Study on co-cracking performance of different hydrocarbon mixture in a steam pyrolysis furnace

Co-cracking is a process where the mixtures of different hydrocarbon feedstocks are cracked in a steam pyrolysis furnace, and widely adopted in chemical industries. In this work, the simulations of the co-cracking of ethane and propane, and LPG and naphtha mixtures have been conducted, and the software packages of COILSIM1 D and Sim CO are used to account for the cracking process in a tube reactor. The effects of the mixing ratio, coil outlet temperature, and pressure on cracking performance have been discussed in detail. The co-cracking of ethane and propane mixture leads to a lower profitability than the cracking of single ethane or single propane. For naphtha, cracking with LPG leads to a higher profitability than single cracking of naphtha, and more LPG can produce a higher profitability.

Addressing the permanent deformation behavior of hot mix asphalt by triaxial cyclic compression testing with cyclic confining pressure

Rutting or permanent deformation is one of the major distress modes of hot mix asphalt in the field. Triaxial cycle compression testing （TCCT） is a standardized and scientifically accepted test method to address this distress mode in the lab and to characterize the resistance to permanent deformation. In most labs and according to EN 12697-25, standard TGCTs are carried out with cyclic axial loading and a constant confining pressure. In road pavements on the other hand, dynamic traffic loading due to passing wheels leads to cyclic confining pressure. In order to bring the TCCT closer to reality, the radial reaction and its phase lag to axial loading in standard TCCTs are analyzed and an enhanced TCCT with cyclic confining pressure is introduced. The cyclic confining pressure takes into account the viscoelastic material response by the radial phase lag to axial phase loading. In a subsequent test program, TCCTs with different confining pressure amplitudes were carried out on two hot mix asphalts. Results from standard and enhanced TCCTs were analyzed, compared and discussed. It is shown that the resistance to permanent deformation in- creases significantly when the viscoelastic material response is taken into account in the TCCT by introducing cyclic confining pressure.

The gelation rule of the polyol acetal derivatives in binary solvent mixtures

The gelation properties of polyol acetal derivatives including 2,4-（3,4-dichlorobenzylidene）-D-sorbitol（DCBS）, 1,3：2,4-di（3,4-dichlorobenzylidene）-D-sorbitol（DDCBS） and 1,3：2,5：4,6-tris（3,4-dichlorobenzylidene）-D-mannitol（TDCBM） in 35 single solvents and 39 binary solvent mixtures have been studied. FTIR and XRD results suggest that the self-assembly patterns of the gelator will not change in either the single solvent component or the corresponding solvent mixtures, but the critical gelation concentration（CGC）will be influenced. The results of SEM and rheology showed that the formation of true gels at saturated concentrations. Improving the heating temperature may promote the dissolving of gelators which are even insoluble at the temperature of the solvent boiling point and change the gelation behaviors. FloryHuggins parameter（x） was used to predict the gelation behavior of DCBS in the mixed solvents, and it is shown that the x values for the mixed solvents that can be gelled by DCBS are either greater or smaller than those for the selected good solvents.