvement and should eliminate feedback.In generic hearing aids the perfor-mance towards different frequencies varies and non uniform.Existing noise can-cellation and speech separation methods drops the voice magnitude under the noise environment.The performance of the HA for frequency response is non uni-form.Existing noise suppression methods reduce the required signal strength also.So,the performance of uniform sub band analysis is poor when hearing aid is con-cern.In this paper,a speech separation method using Non-negative Matrix Fac-torization(NMF)algorithm is proposed for wavelet decomposition.The Proposed non-uniformfilter-bank was validated by parameters like band power,Signal-to-noise ratio(SNR),Mean Square Error(MSE),Signal to Noise and Dis-tortion Ratio(SINAD),Spurious-free dynamic range(SFDR),error and time.The speech recordings before and after separation was evaluated for quality using objective speech quality measures International Telecommunication Union-Telecommunication standard ITU-T P.862.
文摘This research investigates the permeability of CO2 and N2 as well as selectivity of CO2 over N2 of polysulfone (PSF) mixed matrix membranes filled with zeolite 4Å particles. The membranes were prepared by solution-casting method and utilized to determine the permeation rates of N2 and CO2. It was characterized by FTIR and the gas separation performance was analysed by Design of Expert (DOE) method. FTIR result revealed the intensity of peak for sulfone S=O vibration at 1322 cm-1;it was related to O=S=O bound of polysulfone in the sample. The single concentration variable has low outcome, however the mixture concentration interaction was effectively to lead better selectivity of CO2 over N2. In terms of interaction between mixture concentrations, interaction between PSF and N-Methyl-2-pyrrolidone (NMP) has considerable effect on the permeability of CO2 with the highest F value of 0.46 membrane. NMP exhibited a high degree of polarity and hydrogen bonding which led to effect of selective skin and permeation rate. The model regression equations were developed as the potential use for screening the permeability of CO2 and N2 based on the deviation effect of polymer concentration.
文摘Speech recognition rate will deteriorate greatly in human-machine interaction when the speaker's speech mixes with a bystander's voice. This paper proposes a time-frequency approach for Blind Source Seperation (BSS) for intelligent Human-Machine Interaction(HMI). Main idea of the algorithm is to simultaneously diagonalize the correlation matrix of the pre-whitened signals at different time delays for every frequency bins in time-frequency domain. The prososed method has two merits: (1) fast convergence speed; (2) high signal to interference ratio of the separated signals. Numerical evaluations are used to compare the performance of the proposed algorithm with two other deconvolution algorithms. An efficient algorithm to resolve permutation ambiguity is also proposed in this paper. The algorithm proposed saves more than 10% of computational time with properly selected parameters and achieves good performances for both simulated convolutive mixtures and real room recorded speeches.
基金Project supported by National Natural Science Foundation of China (Grant No. 10271071)
文摘Tarnavas established mixed weighted power mean inequality in 1999. A separation of weighted power mean inequslity was derived in this paper. As its applications, some separations of other inequalities were given.
基金The Tianjin Science and Technology Plan Project under contract No.15YFYSGX00010the Tianjin Bureau of Marine Science and Technology Plan Project under contract No.KJXH2015-05
文摘The electromagnetic separation method is a new approach to treat ship-based marine oily wastewater,in which oil droplets are dispersed in seawater(oil-seawater mixed flow).In order to clarify the separation process and determine the separation characteristics,the flow field and volume fraction of the oil droplets of the oil-seawater mixed flow under an applied electromagnetic field with different operating conditions were investigated by 2D numerical simulations with the Eulerian model.The results show that:(1)the downward Lorentz force causes seawater to flow downwards and the oil droplets to move upwards due to the electromagnetic separation force in the effective section of the separation channel;(2)the volume fraction of the oil droplets at the top of the outlet section increases with the current density,magnetic field,and the diameter of the oil droplet and decreases with the inlet velocity of the oily seawater.The results provide useful guidance for the design of electromagnetic separation devices of the oil-seawater mixed flow.
基金supported by Key Research and Development of Tangshan (19140204F)。
文摘To enhance the performance of the polyphenylene sulfone(PPSU) membrane,a novel mixed matrix membrane with hydrophilicity and antifouling properties was prepared.Using PPSU as the ba sic membrane material,polyvinyl pyrrolidone(PVP) as the porogen,N-Methyl pyrrolidone(NMP) as the solvent,and MOF-CAU-1(Al_(4)(OH)_(2)(OCH_(3))_4(H_2 N-BDC)_(3)·xH_(2) O) as the filler,PPSU/CAU-1 mixed matrix membrane(MMM) was prepared by an immersion precipitation and phase transformation technique.By changing the amount of MOF-CAU-1,the properties and performance of the MMM membrane were investigated in terms of hydrophilicity,pore morphology,surface roughness,and dye removal.The results show that the highest pure water flux of the mixed reached 47.9 L·m^(-2)·h^(-1), when the CAU-1 addition amount was 1.0 wt%, which was 23% higher than that of the pure PPSU membrane.Both the rejection rate and the antifouling performance of the MMM membrane also noticeably improved.